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New tunable catalysts for olefin metathesis: Controlling the initiation through electronic factors
16/16 checkable references clean · checked 2026-07-23
Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.
11 without a DOI — not checked. A reference deposited without a DOI is never matched by title or guessed at; it stays outside the checked set, and this line discloses that.
The 16 checked references that resolve
resolves10.1039/b412198h
The metathesis reactions: from a historical perspective to recent developments
resolves10.1021/ar000114f
The Development of L<sub>2</sub>X<sub>2</sub>RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
resolves10.1002/1521-3773(20021104)41:21<4035::AID-ANIE4035>3.0.CO;2-I
A Practical and Highly Active Ruthenium-Based Catalyst that Effects the Cross Metathesis of Acrylonitrile
resolves10.1039/b311496c
Ru complexes bearing bidentate carbenes: from innocent curiosity to uniquely effective catalysts for olefin metathesis
resolves10.1002/ejoc.200390151
A Good Bargain: An Inexpensive, Air‐Stable Ruthenium Metathesis Catalyst Derived from α‐Asarone
resolves10.1002/1521-3773(20020703)41:13<2403::AID-ANIE2403>3.0.CO;2-F
A New Highly Efficient Ruthenium Metathesis Catalyst This work was supported by the Fonds der Chemischen Industrie.
resolves10.1016/S0040-4039(03)00346-0
A highly efficient olefin metathesis initiator: improved synthesis and reactivity studies
resolves10.1002/1521-3773(20021104)41:21<4038::AID-ANIE4038>3.0.CO;2-0
A Highly Efficient Ruthenium Catalyst for Metathesis Reactions
resolves10.1021/ja048794v
Nitro-Substituted Hoveyda−Grubbs Ruthenium Carbenes: Enhancement of Catalyst Activity through Electronic Activation
resolves10.1021/jo049222w
Ortho- and Para-Substituted Hoveyda−Grubbs Carbenes. An Improved Synthesis of Highly Efficient Metathesis Initiators
resolves10.1021/op0580015
First Scale-Up to Production Scale of a Ring Closing Metathesis Reaction Forming a 15-Membered Macrocycle as a Precursor of an Active Pharmaceutical Ingredient
resolves10.1016/S0040-4039(02)02283-9
A PS-DES immobilized ruthenium carbene: a robust and easily recyclable catalyst for olefin metathesis
resolves10.1002/(SICI)1521-3765(20000515)6:10<1847::AID-CHEM1847>3.3.CO;2-T
Cationic Ruthenium Allenylidene Complexes as Catalysts for Ring Closing Olefin Metathesis
The 11 references without a DOI — listed, not checked
no DOI — not checked10.1016/j.molcata.2005.12.049_bib2
no DOI — not checkedFor a review on precatalyst 4 and its variations, see:
no DOI — not checked10.1016/j.molcata.2005.12.049_bib13
no DOI — not checked(−)-Securinine: T. Honda, H. Namiki, K. Kaneda, H. Mizutani, Org. Lett. 6 (2004) 87.
no DOI — not checked(+)-Viroallosecurinine: T. Honda, H. Namiki, M. Watanabe, H. Mizutani, Tetrahedron Lett. 45 (2004) 5211.
no DOI — not checkedAn artificial photosynthesis model: S. Ostrowski, A. Mikus, Mol. Diversity 6 (2003) 315.
no DOI — not checkedFor a recent application of 7 in synthesis of hepatitis C antiviral agent, BILN 2061, see: WO 2004/089974 A1 (2004, Boehringer Ingelheim International GmbH).
no DOI — not checkedA. Michrowska, MSc thesis, Department of Organic Chemistry, Warsaw University of Technology, Warsaw, Poland, 2003.
no DOI — not checkedŁ. Gułajski, MSc thesis, in preparation.
no DOI — not checkedThis observation has another practical consequence. We envisaged that after reaction with polymer-supported acids, like Dowex® resin, complex 9 can be conveniently immobilized by ion exchange. In this novel strategy for ruthenium-based metathesis catalysts immobilization the amino group plays a two-fold role, being first an active anchor for immobilization (vide supra) and secondly, after protonation, activating the catalysts. For preliminary results, see: A. Michrowska, K. Mennecke, U. Kunz, A. Kirschning, K. Grela, manuscript in preparation.
no DOI — not checkedPerfectly stable and thermally or chemically switchable initiators are of great interest in polymer chemistry and related areas. It is desired that monomers and initiator(s) can be mixed and stored without concomitant polymerization. Next, controlled polymerization can be switched on by a certain event, such as irradiation with UV or visible light, treatment with acid, or heat. See, e.g.: C. Slugovc, D. Burtscher, F. Stelzer, K. Mereiter, Organometallics 24 (2005) 2255, and references cited therein.
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