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Efficient Chemoselective Carboxylation of Aromatics to Arylcarboxylic Acids with a Superelectrophilically Activated Carbon Dioxide−Al<sub>2</sub>Cl<sub>6</sub>/Al System
Carboxylation of C−H Bonds Using <i>N</i>-Heterocyclic Carbene Gold(I) Complexes
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no DOI — not checkedref17/cit17
no DOI — not checkedBordwell pKatable, available athttp://www.chem.wisc.edu/areas/reich/pkatable/index.htm.
no DOI — not checkedSix of the seven commercial Cs2CO3tested mediated the carboxylation and gave reproducible results. The six sources are Aldrich (98% and 99.995%), Acros (99.5%), Alfa Aesar (99%), VWR (extra pure), and Chem-Impex (99.9%). Only the Cs2CO3from Alfa Aesar (99.994%) did not work. Control experiment showed that it is likely due to the fact that this Cs2CO3contains ca. 1 equiv of water, which inhibits the reaction. SeeSupporting Informationfor details.
no DOI — not checkedSeeSupporting Information.
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