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Large Negative Thermal Expansion Induced by Synergistic Effects of Ferroelectrostriction and Spin Crossover in PbTiO<sub>3</sub>-Based Perovskites

https://doi.org/10.1021/acs.chemmater.8b04266
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39/39 checkable references clean · checked 2026-07-23

Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.

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The 39 checked references that resolve
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Mesopores induced zero thermal expansion in single-crystal ferroelectrics
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Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW <sub>2</sub> O <sub>8</sub>
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Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF<sub>3</sub>
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Giant negative thermal expansion in Ge-doped anti-perovskite manganese nitrides
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Giant Negative Thermal Expansion in Bonded MnCoGe-Based Compounds with Ni<sub>2</sub>In-Type Hexagonal Structure
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Crystal and magnetic structure of<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Ca</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">RuO</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mo>:</mml:mo></mml:math>Magnetoelastic coupling and the metal-insulator transition
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Negative Volume Thermal Expansion Via Orbital and Magnetic Orders in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:msub><mml:mi>Ca</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi>Ru</mml:mi><mml:mrow><mml:mn>1</mml:mn><mml:mo>−</mml:mo><mml:mi>x</mml:mi></mml:mrow></mml:msub><mml:msub><mml:mi>Cr</mml:mi><mml:mi>x</mml:mi></mml:msub><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>4</mml:mn></mml:msub><mml:mo stretchy="false">(</mml:mo><mml:mn>0</mml:mn><mml:mo>&lt;</mml:mo><mml:mi>x</mml:mi><mml:mo>&lt;</mml:mo><mml:mn>0.13</mml:mn><mml:mo stretchy="false">)</mml:mo></mml:math>
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Colossal Positive and Negative Thermal Expansion in the Framework Material Ag <sub>3</sub> [Co(CN) <sub>6</sub> ]
resolves10.1038/nature07816
Temperature-induced A–B intersite charge transfer in an A-site-ordered LaCu3Fe4O12 perovskite
resolves10.1038/ncomms1361
Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer
resolves10.1103/PhysRevB.61.8687
Tetragonal-to-monoclinic phase transition in a ferroelectric perovskite: The structure of<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">PbZr</mml:mi></mml:mrow><mml:mrow><mml:mn>0.52</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Ti</mml:mi></mml:mrow><mml:mrow><mml:mn>0.48</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>
resolves10.1143/JJAP.40.5999
New High Temperature Morphotropic Phase Boundary Piezoelectrics Based on Bi(Me)O<sub>3</sub>–PbTiO<sub>3</sub> Ceramics
resolves10.1021/ja7100278
Zero Thermal Expansion in PbTiO<sub>3</sub>-Based Perovskites
resolves10.1021/cm052334z
Neutron Powder Diffraction Study on the Crystal and Magnetic Structures of BiCoO<sub>3</sub>
resolves10.1021/ja102987d
Pressure-Induced Spin-State Transition in BiCoO<sub>3</sub>
resolves10.1016/0927-0256(96)00008-0
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
resolves10.1103/PhysRevLett.77.3865
Generalized Gradient Approximation Made Simple
resolves10.1103/PhysRevB.74.224412
Theoretical investigation of magnetoelectric behavior in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:mi mathvariant="normal">Bi</mml:mi><mml:mi mathvariant="normal">Fe</mml:mi><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>
resolves10.1088/0305-4608/14/7/008
Itinerant metamagnetism in YCO<sub>2</sub>
resolves10.1038/nature06459
Origin of morphotropic phase boundaries in ferroelectrics
resolves10.1143/JJAP.41.2099
Preparation and Characterization of High Temperature Perovskite Ferroelectrics in the Solid-Solution (1-<i>x</i>)BiScO<sub>3</sub>–<i>x</i>PbTiO<sub>3</sub>
resolves10.1126/science.1080615
Epitaxial BiFeO <sub>3</sub> Multiferroic Thin Film Heterostructures
resolves10.1038/21778
A century of zero expansion
resolves10.1021/ja5077487
Zero Thermal Expansion and Ferromagnetism in Cubic Sc<sub>1–<i>x</i></sub>M<sub><i>x</i></sub>F<sub>3</sub> (M = Ga, Fe) over a Wide Temperature Range
resolves10.1021/ja056460f
Guest-Dependent Negative Thermal Expansion in Nanoporous Prussian Blue Analogues M<sup>II</sup>Pt<sup>IV</sup>(CN)<sub>6</sub>·<i>x</i>{H<sub>2</sub>O} (0 ≤ <i>x</i> ≤ 2; M = Zn, Cd)
resolves10.1021/ja044959o
Zero Thermal Expansion in a Prussian Blue Analogue
resolves10.1038/srep02458
Effectively control negative thermal expansion of single-phase ferroelectrics of PbTiO3-(Bi,La)FeO3 over a giant range
resolves10.1021/jacs.7b08625
Colossal Volume Contraction in Strong Polar Perovskites of Pb(Ti,V)O<sub>3</sub>
resolves10.1038/ncomms14102
Colossal negative thermal expansion in reduced layered ruthenate
resolves10.1016/j.jssc.2012.01.025
Polar and nonpolar phases of BiMO3: A review
resolves10.1002/xrs.1103
Assignment of pre‐edge peaks in K‐edge x‐ray absorption spectra of 3d transition metal compounds: electric dipole or quadrupole?
resolves10.1103/PhysRevLett.90.227201
Ising-Like Spin Anisotropy and Competing Antiferromagnetic-Ferromagnetic Orders in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:msub><mml:mrow><mml:mi mathvariant="normal">G</mml:mi><mml:mi mathvariant="normal">d</mml:mi><mml:mi mathvariant="normal">B</mml:mi><mml:mi mathvariant="normal">a</mml:mi><mml:mi mathvariant="normal">C</mml:mi><mml:mi mathvariant="normal">o</mml:mi></mml:mrow><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>5.5</mml:mn></mml:msub></mml:math>Single Crystals
resolves10.1107/S0567739476001551
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
resolves10.1103/PhysRev.71.809
Finite Elastic Strain of Cubic Crystals
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