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Enantioselective Insertion of Alkynyl Carbenes into Si–H Bonds: An Efficient Access to Chiral Propargylsilanes and Allenylsilanes

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Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.

The 45 checked references that resolve

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Silicon-Containing Polymers

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Asymmetric synthesis of stereodefined α-alkyl-γ-benzyloxymethyl-β-trimethylsilyl-γ-butyrolactones that serve as an efficient precursor for constructing carbon skeletons having a tertiary or quaternary stereogenic center

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Synthesis and [4 + 2]-Annulation of Enantioenriched (Z)-Crotylsilanes: Preparation of the C1−C13 Fragment of Bistramide A

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Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses

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Enantioselective Total Syntheses of the 5,11-Methanomorphanthridine Amaryllidaceae Alkaloids (−)-Pancracine and (−)-Coccinine

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Optically Active Allenes from β-Lactone Templates: Asymmetric Total Synthesis of (−)-Malyngolide

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Crotylation versus Propargylation: Two Routes for the Synthesis of the C13−C18 Fragment of the Antibiotic Branimycin

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Silyl-Substituted Spirodiepoxides: Stereoselective Formation and Regioselective Opening

resolves10.1016/S0040-4039(97)00762-4

1,3-Asymmetric induction in retro-[1,4]-brook rearrangements of propargyllithium compounds to propargylsilanes

resolves10.1021/ja9737937

Stereospecific Cationic [1,2] Silyl Shift with Retention of Configuration at the Migrating Terminus

resolves10.1021/jo00370a006

Asymmetric synthesis catalyzed by chiral ferrocenylphosphine-transition metal complexes. 3. Preparation of optically active allylsilanes by palladium-catalyzed asymmetric Grignard cross-coupling

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Enantio- and Diastereoselective Tandem Zn-Promoted Brook Rearrangement/Ene−Allene Carbocyclization Reaction

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Enantioselective Synthesis of Alkyne-Substituted Quaternary Carbon Stereogenic Centers through NHC−Cu-Catalyzed Allylic Substitution Reactions with (i-Bu)2(Alkynyl)aluminum Reagents

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A general asymmetric copper-catalysed Sonogashira C(sp3)–C(sp) coupling

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Enantioselective Synthesis of α-Chiral Propargylic Silanes by Copper-Catalyzed 1,4-Selective Addition of Silicon Nucleophiles to Enyne-Type α,β,γ,δ-Unsaturated Acceptors

resolves10.1016/S0040-4039(00)88286-6

The stereochemistry of some SE2′ reactions of allyl- and allenylsilanes

resolves10.1021/ja017138h

Palladium-Catalyzed Asymmetric Hydrosilylation of 4-Substituted 1-Buten-3-ynes. Catalytic Asymmetric Synthesis of Axially Chiral Allenylsilanes

resolves10.1021/ja1066509

Rhodium-Catalyzed Enantioselective 1,6-Addition of Arylboronic Acids to Enynamides: Asymmetric Synthesis of Axially Chiral Allenylsilanes

resolves10.1021/ol2031119

Asymmetric Synthesis of Trisubstituted Allenes: Copper-Catalyzed Alkylation and Arylation of Propargylic Phosphates

resolves10.1002/anie.201908343

Copper‐Catalyzed Asymmetric Silylation of Propargyl Dichlorides: Access to Enantioenriched Functionalized Allenylsilanes

resolves10.1021/ar300051u

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

resolves10.1021/acs.chemrev.5b00121

Modern Organic Synthesis with α-Diazocarbonyl Compounds

resolves10.1016/S0040-4039(00)01453-2

Asymmetric synthesis of 1-alkynylcyclopropane-1-carboxylates

resolves10.1021/acs.orglett.6b02264

Rhodium(II)-Alkynyl Carbenoids Insertion into Si–H bonds: An Entry to Propargylic Geminal Bis(silanes)

resolves10.1039/C6CC09650F

Silver( <scp>i</scp> )-promoted insertion into X–H (X = Si, Sn, and Ge) bonds with N-nosylhydrazones

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Asymmetric Multicomponent Reactions for Efficient Construction of Homopropargyl Amine Carboxylic Esters

resolves10.1039/c39780000726

Synthesis of allenes via reduction of acetylenic tosylhydrazones

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Reactive Carbon-Chain Molecules: Synthesis of 1-Diazo-2,4-pentadiyne and Spectroscopic Characterization of Triplet Pentadiynylidene (H−C⋮C−C̈−C⋮C−H)

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Triplet 1,3-Diphenylpropynylidene (Ph−C−C−C−Ph)

resolves10.1021/jacs.0c04725

Enantioselective Diarylcarbene Insertion into Si–H Bonds Induced by Electronic Properties of the Carbenes

resolves10.1039/C7OB00807D

Recent progress in the catalytic carbene insertion reactions into the silicon–hydrogen bond

resolves10.1002/anie.200803192

Copper‐Catalyzed Highly Enantioselective Carbenoid Insertion into SiH Bonds

resolves10.1021/ja100833h

Iridium(III)-Catalyzed Enantioselective Si−H Bond Insertion and Formation of an Enantioenriched Silicon Center

resolves10.1021/jacs.5b12960

Rhodium(I)-Catalyzed Highly Enantioselective Insertion of Carbenoid into Si–H: Efficient Access to Functional Chiral Silanes

resolves10.1002/anie.201511954

Copper‐Catalyzed Insertion into Heteroatom–Hydrogen Bonds with Trifluorodiazoalkanes

resolves10.1021/acscatal.9b01187

Rhodium-Catalyzed Si–H Bond Insertion Reactions Using Functionalized Alkynes as Carbene Precursors

resolves10.1039/C4QO00208C

Conquering three-carbon axial chirality of allenes

resolves10.1039/C7CY01319A

Recent advances in catalytic asymmetric synthesis of allenes

resolves10.1002/anie.201303501

Combining NHC–Cu and Brønsted Base Catalysis: Enantioselective Allylic Substitution/Conjugate Additions with Alkynylaluminum Reagents and Stereospecific Isomerization of the Products to Trisubstituted Allenes

resolves10.1039/j19680000561

Reactions of tris(triphenylphosphine)platinum(o) and tetrakis(triphenylphosphine)palladium(o) with oxygen and carbon dioxide

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Oxygen Complexes of Zerovalent Nickel, Palladium, and Platinum

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