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Bidentate, Monoanionic Auxiliary-Directed Functionalization of Carbon–Hydrogen Bonds

72/72 checkable references clean · checked 2026-07-22

Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.

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The 72 checked references that resolve

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Bystanding F+ Oxidants Enable Selective Reductive Elimination from High‐Valent Metal Centers in Catalysis

resolves10.1021/cr900184e

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

resolves10.1039/c0cs00182a

C–H functionalization logic in total synthesis

resolves10.1021/cr100412j

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

resolves10.1039/c1cs15058h

Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

resolves10.1021/ar400270x

Low-Valent Cobalt Catalysis: New Opportunities for C–H Functionalization

resolves10.1002/anie.201301451

Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups

resolves10.1021/cr900005n

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

resolves10.1039/C4CS00137K

Arene C–H functionalisation using a removable/modifiable or a traceless directing group strategy

resolves10.1021/ar00051a009

Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution

resolves10.1002/cber.186900201183

Beiträge zur Kenntniss des Acetenylbenzols

resolves10.1002/jlac.18922670203

Ueber Verbindungen des Thiophens, seiner Homologen und einiger Ketone mit Quecksilberchlorid

resolves10.1021/ja01359a030

THE CHEMISTRY OF ORGANIC GOLD COMPOUNDS. III. DIRECT INTRODUCTION OF GOLD INTO THE AROMATIC NUCLEUS (PRELIMINARY COMMUNICATION)

resolves10.1021/jo202342q

Analysis of the Palladium-Catalyzed (Aromatic)C–H Bond Metalation–Deprotonation Mechanism Spanning the Entire Spectrum of Arenes

resolves10.1021/cr00100a004

Mechanisms of intramolecular activation of carbon-hydrogen bonds in transition-metal complexes

resolves10.1021/ja046476q

Selective Addition to Iridium of Aryl C−H Bonds Ortho to Coordinating Groups. Not Chelation-Assisted

resolves10.1021/ja00893a040

The Preparation of Cyclopentadienyl [o-(Phenylazo)Phenyl]Nickel

resolves10.1021/ja01092a063

Formation of Covalent Bonds from Platinum or Palladium to Carbon by Direct Substitution

resolves10.1021/ja01628a120

SYNTHESIS OF PHTHALIMIDINES FROM SCHIFF BASES AND CARBON MONOXIDE

resolves10.1021/ja00365a091

Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H)

resolves10.1021/ja00377a032

Oxidative addition of the carbon-hydrogen bonds of neopentane and cyclohexane to a photochemically generated iridium(I) complex

resolves10.1002/anie.200500589

Anilide ortho‐Arylation by Using CH Activation Methodology

resolves10.1021/ol051255q

Catalytic Coupling of C−H and C−I Bonds Using Pyridine As a Directing Group

resolves10.1021/ol061919b

Direct Palladium-Catalyzed Ortho-Arylation of Benzylamines

resolves10.1021/ja071845e

Two Methods for Directortho-Arylation of Benzoic Acids

resolves10.1016/S0040-4039(00)99328-6

Palladium-mediated 2,6-dialkylation of N-benzilidine imines: Preparation of 2,6-dialkylbenzaldehydes

resolves10.1016/0022-328X(83)85164-X

The facile cyclometallation reaction of 1,3-BIS[(diphenyl-phosphino)methyl]benzene

resolves10.1039/b914080h

Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium

resolves10.1021/ja054549f

Highly Regioselective Arylation of sp3 C−H Bonds Catalyzed by Palladium Acetate

resolves10.1039/c39900000566

Copper(II) mediated aromatic hydroxylation by trimethylamine N-oxide

resolves10.1021/ja411715v

Nickel-Catalyzed Direct Arylation of C(sp3)–H Bonds in Aliphatic Amides via Bidentate-Chelation Assistance

resolves10.1021/ja402806f

β-Arylation of Carboxamides via Iron-Catalyzed C(sp3)–H Bond Activation

resolves10.1002/anie.201309584

Nickel‐Catalyzed CH Alkylations: Direct Secondary Alkylations and Trifluoroethylations of Arenes

resolves10.1021/ja506823u

A Unified Strategy for Iron-Catalyzed ortho-Alkylation of Carboxamides

resolves10.1021/ja910900p

Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 Carbon−Hydrogen Bonds

resolves10.1021/jo4013628

Scope and Limitations of Auxiliary-Assisted, Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 C–H Bonds

resolves10.1002/anie.201200731

Nonnatural Amino Acid Synthesis by Using Carbon–Hydrogen Bond Functionalization Methodology

resolves10.1021/om400704h

Synthesis of Highly Branched Polyethylene Using “Sandwich” (8-p-Tolyl naphthyl α-diimine)nickel(II) Catalysts

resolves10.1021/ol061389j

Novel Acetoxylation and C−C Coupling Reactions at Unactivated Positions in α-Amino Acid Derivatives

resolves10.1002/anie.200905134

Total Synthesis of Celogentin C by Stereoselective CH Activation

resolves10.1021/ja406484v

Stereoselective Synthesis of β-Alkylated α-Amino Acids via Palladium-Catalyzed Alkylation of Unactivated Methylene C(sp3)–H Bonds with Primary Alkyl Halides

resolves10.1039/C4SC00848K

Experimental and computational studies on the mechanism of the Pd-catalyzed C(sp 3 )–H γ-arylation of amino acid derivatives assisted by the 2-pyridylsulfonyl group

resolves10.1039/c3sc51747k

Pd(ii)-catalyzed alkylation of unactivated C(sp3)–H bonds: efficient synthesis of optically active unnatural α-amino acids

resolves10.1021/ja510233h

Site-Selective C(sp3)–H Functionalization of Di-, Tri-, and Tetrapeptides at the N-Terminus

resolves10.1039/c3sc51211h

1,2,3-Triazoles as versatile directing group for selective sp2 and sp3 C–H activation: cyclization vs substitution

resolves10.1002/anie.201311024

Iron‐Catalyzed C(sp2)H and C(sp3)H Arylation by Triazole Assistance

resolves10.1002/anie.201306583

Palladium‐Catalyzed Direct Functionalization of 2‐Aminobutanoic Acid Derivatives: Application of a Convenient and Versatile Auxiliary

resolves10.1021/ja209205x

Total Synthesis and Structural Revision of the Piperarborenines via Sequential Cyclobutane C–H Arylation

resolves10.1002/anie.201203897

Sequential CH Arylation and Olefination: Total Synthesis of the Proposed Structure of Pipercyclobutanamide A

resolves10.1021/jo4027148

Applications of C–H Functionalization Logic to Cyclobutane Synthesis

resolves10.1039/c3sc50310k

Ruthenium-catalyzed ortho-C–H bond alkylation of aromatic amides with α,β-unsaturated ketones via bidentate-chelation assistance

resolves10.1002/1521-3773(20020816)41:16<2991::AID-ANIE2991>3.0.CO;2-6

Aryl CbH Activation by CuII To Form an Organometallic ArylâCuIII Species: A Novel Twist on Copper Disproportionation This research was supported by MICYT of Spain through project PBQ2000-0548 and with the grant SGR-3102-UG-01 as well as the Distinction award from from CIRIT Generalitat de Catalunya (Spain). An FI doctoral grant from CIRIT to X.R. and financial support from the National Institutes of Health (USA; T.D.P.S. GM-50730; K.O.H. RR-01209) are also acknowledged. SSRL operations are funded by the Department of Energy, Basic Energy Sciences, and the SSRL Structural Molecular Biology Program is supported by the NIH NCRR BTP and the DOE OBER.

resolves10.1021/ja802123p

Carbon−Nitrogen Bond Formation Involving Well-Defined Aryl−Copper(III) Complexes

resolves10.1021/ja1045378

Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C−H Bond: Evidence for an Aryl-Copper(III) Intermediate

resolves10.1021/ja2058567

Nucleophilic Aryl Fluorination and Aryl Halide Exchange Mediated by a CuI/CuIII Catalytic Cycle

resolves10.1021/ja412521k

Synthesis of Anthranilic Acid Derivatives through Iron-Catalyzed Ortho Amination of Aromatic Carboxamides with N-Chloroamines

resolves10.1021/ja412880r

Cu(II)-Mediated C–H Amidation and Amination of Arenes: Exceptional Compatibility with Heterocycles

resolves10.1021/ja4026424

Divergence between Organometallic and Single-Electron-Transfer Mechanisms in Copper(II)-Mediated Aerobic C–H Oxidation

resolves10.1021/ja061715q

Cu(II)-Catalyzed Functionalizations of Aryl C−H Bonds Using O2 as an Oxidant

resolves10.1039/c39890001633

Synthesis and X-ray structure of bis(trifluoromethyl)(N,N-diethyldithiocarbamato)-copper; a remarkably stable perfluoroalkylcopper(III) complex

resolves10.1021/ja3092278

Copper-Promoted Sulfenylation of sp2 C–H Bonds

resolves10.1002/anie.201300135

Directed Amination of Non‐Acidic Arene CH Bonds by a Copper–Silver Catalytic System

resolves10.1021/ol402904d

Copper-Catalyzed Etherification of Arene C–H Bonds

resolves10.1021/ja4047125

Copper-Catalyzed, Directing Group-Assisted Fluorination of Arene and Heteroarene C–H Bonds

resolves10.1021/ja5008432

Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C–H Alkenylation/Annulation Sequence

resolves10.1021/ja00291a073

Implications of three-center, two-electron M--H--C bonding for related alkyl migration reactions: design and study of an ethylene polymerization catalyst

resolves10.1002/anie.201404579

Cobalt‐Catalyzed, Aminoquinoline‐Directed C(sp2)H Bond Alkenylation by Alkynes

resolves10.1021/ol502005g

Cobalt-Catalyzed, Aminoquinoline-Directed Coupling of sp2 C–H Bonds with Alkenes

resolves10.1021/ol502007t

Cobalt-Catalyzed Direct Carbonylation of Aminoquinoline Benzamides

resolves10.1021/ja0701614

Palladium-Catalyzed Methylation and Arylation of sp2 and sp3 C−H Bonds in Simple Carboxylic Acids

resolves10.1021/ja016280f

Selective Functionalization of Amino Acids in Water: A Synthetic Method via Catalytic C−H Bond Activation

resolves10.1038/nature13389

Palladium-catalysed C–H activation of aliphatic amines to give strained nitrogen heterocycles

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