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Voltage- and time-dependent valence state transition in cobalt oxide catalysts during the oxygen evolution reaction

https://doi.org/10.1038/s41467-020-15925-2
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Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.

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The 66 checked references that resolve
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Nonstoichiometric Oxides as Low-Cost and Highly-Efficient Oxygen Reduction/Evolution Catalysts for Low-Temperature Electrochemical Devices
resolves10.1021/jacs.8b04546
Transition Metal Oxides as Electrocatalysts for the Oxygen Evolution Reaction in Alkaline Solutions: An Application-Inspired Renaissance
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In Operando Identification of Geometrical-Site-Dependent Water Oxidation Activity of Spinel Co<sub>3</sub>O<sub>4</sub>
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Unified structural motifs of the catalytically active state of Co(oxyhydr)oxides during the electrochemical oxygen evolution reaction
resolves10.1126/science.aam7092
Perovskites in catalysis and electrocatalysis
resolves10.1126/science.1212858
A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles
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Rock Salt Ni/Co Oxides with Unusual Nanoscale‐Stabilized Composition as Water Splitting Electrocatalysts
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Homogeneously dispersed multimetal oxygen-evolving catalysts
resolves10.1038/s41560-019-0355-9
Chemical and structural origin of lattice oxygen oxidation in Co–Zn oxyhydroxide oxygen evolution electrocatalysts
resolves10.1021/ja511559d
Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocatalytic Water Splitting
resolves10.1021/jacs.6b12250
Tracking Catalyst Redox States and Reaction Dynamics in Ni–Fe Oxyhydroxide Oxygen Evolution Reaction Electrocatalysts: The Role of Catalyst Support and Electrolyte pH
resolves10.1021/ja405997s
Theoretical Investigation of the Activity of Cobalt Oxides for the Electrochemical Oxidation of Water
resolves10.1039/C7EE02052J
Charge-transfer-energy-dependent oxygen evolution reaction mechanisms for perovskite oxides
resolves10.1038/nchem.2695
Activating lattice oxygen redox reactions in metal oxides to catalyse oxygen evolution
resolves10.1038/ncomms11053
Water electrolysis on La1−xSrxCoO3−δ perovskite electrocatalysts
resolves10.1126/science.aad4998
Combining theory and experiment in electrocatalysis: Insights into materials design
resolves10.1021/jp3126768
Structural Changes of Cobalt-Based Perovskites upon Water Oxidation Investigated by EXAFS
resolves10.1021/jz301414z
Influence of Oxygen Evolution during Water Oxidation on the Surface of Perovskite Oxide Catalysts
resolves10.1016/S1872-2067(19)63441-8
Understanding the origin of high oxygen evolution reaction activity in the high Sr-doped perovskite
resolves10.1038/nmat4938
Dynamic surface self-reconstruction is the key of highly active perovskite nano-electrocatalysts for water splitting
resolves10.1038/nature22389
Electric-field control of tri-state phase transformation with a selective dual-ion switch
resolves10.1021/ja063207m
Time-Resolved in Situ Studies of Oxygen Intercalation into SrCoO<sub>2.5</sub>, Performed by Neutron Diffraction and X-ray Absorption Spectroscopy
resolves10.1038/nchem.1874
Time-resolved observations of water oxidation intermediates on a cobalt oxide nanoparticle catalyst
resolves10.1038/nchem.2497
Detecting the oxyl radical of photocatalytic water oxidation at an n-SrTiO3/aqueous interface through its subsurface vibration
resolves10.1038/nchem.2557
Determination of photoelectrochemical water oxidation intermediates on haematite electrode surfaces using operando infrared spectroscopy
resolves10.1038/s41929-019-0332-5
Selecting between two transition states by which water oxidation intermediates decay on an oxide surface
resolves10.1103/PhysRevB.100.205139
Spin-orbit coupling and crystal-field distortions for a low-spin <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mn>3</mml:mn><mml:msup><mml:mi>d</mml:mi><mml:mn>5</mml:mn></mml:msup></mml:mrow></mml:math> state in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi mathvariant="normal">BaCoO</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:math>
resolves10.1103/PhysRevB.51.11501
Possibility for an intermediate-spin ground state in the charge-transfer material<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">SrCoO</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>
resolves10.1103/PhysRevLett.111.056404
Role of Oxygen Holes in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:msub><mml:mi>Li</mml:mi><mml:mi>x</mml:mi></mml:msub><mml:msub><mml:mi>CoO</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math>Revealed by Soft X-Ray Spectroscopy
resolves10.1103/PhysRevLett.94.146402
Orbital Symmetry and Electron Correlation in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:msub><mml:mi>Na</mml:mi><mml:mi>x</mml:mi></mml:msub><mml:msub><mml:mi>CoO</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math>
resolves10.1038/ncomms4949
Spinel-type lithium cobalt oxide as a bifunctional electrocatalyst for the oxygen evolution and oxygen reduction reactions
resolves10.1021/jacs.5b06814
In Situ Observation of Active Oxygen Species in Fe-Containing Ni-Based Oxygen Evolution Catalysts: The Effect of pH on Electrochemical Activity
resolves10.1021/acsenergylett.8b01818
Revealing pH-Dependent Activities and Surface Instabilities for Ni-Based Electrocatalysts during the Oxygen Evolution Reaction
resolves10.1002/adma.201802912
Enlarged CoO Covalency in Octahedral Sites Leading to Highly Efficient Spinel Oxides for Oxygen Evolution Reaction
resolves10.1103/PhysRevB.47.13763
Electron-energy-loss near-edge structures in the oxygen<i>K</i>-edge spectra of transition-metal oxides
resolves10.1103/PhysRevB.77.125124
Local electronic structure and magnetic properties of<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:mi mathvariant="normal">La</mml:mi><mml:msub><mml:mi mathvariant="normal">Mn</mml:mi><mml:mn>0.5</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">Co</mml:mi><mml:mn>0.5</mml:mn></mml:msub><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>studied by x-ray absorption and magnetic circular dichroism spectroscopy
resolves10.1103/PhysRevB.81.115138
Local orbital occupation and energy levels of Co in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mtext>Na</mml:mtext></mml:mrow><mml:mi>x</mml:mi></mml:msub><mml:msub><mml:mrow><mml:mtext>CoO</mml:mtext></mml:mrow><mml:mn>2</mml:mn></mml:msub></mml:mrow></mml:math>: A soft x-ray absorption study
resolves10.1021/jp511176j
Evidence of Localized Lithium Removal in Layered and Lithiated Spinel Li<sub>1–<i>x</i></sub>CoO<sub>2</sub>(0 ≤<i>x</i>≤ 0.9) under Oxygen Evolution Reaction Conditions
resolves10.1021/acs.jpcc.7b03875
Insight into the Role of Metal–Oxygen Bond and O 2p Hole in High-Voltage Cathode LiNi<sub><i>x</i></sub>Mn<sub>2–<i>x</i></sub>O<sub>4</sub>
resolves10.1038/ncomms3439
Double perovskites as a family of highly active catalysts for oxygen evolution in alkaline solution
resolves10.1073/pnas.1310703110
Importance of trivalency and the e <sub>g</sub> <sup>1</sup> configuration in the photocatalytic oxidation of water by Mn and Co oxides
resolves10.1103/PhysRevLett.102.116401
Spin Blockade, Orbital Occupation, and Charge Ordering in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:msub><mml:mi>La</mml:mi><mml:mn>1.5</mml:mn></mml:msub><mml:msub><mml:mi>Sr</mml:mi><mml:mn>0.5</mml:mn></mml:msub><mml:msub><mml:mi>CoO</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:math>
resolves10.1103/PhysRevB.68.174407
Two- and three-dimensional magnetic order in the layered cobalt oxychloride<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">CoO</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mi mathvariant="normal">Cl</mml:mi></mml:math>
resolves10.1103/PhysRevB.83.235105
Co–O–O–Co superexchange pathways enhanced by small charge-transfer energy in multiferroic BiCoO<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow/><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>
resolves10.1021/ja102987d
Pressure-Induced Spin-State Transition in BiCoO<sub>3</sub>
resolves10.1002/pssr.201800147
Experimental and Theoretical Soft X‐Ray Absorption Study on Co<sup>3+</sup> Ion Spin States in Sr<sub>2−<i>x</i></sub>Ca<i><sub>x</sub></i>CoO<sub>3</sub>F
resolves10.1103/PhysRevB.46.3771
Electronic structure of 3<i>d</i>-transition-metal compounds by analysis of the 2<i>p</i>core-level photoemission spectra
resolves10.1103/PhysRevLett.95.187205
Controlling Orbital Moment and Spin Orientation in CoO Layers by Strain
resolves10.1103/PhysRevB.44.6090
Electronic structure of CoO, Li-doped CoO, and<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">LiCoO</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>
resolves10.1103/PhysRevLett.97.176405
Spin State Transition in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:msub><mml:mi>LaCoO</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:math>Studied Using Soft X-ray Absorption Spectroscopy and Magnetic Circular Dichroism
resolves10.1103/PhysRevB.65.165120
X-ray absorption of the negative charge-transfer material<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">SrFe</mml:mi></mml:mrow><mml:mrow><mml:mn>1</mml:mn><mml:mi>−</mml:mi><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Co</mml:mi></mml:mrow><mml:mrow><mml:mi>x</mml:mi></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>
resolves10.1038/s41929-019-0325-4
Iron-facilitated dynamic active-site generation on spinel CoAl2O4 with self-termination of surface reconstruction for water oxidation
resolves10.1038/s41467-019-10838-1
Atomic-scale perturbation of oxygen octahedra via surface ion exchange in perovskite nickelates boosts water oxidation
resolves10.1038/nmat4551
Anionic redox processes for electrochemical devices
resolves10.1007/s12274-018-2065-1
Molten-salt synthesis of porous La0.6Sr0.4Co0.2Fe0.8O2.9 perovskite as an efficient electrocatalyst for oxygen evolution
resolves10.1002/adma.201905025
Boosting Oxygen Evolution Reaction by Creating Both Metal Ion and Lattice‐Oxygen Active Sites in a Complex Oxide
resolves10.1103/PhysRevA.47.3554
Quantum projection noise: Population fluctuations in two-level systems
resolves10.1103/PhysRevB.47.3354
Orbital character of states at the Fermi level in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">La</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn><mml:mi mathvariant="normal">−</mml:mi><mml:mi mathvariant="italic">x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Sr</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant="italic">x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">CuO</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>and<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="italic">R</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn><mml:mi mathvariant="normal">−</mml:mi><mml:mi mathvariant="italic">x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Ce</mml:mi></mml:mrow><mml:mrow><mml:mi mathvariant="italic">x</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">CuO</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>(<i>R</i>=Nd,Sm)
resolves10.1116/1.2747620
Soft-x-ray spectroscopy experiment of liquids
resolves10.1016/j.elecom.2010.03.042
In situ soft X-ray absorption spectroscopy investigation of electrochemical corrosion of copper in aqueous NaHCO3 solution
resolves10.1595/147106708X297855
Platinum as a Reference Electrode in Electrochemical Measurements
resolves10.1038/ncomms11510
Engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition
resolves10.1103/PhysRevB.54.11169
Efficient iterative schemes for<i>ab initio</i>total-energy calculations using a plane-wave basis set
resolves10.1103/PhysRevB.59.1758
From ultrasoft pseudopotentials to the projector augmented-wave method
resolves10.1103/PhysRevLett.77.3865
Generalized Gradient Approximation Made Simple
resolves10.1103/PhysRevB.57.1505
Electron-energy-loss spectra and the structural stability of nickel oxide:  An LSDA+U study
The 1 reference without a DOI — listed, not checked
no DOI — not checkedJenkins, S. CRC Handbook of Chemistry and Physics 93rd ed., (CRC Press, Boca Raton, FL, 2012).
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