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Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

38/38 checkable references clean · checked 2026-07-23

Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.

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The 38 checked references that resolve

resolves10.1002/adsc.200303094

Catalytic Methods for CH Bond Functionalization: Application in Organic Synthesis

resolves10.1055/s-2006-956468

Regioselective Functionalization of Unreactive Carbon-Hydrogen Bonds

resolves10.1039/b606984n

Direct transition metal-catalyzed functionalization of heteroaromatic compounds

resolves10.1021/cr0509760

Aryl−Aryl Bond Formation by Transition-Metal-Catalyzed Direct Arylation

resolves10.1021/ja060809x

Room Temperature Palladium-Catalyzed 2-Arylation of Indoles

resolves10.1021/ja051402f

Oxidative C−H Activation/C−C Bond Forming Reactions: Synthetic Scope and Mechanistic Insights

resolves10.1021/ol053021c

Catalytic C−H Arylation of SEM-Protected Azoles with Palladium Complexes of NHCs and Phosphines

resolves10.1021/ol070697u

Direct Pd-Catalyzed Arylation of 1,2,3-Triazoles

resolves10.1021/ja062509l

Catalytic Intermolecular Direct Arylation of Perfluorobenzenes

resolves10.1021/ja055819x

Catalytic Direct Arylation with Aryl Chlorides, Bromides, and Iodides: Intramolecular Studies Leading to New Intermolecular Reactions

resolves10.1021/ja056165v

Proton Abstraction Mechanism for the Palladium-Catalyzed Intramolecular Arylation

resolves10.1002/anie.200500589

Anilide ortho‐Arylation by Using CH Activation Methodology

resolves10.1021/ol0619866

ortho-Arylation of Benzamides

resolves10.1002/anie.200700590

Suzuki–Miyaura Coupling Reaction by PdII‐Catalyzed Aromatic CH Bond Activation Directed by an N‐Alkyl Acetamino Group

resolves10.1021/ja7107068

C2, C5, and C4 Azole N-Oxide Direct Arylation Including Room-Temperature Reactions

resolves10.1021/ja0748985

Rh(I)-Catalyzed Arylation of Heterocycles via C−H Bond Activation: Expanded Scope through Mechanistic Insight

resolves10.1021/ja050279p

Direct C-Arylation of Free (NH)-Indoles and Pyrroles Catalyzed by Ar−Rh(III) Complexes Assembled In Situ

resolves10.1021/ja064500p

Direct C−H Arylation of (Hetero)arenes with Aryl Iodides via Rhodium Catalysis

resolves10.1002/anie.200504450

Catalytic Arylation Reactions by CH Bond Activation with Aryl Tosylates

resolves10.1021/ja077862l

Copper-Catalyzed Arylation and Alkenylation of Polyfluoroarene C−H Bonds

resolves10.1021/ja0259279

Palladium-Catalyzed Multiple Arylation of Thiophenes

resolves10.1246/bcsj.71.467

Palladium-Catalyzed Arylation of Azole Compounds with Aryl Halides in the Presence of Alkali Metal Carbonates and the Use of Copper Iodide in the Reaction

resolves10.1021/ja043273t

Direct Palladium-Catalyzed C-2 and C-3 Arylation of Indoles: A Mechanistic Rationale for Regioselectivity

resolves10.1021/ol049866q

Palladium-Catalyzed Arylation and Heteroarylation of Indolizines

resolves10.1021/ol027266q

Regioselective Palladium-Catalyzed Arylation of 3-Carboalkoxy Furan and Thiophene

resolves10.1021/ja071034a

Proton-Abstraction Mechanism in the Palladium-Catalyzed Intramolecular Arylation: Substituent Effects

resolves10.1021/ja710276x

Direct Arylation of Arene C−H Bonds by Cooperative Action of NHCarbene−Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism

resolves10.1021/ol800773x

Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents

resolves10.1021/ja060173+

Electrophilic C−H Activation at {Cp*Ir}: Ancillary-Ligand Control of the Mechanism of C−H Activation

resolves10.3987/COM-91-S29

Palladium-catalyzed Cross-coupling Ractions of Chloropyrazines with Aromatic Heterocycles

resolves10.1021/ol035878k

Palladium-Catalyzed Regioselective Arylation of Imidazo[1,2-a]pyrimidine

resolves10.1021/ol0619967

Mild and General Conditions for the Cross-Coupling of Aryl Halides with Pentafluorobenzene and Other Perfluoroaromatics

resolves10.1021/ja067144j

Palladium-Catalyzed Benzene Arylation: Incorporation of Catalytic Pivalic Acid as a Proton Shuttle and a Key Element in Catalyst Design

resolves10.1063/1.464913

Density-functional thermochemistry. III. The role of exact exchange

resolves10.1103/PhysRevB.37.785

Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density

resolves10.1021/ed080p679

The Anomalous Reactivity of Fluorobenzene in Electrophilic Aromatic Substitution and Related Phenomena

resolves10.1021/ja075785o

Origin of Regioselectivity in Palladium-Catalyzed Cross-Coupling Reactions of Polyhalogenated Heterocycles

resolves10.1016/0009-2614(83)80005-0

Charge, bond order and valence in the AB initio SCF theory

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