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A Mixed-Valence V<sup>IV</sup>/V<sup>V</sup> Alkoxo-polyoxovanadium Cluster Series [V<sub>6</sub>O<sub>8</sub>(OCH<sub>3</sub>)<sub>11</sub>]<sup><i>n</i>+/−</sup>: Exploring the Influence of a μ-Oxo Ligand in a Spin Frustrated Structure
51/51 checkable references clean · checked 2026-07-23
Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.
21 without a DOI — not checked. A reference deposited without a DOI is never matched by title or guessed at; it stays outside the checked set, and this line discloses that.
The 51 checked references that resolve
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Present General Status of Understanding of Heteropoly Electrolytes and a Tracing of Some Major Highlights in the History of Their Elucidation
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Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines
resolves10.1021/cr960393d
Main-Group Element, Organic, and Organometallic Derivatives of Polyoxometalates
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The First “Vanadate Hexamer” Capped by Four Pentamethylcyclopentadienyl-rhodium or -iridium Groups
resolves10.1021/ic00005a028
Site-selective oxygen exchange and substitution of organometallic groups in an amphiphilic quadruple-cubane-type cluster. Synthesis and molecular structure of [(MCp*)4V6O19] (M = rhodium, iridium)
resolves10.1021/ic00333a003
Crystal structure of lithium niobium ethoxide (LiNb(OCH2CH3)6: a precursor for lithium niobate ceramics
resolves10.1021/ic00035a007
Hexavanadium polyoxoalkoxide anion clusters: structures of the mixed-valence species (Me3NH)[VIV5VVO7(OH)3{CH3C(CH2O)3}3] and of the reduced complex Na2[VIV6O7{CH3CH2C(CH2O)3}4]
resolves10.1021/ja00038a033
Coordination compounds of polyoxovanadates with a hexametalate core. Chemical and structural characterization of [VV6O13[(OCH2)3CR]2]2-, [VV6O11(OH)2[(OCH2)3CR]2], [VIV4VV2O9(OH)4[(OCH2)3CR]2]2-, and [VIV6O7(OH)6](OCH2)3CR]2]2-
resolves10.1021/ic00065a022
Hydrothermal synthesis and characterization of hexavanadium polyoxo alkoxide anion clusters: crystal structures of the vanadium(IV) species Ba[V6O7(OH)3{(OCH2)3CCH3}3].3H2O and Na2[V6O7{(OCH2)3CCH2CH3}4], of the mixed-valence complex (Me3NH)[VIV5VVO7(OH)3{(OCH2)3CCH3}3], and of the fluoro derivative Na[V6O6F(OH)3{(OCH2)3CCH3}3].3H2O
resolves10.1016/S0020-1693(00)85590-5
Synthesis and characterization of a polyvanadate polyester involving a monodentate alcohol, [(n-C4H9)4N][V6O12(OCH3)7]
resolves10.1002/zaac.19956211103
Cis‐/Trans‐Isomerie bei Bis‐(trisalkoxy)‐hexavanadaten: cis‐Na<sub>2</sub>[VO<sub>7</sub>(OH)<sub>6</sub>{(OCH<sub>2</sub>)<sub>3</sub>CCH<sub>2</sub>OH}<sub>2</sub>] · 8 H<sub>2</sub>O, cis‐(CN<sub>3</sub>H<sub>6</sub>)<sub>3</sub>[V<sup>IV</sup>VO<sub>13</sub>{(OCH<sub>2</sub>)<sub>3</sub>CCH<sub>2</sub>OH}<sub>2</sub>] · 4,5 H<sub>2</sub>O und trans‐(CN<sub>3</sub>H<sub>6</sub>)<sub>2</sub>[VO<sub>13</sub>{(OCH<sub>2</sub>)<sub>3</sub>CCH<sub>2</sub>OH}<sub>2</sub>] · H<sub>2</sub>O
resolves10.1002/1521-3773(20020715)41:14<2523::AID-ANIE2523>3.0.CO;2-#
Bridging the Gap between Polyoxometalates and Classic Coordination Compounds: A Novel Type of Hexavanadate Complex
resolves10.1002/anie.200390306
Synthesis and Structural Characterization of Redox‐Active Dodecamethoxoheptaoxohexavanadium Clusters
resolves10.1021/ja052902b
Neutral and Cationic V<sup>IV</sup>/V<sup>V</sup> Mixed-Valence Alkoxo-polyoxovanadium Clusters [V<sub>6</sub>O<sub>7</sub>(OR)<sub>12</sub>]<i><sup>n</sup></i><i><sup>+</sup></i> (R = −CH<sub>3</sub>, −C<sub>2</sub>H<sub>5</sub>): Structural, Cyclovoltammetric and IR-Spectroscopic Investigations on Mixed Valency in a Hexanuclear Core
resolves10.1016/S1387-7003(00)00050-2
The mystery of VO(OEt)3 conversion on microhydrolysis disclosed: the X-ray single crystal study of V6O7(OEt)12
resolves10.1039/b412427h
EPR study of the magnetic states of a mixed-valence VIV4VV2 alkoxypolyoxovanadium cluster
resolves10.1021/ic7006974
Exchange Interactions and Electron Delocalization in the Mixed-Valence Cluster V<sub>4</sub><sup>IV</sup>V<sub>2</sub><sup>V</sup>O<sub>7</sub>(OC<sub>2</sub>H<sub>5</sub>)<sub>12</sub>
resolves10.1016/S1387-3806(03)00236-7
Ion chemistry of the hexanuclear methoxo-oxovanadium cluster V6O7(OCH3)12
resolves10.1002/cphc.200700255
Gas‐Phase Infrared Photodissociation Spectroscopy of Tetravanadiumoxo and Oxo–Methoxo Cluster Anions
resolves10.1002/anie.200600045
Gas‐Phase Oxidation of Propane and 1‐Butene with [V<sub>3</sub>O<sub>7</sub>]<sup>+</sup>: Experiment and Theory in Concert
resolves10.1002/anie.200600188
Thermal Activation of Methane by Tetranuclear [V<sub>4</sub>O<sub>10</sub>]<sup>+</sup>
resolves10.1021/jp067454o
Dehydrogenation of Methanol by Vanadium Oxide and Hydroxide Cluster Cations in the Gas Phase
resolves10.1002/zaac.19130820109
Über Vanadinsäureester und einige andere organische Vanadinverbindungen
resolves10.1107/S0021889899006020
<i>WinGX</i>suite for small-molecule single-crystal crystallography
resolves10.1351/pac198456040461
Recommendations on reporting electrode potentials in nonaqueous solvents (Recommendations 1983)
resolves10.1002/anie.198408313
Cyclic Voltammetry—“Electrochemical Spectroscopy”. New Analytical Methods (25)
resolves10.1021/ja00524a048
An electrochemical method for measuring electronic delocalization in mixed-valent species
resolves10.1021/ic9605938
Tetranuclear and Pentanuclear Vanadium(IV/V) Carboxylate Complexes: [V<sub>4</sub>O<sub>8</sub>(NO<sub>3</sub>)(O<sub>2</sub>CR)<sub>4</sub>]<sup>2-</sup> and [V<sub>5</sub>O<sub>9</sub>X(O<sub>2</sub>CR)<sub>4</sub>]<sup>2-</sup> (X = Cl<sup>-</sup>, Br<sup>-</sup>) Salts
resolves10.1021/ic00020a035
Synthesis and spectroscopic and magnetic properties of a unique diamagnetic binuclear .mu.-oxo vanadium(IV) complex. Crystal structure of [(tpa)VO(.mu.-O)VO(tpa)](ClO4)2 (tpa = tris(2-pyridylmethyl)amine)
resolves10.1016/S0009-2614(96)01424-8
Competing spin interactions and degenerate frustration for discrete molecular species
resolves10.1021/ic00018a019
Preparation and properties of models for the photosynthetic water oxidation center: spin frustration in the manganese [Mn4O2(O2CR)7(pic)2]- anion
resolves10.1021/ic0010555
Two New Mixed-Valence Manganese Complexes of Formula [Mn<sub>4</sub>O<sub>2</sub>(X-benzoato)<sub>7</sub>(bpy)<sub>2</sub>] (X = 2-Cl, 2-Br) and the Crystal Structure of the 2-Cl Complex: Ground-State Spin Variability in the [Mn<sub>4</sub>O<sub>2</sub>]<sup>7+</sup>Complexes
resolves10.1021/ic00131a007
Vibrational investigations of polyoxometallates. 1. Valence force field of Mo6O192- based on total isotopic substitution (oxygen-18, molybdenum-92, molybdenum-100)
resolves10.1021/ic0260567
Electronic Structure of Oxovanadium(IV) Complexes of α-Hydroxycarboxylic Acids
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no DOI — not checkedbPope, M. T.InComprehensive Coordination Chemistry II;McCleverty, J. A. and Meyer, T. J., Eds.Elsevier:Oxford 2004; Vol. 4, pp635−678
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no DOI — not checkedPolyoxometalate Chemistry: From Topology via Self-Assembly to Applications
no DOI — not checkedCatalysis by Polyoxometalates
no DOI — not checkedbHill, C. L.InComprehensive Coordination Chemistry II;McCleverty, J. A. and Meyer, T. J., Eds.Elsevier:Oxford 2004; Vol. 4, pp679−759
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no DOI — not checkedSpeiser, B.InEncyclopedia of Electrochemistry;Bard, A. J. and Stratmann, M., Eds.Wiley-VCH:Weinheim, 2003; Vol. 3, pp81−104
no DOI — not checkedbCrutchley, R. J.InComprehensive Coordination Chemistry II;McCleverty, J. A. and Meyer, T. J., Eds.Elsevier:Oxford, 2004; Vol. 2, pp235−244
no DOI — not checkedaKahn, O.Molecular Magnetism;VCH:Weinheim, 1993; pp241−248
no DOI — not checkedLever, A. B. P.Inorganic Electronic Spectroscopy;Elsevier:Amsterdam 1984, 388.
no DOI — not checkedaHush, N. S.InMixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology, and Biology;Brown, D. B., Ed.D. Reidel Publishing Company:Dordrecht, 1980; pp151−188
no DOI — not checkedbSchatz, P. N.InInorganic Electronic Structure and Spectroscopy;Solomon, E. I. and Lever, A. B. P., Eds.John Wiley & Sons:New York, 1999; Vol. 2, pp175−226and references therein.
no DOI — not checkeddHupp, J. T.InComprehensive Coordination Chemistry II;McCleverty, J. A. and Meyer, T. J., Eds.Elsevier:Oxford 2004; Vol. 2, pp709−716and references therein.
no DOI — not checkedDay, P.InMixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology, and Biology;Brown, D. B., Ed.D. Riedel Publishing Company:Dordrecht, 1980; p16−17
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