Reference health

On the Mechanism of the Initiation Reaction in Grubbs–Hoveyda Complexes

https://doi.org/10.1021/ja208967h
CiteStamped reference-health badge
79/79 checkable references clean · checked 2026-07-23

Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.

8 without a DOI — not checked. A reference deposited without a DOI is never matched by title or guessed at; it stays outside the checked set, and this line discloses that.

The 79 checked references that resolve
resolves10.1038/nature06351
The remarkable metal-catalysed olefin metathesis reaction
resolves10.1016/j.polymer.2010.05.002
The ROMP toolbox upgraded
resolves10.1002/marc.200400150
The Ring Opening Metathesis Polymerisation Toolbox
resolves10.1039/B924852H
Acyclic dienemetathesis: a versatile tool for the construction of defined polymer architectures
resolves10.1039/b912410c
Chemoselective olefin metathesis transformations mediated by ruthenium complexes
resolves10.1073/pnas.1000313107
Cross-metathesis–based approaches to heteroaromatics: Combining catalysts for furan formation
resolves10.1002/anie.200904491
Catalytic Enantioselective Olefin Metathesis in Natural Product Synthesis. Chiral Metal‐Based Complexes that Deliver High Enantioselectivity and More
resolves10.1039/c1cc10464k
Metathesis in total synthesis
resolves10.1002/macp.200900168
Metathesis with Oleochemicals: New Approaches for the Utilization of Plant Oils as Renewable Resources in Polymer Science
resolves10.1002/cbic.200900002
Olefin Metathesis for Site‐Selective Protein Modification
resolves10.1021/op800225f
Second-Generation Process for the HCV Protease Inhibitor BILN 2061: A Greener Approach to Ru-Catalyzed Ring-Closing Metathesis
resolves10.1016/j.steroids.2011.04.002
Application of olefin metathesis in the synthesis of steroids
resolves10.1021/cr800502p
Recent Advances in High Oxidation State Mo and W Imido Alkylidene Chemistry
resolves10.1021/cr800524f
Ruthenium-Based Olefin Metathesis Catalysts Bearing <i>N</i>-Heterocyclic Carbene Ligands
resolves10.1021/cr9002424
Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts
resolves10.1021/ja010624k
Mechanism and Activity of Ruthenium Olefin Metathesis Catalysts
resolves10.1021/ja027472t
Synthesis, Structure, and Activity of Enhanced Initiators for Olefin Metathesis
resolves10.1002/1521-3773(20010105)40:1<247::AID-ANIE247>3.0.CO;2-4
Highly Active Metathesis Catalysts Generated In Situ from Inexpensive and Air-Stable Precursors
resolves10.1002/chem.200903275
[(NHC)(NHC<sub>ewg</sub>)RuCl<sub>2</sub>(CHPh)] Complexes with Modified NHC<sub>ewg</sub> Ligands for Efficient Ring‐Closing Metathesis Leading to Tetrasubstituted Olefins
resolves10.1002/anie.200900935
An [(NHC)(NHC<sub>EWG</sub>)RuCl<sub>2</sub>(CHPh)] Complex for the Efficient Formation of Sterically Hindered Olefins by Ring‐Closing Metathesis
resolves10.1021/om1002717
Synthesis and RCM Activity of [(NHC)(NHC<sub>ewg</sub>)RuCl<sub>2</sub>(3-phenylindenylid-1-ene)] Complexes
resolves10.1016/j.jorganchem.2010.07.014
Facile synthesis of [(NHC)(NHCewg)RuCl2(CHPh)] complexes
resolves10.1002/ange.200461374
Rapidly Initiating Ruthenium Olefin‐Metathesis Catalysts
resolves10.1021/ja042259d
Direct Observation of a 14-Electron Ruthenacyclobutane Relevant to Olefin Metathesis
resolves10.1021/ja0666598
Ruthenium Metallacycles Derived from 14-Electron Complexes. New Insights into Olefin Metathesis Intermediates
resolves10.1021/ja0675245
Mechanistic Studies on 14-Electron Ruthenacyclobutanes:  Degenerate Exchange with Free Ethylene
resolves10.1021/ja710364e
Generation and Spectroscopic Characterization of Ruthenacyclobutane and Ruthenium Olefin Carbene Intermediates Relevant to Ring Closing Metathesis Catalysis
resolves10.1021/om8008519
DFT Study of the Isomerization and Spectroscopic/Structural Properties of Ruthenacyclobutane Intermediates Relevant to Olefin Metathesis
resolves10.1021/ja2009746
Characterization and Dynamics of Substituted Ruthenacyclobutanes Relevant to the Olefin Cross-Metathesis Reaction
resolves10.1038/nchem.653
Mechanistic insights into the ruthenium-catalysed diene ring-closing metathesis reaction
resolves10.1002/chem.200701340
In an Attempt to Provide a User's Guide to the Galaxy of Benzylidene, Alkoxybenzylidene, and Indenylidene Ruthenium Olefin Metathesis Catalysts
resolves10.1002/ejic.200900526
The Versatile Alkylidene Moiety in Ruthenium Olefin Metathesis Catalysts
resolves10.1002/chem.200903457
Studies on Electronic Effects in O‐, N‐ and S‐Chelated Ruthenium Olefin‐Metathesis Catalysts
resolves10.1021/ja048794v
Nitro-Substituted Hoveyda−Grubbs Ruthenium Carbenes:  Enhancement of Catalyst Activity through Electronic Activation
resolves10.1016/j.molcata.2005.12.049
New tunable catalysts for olefin metathesis: Controlling the initiation through electronic factors
resolves10.1002/anie.200250632
Controlled Living Ring‐Opening‐Metathesis Polymerization by a Fast‐Initiating Ruthenium Catalyst
resolves10.1039/b902345n
Latent olefin metathesis catalysts
resolves10.1002/masy.200900036
Latent and Switchable Olefin Metathesis Catalysts
resolves10.1002/pola.22083
Ruthenium quinoline and quinoxaline complexes: Thermally triggered initiators for ring opening metathesis polymerization
resolves10.1021/om0493210
Latent Ruthenium Olefin Metathesis Catalysts That Contain an N-Heterocyclic Carbene Ligand
resolves10.1021/ja983222u
A Recyclable Ru-Based Metathesis Catalyst
resolves10.1021/ja001179g
Efficient and Recyclable Monomeric and Dendritic Ru-Based Metathesis Catalysts
resolves10.1016/S0040-4039(00)01808-6
Synthesis and metathesis reactions of a phosphine-free dihydroimidazole carbene ruthenium complex
resolves10.1039/b311496c
Ru complexes bearing bidentate carbenes: from innocent curiosity to uniquely effective catalysts for olefin metathesis
resolves10.1021/ja903554v
Impact of NHC Ligand Conformation and Solvent Concentration on the Ruthenium-Catalyzed Ring-Closing Metathesis Reaction
resolves10.1021/ja900067c
Effects of NHC-Backbone Substitution on Efficiency in Ruthenium-Based Olefin Metathesis
resolves10.1021/cr800541y
Equilibrium Ring-Closing Metathesis
resolves10.1002/anie.201000581
Probing the Mechanism of Olefin Metathesis in Grubbs–Hoveyda and Grela Type Complexes
resolves10.1002/chem.201001832
How Important Is the Release–Return Mechanism in Olefin Metathesis?
resolves10.1016/S0040-4020(03)01029-9
Ruthenium olefin metathesis catalysts with modified styrene ethers: influence of steric and electronic effects
resolves10.1002/1521-3773(20021104)41:21<4038::AID-ANIE4038>3.0.CO;2-0
A Highly Efficient Ruthenium Catalyst for Metathesis Reactions
resolves10.1021/jo049222w
Ortho- and Para-Substituted Hoveyda−Grubbs Carbenes. An Improved Synthesis of Highly Efficient Metathesis Initiators
resolves10.1021/ja063186w
Advanced Fine-Tuning of Grubbs/Hoveyda Olefin Metathesis Catalysts:  A Further Step toward an Optimum Balance between Antinomic Properties
resolves10.1002/adsc.200600478
Probing of the Ligand Anatomy: Effects of the Chelating Alkoxy Ligand Modifications on the Structure and Catalytic Activity of Ruthenium Carbene Complexes
resolves10.1002/chem.200800704
Is the Hoveyda–Grubbs Complex a Vinylogous Fischer‐Type Carbene? Aromaticity‐Controlled Activity of Ruthenium Metathesis Catalysts
resolves10.1002/chem.200903525
DFT Mechanistic Study on Diene Metathesis Catalyzed by Ru‐Based Grubbs–Hoveyda‐Type Carbenes: The Key Role of π‐Electron Density Delocalization in the Hoveyda Ligand
resolves10.1002/chem.201003410
Mechanistic Insights into Ring‐Closing Enyne Metathesis with the Second‐Generation Grubbs–Hoveyda Catalyst: A DFT Study
resolves10.1002/chem.200800470
Ruthenium‐Based Olefin Metathesis Catalysts Coordinated with Unsymmetrical N‐Heterocyclic Carbene Ligands: Synthesis, Structure, and Catalytic Activity
resolves10.1039/C1CC11230A
What is the initiation step of the Grubbs-Hoveyda olefinmetathesiscatalyst?
resolves10.1002/anie.200502182
Redox‐Switchable Phase Tags for Recycling of Homogeneous Catalysts
resolves10.1021/cr00002a004
A survey of Hammett substituent constants and resonance and field parameters
resolves10.1039/b512008j
π-Face donor properties of N-heterocyclic carbenes
resolves10.1002/chem.200800139
π‐Face Donor Properties of N‐Heterocyclic Carbenes in Grubbs II Complexes
resolves10.1021/om1004226
Differentially Substituted Acyclic Diaminocarbene Ligands Display Conformation-Dependent Donicities
resolves10.1016/j.jorganchem.2008.12.047
Synthesis of (NHC)Rh(cod)Cl and (NHC)RhCl(CO)2 complexes – Translation of the Rh- into the Ir-scale for the electronic properties of NHC ligands
resolves10.1002/(SICI)1521-3765(19990201)5:2<557::AID-CHEM557>3.0.CO;2-A
The First Grubbs-Type Metathesis Catalyst withcis Stereochemistry: Synthesis of [(η2-dtbpm)Cl2Ru=CH−CH=CMe2] from a Novel, Coordinatively Unsaturated Dinuclear Ruthenium Dihydride
resolves10.1021/ja0747674
An Electronic Rationale for Observed Initiation Rates in Ruthenium-Mediated Olefin Metathesis:  Charge Donation in Phosphine and N-Heterocyclic Carbene Ligands
resolves10.1002/3527600825
Kinetics and Mechanism of Reactions of Transition Metal Complexes
resolves10.1021/ja0305757
Mechanism and Activity of Ruthenium Olefin Metathesis Catalysts:  The Role of Ligands and Substrates from a Theoretical Perspective
resolves10.1021/om200463u
Rational Design and Evaluation of Upgraded Grubbs/Hoveyda Olefin Metathesis Catalysts: Polyfunctional Benzylidene Ethers on the Test Bench
resolves10.1021/ja0618090
Model Compounds of Ruthenium−Alkene Intermediates in Olefin Metathesis Reactions
resolves10.1021/ja8078913
Conformations of N-Heterocyclic Carbene Ligands in Ruthenium Complexes Relevant to Olefin Metathesis
resolves10.1002/adsc.200600465
Ligand Influence on Metathesis Activity of Ruthenium Carbene Catalysts: A DFT Study
resolves10.1021/ja064924j
The Elusive Mechanism of Olefin Metathesis Promoted by (NHC)Ru-Based Catalysts:  A Trade between Steric, Electronic, and Solvent Effects
resolves10.1021/ic00248a036
Dissociative substitution in four-coordinate planar platinum(II) complexes. 2. Crystal structure of cis-diphenylbis(dimethyl sulfide)platinum(II) and kinetics of thioether displacement by bidentate ligands in benzene
resolves10.1002/anie.200501114
Origin of the High Activity of Second‐Generation Grubbs Catalysts
resolves10.1021/ja060832i
Quantitative Structure−Activity Relationships of Ruthenium Catalysts for Olefin Metathesis
resolves10.1002/ejoc.200390151
A Good Bargain: An Inexpensive, Air‐Stable Ruthenium Metathesis Catalyst Derived from α‐Asarone
resolves10.1002/chem.200305747
Factors Relevant for the Ruthenium–Benzylidene‐Catalyzed Cyclopolymerization of 1,6‐Heptadyines
The 8 references without a DOI — listed, not checked
no DOI — not checkedref2/cit2d
no DOI — not checkedref13/cit13d
no DOI — not checkedref18/cit18b
no DOI — not checkedref19/cit19c
no DOI — not checkedDoppiu, A.; Winde, R.; Wörner, E.; Rivas-Nass, A.; Slugovc, C.; Lexer, C.Method for preparation of ruthenium-based metathesis catalyst with chelating alkylidene ligand. Patent WO 2010/127829, November 11, 2010.
no DOI — not checkedModern Physical Organic Chemistry
no DOI — not checkedref50/cit50b
no DOI — not checkedPhysikalische Chemie
What this badge says. CiteStamped means the CHECKABLE references of this work were clean at the dated check: each resolved to a known work in a public registry, and none carried a retraction notice at that time. It says nothing about the quality, findings, or importance of the work itself, and nothing about references deposited without a DOI.

checked 2026-07-23 — re-checked daily as this page is visited; titles and statuses come from Crossref and DataCite and are not part of the signed record

Embed this badge

Both snippets point at the live badge image and link back to this page. The badge re-renders from the daily check, so an embed never goes stale by more than a day of visits.

<a href="https://citestamp.com/citestamped/10.1021/ja208967h"><img src="https://citestamp.com/citestamped/10.1021/ja208967h/badge.svg" alt="CiteStamped reference-health badge" width="460" height="64"></a>
[![CiteStamped reference-health badge](https://citestamp.com/citestamped/10.1021/ja208967h/badge.svg)](https://citestamp.com/citestamped/10.1021/ja208967h)