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Rhodium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient Alkyne Hydrosilylation Catalysts
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Interplay of Linker,<i>N-</i>Substituent, and Counterion Effects in the Formation and Geometrical Distortion of<i>N-</i>Heterocyclic Biscarbene Complexes of Rhodium(I)
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Reactivity Differences in the Syntheses of Chelating N-Heterocyclic Carbene Complexes of Rhodium Are Ascribed to Ligand Anisotropy
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Preparation of Functionalized Imidazolium Salts under Microwave Irradiation
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C−H Oxidative Addition of Bisimidazolium Salts to Iridium and Rhodium Complexes, and N-Heterocyclic Carbene Generation. A Combined Experimental and Theoretical Study
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Synthesis and Catalytic Properties of Two Trinuclear Complexes of Rhodium and Iridium with the N-Heterocyclic Tris-carbene Ligand TIMEN<sup>iPr</sup>
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Dehydrogenative silation, isomerization and the control of syn- vs. anti-addition in the hydrosilation of alkynes
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Ruthenium-catalyzed hydrosilylation of terminal alkynes: stereodivergent synthesis of (E)- and (Z)-alkenylsilanes
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Reactions ofgem-Dibromo Compounds with Trialkylmagnesate Reagents to Yield Alkylated Organomagnesium Compounds
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Stereodivergent Syntheses of (<i>Z</i>)- and (<i>E</i>)-Alkenylsilanes via Hydrosilylation of Terminal Alkynes Catalyzed by Rhodium(I) Iodide Complexes and Application to Silicon-Containing Polymer Syntheses
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Kinetic studies on the hydrosilylation of phenylacetylene with R3SiH (R3?=?PhMe2, Ph2Me, Ph3, Et3) using bis(1,2-diphenylphosphinoethane)norbornadiene rhodium(I) hexafluorophosphate as catalyst
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Rhodium(II) perfluorobutyrate catalyzed hydrosilylation of 1-alkynes. Trans addition and rearrangement to allylsilanes
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Hydrosilylation of alkynylsilanes utilizing organolanthanide and Group 3 metallocene complexes
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Hydrosilylation of Alkynes with a Cationic Rhodium Species Formed in an Anionic Micellar System
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Tunable Stereoselective Hydrosilylation of PhC⋮CH Catalyzed by Cp*Rh Complexes
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Carbene Complexes of Rhodium and Iridium from Tripodal N-Heterocyclic Carbene Ligands: Synthesis and Catalytic Properties
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Alkyne Hydrosilylation Catalyzed by a Cationic Ruthenium Complex: Efficient and General Trans Addition
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A Theoretical Study on the Mechanism, Regiochemistry, and Stereochemistry of Hydrosilylation Catalyzed by Cationic Ruthenium Complexes
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Trans Additions of Silanes to 1-Alkynes Catalyzed by Ruthenium Complexes: Role of in Situ Formed Polynuclear Aggregates
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Intramolecular Endo-Dig Hydrosilylation Catalyzed by Ruthenium: Evidence for a New Mechanistic Pathway
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An η2-vinyl pathway may explain net trans hydrosilylation via transition metal catalysis even in cyclic cases
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Ruthenium-Catalyzed Hydrosilylation of 1-Alkynes with Novel Regioselectivity
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Reactions of Diamidonaphthalene-Bridged Diiridium Tetrahydrides with Alkynes: Hydrogenation, Vinylidene Formation, and Catalytic C−C Coupling
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Novel Metal-to-Metal Silyl-Migration Reactions in Heterometallic Complexes
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Silyl Migration of Me<sub>3</sub>SiCCPh Coordinated to [RuH(CO)(P<sup>t</sup>Bu<sub>2</sub>Me)<sub>2</sub>]BAr‘<sub>4</sub>Can Be Reversed: Synthesis and Structure of [Ru(CHC(SiMe<sub>3</sub>)(Ph))(CO)(P<sup>t</sup>Bu<sub>2</sub>Me)<sub>2</sub>]BAr‘<sub>4</sub>
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Dicationic chelating N-heterocyclic carbene complexes of palladium: new catalysts for the copolymerisation of C2H4 and CO
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