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The Development and Catalytic Uses of N-Heterocyclic Carbene Gold Complexes
76/76 checkable references clean · checked 2026-07-23
Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.
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The 76 checked references that resolve
resolves10.1021/cr068435d
Alternative Synthetic Methods through New Developments in Catalysis by Gold
resolves10.1021/ar800020y
Well-Defined N-Heterocyclic Carbenes−Palladium(II) Precatalysts for Cross-Coupling Reactions
resolves10.1039/b718287b
Ruthenium–indenylidene complexes: powerful tools for metathesis transformations
resolves10.1002/zaac.200300247
Synthesis of the First Gold(I) Carbene Complex with a Gold‐Oxygen Bond — First Catalytic Application of Gold(I) Complexes Bearing <i>N</i>‐Heterocyclic Carbenes
resolves10.1002/(SICI)1521-3773(19980605)37:10<1415::AID-ANIE1415>3.0.CO;2-N
Cationic Gold(I) Complexes: Highly Efficient Catalysts for the Addition of Alcohols to Alkynes
resolves10.1021/om050111c
Synthesis and Structural Characterization of <i>N</i>-Heterocyclic Carbene Gold(I) Complexes
resolves10.1021/ja042257t
Intramolecular [4 + 2] Cycloadditions of 1,3-Enynes or Arylalkynes with Alkenes with Highly Reactive Cationic Phosphine Au(I) Complexes
resolves10.1021/om9709704
Facile Synthesis of Silver(I)−Carbene Complexes. Useful Carbene Transfer Agents
resolves10.1021/om050735i
Synthesis of Well-Defined <i>N</i>-Heterocyclic Carbene Silver(I) Complexes
resolves10.1039/B601547F
Synthesis, isolation and characterization of cationic gold(
<scp>i</scp>
) N-heterocyclic carbene (NHC) complexes
resolves10.1016/j.jorganchem.2008.10.047
Cationic NHC–gold(I) complexes: Synthesis, isolation, and catalytic activity
resolves10.1021/ol0515917
Phosphine Gold(I) Bis-(trifluoromethanesulfonyl)imidate Complexes as New Highly Efficient and Air-Stable Catalysts for the Cycloisomerization of Enynes
resolves10.1002/anie.200601688
Cationic η<sup>1</sup>/η<sup>2</sup>‐Gold(I) Complexes of Simple Arenes
resolves10.1021/om060887t
Synthesis, Characterization and Reactivity of <i>N</i>-Heterocyclic Carbene Gold(III) Complexes
resolves10.1039/b907109a
Synthesis and characterization of IPrMe-containing silver(I), gold(I) and gold(III) complexes
resolves10.1002/anie.200353207
Cationic Gold(<scp>I</scp>) Complexes: Highly Alkynophilic Catalysts for the <i>exo</i>‐ and <i>endo</i>‐Cyclization of Enynes
resolves10.1021/ja048094q
Platinum- and Gold-Catalyzed Cycloisomerization Reactions of Hydroxylated Enynes
resolves10.1002/1521-3773(20020617)41:12<2132::AID-ANIE2132>3.0.CO;2-S
The Effect of a Hydroxy Protecting Group on the PtCl2-Catalyzed Cyclization of Dienynes—A Novel, Efficient, and Selective Synthesis of Carbocycles Acknowledgement is made to the EU for the COST D12 Action “Cascade Free Radical Reactions” and for a short-term scientific mission to Madrid (EM). We thank Nieves Arroyo (CSIC) for preliminary experiments, Dr. J. Vaissermann (UPMC) for the X-ray analysis of 3 e, Dr. M. L. Jimeno (CNQO) for NMR studies on 3 a, Dr. M.-N. Rager (ENSCP) for NMR studies on 3 h, 6, and 11, and Matthieu Bernard (UPMC) for performing some of the experiments. We also thank Dr. Emmanuel Lacôte and Dr. Henri Rudler (UPMC) for helpful discussions.
resolves10.1002/hlca.19760590435
Zur Cyclisierung von Dehydrolinalylacetat in Gegenwart von Zinkchlorid
resolves10.1002/anie.200504543
Synthesis of (−)‐Cubebol by Face‐Selective Platinum‐, Gold‐, or Copper‐Catalyzed Cycloisomerization: Evidence for Chirality Transfer
resolves10.1002/chem.200901292
Synthesis of (−)‐Cubebol by Face‐Selective Platinum‐, Gold‐, or Copper‐Catalyzed Cycloisomerization: Evidence of Chirality Transfer and Mechanistic Insights
resolves10.1039/B602839J
Au
<sup>I</sup>
-catalyzed cycloisomerization of 1,5-enynes bearing a propargylic acetate: formation of unexpected bicyclo[3.1.0]hexene
resolves10.1002/chem.200801387
Gold‐ and Platinum‐Catalyzed Cycloisomerization of Enynyl Esters versus Allenenyl Esters: An Experimental and Theoretical Study
resolves10.1002/anie.200703769
Golden Carousel in Catalysis: The Cationic Gold/Propargylic Ester Cycle
resolves10.1021/ja00809a054
Thermal and mercuric ion catalyzed [3,3]-sigmatropic rearrangement of allylic trichloroacetimidates. 1,3 Transposition of alcohol and amine functions
resolves10.1002/anie.198405791
Mercury(<scp>II</scp>)‐ and Palladium(<scp>II</scp>)‐Catalyzed [3,3]‐Sigmatropic Rearrangements [New Synthetic Methods (46)]
resolves10.1021/ol802430m
Mechanism of the [(NHC)Au<sup>I</sup>]-Catalyzed Rearrangement of Allylic Acetates. A DFT Study
resolves10.1002/anie.200600571
Au<sup>I</sup>‐Catalyzed Tandem [3,3] Rearrangement–Intramolecular Hydroarylation: Mild and Efficient Formation of Substituted Indenes
resolves10.1002/chem.200700134
[(NHC)Au<sup>I</sup>]‐Catalyzed Formation of Conjugated Enones and Enals: An Experimental and Computational Study
resolves10.1016/j.tet.2008.10.111
[(NHC)AuCl]-catalyzed Meyer–Schuster rearrangement: scope and limitations
resolves10.1021/ja809403e
[(NHC)Au<sup>I</sup>]-Catalyzed Acid-Free Alkyne Hydration at Part-per-Million Catalyst Loadings
resolves10.1021/jo00011a058
Effective transformation of unactivated alkynes into ketones or acetals with a gold(III) catalyst
resolves10.1021/jo802558e
Isolable Gold(I) Complexes Having One Low-Coordinating Ligand as Catalysts for the Selective Hydration of Substituted Alkynes at Room Temperature without Acidic Promoters
resolves10.1021/jo8014769
Gold(I)-Catalyzed Intermolecular Addition of Carbon Nucleophiles to 1,5- and 1,6-Enynes
resolves10.1021/om7006002
Synthesis and Reactivity of Air-Stable N-Heterocyclic Carbene Gold(I) Bis(trifluoromethanesulfonyl)imidate Complexes
resolves10.1021/om9005774
Copper-Catalyzed Huisgen [3 + 2] Cycloaddition of Gold(I) Alkynyls with Benzyl Azide. Syntheses, Structures, and Optical Properties
resolves10.1002/ejic.200900307
Synthesis, Structures, and Excited‐State Geometries of Alkynylgold(I) Complexes
resolves10.1021/ja103429q
Carboxylation of C−H Bonds Using <i>N</i>-Heterocyclic Carbene Gold(I) Complexes
resolves10.1021/ol062107i
Room Temperature Hydroamination of<i>N</i>-Alkenyl Ureas Catalyzed by a Gold(I)<i>N</i>-Heterocyclic Carbene Complex
resolves10.1021/ol8010858
Intermolecular Hydroamination of Allenes with <i>N</i>-Unsubstituted Carbamates Catalyzed by a Gold(I) <i>N</i>-Heterocyclic Carbene Complex
resolves10.1021/ol800646h
Regio- and Stereoselective Synthesis of Alkyl Allylic Ethers via Gold(I)-Catalyzed Intermolecular Hydroalkoxylation of Allenes with Alcohols
resolves10.1021/ol070814l
Synthesis of Substituted 1,2-Dihydroquinolines and Quinolines from Aromatic Amines and Alkynes by Gold(I)-Catalyzed Tandem Hydroamination−Hydroarylation under Microwave-Assisted Conditions
resolves10.1021/ol8025523
Intermolecular Reaction of Internal Alkynes and Imines: Propargyl Tosylates as Key Partners in a Gold-Catalyzed [4 + 1] Unusual Cyclization Leading to Cyclopent-2-enimines
resolves10.1021/ol100595s
NHC-Stabilized Gold(I) Complexes: Suitable Catalysts for 6-<i>exo</i>-dig Heterocyclization of 1-(<i>o</i>-Ethynylaryl)ureas
resolves10.1021/ol902675k
Regioselective Synthesis of <i>tert</i>-Allylic Ethers via Gold(I)-Catalyzed Intermolecular Hydroalkoxylation of Allenes
resolves10.1002/anie.200501056
A Gold Catalyst for Carbene‐Transfer Reactions from Ethyl Diazoacetate
resolves10.1002/ejic.200500030
Stabilization of Organometallic Species Achieved by the Use of N‐Heterocyclic Carbene (NHC) Ligands
resolves10.1002/chem.200901062
Structure and Bonding in Neutral and Cationic 14‐Electron Gold Alkyne π Complexes
resolves10.1002/anie.200907194
Steering the Surprisingly Modular π‐Acceptor Properties of N‐Heterocyclic Carbenes: Implications for Gold Catalysis
resolves10.1021/om060733d
Synthesis and Characterization of Gold(I) <i>N</i>-Heterocyclic Carbene Complexes Bearing Biologically Compatible Moieties
resolves10.1021/ja075889z
Anticancer and Antimicrobial Metallopharmaceutical Agents Based on Palladium, Gold, and Silver N-Heterocyclic Carbene Complexes
The 22 references without a DOI — listed, not checked
no DOI — not checkedNumerous reviews recently published in two thematic issues, see:
no DOI — not checkedFor reviews on the use of gold in homogeneous catalysis, see:
no DOI — not checkedFor recent reviews on coinage metal in catalysis, see:
no DOI — not checkedref4/cit4c
no DOI — not checkedaAt the offset of this project in 2004, only one report describing the catalytic activity of a NHC-Au complex had been published:
no DOI — not checkedbIt should also be noted that, prior to this date, Teles and co-workers mentioned the use of NHCs for the hydroalkoxylation of alkynes. Nevertheless, it is only the subject of a footnote and no experimental details were given, see:
no DOI — not checkedbFor an early synthesis of [Au(IMes)Cl], see:
no DOI — not checkedUse of the other commonly encountered gold precursor, [Au(THT)Cl] (THT= tetrahydrothiophene), is also a viable synthetic route leading to the [Au(NHC)Cl] complexes.
no DOI — not checkedbFor the isolation of a [Au(PR3)(L)]+A-(L = ligand) complex, see:
no DOI — not checkedThe interest in this chemistry—now spanning some 35 years—continues at Firmenich under the direction of Dr. Charles Fehr; see:
no DOI — not checkedbFor an early report on sigmatropic rearrangement and its mechanism, see the seminal work of Overman:
no DOI — not checkedbFor a recent report describing an updated mechanism, see:
no DOI — not checkedref24/cit24ba
no DOI — not checkedbFor an original report on hydration of alkyne, see:
no DOI — not checkedFor phosphine-bearing analogues:
no DOI — not checkedaReference(9).
no DOI — not checkedbFor a general protocol to generate the putative [Au(NHC)]+species without the use of silver additives, see:
no DOI — not checkedref32/cit32ba
no DOI — not checkedShortly after our report, a disclosure on the use of gold for C−H activation of fluoroarene C−H bonds appeared:
no DOI — not checkedref34/cit34
no DOI — not checkedFor synthesis and properties of [Au(NHC)(alkynyl)] complexes, see, for example,
no DOI — not checkedComplex1is commercially available as a white air and moisture stable solid from Strem and Aldrich.
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