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Extremely Low Barrier Activation of Methane on Spin-Polarized Ferryl Ion [Feo]2+ at the Four-Membered Ring of Zeolite

https://doi.org/10.2139/ssrn.4088778
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30/30 checkable references clean · checked 2026-07-22

Every reference with a DOI in the deposited reference list resolved to a known work in Crossref or DataCite at the dated check, and none carried a retraction, withdrawal, or removal notice.

5 without a DOI — not checked. A reference deposited without a DOI is never matched by title or guessed at; it stays outside the checked set, and this line discloses that.

The 30 checked references that resolve
resolves10.1016/0920-5861(95)00035-E
Selective oxidation of methane to methanol on a FeZSM-5 surface
resolves10.1016/S1381-1169(97)00051-4
Kinetic isotope effects and mechanism of biomimetic oxidation of methane and benzene on FeZSM-5 zeolite
resolves10.1021/ic1000073
Is [FeO]<sup>2+</sup> the Active Center Also in Iron Containing Zeolites? A Density Functional Theory Study of Methane Hydroxylation Catalysis by Fe-ZSM-5 Zeolite
resolves10.1038/nature19059
The active site of low-temperature methane hydroxylation in iron-containing zeolites
resolves10.1023/A:1006722207492
The Fe Active Sites in FeZSM-5 Catalyst for Selective Oxidation of CH4 to CH3OH at Room Temperature
resolves10.1016/j.cattod.2006.09.021
The nature of the active site in the Fe-ZSM-5/N2O system studied by (resonant) inelastic X-ray scattering
resolves10.1002/anie.201108706
Direct Catalytic Conversion of Methane to Methanol in an Aqueous Medium by using Copper‐Promoted Fe‐ZSM‐5
resolves10.1006/jcat.2002.3552
Evolution of Iron States and Formation of α-Sites upon Activation of FeZSM-5 Zeolites
resolves10.1023/A:1019063511784
Unusual structure and stability of iron-oxygen nano- clusters in Fe-ZSM-5 catalysts
resolves10.1134/S0023158411040173
O− radical anions on oxide catalysts: Formation, properties, and reactions
resolves10.1021/acscatal.6b02640
Computationally Exploring Confinement Effects in the Methane-to-Methanol Conversion Over Iron-Oxo Centers in Zeolites
resolves10.1016/j.cbpa.2009.02.007
Quantum chemical studies of C–H activation reactions by high-valent nonheme iron centers
resolves10.1016/j.cplett.2005.08.101
Electron structure of oxygen complexes of ferrous ion center
resolves10.1016/j.cplett.2014.11.061
The routes of association of (hydro)oxo centers on iron hydroxide at the water oxidation process: DFT predictions
resolves10.1134/S0023158418010032
Oxidation of Water to Molecular Oxygen by One-Electron Oxidants on Transition Metal Hydroxides
resolves10.1016/j.mcat.2017.11.039
Hydrogen abstraction from methane on cristobalite supported W and Mn oxo complexes: A DFT study
resolves10.1038/nchem.943
Exchange-enhanced reactivity in bond activation by metal–oxo enzymes and synthetic reagents
resolves10.1063/1.1742605
Indirect Hyperfine Interactions in the Paramagnetic Resonance Spectra of Aromatic Free Radicals
resolves10.1016/j.cplett.2004.06.144
Unrestricted density functional theory of the bonding between NO radical and ferrous ion
resolves10.1016/j.cplett.2017.05.002
Hidden radical reactivity of the [FeO]2+ group in the H-abstraction from methane: DFT and CASPT2 supported mechanism by the example of model iron (hydro)oxide species
resolves10.1021/ja0017965
Methane-to-Methanol Conversion by First-Row Transition-Metal Oxide Ions:  ScO<sup>+</sup>, TiO<sup>+</sup>, VO<sup>+</sup>, CrO<sup>+</sup>, MnO<sup>+</sup>, FeO<sup>+</sup>, CoO<sup>+</sup>, NiO<sup>+</sup>, and CuO<sup>+</sup>
resolves10.1021/acscatal.6b01721
Direct Conversion of Methane to Methanol by Metal-Exchanged ZSM-5 Zeolite (Metal = Fe, Co, Ni, Cu)
resolves10.1039/C8CY02414F
Methane selective oxidation to methanol by metal-exchanged zeolites: a review of active sites and their reactivity
resolves10.1002/cssc.201801959
Tuning the Aluminum Distribution in Zeolites to Increase their Performance in Acid‐Catalyzed Reactions
resolves10.1134/S0022476616050218
Analysis of spin-polarized solutions in the basis set of paired orbitals
resolves10.1016/j.cplett.2015.10.016
Distinct activity of the oxyl FeIIIO group in the methane dissociation by activated iron hydroxide: DFT predictions
resolves10.1021/ic802095m
What Singles out the FeO<sup>2+</sup>Moiety? A Density-Functional Theory Study of the Methane-to-Methanol Reaction Catalyzed by the First Row Transition-Metal Oxide Dications MO(H<sub>2</sub>O)<sub><i>p</i></sub><sup>2+</sup>, M = V−Cu
resolves10.1021/acscatal.7b03597
Understanding and Breaking Scaling Relations in Single-Site Catalysis: Methane to Methanol Conversion by Fe <sup>IV</sup> ═O
resolves10.1002/ejic.200601238
The Role of Equatorial and Axial Ligands in Promoting the Activity of Non‐Heme Oxidoiron(IV) Catalysts in Alkane Hydroxylation
resolves10.1021/acs.chemrev.7b00344
Iron and Copper Active Sites in Zeolites and Their Correlation to Metalloenzymes
The 5 references without a DOI — listed, not checked
no DOI — not checkedSelective Formation of ?-Fe(II) Sites on Fe-Zeolites through One-Pot Synthesis
no DOI — not checkedref13
no DOI — not checkedDFT Predictions for Hydrogen Atom Transfer at the [FeO]2+ Group: A Distinct Activity of the Oxyl State FeIII-O
no DOI — not checkedSiting and Distribution of Framework Aluminium Atoms in Silicon-Rich Zeolites and Impact on Catalysis
no DOI — not checkedref28
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