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Active Site Engineering in Heterovalent Metal Organic Frameworks for Photocatalytic Ammonia Synthesis

https://doi.org/10.2139/ssrn.4060018
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33/33 checkable references clean · checked 2026-08-02

Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.

11 without a DOI — not checked. A reference deposited without a DOI is never matched by title or guessed at; it stays outside the checked set, and this line discloses that.

The 33 checked references that resolve
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Catalytic N<sub>2</sub>-to-NH<sub>3</sub>(or -N<sub>2</sub>H<sub>4</sub>) Conversion by Well-Defined Molecular Coordination Complexes
resolves10.1016/j.cej.2019.03.283
Photocatalytic conversion of nitrogen to ammonia with water on triphase interfaces of hydrophilic-hydrophobic composite Bi4O5Br2/ZIF-8
resolves10.1016/j.cej.2018.07.116
Sulfur-doped g-C3N4 nanosheets with carbon vacancies: General synthesis and improved activity for simulated solar-light photocatalytic nitrogen fixation
resolves10.1016/j.apcatb.2021.120379
Precise location and regulation of active sites for highly efficient photocatalytic synthesis of ammonia by facet-dependent BiVO4 single crystals
resolves10.1021/acscatal.1c02465
Boosting Nitrogen Activation via Bimetallic Organic Frameworks for Photocatalytic Ammonia Synthesis
resolves10.1016/j.cej.2020.126868
Efficient photocatalytic nitrogen fixation to ammonia over bismuth monoxide quantum dots-modified defective ultrathin graphitic carbon nitride
resolves10.1021/acscentsci.0c00552
Highly Efficient Photo-/Electrocatalytic Reduction of Nitrogen into Ammonia by Dual-Metal Sites
resolves10.1016/j.cej.2018.09.084
Robust photocatalytic reduction of Cr(VI) on UiO-66-NH2(Zr/Hf) metal-organic framework membrane under sunlight irradiation
resolves10.1038/s41929-021-00665-3
Self-adaptive dual-metal-site pairs in metal-organic frameworks for selective CO2 photoreduction to CH4
resolves10.1021/acscatal.0c04426
Enhanced Photocatalytic CO<sub>2</sub> Reduction Activity over NH<sub>2</sub>-MIL-125(Ti) by Facet Regulation
resolves10.1021/jacs.0c13342
Metal–Organic Framework Membranes Encapsulating Gold Nanoparticles for Direct Plasmonic Photocatalytic Nitrogen Fixation
resolves10.1016/j.apcatb.2020.118686
Toward visible-light-assisted photocatalytic nitrogen fixation: A titanium metal organic framework with functionalized ligands
resolves10.1021/acsnano.0c10947
Atomically Dispersed Iron Metal Site in a Porphyrin-Based Metal–Organic Framework for Photocatalytic Nitrogen Fixation
resolves10.1039/C6CY02355J
Activation performance and mechanism of a novel heterogeneous persulfate catalyst: metal–organic framework MIL-53(Fe) with Fe <sup>II</sup> /Fe <sup>III</sup> mixed-valence coordinatively unsaturated iron center
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resolves10.1016/j.talanta.2018.05.077
β-Cyclodextrin functionalization of metal-organic framework MOF-235 with excellent chemiluminescence activity for sensitive glucose biosensing
resolves10.1021/ie503705w
One-Pot Fabrication of C–Fe-Codoped TiO<sub>2</sub> Sheets with Dominant {001} Facets for Enhanced Visible Light Photocatalytic Activity
resolves10.1038/nature06964
Anatase TiO2 single crystals with a large percentage of reactive facets
resolves10.1021/acscatal.9b03462
Coordination between Electron Transfer and Molecule Diffusion through a Bioinspired Amorphous Titania Nanoshell for Photocatalytic Nicotinamide Cofactor Regeneration
resolves10.1021/acscatal.9b00255
Artificial Thylakoid for the Coordinated Photoenzymatic Reduction of Carbon Dioxide
resolves10.1016/j.materresbull.2020.110970
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resolves10.1016/j.matchemphys.2020.123621
Biomimetic synthesis of 2D/2D mixed graphitic carbon nitride /carbonized polydopamine nanosheets with excellent photocatalytic performance
resolves10.1002/smll.201601660
Tubular g‐C<sub>3</sub>N<sub>4</sub> Isotype Heterojunction: Enhanced Visible‐Light Photocatalytic Activity through Cooperative Manipulation of Oriented Electron and Hole Transfer
resolves10.1021/acscatal.9b05240
Synergy of Electron Transfer and Electron Utilization via Metal–Organic Frameworks as an Electron Buffer Tank for Nicotinamide Regeneration
resolves10.1021/acs.iecr.8b05293
One-Pot Fabrication of g-C<sub>3</sub>N<sub>4</sub>/MWCNTs Nanocomposites with Superior Visible-Light Photocatalytic Performance
resolves10.1021/jacs.5b03105
Efficient Visible Light Nitrogen Fixation with BiOBr Nanosheets of Oxygen Vacancies on the Exposed {001} Facets
resolves10.1021/jacs.7b12101
A Spectroscopic Study on the Nitrogen Electrochemical Reduction Reaction on Gold and Platinum Surfaces
resolves10.1021/acscatal.0c03166
Identifying Surface Reaction Intermediates in Plasma Catalytic Ammonia Synthesis
resolves10.1021/jacs.7b06634
Photocatalytic Conversion of Nitrogen to Ammonia with Water on Surface Oxygen Vacancies of Titanium Dioxide
resolves10.1039/C7TA09350K
MXene-derived TiO <sub>2</sub> @C/g-C <sub>3</sub> N <sub>4</sub> heterojunctions for highly efficient nitrogen photofixation
resolves10.1039/D1TA06296D
Refining active sites and hydrogen spillover for boosting visible-light-driven ammonia synthesis at room temperature
The 11 references without a DOI — listed, not checked
no DOI — not checkedNitrogen fixation reaction derived from nanostructured catalytic materials
no DOI — not checkedNitrogenase-inspired mixed-valence MIL-53(Fe II /Fe III ) for photocatalytic nitrogen fixation
no DOI — not checkedref12
no DOI — not checkedModular assembly of electron transfer pathways in bimetallic MOFs for photocatalytic ammonia synthesis
no DOI — not checkedNitrogenase-inspired bimetallic metal organic frameworks for visible-lightdriven nitrogen fixation
no DOI — not checked/C photocatalysts: Synergistically intensified charge generation and charge transfer for NADH regeneration
no DOI — not checkedOn-surface bottom-up construction of COF nanoshells towards photocatalytic H 2 production
no DOI — not checkedEfficient photocatalytic nitrogen fixation over Cu ?+ -modified defective ZnAl-layered double hydroxide nanosheets
no DOI — not checkedref37
no DOI — not checkedLight-switchable oxygen vacancies in ultrafine Bi 5 O 7 Br nanotubes for boosting solar-driven nitrogen fixation in pure water
no DOI — not checkedref44
What this badge says. CiteStamped means the CHECKABLE references of this work were clean at the dated check: each resolved to a known work in a public registry, and none carried a retraction notice at that time. It says nothing about the quality, findings, or importance of the work itself, and nothing about references deposited without a DOI.

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