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Computational and Experimental Insights into Carboxylate-Assisted Carboxylation of Thiophene with CO <sub>2</sub> in the Solvent-Free Carbonate Medium

https://doi.org/10.2139/ssrn.3978459
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34/34 checkable references clean · checked 2026-07-23

Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.

6 without a DOI — not checked. A reference deposited without a DOI is never matched by title or guessed at; it stays outside the checked set, and this line discloses that.

The 34 checked references that resolve
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Transformation of Carbon Dioxide
resolves10.1002/cssc.201701058
C−H Carboxylation of Aromatic Compounds through CO<sub>2</sub> Fixation
resolves10.1002/cssc.201802012
C−H Bond Carboxylation with Carbon Dioxide
resolves10.1021/ja020787o
Efficient Chemoselective Carboxylation of Aromatics to Arylcarboxylic Acids with a Superelectrophilically Activated Carbon Dioxide−Al<sub>2</sub>Cl<sub>6</sub>/Al System
resolves10.1021/ie801524e
Effect of Incubation of CO<sub>2</sub> and Lewis Acid on the Generation of Toluic Acid from Toluene and CO<sub>2</sub>
resolves10.1021/ie100533c
Combined Influence of Fluorinated Solvent and Base in Friedel−Crafts Reaction of Toluene and CO<sub>2</sub>
resolves10.1021/jo101808z
Direct Carboxylation of Arenes and Halobenzenes with CO<sub>2</sub> by the Combined Use of AlBr<sub>3</sub> and R<sub>3</sub>SiCl
resolves10.1016/j.tetlet.2009.05.076
Carboxylation of indoles and pyrroles with CO2 in the presence of dialkylaluminum halides
resolves10.1246/bcsj.20110335
Direct Carboxylation of Thiophenes and Benzothiophenes with the Aid of EtAlCl2
resolves10.1021/acs.orglett.6b00918
EtAlCl<sub>2</sub>/2,6-Disubstituted Pyridine-Mediated Carboxylation of Alkenes with Carbon Dioxide
resolves10.1002/aic.15519
Performance of combined use of chlorosilanes and AlCl<sub>3</sub> in the carboxylation of toluene with CO<sub>2</sub>
resolves10.1021/ja103429q
Carboxylation of C−H Bonds Using <i>N</i>-Heterocyclic Carbene Gold(I) Complexes
resolves10.1002/anie.201004153
Carboxylation of NH/CH Bonds Using N‐Heterocyclic Carbene Copper(I) Complexes
resolves10.1021/ol3025082
Base-Mediated Carboxylation of Unprotected Indole Derivatives with Carbon Dioxide
resolves10.1039/C6GC00200E
C–H carboxylation of heteroarenes with ambient CO <sub>2</sub>
resolves10.1002/chem.201805926
Direct Carboxylation of Electron‐Rich Heteroarenes Promoted by LiO‐<i>t</i>Bu with CsF and [18]Crown‐6
resolves10.1021/acs.orglett.9b01386
Double-Carboxylation of Two C–H Bonds in 2-Alkylheteroarenes Using LiO-<i>t</i>-Bu/CsF
resolves10.1002/ejoc.202000272
Direct C‐2 Carboxylation of 3‐Substituted Indoles Using a Combined Brønsted Base Consisting of LiO‐<i>t</i>Bu/CsF/18‐crown‐6
resolves10.1021/ol101450u
Carbon Dioxide as the C1 Source for Direct C−H Functionalization of Aromatic Heterocycles
resolves10.1038/nature17185
Carbon dioxide utilization via carbonate-promoted C–H carboxylation
resolves10.1039/C7GC01059A
A scalable carboxylation route to furan-2,5-dicarboxylic acid
resolves10.1039/C9SC04460D
Polyamide monomers <i>via</i> carbonate-promoted C–H carboxylation of furfurylamine
resolves10.1021/acs.jpclett.0c02210
Phase Behavior That Enables Solvent-Free Carbonate-Promoted Furoate Carboxylation
resolves10.1016/j.tet.2006.12.032
What are the pKa values of C–H bonds in aromatic heterocyclic compounds in DMSO?
resolves10.1021/acscentsci.8b00108
Carbonate-Promoted Hydrogenation of Carbon Dioxide to Multicarbon Carboxylates
resolves10.1021/ja067144j
Palladium-Catalyzed Benzene Arylation:  Incorporation of Catalytic Pivalic Acid as a Proton Shuttle and a Key Element in Catalyst Design
resolves10.1002/chem.200802001
Phosphine‐Free, Palladium‐Catalyzed Arylation of Heterocycles through CH Bond Activation with Pivalic Acid as a Cocatalyst
resolves10.1021/ja5071174
Key Mechanistic Features of Ni-Catalyzed C–H/C–O Biaryl Coupling of Azoles and Naphthalen-2-yl Pivalates
resolves10.1021/acscatal.9b05328
Roles of Base in the Pd-Catalyzed Annulative Chlorophenylene Dimerization
resolves10.1002/wcms.1221
The activation strain model and molecular orbital theory
resolves10.1002/anie.201701486
Analyzing Reaction Rates with the Distortion/Interaction‐Activation Strain Model
resolves10.1021/ja411699u
Distortion/Interaction Analysis Reveals the Origins of Selectivities in Iridium-Catalyzed C–H Borylation of Substituted Arenes and 5-Membered Heterocycles
resolves10.1002/cmtd.202100007
Interaction Region Indicator: A Simple Real Space Function Clearly Revealing Both Chemical Bonds and Weak Interactions**
resolves10.1002/jcc.22885
Multiwfn: A multifunctional wavefunction analyzer
The 6 references without a DOI — listed, not checked
no DOI — not checkedref4
no DOI — not checkedref30
no DOI — not checkedA sustainable and green route to futan-2,5-dicarboxylaic acid by direct carboxylation of 2-furoic acid and CO 2
no DOI — not checkedref32
no DOI — not checkedThe importance of kinetic and thermodynamic control when assessing mechanisms of carboxylate-assisted C-H activation
no DOI — not checkedref34
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