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Catalytic Enantioselective C−H Activation by Means of Metal−Carbenoid-Induced C−H Insertion

https://doi.org/10.1021/cr0200217

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References needing attention

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C−C Bond Formation via C−H Bond Activation: Catalytic Arylation and Alkenylation of Alkane Segments

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Intermediacy of an N-Heterocyclic Carbene Complex in the Catalytic C−H Activation of a Substituted Benzimidazole

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Site- and Enantiocontrol in Intramolecular C-H Insertion Reactions of .ALPHA.-Diazo Carbonyl Compounds Catalyzed by Dirhodium(II) Carboxylates.

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Rhodium (II) catalyzed reactions of diazo-carbonyl compounds

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Natural Product Synthesis by Rh‐Mediated Intramolecular C‐H Insertion

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Highly selective γ-lactone syntheses by intramolecular carbenoid carbon-hydrogen insertion in rhodium(II) carboxylate and rhodium(II) carboxamide catalyzed reactions of diazo esters

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Dirhodium tetraacetate catalyzed carbon-hydrogen insertion reaction in N-substituted .alpha.-carbomethoxy-.alpha.-diazoacetanilides and structural analogs. Substituent and conformational effects

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Electronic and steric control in carbon-hydrogen insertion reactions of diazoacetoacetates catalyzed by dirhodium(II) carboxylates and carboxamides

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Rh(II)-Catalyzed Reaction Of Some α‘,α‘- and β‘-Branched-O-Alkyl α-(Alkoxycarbonyl)-α-diazoacetates

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Investigation of Electronic Effects of Rh(II)-Mediated α-Methyl-Substituted Carbenoid Intramolecular C−H Insertion

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Carbenoid Reactions in Rhodium(II)‐Catalyzed Decomposition of Iodonium Ylides

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Rhodium(II)-catalyzed aziridinations and CH insertions with [N-(p-nitrobenzenesulfonyl)imino]phenyliodinane

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Enhanced extraction of isoflavones from Korean soybean by ultrasonic wave

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Asymmetric amidation of saturated C–H bonds catalysed by chiral ruthenium and manganese porphyrins

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The Enantioselectivity and the Stereochemical Course of Copper-Catalyzed Intramolecular CH Insertions of Phenyliodonium Ylides

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Enantioselective Intramolecular CH-Insertions upon Cu-Catalyzed Decomposition of Phenyliodonium Ylides

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Transition-Metal-Catalyzed Carbenoid Reactions of Sulfonium Ylides

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Metal‐catalyzed carbenoid reactions with iodonium and sulfonium ylides

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Rhodium(II)‐Catalyzed CH Insertions with {[(4‐Nitrophenyl)sulfonyl]imino}phenyl‐λ3‐iodane

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Enantioselective carbocyclization: a facile route to chiral cyclopentanes

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Enantioselective ring construction: synthesis of (+)-estrone methyl ether

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Enantioselective Synthesis of a 1,2-Disubstituted Mitosene by a Copper-Catalyzed Intramolecular Carbon-Hydrogen Insertion Reaction of a Diazo Ester

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Synthesis of the antitumor antibiotic FR-66979: Dmitrienko oxidative expansion of a fully functional core structure

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Asymmetric approaches to 1,2-disubstituted mitosenes based on the intramolecular cyclization of diazoesters

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Steric and Electronic Influences on the Diastereoselectivity of the Rh2(OAc)4-Catalyzed C−H Insertion in Chiral Ester Diazoanilides: Synthesis of Chiral, Nonracemic 4-Substituted 2-Pyrrolidinones

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Homochiral group transfer in organic synthesis viaα-diazocarbonyl intermediates

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First Example of Intramolecular C-H Insertion Reaction in an Amino Acid Derived α-Diazoketone

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A Novel Synthetic Route to Chiral γ-Lactams from α-Amino Acids via Rh-Catalyzed Intramolecular C−H Insertion

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Asymmetric Synthesis of (+)-Morphine. The Phenanthrene Route Revisited

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Chemo- and stereoselective dirhodium(II)-catalyzed C-H insertion reaction of 5,6-dioxygenated 2-diazo-3-oxohexanoates: Synthesis of an optically active highly functionalized cyclopentane

resolves10.1021/jo0102765

Enantiospecific Total Synthesis of (−)-4-Thiocyanatoneopupukeanane

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C−H Insertion Approach to the Synthesis of endo,exo-Furofuranones: Synthesis of (±)-Asarinin, (±)-Epimagnolin A, and (±)-Fargesin

resolves10.1021/jo010751z

Asymmetric Synthesis of (−)-Eburnamonine and (+)-epi-Eburnamonine from (4S)-4-Ethyl-4-[2-(hydroxycarbonyl)ethyl]-2-butyrolactone

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An Enantioselective 1,2-Aziridinomitosene Synthesis via a Chemoselective Carbon−Hydrogen Insertion Reaction of a Metal Carbene

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A Concise Synthesis of (+)-α-Allokainic Acid via Site- and Diastereoselective Intramolecular C-H Insertion Process

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Cyclohexenone Annelation by Alkylidene C−H Insertion: Synthesis of Oxo-T-cadinol

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Cyclohexenone Construction by Intramolecular Alkylidene C−H Insertion: Synthesis of (+)-Cassiol

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Enantioselective Construction of Cyclic Quaternary Centers: (−)-Mesembrine

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Synthesis of (−)-malyngolide using reactions of alkylidenecarbenes

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Enantioselective Synthesis of the Excitatory Amino Acid (1S,3R)-1-Aminocyclopentane-1,3-dicarboxylic Acid

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Asymmetric creation of quaternary carbon centers by enantiotopically selective aromatic C-H insertion catalyzed by chiral dirhodium(II) car☐ylates

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Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]: A Notable Catalyst for Enantiotopically Selective Aromatic Substitution Reactions of α-Diazocarbonyl Compounds

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Ligand effects in the metal catalysed reactions of N-aryldiazoamides: Ylide formation vs. insertion reactions

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Insertion of Carbenoids into CpH Bonds of Ferrocenes: An Enantioselective‐Catalytic Entry to Planar‐Chiral Ferrocenes

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Reactivity of (η 6 -Arene)tricarbonylchromium Complexes with Carbenoids: Arene Activation or Protection?

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Cyclopropanes from reactions of transition metal carbene complexes with olefins

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Control of chemoselectivity in catalytic carbenoid reactions. Dirhodium(II) ligand effects on relative reactivities

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Ligand effects on dirhodium(II) carbene reactivities. Highly effective switching between competitive carbenoid transformations

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Improved enantioselection for chiral dirhodium(II) carboxamide-catalysed carbon-hydrogen insertion reactions of tertiary alkyl diazoacetates

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Electronic Effects in Dirhodium(II) Carboxylates. Linear Free Energy Relationships in Catalyzed Decompositions of Diazo Compounds and CO and Isonitrile Complexation

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Ligand Effects in the Rhodium(II)-Catalyzed Reactions of .alpha.-Diazoamides. Oxindole Formation is Promoted by the Use of Rhodium(II) Perfluorocarboxamide Catalysts

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Ligand effects in the rhodium(II) catalysed reactions of diazoamides and diazoimides

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New Rhodium (II) Catalysts for Selective Carbene Transfer Reactions

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Cyclopentane construction by dirhodium tetraacetate-mediated intramolecular C-H insertion: steric and electronic effects

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Regiocontrol by electron withdrawing groups in the Rh-catalyzed C H insertion of α-diazoketones

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Model Studies of the Stereoelectronic Effect in Rh(II) Mediated Carbenoid C-H Insertion Reactions

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Predicting the Diastereoselectivity of Rh-Mediated Intramolecular C−H Insertion

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Conformational and electronic preferences in rhodium(II) carboxylate and rhodium(II) carboxamide catalyzed carbon-hydrogen insertion reactions of N,N-disubstituted diazoacetoacetamides

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Synthesis of nitrogen-containing polycycles via rhodium(II)-induced cyclization-cycloaddition and insertion reactions of N-(diazoacetoacetyl)amides. Conformational control of reaction selectivity

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Regiocontrol by the carbon-carbon double bond in the Rh2(OAc)4 mediated carbon-hydrogen insertion of α-diazo-ketones.

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Dirhodium(II) tetra(triphenylacetate): A highly efficient catalyst for the site-selective intramolecular C-H insertion reactions of α-Diazo β-Keto Esters

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Electronic Effects of Rh(II)-Mediated Carbenoid Intramolecular C−H Insertion: A Linear Free Energy Correlation Study

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Transition metal catalysed reactions of diazocompounds - II insertion in the hydroxylic bond

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Transition-metal-catalysed reactions of diazoesters. Insertion into C–H bonds of paraffins by carbenoids

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Transition‐Metal‐Catalysed Reactions of Diazoesters. Insertion into C‐H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C‐H Bonds

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Shape selective alkane functionalisation by ethyl diazoacetate catalysed by rhodium carboxylates

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Homologation of n-alkanes using diazoesters and rhodium(III)porphyrins. Enhanced attack on primary CH bonds.

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Intermolecular carbon-hydrogen insertion of copper carbenoids

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Rhodium acetate catalyzes the addition of carbenoids α- to ether oxygens

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Regiospecific control of Rh(II) carbenoids in the C-H insertion reaction

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Enantioselective ring construction: synthesis of (+)-.alpha.-cuparenone

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Construction of .beta.-lactams by highly selective intramolecular carbon-hydrogen insertion from rhodium(II) carboxylate catalyzed reactions of diazoacetamides

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Enantioselective β-Lactone Formation from Phenyldiazoacetates via Catalytic Intramolecular Carbon-Hydrogen Insertion

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Rhodium(II) acetate and Nafion-H catalyzed decomposition of N-aryldiazoamides. Efficient synthesis of 2(3H)-indolinones

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Rh2(OAc)4-mediated decomposition of diazocarbonyl compounds: A comparison of α-diazo ketones and α-diazo β-keto esters reactivity.

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Spirolactones from Dirhodium(II)-Catalyzed Diazo Decomposition with Regioselective Carbon-Hydrogen Insertion

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Ligand-Induced Selectivity in the Rhodium(II)-Catalyzed Reactions of α-Diazo Carbonyl Compounds

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Rhodium Chemzymes: Michaelis−Menten Kinetics in Dirhodium(II) Carboxylate-Catalyzed Carbenoid Reactions

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Chemoselectivity and stereoselectivity of cyclisation of α-diazocarbonyls leading to oxygen and sulfur heterocycles catalysed by chiral rhodium and copper catalysts

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Effect of Rhodium Carbenoid Structure on Cyclopropanation Chemoselectivity

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Tandem cyclopropanation/cope rearrangement: a general method for the construction of seven-membered rings

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[3+4] annulation between rhodium-stabilized vinylcarbenoids and dienes

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Asymmetric Intermolecular Carbenoid C−H Insertions Catalyzed by Rhodium(II) (S)-N-(p-Dodecylphenyl)sulfonylprolinate

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Mechanism of C−H Bond Activation/C−C Bond Formation Reaction between Diazo Compound and Alkane Catalyzed by Dirhodium Tetracarboxylate

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Ligand Effects on the Chemoselectivity of Ortho-Metalated Rhodium(II) Catalyzed α-Diazo Ketone Transformations

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Enantioselective Rhodium(<scp>II</scp>) Catalysts

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Dirhodium(II) tetrakis(carboxamidates) with chiral ligands. Structure and selectivity in catalytic metal-carbene transformations

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Synthesis and Structures of (2,2-cis)-Dirhodium(II) Tetrakis[methyl 1-acyl-2-oxoimidazolidine-4(S)-carboxylates]. Chiral Catalysts for Highly Stereoselective Metal Carbene Transformations

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New catalysts and methods for highly enantioselective metal carbene reactions

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First attempts at differential diastereoselection in catalytic reactions of N-chirally substituted dirhodium(ii) tetrakis[methyl 2-oxoimidazolidine-4(S)-carboxylates] with diazoacetates

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Reactivity Enhancement for Chiral Dirhodium(II) Tetrakis(Carboxamidates)

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Dirhodium(II) Tetrakis[methyl 2-oxaazetidine-4-carboxylate]: A Chiral Dirhodium(II) Carboxamidate of Exceptional Reactivity and Selectivity

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Enantiocontrol in catalytic metal carbene reactions

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Dirhodium(II) Tetrakis[3(S)-phthalimido-2-piperidinonate]: A Novel Dirhodium(II) Carboxamidate Catalyst for Asymmetric Cyclopropanation

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Efficient RhII binaphthol phosphate catalysts for enantioselective intramolecular tandem carbonyl ylide formation–cycloaddition of α-diazo-β-keto esters

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Speciation and Mechanistic Studies of Chiral Copper(I) Schiff Base Precursors Mediating Asymmetric Carbenoid Insertion Reactions of Diazoacetates into the Si−H Bond of Silanes

resolves10.1016/S0040-4039(01)00408-7

Cyclopropanation versus carbon–hydrogen insertion. The influences of substrate and catalyst on selectivity

resolves10.1021/jo005589z

Selectivity in Reactions of Allyl Diazoacetates as a Function of Catalyst and Ring Size from γ-Lactones to Macrocyclic Lactones

resolves10.1016/0040-4039(96)00056-1

Synthesis of pyrrolizidine bases by highly diastereoselective and regioselective catalytic carbon-hydrogen insertion reactions of chiral pyrrolidinediazoacetamides

resolves10.1021/jo010753j

A Dirhodium(II)−Carbenoid Route to (−)- and (+)-Geissman−Waiss Lactone: Synthesis of (1R,7R,8R)-(−)-Turneforcidine

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Rhodium(II)- and Copper(I)-Catalyzed Intramolecular Carbon-Hydrogen Bond Insertions with Metal Carbenoids Derived from Diazo Ketones

resolves10.1002/anie.199602201

New Catalysts and Conditions for a CH Insertion Reaction Identified by High Throughput Catalyst Screening

resolves10.1021/ja991466o

Enantioselective Synthesis of <scp>d</scp>-threo-Methylphenidate

resolves10.1002/recl.19911100702

Chiral catalysts for enantioselective carbenoid cyclopropanation reactions

resolves10.1016/0040-4039(94)85379-7

Stereoselective synthesis of disubstituted 3(2H)-furanones via catalytic intramolecular C-H insertion reactions of α-diazo-β-keto esters including asymmetric induction

resolves10.1039/C39900000361

Asymmetric synthesis in carbon–carbon bond forming reactions of α-diazoketones catalysed by homochiral rhodium( <scp>II</scp> ) carboxylates

resolves10.1039/C39920000823

Asymmetric synthesis of substituted chromanones via C–H insertion reactions of α-diazoketones catalysed by homochiral rhodium( <scp>II</scp> ) carboxylates

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A Facile Synthesis of Homochiral Rh(II) Carboxylates

resolves10.1016/S0040-4039(00)79298-7

Enantioselective synthesis of vinylcyclopropanes by rhodium(II) catalyzed decomposition of vinyldiazomethanes in the presence of alkenes

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Asymmetric Cyclopropanations by Rhodium(II) N-(Arylsulfonyl)prolinate Catalyzed Decomposition of Vinyldiazomethanes in the Presence of Alkenes. Practical Enantioselective Synthesis of the Four Stereoisomers of 2-Phenylcyclopropan-1-amino Acid

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Catalytic Asymmetric C−H Activation of Alkanes and Tetrahydrofuran

resolves10.1016/0040-4039(96)00823-4

Effect of diazoalkane structure on the stereoselectivity of rhodium(II) (S)-N-(arylsulfonyl)prolinate catalyzed cyclopropanations

resolves10.1016/0040-4039(96)00822-2

Chiral catalysts for enantioselective intermolecular cyclopropanation reactions with methyl phenyldiazoacetate. Origin of the solvent effect in reactions catalyzed by homochiral dirhodium(II) prolinates

resolves10.1016/S0040-4039(99)01000-X

Novel dirhodium tetraprolinate catalysts containing bridging prolinate ligands for asymmetric carbenoid reactions

resolves10.1016/S0040-4039(97)00897-6

Synthesis and evaluation of a novel dirhodium tetraprolinate catalyst containing bridging prolinate ligands

resolves10.1016/S0040-4039(00)97834-1

Enantioselecitve intramolecular CH insertion of α-diazo [β-keto esters catalyzed by homochiral rhodium(II) carboxylates

resolves10.1021/ol0267127

Enantio- and Diastereoselective Synthesis of cis-2-Aryl-3-methoxycarbonyl-2,3-dihydrobenzofurans via the Rh(II)-Catalyzed C−H Insertion Process

resolves10.1039/b103747c

Catalytic asymmetric synthesis of 1,1′-spirobi[indan-3,3′-dione] via a double intramolecular C–H insertion process

resolves10.1016/S0040-4039(97)10493-2

Enantioselective Synthesis of 4-Substituted 2-Pyrrolidinones by Site-selective C-H Insertion of α-Methoxycarbonyl-α-diazoacetanilides Catalyzed by Dirhodium(II) Tetrakis[N-phthaloyl-(S)-tert-leucinate]

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Highly enantioselective construction of the key azetidin-2-ones for the synthesis of carbapenem antibiotics via intramolecular C–H insertion reactions of α-methoxycarbonyl-α-diazoacetamides catalysed by chiral dirhodium() carboxylates

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Enantioselective Intramolecular C-H Insertion Reactions of α-Diazo β-Keto Esters Catalyzed by Dirhodium(II) Tetrakis[N-phthaloyl-(S)-phenylalaninate]: The Effect of the Substituent at the Insertion Site on Enantioselectivity

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Synthesis of Optically Active Ferrocene Analogues of Salicylic Acid Derivatives and Rhodium(II)-Catalyzed Asymmetric Intramolecular C–H Insertion of α-Diazo β-Keto Esters Using New Chiral Carboxylato Ligands

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(1R,5S)-(&#8722;)-6,6-DIMETHYL-3-OXABICYCLO[3.1.0]HEXAN-2-ONE. HIGHLY ENANTIOSELECTIVE INTRAMOLECULAR CYCLOPROPANATION CATALYZED BY DIRHODIUM(II) TETRAKIS[METHYL 2-PYRROLIDONE-5(R)-CARBOXYLATE]

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Tetrakis[(4S)‐4‐phenyloxazolidin‐2‐one]dirhodium(II) and Its Catalytic Applications for Metal Carbene Transformations

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Enhanced enantiocontrol in catalytic metal carbene transformations with dirhodium (II) tetrakis[methyl 2‐oxooxazolidin‐4(S)‐carboxylate], Rh2(4S‐MEOX)4

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Dirhodium(II) Tetrakis[alkyl 2-oxaazetidine-4(S)-carboxylates]. A New Set of Effective Chiral Catalysts for Asymmetric Intermolecular Cyclopropanation Reactions with Diazoacetates

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Optimization of enantiocontrol in cis-selective cyclopropanation reactions catalyzed by dirhodium(ii) tetrakis[alkyl 2-oxaazetidine-4(S)-carboxylates]

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High Selectivity from Configurational Match/Mismatch in Carbon−Hydrogen Insertion Reactions of Steroidal Diazoacetates Catalyzed by Chiral Dirhodium(II) Carboxamidates

resolves10.1016/S0040-4039(00)61106-1

A new rhodium(II) phosphate catalyst for diazocarbonyl reactions including asymmetric synthesis

resolves10.1016/S0040-4039(00)61107-3

Asymmetric dipolar cycloaddition reactions of diazocompounds mediated by a binaphtholphosphate rhodium catalyst

resolves10.1021/ja9819559

Synthesis, Structure, and Reactivity of the First Enantiomerically Pure Ortho-Metalated Rhodium(II) Dimer

resolves10.1021/om971070q

Reactivity and Selectivity of Ortho-Metalated Rhodium(II) Complexes in C−H Insertion Reactions of α-Diazo Compounds

resolves10.1016/S0022-328X(00)00357-0

ortho-Metalated dirhodium(II)-catalyzed α-diazocarbonyl transformation. Diastereoselective cyclopropanation of menthyl-α-diazo-β-keto ester and CH insertion of α-diazo ester

resolves10.1021/jo961607u

Intramolecular Regioselective Insertion into Unactivated Prochiral Carbon−Hydrogen Bonds with Diazoacetates of Primary Alcohols Catalyzed by Chiral Dirhodium(II) Carboxamidates. Highly Enantioselective Total Synthesis of Natural Lignan Lactones

resolves10.1021/ja00023a077

Asymmetric synthesis of lactones with high enantioselectivity by intramolecular carbon-hydrogen insertion reactions of alkyl diazoacetates catalyzed by chiral rhodium(II) carboxamides

resolves10.1021/jo00126a002

Optimization of Enantiocontrol for Carbon-Hydrogen Insertion with Chiral Dirhodium(II) Carboxamidates. Synthesis of Natural Dibenzylbutyrolactone Lignans from 3-Aryl-1-propyl Diazoacetates in High Optical Purity

resolves10.1021/jo016220s

Total Synthesis of (S)-(+)-Imperanene. Effective Use of Regio- and Enantioselective Intramolecular Carbon−Hydrogen Insertion Reactions Catalyzed by Chiral Dirhodium(II) Carboxamidates

resolves10.1002/1615-4169(200201)344:1<91::AID-ADSC91>3.0.CO;2-S

Highly Selective Synthesis of a 2-Deoxyxylonolactam via Enantioselective Carbon-Hydrogen Insertion Reactions Using Chiral Dirhodium(II) Carboxamidates

resolves10.1002/chir.10060

Enantioselective carbon‐‐hydrogen insertion is an effective and efficient methodology for the synthesis of (r)‐(‐)‐baclofen

resolves10.1021/ja961682m

Chiral Catalyst Controlled Diastereoselection and Regioselection in Intramolecular Carbon−Hydrogen Insertion Reactions of Diazoacetates

resolves10.1021/jo00049a010

Enantioselective metal carbene transformations with polyethylene-bound soluble recoverable dirhodium(II) 2-pyrrolidone-5(S)-carboxylates

resolves10.1016/S0040-4039(00)76684-6

Synthesis of 2-deoxyxylolactone from glycerol derivatives via highly enantioselective carbon-hydrogen insertion reactions

resolves10.1016/0040-4039(95)01561-U

Enhancement of enantiocontrol/diastereocontrol in catalytic intramolecular cyclopropanation and carbon-hydrogen insertion reactions of diazoacetates with Rh2(4S-MPPIM)4

resolves10.1021/jo991211t

Enantioselective Syntheses of 2-Deoxyxylono-1,4-lactone and 2-Deoxyribono-1,4-lactone from 1,3-Dioxan-5-yl Diazoacetates

resolves10.1021/ja00089a062

Diastereocontrol for Highly Enantioselective Carbon-Hydrogen Insertion Reactions of Cycloalkyl Diazoacetates

resolves10.1002/hlca.19940770307

Enantioselective Formation of Bicyclic Lactones by Rhodium‐Catalyzed Intramolecular CH‐insertion reactions

resolves10.1021/ja9945414

Enantiocontrolled Macrocycle Formation by Catalytic Intramolecular Cyclopropanation

resolves10.1016/S0040-4039(00)83988-X

A stereocontrolled route to optically active 1-methyl carbapenems

resolves10.1016/S0040-4039(00)74752-6

Enantiocontrol and regiocontrol in lactam syntheses by intramolecular carbon-hydrogen insertion reactions of diazoacetamides catalyzed by chiral rhodium(II) carboxamides

resolves10.1055/s-1995-5176

Highly Enantioselective Route to β-Lactams via Intramolecular C-H Insertion Reactions of Diazoacetylazacycloalkanes Catalyzed by Chiral Dirhodium(II) Carboxamidates

resolves10.1016/S0040-4039(01)02261-4

Synthesis of (±)-7-episordidin

resolves10.1007/BF02496127

Enantiocontrol in intramolecular cyclopropanation of diazoketones. Conformational control of metal carbene alignment

resolves10.1039/p19950000619

A new catalytic transformation of diazo esters: hydride abstraction in dirhodium(II)-catalysed reactions

resolves10.1021/jo990797g

Anomalous Products from Intramolecular C−H Insertion by a Rhodium Carbenoid. Possible Involvement of a Zwitterionic Mechanism

resolves10.1021/jo970842p

Anomalous Products from Intramolecular Insertion Reactions of Rhodium Carbenoids into the α-C−H Bonds of Ethers

resolves10.1016/S0040-4039(01)01173-X

Probing the mechanism of the anomalous intramolecular C–H insertion reaction of rhodium carbenoids by analysis of kinetic isotope effects

resolves10.1016/0040-4039(95)02252-X

Structure determination and synthesis of a new gibberellin, GA99, from spinach plants: 2β-hydroxy-GA19

resolves10.1080/00397919408010251

Double Asymmetric Induction in Intramolecular C-H Insertion Reactions ofα-Diazoβ-Keto Esters

resolves10.1016/S0040-4039(00)60689-5

Enhancement of enantioselectivity in intramolecular C-H insertion reactions of α-diazo β-keto esters catalyzed by chiral dirhodium(II) carboxylates

resolves10.1021/jo001519g

Synthesis of (−)-Astrogorgiadiol

resolves10.1055/s-1994-23075

Enantioselective Intramolecular C-H Insertion Reactions ofN-Alkyl-N-tert-Butyl-α-Methoxycarbonyl-α-Diazoacetamides Catalyzed by Dirhodium(II) Carboxylates: Catalytic, Asymmetric Construction of 2-Azetidinones

resolves10.1016/0040-4039(95)02115-9

The Rh2(OAc)4 catalysed CH insertion in chiral ester diazoanilides

resolves10.3987/COM-99-8805

Studies on the Rh(II)-catalyzed C-H Insertion Reaction of Some Derivatives of N -[4-{(S)-1,2-Dihydroxy- butyl}]-a-diazoanilides: Site-Selectivity

resolves10.1055/s-1999-2958

Catalytic Enantioselective Synthesis of the Phosphodiesterase Type IV Inhibitor (R)-(-)-Rolipram via Intramolecular C-H Insertion Process

resolves10.1039/c39790000846

Preparation of 8-oxo-7-(1-hydroxyethyl)-3-oxa-1-azabicyclo[4.2.0]octane derivatives: intermediates for thienamycin synthesis

resolves10.1016/S0040-4039(98)02055-3

Enantioselective intramolecular CH insertion route to a key intermediate for the synthesis of trinem antibiotics

resolves10.3987/COM-99-S102

Double Stereodifferentiation in Intramolecular C-H Insertion Reaction toward the Synthesis of 1b-Methylcarbapenem Antibiotics

resolves10.1021/ol0157858

Asymmetric Intramolecular C−H Insertions of Aryldiazoacetates

resolves10.1016/S0040-4039(98)00836-3

Effect of carbenoid structure on the reactivity of rhodium-stabilized carbenoids

resolves10.1016/S0040-4020(00)00076-4

Intermolecular Cyclopropanation versus CH Insertion in RhII-Catalyzed Carbenoid Reactions

resolves10.1016/S0040-4020(01)91934-9

Transition metal catalyzed reactions of diazoesters

resolves10.1016/S0040-4039(00)00104-0

Effect of carbenoid structure on the reactions of rhodium-stabilized carbenoids with cycloheptatriene

resolves10.1021/ja0035607

Catalytic Asymmetric C−H Activation of Silyl Enol Ethers as an Equivalent of an Asymmetric Michael Reaction

resolves10.1021/ja016798j

Intermolecular Copper-Catalyzed Carbon−Hydrogen Bond Activation via Carbene Insertion

resolves10.1021/jo971910a

Rhodium-Catalyzed Insertion of Carbenoids into β C−H Bonds of Silacycloalkanes: A Facile and General Approach to Functionalized Silacycloalkanes

resolves10.1021/ol0167255

Catalytic Asymmetric Allylic C−H Activation as a Surrogate of the Asymmetric Claisen Rearrangement

resolves10.1016/S0040-4039(02)00956-5

Catalytic asymmetric C–H activation by methyl thiophen-3-yldiazoacetate applied to the synthesis of (+)-cetiedil

resolves10.1021/ol9905699

Catalytic Asymmetric Synthesis of Diarylacetates and 4,4-Diarylbutanoates. A Formal Asymmetric Synthesis of (+)-Sertraline

resolves10.1016/S0040-4039(02)00941-3

Asymmetric synthesis of (+)-indatraline using rhodium-catalyzed C–H activation

resolves10.1021/jo016351t

Catalytic Asymmetric Benzylic C−H Activation by Means of Carbenoid-Induced C−H Insertions

resolves10.1016/S0957-4166(03)00154-X

Intermolecular C–H activation at benzylic positions: synthesis of (+)-imperanene and (−)-α-conidendrin

resolves10.1021/ja9910715

Highly Regio-, Diastereo-, and Enantioselective C−H Insertions of Methyl Aryldiazoacetates into Cyclic N-Boc-Protected Amines. Asymmetric Synthesis of Novel C2-Symmetric Amines and threo-Methylphenidate

resolves10.1002/1521-3773(20020617)41:12<2197::AID-ANIE2197>3.0.CO;2-N

Catalytic Enantioselective Synthesis of β2-Amino Acids This work was supported by the National Science Foundation (CHE 0092490) and the National Institutes of Health (GM57425).

resolves10.1021/ol015974q

Kinetic Resolution and Double Stereodifferentiation in Catalytic Asymmetric C−H Activation of 2-Substituted Pyrrolidines

resolves10.1021/ol9905809

Catalytic Asymmetric Synthesis ofSyn-Aldol Products from Intermolecular C−H Insertions between Allyl Silyl Ethers and Methyl Aryldiazoacetates

resolves10.1021/ol006671j

Asymmetric Catalytic C−H Activation Applied to the Synthesis of Syn-Aldol Products

resolves10.1016/S0040-4039(00)95992-6

Tandem cyclopropanation/Cope rearrangement sequence. Stereospecific [3 + 4] cycloaddition reaction of vinylcarbenoids with cyclopentadiene

resolves10.1016/0040-4039(88)85312-7

Novel approach to seven-membered rings by the intramolecular tandem cyclopropanation/cope rearrangement sequence

resolves10.1021/jo00265a037

Scope and stereochemistry of the tandem intramolecular cyclopropanation/Cope rearrangement sequence

resolves10.1021/jo00012a011

Stereoselective synthesis of seven-membered carbocycles by a tandem cyclopropanation/Cope rearrangement between rhodium(II)-stabilized vinylcarbenoids and dienes

resolves10.1021/ja974201n

Tandem Asymmetric Cyclopropanation/Cope Rearrangement. A Highly Diastereoselective and Enantioselective Method for the Construction of 1,4-Cycloheptadienes

resolves10.1021/ja016928o

A Stable Dirhodium Tetracarboxylate Carbenoid: Crystal Structure, Bonding Analysis, and Catalysis

resolves10.1021/ja961806v

Saturation Kinetics in Dirhodium(II) Carboxylate-Catalyzed Decompositions of Diazo Compounds

resolves10.1016/0040-4020(89)80034-1

Kinetics of the dirhodium tetraacetate catalyzed decomposition of ethyl diazoacetate in 1,4-dioxane. Is nitrogen involved in the transition state?

resolves10.1021/jo9803434

Rhodium-Mediated Intramolecular C−H Insertion: Probing the Geometry of the Transition State

resolves10.1021/jo0107352

A Kinetic Study on the Pairwise Competition Reaction of α-Diazo Esters with Rhodium(II) Catalysts: Implication for the Mechanism of Rh(II)-Carbene Transfer

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