Reference health
An enzymatic platform for the asymmetric amination of primary, secondary and tertiary C(sp3)–H bonds
40/40 checkable references clean · checked 2026-07-22
Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.
2 without a DOI — not checked. A reference deposited without a DOI is never matched by title or guessed at; it stays outside the checked set, and this line discloses that.
The 40 checked references that resolve
resolves10.1126/science.aao4798
Enantioselective C(sp
<sup>3</sup>
)‒H bond activation by chiral transition metal catalysts
resolves10.1021/acscentsci.6b00032
Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities
resolves10.1039/C0CS00070A
Catalytic C–H functionalization by metalloporphyrins: recent developments and future directions
resolves10.1021/jacs.6b12234
Palladium-Catalyzed Enantioselective C–H Activation of Aliphatic Amines Using Chiral Anionic BINOL-Phosphoric Acid Ligands
resolves10.1021/acs.chemrev.6b00731
Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations
resolves10.1126/science.1231434
Olefin Cyclopropanation via Carbene Transfer Catalyzed by Engineered Cytochrome P450 Enzymes
resolves10.1126/science.aah6219
Directed evolution of cytochrome c for carbon–silicon bond formation: Bringing silicon to life
resolves10.1021/jacs.6b11410
Chemoselective, Enzymatic C–H Bond Amination Catalyzed by a Cytochrome P450 Containing an Ir(Me)-PIX Cofactor
resolves10.1016/j.copbio.2017.06.005
Exploiting and engineering hemoproteins for abiological carbene and nitrene transfer reactions
resolves10.1021/cs400893n
P450-Catalyzed Intramolecular sp
<sup>3</sup>
C–H Amination with Arylsulfonyl Azide Substrates
resolves10.1038/s41586-018-0808-5
Enzymatic assembly of carbon–carbon bonds via iron-catalysed sp3 C–H functionalization
resolves10.1002/anie.201304401
Enantioselective Intramolecular CH Amination Catalyzed by Engineered Cytochrome P450 Enzymes In Vitro and In Vivo
resolves10.1021/ja509308v
Enzyme-Controlled Nitrogen-Atom Transfer Enables Regiodivergent C–H Amination
resolves10.1038/nchem.2783
Enantioselective, intermolecular benzylic C–H amination catalysed by an engineered iron-haem enzyme
resolves10.1002/anie.201005552
Selective Intramolecular CH Amination through the Metalloradical Activation of Azides: Synthesis of 1,3‐Diamines under Neutral and Nonoxidative Conditions
resolves10.1002/anie.201101801
Enantioselective Intramolecular Benzylic CH Bond Amination: Efficient Synthesis of Optically Active Benzosultams
resolves10.1021/ar200318q
Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds
resolves10.1038/nchem.2366
A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp3)–H amination
resolves10.1038/s41557-018-0020-0
Manganese-catalysed benzylic C(sp3)–H amination for late-stage functionalization
resolves10.1002/anie.201808923
Catalytic Radical Process for Enantioselective Amination of C(sp<sup>3</sup>)−H Bonds
resolves10.1039/C6SC02231F
Intramolecular 1,5-C(sp
<sup>3</sup>
)–H radical amination via Co(
<scp>ii</scp>
)-based metalloradical catalysis for five-membered cyclic sulfamides
resolves10.1074/jbc.271.37.22663
The Highly Stereoselective Oxidation of Polyunsaturated Fatty Acids by Cytochrome P450BM-3
resolves10.1002/anie.201703311
Catalytic Desymmetrization by C−H Functionalization as a Solution to the Chiral Methyl Problem
resolves10.1126/science.aad8313
Asymmetric copper-catalyzed C-N cross-couplings induced by visible light
resolves10.1038/s41586-018-0042-1
Quaternary stereocentres via an enantioconvergent catalytic SN1 reaction
resolves10.1126/science.aau7797
An enantioconvergent halogenophilic nucleophilic substitution (S
<sub>N</sub>
2X) reaction
resolves10.1039/C3SC52533C
Iron-mediated intermolecular N-group transfer chemistry with olefinic substrates
resolves10.1021/cs5018612
Enzymatic C(sp<sup>3</sup>)-H Amination: P450-Catalyzed Conversion of Carbonazidates into Oxazolidinones
resolves10.1021/ja2028958
A General Copper–BINAP-Catalyzed Asymmetric Propargylation of Ketones with Propargyl Boronates
resolves10.1126/science.aab3753
Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines
resolves10.1021/jacs.7b06960
Rare Examples of Fe(IV) Alkyl-Imide Migratory Insertions: Impact of Fe—C Covalency in (Me<sub>2</sub>IPr)Fe(═NAd)R<sub>2</sub> (R = <sup>neo</sup>Pe, 1-nor)
The 2 references without a DOI — listed, not checked
no DOI — not checkedDavies, H. M. L. & Manning, J. R. Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion. Nature 451, 417–424 (2008).
no DOI — not checkedKey, H. M., Dydio, P., Clark, D. S. & Hartwig, J. F. Abiological catalysis by artificial haem proteins containing noble metals in place of iron. Nature 534, 534–537 (2016).
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