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Palladacycles in catalysis – a critical survey

https://doi.org/10.1016/j.jorganchem.2004.07.054
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Highly active, stable, catalysts for the Heck reaction; further suggestions on the mechanism
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Highly Efficient Phosphapalladacyclic Catalysts for the Hydroarylation of Norbornene
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New highly active chiral phosphapalladacycle catalysts. First isolation and characterization of a Pd(iv) intermediate
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A simple direct synthesis of an alkylaromatic palladacycle
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Palladacycle formation by electrophilic aromatic substitution, as monitored by 1H NMR spectroscopy
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Palladium-catalyzed sequential reactions: a new termination step leading to spirocyclohexadienone formation from p-iodophenol and bicyclo[2.2.1]heptene
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Aromatic arylation via palladacycles: interception of reaction intermediates
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A new catalytic method for the synthesis of selectively substituted biphenyls containing an oxoalkyl chain
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Symmetrical and unsymmetrical 2,6-dialkyl-1,1′-biaryls by combined catalysis of aromatic alkylation via palladacycles and Suzuki-type coupling
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A New Convergent Approach to Biphenomycin Antibiotics
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Palladium-catalyzed coupling of functionalized bromoarenes to a polystyrene-bound aryl tributylstannane
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Palladium-Catalyzed (Ullmann-Type) Homocoupling of Aryl Halides:  A Convenient and General Synthesis of Symmetrical Biaryls via Inter- and Intramolecular Coupling Reactions
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Phosphites as Ligands for Efficient Catalysis of Heck Reactions
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Orthopalladated triarylphosphite complexes as highly efficient catalysts in the Heck reaction
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Orthopalladated triaryl phosphite complexes as highly active catalysts in biaryl coupling reactions
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Orthopalladated and ‐platinated Bulky Triarylphosphite Complexes: Synthesis, Reactivity and Application as High‐Activity Catalysts for Suzuki and Stille Coupling Reactions
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Highly Active Palladium Catalysts for Suzuki Coupling Reactions
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Palladacyclic phosphinite complexes as extremely high activity catalysts in the Suzuki reaction
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Enhancement of catalytic activity through orthometalation. Synthesis, structure, and catalytic activity of a new orthometalated ruthenium complex
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Highly active PdII cyclometallated imine catalysts for the Heck reaction
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Comprehensive Kinetic Screening of Catalysts Using Reaction Calorimetry
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Thermomorphic fluorous imine and thioether palladacycles as precursors for highly active Heck and Suzuki catalysts; evidence for palladium nanoparticle pathways
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Observation of Unusual Kinetics in Heck Reactions of Aryl Halides:  The Role of Non-Steady-State Catalyst Concentration
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Cyclopalladated imine catalysts in Heck arylation: search for the catalytic species
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Cyclopalladated ferrocenylimines: highly active catalysts for Heck reactions
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Highly Active Thermomorphic Fluorous Palladacycle Catalyst Precursors for the Heck Reaction; Evidence for a Palladium Nanoparticle Pathway
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Highly active PdII cyclometallated imine catalyst for the Suzuki reaction
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Aryl–Pd covalently bonded palladacycles, novel amino and oxime catalysts {di-μ-chlorobis(benzaldehydeoxime-6-C,N)dipalladium(II), di-μ-chlorobis(dimethylbenzylamine-6-C,N)dipalladium(II)} for the Heck reaction
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Oxime Palladacycles:  Stable and Efficient Catalysts for Carbon−Carbon Coupling Reactions
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Acetylferrocenyloxime palladacycle-catalyzed Heck reactions
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Oxime-Derived Palladium Complexes as Very Efficient Catalysts for the Heck–Mizoroki Reaction
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Highly Active Oxime-Derived Palladacycle Complexes for Suzuki−Miyaura and Ullmann-Type Coupling Reactions
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A Convenient Oxime-Carbapalladacycle-Catalyzed Suzuki Cross-Coupling of Aryl Chlorides in Water
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Cross-coupling reactions with boronic acids in water catalysed by oxime-derived palladacycles
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An oxime–carbapalladacycle complex covalently anchored to silica as an active and reusable heterogeneous catalyst for Suzuki cross-coupling in water
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Oxime Carbapalladacycle Covalently Anchored to High Surface Area Inorganic Supports or Polymers as Heterogeneous Green Catalysts for the Suzuki Reaction in Water
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Cyclopalladated complexes of tertiary arylamines as highly efficient catalysts using in the Heck reactions
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Organopalladium (II) Complexes Containing Carbon-bonded Pyridine and Picoline as a Ligand: Preparation, Structures, and Reactions
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Sulfilimine palladacycles: stable and efficient catalysts for carbon–carbon coupling reactions
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Sulfur-Containing Palladacycles:  Efficient Phosphine-Free Catalyst Precursors for the Suzuki Cross-Coupling Reaction at Room Temperature
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PdCl2(SEt2)2 and Pd(OAc)2: simple and efficient catalyst precursors for the Suzuki cross-coupling reaction
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Synthesis and Catalytic Properties of Configurationally Stable and Non-racemic Sulfur-Containing Palladacycles
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Platinum Group Organometallics Based on “Pincer” Complexes: Sensors, Switches, and Catalysts
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The first synthesis of stable palladium(II) PCP-type catalysts supported on silica—application to the Heck reaction
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The synthesis of a new palladacycle catalyst. Development of a high performance catalyst for Heck reactions
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Synthesis of Novel Pd−NCN Pincer Complexes Having Additional Nitrogen Coordination Sites and Their Application as Catalysts for the Heck Reaction
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1,2,4-Triazole-Based Palladium Pincer Complexes. A New Type of Catalyst for the Heck Reaction
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A New Generation of Air Stable, Highly Active Pd Complexes for CC and CN Coupling Reactions with Aryl Chlorides
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Highly active catalysts for the Suzuki coupling of aryl chlorides
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A Defined N-Heterocyclic Carbene Complex for the Palladium-Catalyzed Suzuki Cross-Coupling of Aryl Chlorides at Ambient Temperatures
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Suzuki–Miyaura coupling with high turnover number using an N-acyl-N-heterocyclic carbene palladacycle precursor
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High Enantioselection in the Rearrangement of Allylic Imidates with Ferrocenyl Oxazoline Catalysts
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Preparation of bis[palladacycles] and application to asymmetric aza-Claisen rearrangement of allylic imidates
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Catalytic Asymmetric Rearrangement of Allylic Trichloroacetimidates. A Practical Method for Preparing Allylic Amines and Congeners of High Enantiomeric Purity
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Catalytic Asymmetric Rearrangement of Allylic <i>N</i>-Aryl Trifluoroacetimidates. A Useful Method for Transforming Prochiral Allylic Alcohols to Chiral Allylic Amines
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<i>para</i>‐Functionalized NCN‐Pincer Palladium(<scp>II</scp>) Complexes: Synthesis, Catalysis and DFT Calculations
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Development of Chiral Pincer Palladium Complexes Bearing a Pyrroloimidazolone Unit. Catalytic Use for Asymmetric Michael Addition
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Application of a Homogeneous Dodecakis(NCN‐Pd<sup>II</sup>) Catalyst in a Nanofiltration Membrane Reactor under Continuous Reaction Conditions
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Design and Performance of Rigid Nanosize Multimetallic Cartwheel Pincer Compounds as Lewis-Acid Catalysts
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Thermodynamics and Mechanism of the Reversible Tin-to-Palladium Transmetalation of the Furyl Group
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Palladium‐Catalyzed Electrophilic Substitution via Monoallylpalladium Intermediates
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Palladium Pincer Complex-Catalyzed Trimethyltin Substitution of Functionalized Propargylic Substrates. An Efficient Route to Propargyl- and Allenyl-Stannanes
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