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The Importance of Kinetic and Thermodynamic Control when Assessing Mechanisms of Carboxylate-Assisted C–H Activation

https://doi.org/10.1021/jacs.9b02073
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The 52 checked references that resolve
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Rhodium-Catalyzed Annulation of Tertiary Aniline <i>N</i>-Oxides to <i>N</i>-Alkylindoles: Regioselective C–H Activation, Oxygen-Atom Transfer, and <i>N</i>-Dealkylative Cyclization
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Synthesis of 2,3-Disubstituted <i>NH</i> Indoles via Rhodium(III)-Catalyzed C–H Activation of Arylnitrones and Coupling with Diazo Compounds
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Proton-Abstraction Mechanism in the Palladium-Catalyzed Intramolecular Arylation:  Substituent Effects
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The Role of Fluorine Substituents in the Regioselectivity of Intramolecular C–H Bond Functionalization of Benzylamines at Palladium(II)
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Cyclometalation of Aryl‐Substituted Phosphinines through CH‐Bond Activation: A Mechanistic Investigation
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Theoretical Study on Iridacycle and Rhodacycle Formation via C–H Activation of Phenyl Imines
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Metal control of selectivity in acetate-assisted C–H bond activation: an experimental and computational study of heterocyclic, vinylic and phenylic C(sp <sup>2</sup> )–H bonds at Ir and Rh
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Rhodium(III)-Catalyzed Oxidative Coupling of 5-Aryl-1<i>H</i>-pyrazoles with Alkynes and Acrylates
resolves10.1021/ja402761p
Rhodium(III)-Catalyzed Indazole Synthesis by C–H Bond Functionalization and Cyclative Capture
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Rhodium(III)‐Catalyzed Synthesis of Cinnolinium Salts from Azobenzenes and Alkynes: Application to the Synthesis of Indoles and Cinnolines
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Synthesis and Anticancer Evaluation of 2,3‐Disubstituted Indoles Derived from Azobenzenes and Internal Olefins
resolves10.1002/adsc.201800326
Rhodium(III)‐Catalyzed Synthesis of Cinnolinium Salts from Azobenzenes and Diazo Compounds
resolves10.1021/ja103776u
Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H Activation
resolves10.1021/ja806955s
Indole Synthesis via Rhodium Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes
resolves10.1021/acs.organomet.6b00308
Nondirected C–H Activation of Arenes with Cp*Ir(III) Acetate Complexes: An Experimental and Computational Study
resolves10.1021/jacs.8b08150
Benzoate Cyclometalation Enables Oxidative Addition of Haloarenes at a Ru(II) Center
resolves10.1039/c0dt00280a
Alkyne insertion into cyclometallated pyrazole and imine complexes of iridium, rhodium and ruthenium; relevance to catalytic formation of carbo- and heterocycles
resolves10.1021/acscatal.7b00207
Cobalt(III)-Catalyzed Hydroarylation of Allenes via C–H Activation
resolves10.1021/jacs.5b04858
Experimental and DFT Studies Explain Solvent Control of C–H Activation and Product Selectivity in the Rh(III)-Catalyzed Formation of Neutral and Cationic Heterocycles
resolves10.1039/C7DT03525J
Chasing the agostic interaction in ligand assisted cyclometallation reactions of palladium( <scp>ii</scp> )
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On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition‐Metal Complexes
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Combined Experimental and Computational Investigations of Rhodium- and Ruthenium-Catalyzed C–H Functionalization of Pyrazoles with Alkynes
The 1 reference without a DOI — listed, not checked
no DOI — not checkedAdvanced Organic Chemistry
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