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Experimental and computational studies on H <sub>2</sub> O-promoted, Rh-catalyzed transient-ligand-free <i>ortho</i> -C(sp <sup>2</sup> )–H amidation of benzaldehydes with dioxazolones
69/69 checkable references clean · checked 2026-07-22
Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.
The 69 checked references that resolve
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Enantioselective Catalytic Aziridinations and Asymmetric Nitrene Insertions into CH Bonds
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Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion
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Selective functionalisation of saturated C–H bonds with metalloporphyrin catalysts
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Transition‐Metal‐Catalyzed Electrophilic Amination: Application of <i>O</i>‐Benzoylhydroxylamines in the Construction of the C−N Bond
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Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation
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Organic azides: “
<i>energetic reagents</i>
” for the
<i>inter</i>
molecular amination of C–H bonds
resolves10.1021/acs.accounts.5b00020
Transition-Metal-Catalyzed C–N Bond Forming Reactions Using Organic Azides as the Nitrogen Source: A Journey for the Mild and Versatile C–H Amination
resolves10.1039/C4QO00350K
Cu- or Fe-catalyzed C–H/C–C bond nitrogenation reactions for the direct synthesis of N-containing compounds
resolves10.1021/acscatal.5b02417
Catalytic Methods for Aromatic C–H Amination: An Ideal Strategy for Nitrogen-Based Functional Molecules
resolves10.1021/acs.chemrev.6b00644
Transition Metal-Catalyzed C–H Amination: Scope, Mechanism, and Applications
resolves10.1002/cctc.201600079
Directing‐Group‐Assisted Transition‐Metal‐Catalyzed Direct Intermolecular C−H Amidation and Amination of Arenes
resolves10.1021/acscatal.6b02015
Chelation-Assisted Rhodium-Catalyzed Direct Amidation with Amidobenziodoxolones: C(sp<sup>2</sup>)–H, C(sp<sup>3</sup>)–H, and Late-Stage Functionalizations
resolves10.1002/chem.201702397
Mechanism‐Driven Approach To Develop a Mild and Versatile C−H Amidation through Ir<sup>III</sup> Catalysis
resolves10.1021/ja106364r
Pd-Catalyzed Intermolecular <i>ortho</i>-C−H Amidation of Anilides by <i>N</i>-Nosyloxycarbamate
resolves10.1021/ja502270y
Iridium-Catalyzed C–H Amination with Anilines at Room Temperature: Compatibility of Iridacycles with External Oxidants
resolves10.1021/acscatal.5b02165
Iridium-Catalyzed Direct C–H Amination with Alkylamines: Facile Oxidative Insertion of Amino Group into Iridacycle
resolves10.1002/anie.201703300
Ligand‐Promoted Rhodium(III)‐Catalyzed <i>ortho</i>‐C−H Amination with Free Amines
resolves10.1021/ja108450m
Palladium-Catalyzed Intermolecular Directed C−H Amidation of Aromatic Ketones
resolves10.1002/chem.201301025
Ruthenium‐Catalyzed Direct CH Amidation of Arenes Including Weakly Coordinating Aromatic Ketones
resolves10.1039/c3cc41915k
Ru(ii)-catalyzed intermolecular ortho-C–H amidation of aromatic ketones with sulfonyl azides
resolves10.1039/c3cc42613k
Ru(ii)-catalyzed intermolecular C–H amidation of weakly coordinating ketones
resolves10.1002/anie.201310544
Iridium‐Catalyzed Direct CH Amidation with Weakly Coordinating Carbonyl Directing Groups under Mild Conditions
resolves10.1039/c0ob00223b
Bifunctional thiourea-promoted cascade aza-Michael-Henry-dehydration reactions: asymmetric preparation of 3-nitro-1,2-dihydroquinolines
resolves10.1002/adsc.201000015
Efficient and General Synthesis of 3‐Aminoindolines and 3‐Aminoindoles <i>via</i> Copper‐Catalyzed Three‐Component Coupling Reaction
resolves10.1039/c1sc00506e
Divergent reactions of indoles with aminobenzaldehydes: indole ring-opening vs. annulation and facile synthesis of neocryptolepine
resolves10.1021/jo300949d
Aminoindolines versus Quinolines: Mechanistic Insights into the Reaction between 2-Aminobenzaldehydes and Terminal Alkynes in the Presence of Metals and Secondary Amines
resolves10.1021/jo400522m
Solvent-Free Enantioselective Friedländer Condensation with Wet 1,1′-Binaphthalene-2,2′-diamine-Derived Prolinamides as Organocatalysts
resolves10.1039/C4CC07807A
One-pot synthesis of dibenzo[b,h][1,6]naphthyridines from 2-acetylaminobenzaldehyde: application to a fluorescent DNA-binding compound
resolves10.1021/acs.orglett.5b03287
Synthesis of Quinoline-Fused 1-Benzazepines through a Mannich-Type Reaction of a C,N-Bisnucleophile Generated from 2-Aminobenzaldehyde and 2-Methylindole
resolves10.1002/ejoc.201501359
TBHP/CoCl<sub>2</sub>‐Mediated Intramolecular Oxidative Cyclization of <i>N</i>‐(2‐Formylphenyl)amides: An Approach to the Construction of 4<i>H</i>‐3,1‐Benzoxazin‐4‐ones
resolves10.1016/j.tetlet.2005.02.023
Selective palladium-catalyzed arylation(s) of benzaldehyde derivatives by N-heterocarbene ligands
resolves10.1021/ol3000684
Highly Regio- and Stereoselective Ruthenium(II)-Catalyzed Direct <i>ortho</i>-Alkenylation of Aromatic and Heteroaromatic Aldehydes with Activated Alkenes under Open Atmosphere
resolves10.1021/jacs.5b10447
Ligand-Controlled Divergent C—H Functionalization of Aldehydes with Enynes by Cobalt Catalysts
resolves10.1021/acs.orglett.7b02931
Rhodium-Catalyzed Direct <i>Ortho</i> C–H Arylation Using Ketone as Directing Group with Boron Reagent
resolves10.1021/acs.orglett.6b02406
Iridium-Catalyzed Direct ortho-C–H Amidation of Benzaldehydes through <i>N</i>-Sulfonyl Imines as Mask
resolves10.1021/acs.joc.7b01280
Synthesis and Anti-inflammatory Evaluation of 2-Aminobenzaldehydes via Ir(III)-Catalyzed C–H Amidation of Aldimines with Acyl Azides
resolves10.1039/C7CC05297A
Rh
<sup>III</sup>
-Catalyzed site-selective amidation with nitrone as a traceless directing group: an approach to functionalized arylaldehydes
resolves10.1002/chem.201603805
Ir‐Catalyzed C−H Amidation of Aldehydes with Stoichiometric/Catalytic Directing Group
resolves10.1021/jacs.6b11188
Diverse <i>ortho</i>-C(sp<sup>2</sup>)–H Functionalization of Benzaldehydes Using Transient Directing Groups
resolves10.1021/acs.joc.7b00531
Iridium-Catalyzed <i>ortho</i>-C(sp<sup>2</sup>)–H Amidation of Benzaldehydes with Organic Azides
resolves10.1039/C8QO00413G
Synthesis of 2-aminobenzaldehydes by rhodium(
<scp>iii</scp>
)-catalyzed C–H amidation of aldehydes with dioxazolones
resolves10.1021/acscatal.6b03621
Palladium-Catalyzed Direct Intermolecular Amination of Unactivated Methylene C(sp<sup>3</sup>)–H Bonds with Azodiformates via Bidentate-Chelation Assistance
resolves10.1021/acs.orglett.8b01183
Metal-Controlled, Regioselective, Direct Intermolecular α- or γ-Amination with Azodicarboxylates
resolves10.1002/anie.201506323
Rhodium(III)‐Catalyzed Amidation of Unactivated C(sp<sup>3</sup>)H Bonds
resolves10.1002/anie.201505820
Comparative Catalytic Activity of Group 9 [Cp*M<sup>III</sup>] Complexes: Cobalt‐Catalyzed CH Amidation of Arenes with Dioxazolones as Amidating Reagents
resolves10.1002/anie.201603260
Overcoming the Limitations of C−H Activation with Strongly Coordinating N‐Heterocycles by Cobalt Catalysis
resolves10.1021/acscatal.7b00582
Mechanochemical Rhodium(III)-Catalyzed C–H Bond Amidation of Arenes with Dioxazolones under Solventless Conditions in a Ball Mill
resolves10.1002/anie.201709273
Thioamide‐Directed Cobalt(III)‐Catalyzed Selective Amidation of C(sp<sup>3</sup>)−H Bonds
resolves10.1126/science.aap7503
Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts
resolves10.1002/adsc.201701331
Rh‐Catalyzed Annulation of <i>ortho</i>‐C−H Bonds of 2‐Arylimidazoles with 1,4,2‐Dioxazol‐5‐ones toward 5‐Arylimidazo[1,2‐<i>c</i>]quinazolines
resolves10.1021/ol400198q
Synthesis of Indene Frameworks via Rhodium-Catalyzed Cascade Cyclization of Aromatic Ketone and Unsaturated Carbonyl Compounds
resolves10.1002/anie.201407175
Rhodium(III)‐Catalyzed [3+2] Annulation of 5‐Aryl‐2,3‐dihydro‐1<i>H</i>‐pyrroles with Internal Alkynes through C(sp<sup>2</sup>)H/Alkene Functionalization
resolves10.1002/anie.201501260
Rhodium(III)‐Catalyzed [3+2]/[5+2] Annulation of 4‐Aryl 1,2,3‐Triazoles with Internal Alkynes through Dual C(sp<sup>2</sup>)H Functionalization
resolves10.1021/acs.joc.5b01666
Rhodium(III)-Catalyzed Direct Cyanation of Aromatic C–H Bond to Form 2-(Alkylamino)benzonitriles Using <i>N</i>-Nitroso As Directing Group
resolves10.1021/jacs.5b01324
Mechanistic Studies on the Rh(III)-Mediated Amido Transfer Process Leading to Robust C–H Amination with a New Type of Amidating Reagent
resolves10.1002/anie.201701138
Iterative C−H Functionalization Leading to Multiple Amidations of Anilides
resolves10.1002/cjoc.201700726
Rh‐catalyzed Transient Directing Group Promoted C—H Amidation of Benzaldehydes Utilizing Dioxazolones
resolves10.1021/ol502554e
A Convenient Allenoate-Based Synthesis of 2-Quinolin-2-yl Malonates and β-Ketoesters
resolves10.1002/anie.201709075
Asymmetric Iron‐Catalyzed C−H Alkylation Enabled by Remote Ligand <i>meta</i>‐Substitution
resolves10.1021/acs.joc.5b02618
PPh<sub>3</sub>O as an Activating Reagent for One-Pot Stereoselective Syntheses of Di- and Polybrominated Esters from Simple Aldehydes
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