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Heptadentate, Octadentate, Or Even Nonadentate? Denticity in the Unexpected Formation of an All-Carbon Donor-Atom Ligand in Rh<sup>III</sup>(Cp*)(Anthracenyl-NHC) Complexes
40/40 checkable references clean · checked 2026-07-25
Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.
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The 40 checked references that resolve
resolves10.1038/nature15691
Rhodium-catalysed syn-carboamination of alkenes via a transient directing group
resolves10.1038/nchem.2360
Rhodium-catalysed asymmetric allylic arylation of racemic halides with arylboronic acids
resolves10.1038/ncomms11506
Merging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation
resolves10.1021/cr900005n
Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation
resolves10.1021/om101016s
An Iridium(IV) Species, [Cp*Ir(NHC)Cl]<sup>+</sup>, Related to a Water-Oxidation Catalyst
resolves10.1021/om2012166
C–H Bond Activation by Cationic Iridium(III) NHC Complexes: A Combined Experimental and Computational Study
resolves10.1039/C8CC03144D
Directed
<i>ortho</i>
C–H borylation catalyzed using Cp*Rh(
<scp>iii</scp>
)–NHC complexes
resolves10.1021/acs.organomet.7b00091
C–H Activation of Cp* Ligand Coordinated to Ruthenium Center: Synthesis and Reactivity of a Thiolate-Bridged Diruthenium Complex Featuring Fulvene-like Cp* Ligand
resolves10.1021/acs.accounts.8b00175
Carbolong Chemistry: A Story of Carbon Chain Ligands and Transition Metals
resolves10.1002/chem.201801271
Multifunctional Cyclopentadienes as a Scaffold for Combinatorial Bioorganometallics in [(η<sup>5</sup>‐C<sub>5</sub>H<sub>2</sub>R<sub>1</sub>R<sub>2</sub>R<sub>3</sub>)M(CO)<sub>3</sub>] (M=Re, <sup>99m</sup>Tc) Piano‐Stool Complexes
resolves10.1039/b901195a
Easy preparation of Cp*-functionalized N-heterocyclic carbenes and their coordination to rhodium and iridium
resolves10.1002/anie.201206175
Unconventional Reactivity of Imidazolylidene Pyridylidene Ligands in Iridium(III) and Rhodium(III) Complexes
resolves10.1021/acs.organomet.8b00164
Tethering of Pentamethylcyclopentadienyl and N-Heterocycle Stabilized Carbene Ligands by Intramolecular 1,4-Addition to a Polyfluorophenyl Substituent
resolves10.1039/C7SC05058E
New activation mechanism for half-sandwich organometallic anticancer complexes
resolves10.1021/om020874p
Intramolecular Dehydrofluorinative Coupling of the Asymmetric Diphosphine Ph<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>PPh(C<sub>5</sub>F<sub>4</sub>N-4) and Pentamethylcyclopentadienyl Ligands in a Rhodium Complex
resolves10.1021/om800867h
Facile Single or Double C−H Bond Activation on a Cp* Ligand Promoted by the Presence of Alkynylphosphine Ligands
resolves10.1002/chem.201002604
The Scope of Ambiphilic Acetate‐Assisted Cyclometallation with Half‐Sandwich Complexes of Iridium, Rhodium and Ruthenium
resolves10.1002/anie.201006877
Stereoselective Coordination of <i>C</i><sub>5</sub>‐Symmetric Corannulene Derivatives with an Enantiomerically Pure [Rh<sup>I</sup>(nbd*)] Metal Complex
resolves10.1002/ange.202005758
A Multitargeted Approach: Organorhodium Anticancer Agent Based on Vorinostat as a Potent Histone Deacetylase Inhibitor
resolves10.1039/C8CC02433B
Unexpected arene ligand exchange results in the oxidation of an organoruthenium anticancer agent: the first X-ray structure of a protein–Ru(carbene) adduct
resolves10.1021/acs.inorgchem.8b02634
From Catalysis to Cancer: Toward Structure–Activity Relationships for Benzimidazol-2-ylidene-Derived <i>N</i>-Heterocyclic-Carbene Complexes as Anticancer Agents
resolves10.1021/acs.organomet.8b00153
(Pyridin-2-yl)-NHC Organoruthenium Complexes: Antiproliferative Properties and Reactivity toward Biomolecules
resolves10.1021/acs.inorgchem.9b03640
Potent Inhibition of Thioredoxin Reductase by the Rh Derivatives of Anticancer M(arene/Cp*)(NHC)Cl<sub>2</sub>Complexes
resolves10.1021/acs.jmedchem.5b01159
Rhodium(I) N-Heterocyclic Carbene Bioorganometallics as in Vitro Antiproliferative Agents with Distinct Effects on Cellular Signaling
resolves10.1002/cmdc.201600557
Metal NHC Complexes with Naphthalimide Ligands as DNA‐Interacting Antiproliferative Agents
resolves10.1002/chem.201604512
Gold(I) NHC Complexes: Antiproliferative Activity, Cellular Uptake, Inhibition of Mammalian and Bacterial Thioredoxin Reductases, and Gram‐Positive Directed Antibacterial Effects
resolves10.1016/S0022-328X(00)82604-2
(Pentamethylcyclopentadienyl)rhodium and -iridium complexes. V. Complexes with oxy-ligands and the exchange of methyl protons by deuterium under basic conditions
resolves10.1002/cssc.201701416
Ligand Substituents Govern the Efficiency and Mechanistic Path of Hydrogen Production with [Cp*Rh] Catalysts
resolves10.1021/ic300337a
Monomeric Platinum(II) Hydroxides Supported by Sterically Dominant α-Diimine Ligands
resolves10.1021/om00161a006
Deprotonation of a Cp* methyl group by an iridium anilide: formation, structure, and solution dynamics of an .eta.4-tetramethylfulvene complex
resolves10.1070/MC1991v001n01ABEH000013
Deprotonation of 1,2,3,4,5-Pentamethylrhodocenium; a New Route to 1-Substituted-2,3,4,5-tetramethylcyclopentadienylrhodium Complexes
resolves10.1021/om3010492
η<sup>6</sup>-Tetramethylfulvene and μ-η<sup>3</sup>:η<sup>3</sup>-Benzene Complexes of Iridium
resolves10.1021/jacs.8b11752
Base-Promoted, Remote C–H Activation at a Cationic (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Ir(III) Center Involving Reversible C–C Bond Formation of Bound C<sub>5</sub>Me<sub>5</sub>
resolves10.1039/c003056m
Counterion-dependent deuteration of pentamethylcyclopentadiene in water-soluble cationic Rh(iii) complexes assisted by PTA
resolves10.1246/cl.160909
Structure and Reactivity of a Ru-based Peroxide Complex as a Reactive Intermediate of O<sub>2</sub>-Promoted Activation of a C–H Bond in a Cp* Ligand
resolves10.1039/dt9730002039
Isocyanide complexes of rhodium and iridium. Part I. Tetrakisisocyanide species, their oxidative addition reactions, and some allyl complexes
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