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Oxidation State Modulation of Bismuth for Efficient Electrocatalytic Nitrogen Reduction to Ammonia

https://doi.org/10.1002/adfm.202100300

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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inferred← citeshttps://doi.org/10.1016/j.apsusc.2021.151257openalex-snapshot

The surface engineering of MOF-derived titanium oxide–carbon multifunctional composite catalyst for efficient electrochemical nitrogen reduction

inferred← citeshttps://doi.org/10.1016/j.apsusc.2021.151441openalex-snapshot

Theoretical investigation of novel p-block metal-based electrocatalysts for nitrogen reduction reaction

inferred← citeshttps://doi.org/10.1016/j.apsusc.2023.157189openalex-snapshot

Nanoporous NiBi catalyst for efficient electrochemical N2 fixation

inferred← citeshttps://doi.org/10.1016/j.apsusc.2025.162545openalex-snapshot

Ab initio study of atomically dispersed catalysts on original and B-doped corrugated carbon nitride surface for effective nitrogen reduction

inferred← citeshttps://doi.org/10.1016/j.ccr.2022.214981openalex-snapshot

Recent progress in electrocatalytic nitrogen reduction to ammonia (NRR)

inferred← citeshttps://doi.org/10.1016/j.ccr.2025.217401openalex-snapshot

A Review of Advanced Nanomaterials for Electrochemical Nitrate Reduction to Ammonia

inferred← citeshttps://doi.org/10.1016/j.ccr.2026.218627openalex-snapshot

Recent advances in Mo-based electrocatalysts: correlating electronic spin configurations with electrochemical nitrogen reduction reaction performance

inferred← citeshttps://doi.org/10.1016/j.cej.2021.133752openalex-snapshot

Tailoring electronic structure of copper nanosheets by silver doping toward highly efficient electrochemical reduction of nitrogen to ammonia

inferred← citeshttps://doi.org/10.1016/j.cej.2023.141939openalex-snapshot

In-situ/operando Raman techniques for in-depth understanding on electrocatalysis

inferred← citeshttps://doi.org/10.1016/j.cej.2023.145711openalex-snapshot

Bi19Br3S27 nanorods for formate production from CO2 electroreduction with high efficiency and selectivity

inferred← citeshttps://doi.org/10.1016/j.cej.2024.155124openalex-snapshot

Synergistic effect of Bi and Fe for suppressing hydrogen evolution reaction (HER) and enhancing electrochemical nitrogen reduction reaction (eNRR) performance

inferred← citeshttps://doi.org/10.1016/j.cej.2024.156343openalex-snapshot

Efficient nitrate electroreduction to ammonia over copper catalysts supported on electron-delocalized covalent organic frameworks

inferred← citeshttps://doi.org/10.1016/j.cej.2024.158066openalex-snapshot

Reconstructed Bismuth Nanoparticles@Porous Carbon Nanorod with Modulated Bismuth-Oxygen Structure and Active Sites for Highly Efficient Electrochemical Dechlorination

inferred← citeshttps://doi.org/10.1016/j.cej.2025.164917openalex-snapshot

Iron-doped SnS2/SnO2 heterostructures modulate interfacial electric field for efficient ammonia synthesis

inferred← citeshttps://doi.org/10.1016/j.cej.2026.176224openalex-snapshot

Interfacial work function engineering for vanadium redox flow batteries

inferred← citeshttps://doi.org/10.1016/j.ces.2021.117409openalex-snapshot

Bismuthene with stable Bi O bonds for efficient CO2 electroreduction to formate

inferred← citeshttps://doi.org/10.1016/j.checat.2021.12.004openalex-snapshot

Efficient ammonia electrosynthesis by coupling to concurrent methanol oxidation

inferred← citeshttps://doi.org/10.1016/j.checat.2023.100871openalex-snapshot

Recent progress in amorphous nanomaterials for electrochemical synthesis of N-containing compounds

inferred← citeshttps://doi.org/10.1016/j.desal.2025.118919openalex-snapshot

Bi-based materials: from electrochemical energy storage to novel electrochemical separation technologies

inferred← citeshttps://doi.org/10.1016/j.electacta.2025.145893openalex-snapshot

Early-stage techno-economic evaluation of electrochemical nitrogen reduction to ammonia based on catalyst performance

inferred← citeshttps://doi.org/10.1016/j.ensm.2022.10.007openalex-snapshot

Electrochemical nitrogen fixation in metal-N2 batteries: A paradigm for simultaneous NH3 synthesis and energy generation

inferred← citeshttps://doi.org/10.1016/j.est.2024.112035openalex-snapshot

Fine and dense bismuth electrocatalysts achieving high power density and cycling stability in vanadium flow batteries

inferred← citeshttps://doi.org/10.1016/j.fuel.2025.138228openalex-snapshot

Bismuth nanostructures: catalytic pathways to sustainable technologies

inferred← citeshttps://doi.org/10.1016/j.gee.2022.01.009openalex-snapshot

Intercalation assisted liquid phase production of disulfide zirconium nanosheets for efficient electrocatalytic dinitrogen reduction to ammonia

inferred← citeshttps://doi.org/10.1016/j.ijhydene.2025.04.288openalex-snapshot

Subsize Ru nanoparticles embedded in porous carbon with highly metallic surface enable efficient hydrogen evolution

inferred← citeshttps://doi.org/10.1016/j.inoche.2025.114520openalex-snapshot

Single atom catalysis perspective to reveal N2 and NRR intermediate adsorption properties on non-benzenoid carbon allotrope: A DFT study

inferred← citeshttps://doi.org/10.1016/j.jallcom.2023.170969openalex-snapshot

Bi nanoparticles with different oxidation states embedded in porous carbon nanosheets as high-performance anode for lithium-ion battery

inferred← citeshttps://doi.org/10.1016/j.jallcom.2023.171253openalex-snapshot

Construction of ZnCdS@CAU-17 heterostructures containing intermediate mediator Bi2S3 as a highly efficient photocatalyst for nitrogen reduction reaction

inferred← citeshttps://doi.org/10.1016/j.jallcom.2024.174729openalex-snapshot

Boosting photocatalytic nitrogen fixation over Ni/Fe co-doped BiOBr in pure water under the synergistic effect of enhanced internal electric field and oxygen vacancies

inferred← citeshttps://doi.org/10.1016/j.jallcom.2025.182329openalex-snapshot

Synergistic NiBi catalysts: A leap forward in electrochemical nitrogen reduction

inferred← citeshttps://doi.org/10.1016/j.jcat.2025.116566openalex-snapshot

Unraveling the nitrogen fixation and electrochemical reduction to ammonia on IrO2 (1 1 0): DFT, ESM-RISM, and microkinetic simulation

inferred← citeshttps://doi.org/10.1016/j.jcis.2023.09.117openalex-snapshot

Interface engineering of NiS/NiCo2S4 heterostructure with charge redistribution for boosting overall water splitting

inferred← citeshttps://doi.org/10.1016/j.jcis.2024.02.130openalex-snapshot

Electron deficient Bi3+δ serves as N2 absorption sites and inhibits carriers recombination to enhance N2 photo-fixation in BiOBr/TiO2 S-scheme heterojunction

inferred← citeshttps://doi.org/10.1016/j.jcis.2024.07.020openalex-snapshot

Understanding electron structure of covalent triazine framework embraced with gold nanoparticles for nitrogen reduction to ammonia

inferred← citeshttps://doi.org/10.1016/j.jcis.2024.09.211openalex-snapshot

Photoirradiation-enhanced behavior via morphological manipulation of CoFe2O4/g-C3N4 heterojunction for supercapacitor and CO2 reduction

inferred← citeshttps://doi.org/10.1016/j.jcis.2026.140213openalex-snapshot

Engineering plasmon-enhanced cathode for photo-electrocatalytic conversion of CO2: Insight into the activity trends

inferred← citeshttps://doi.org/10.1016/j.jece.2024.113008openalex-snapshot

Reinforcing the efficiency of photocatalytic CO2 conversion with H2O vapor through the integration of photothermal Cu/C@Bi/C supported on 3D g-C3N4 under full-spectrum solar irradiation

inferred← citeshttps://doi.org/10.1016/j.jelechem.2025.119621openalex-snapshot

Engineering the surface chemical microenvironment over CuO porous nano-olives by proline for efficient ammonia electrosynthesis from nitrite

inferred← citeshttps://doi.org/10.1016/j.jelechem.2026.119790openalex-snapshot

Research progress on catalyst for electrochemical synthesis of ammonia by nitrogen reduction reaction (eNRR)

inferred← citeshttps://doi.org/10.1016/j.jpowsour.2025.238483openalex-snapshot

Bi-Sn bimetallic catalysts for efficient electrocatalytic nitrogen reduction to ammonia

inferred← citeshttps://doi.org/10.1016/j.jpowsour.2026.239490openalex-snapshot

Recent progress towards advanced catalysts for efficient thermocatalytic ammonia synthesis

inferred← citeshttps://doi.org/10.1016/j.jpowsour.2026.241185openalex-snapshot

Asymmetric electrode design incorporating N-doped positive and Bi-modified negative electrodes for enhanced energy efficiency and durability in vanadium redox flow batteries

inferred← citeshttps://doi.org/10.1016/j.matre.2021.100076openalex-snapshot

Perspectives on electrochemical nitrogen fixation catalyzed by two-dimensional MXenes

inferred← citeshttps://doi.org/10.1016/j.mseb.2024.117884openalex-snapshot

Bi-exsolved perovskites promote ammonia synthesis with HER inhibition via a protonic ceramic electrolysis cell

inferred← citeshttps://doi.org/10.1016/j.mssp.2023.107957openalex-snapshot

Cobalt-doped β-Ni(OH)2 electrode fabricated by in-situ chemical corrosion for photo-assisted supercapacitor with low-temperature operation

inferred← citeshttps://doi.org/10.1016/j.mtcomm.2023.106048openalex-snapshot

Efficient electrocatalytic properties of transition metal (Mn, Co, Cu) doped LaFeO3 for ammonia synthesis via nitrate reduction

inferred← citeshttps://doi.org/10.1016/j.mtener.2021.100884openalex-snapshot

Uniform octahedral ZrO2@C from carbonized UiO-66 for electrocatalytic nitrogen reduction

inferred← citeshttps://doi.org/10.1016/j.mtener.2022.101240openalex-snapshot

Rational design of Mo2C nanosheets anchored on hierarchically porous carbon for boosting electrocatalytic N2 reduction to NH3

inferred← citeshttps://doi.org/10.1016/j.mtener.2025.102004openalex-snapshot

Hyperdispersed and highly stable Bi single atom doped core-shell CuO for efficient photocatalytic CO2 reduction via modulation of electronic structure

inferred← citeshttps://doi.org/10.1016/j.mtphys.2022.100945openalex-snapshot

Electrochemical ammonia synthesis via nitrogen reduction reaction on 1T/2H mixed-phase MoSSe catalyst: Theoretical and experimental studies

inferred← citeshttps://doi.org/10.1016/j.nanoen.2025.110693openalex-snapshot

Structural engineering and operando characterization of advanced catalysts for electrochemical nitrogen reduction reaction

inferred← citeshttps://doi.org/10.1016/j.nanoen.2025.110896openalex-snapshot

Relay catalyst for accelerating lithium polysulfide conversion kinetics and long-life lithium sulfur batteries

inferred← citeshttps://doi.org/10.1016/j.nanoms.2025.12.016openalex-snapshot

Advances and challenges in electrocatalytic nitrate-to-ammonia conversion for nitrogen recycling

inferred← citeshttps://doi.org/10.1016/j.pmatsci.2022.101044openalex-snapshot

When nitrogen reduction meets single-atom catalysts

inferred← citeshttps://doi.org/10.1016/j.scib.2025.05.032openalex-snapshot

Adsorption configuration control on Pt-Bi2O3 for the oriented conversion of glycerol to glyceric acid via terminal hydroxyl oxidation

inferred← citeshttps://doi.org/10.1016/j.seppur.2026.139682openalex-snapshot

Synergistic vacancy and heterojunction engineering in one-pot synthesized BiOBr/Bi/Bi3O4Br for enhanced photocatalytic nitrogen fixation

inferred← citeshttps://doi.org/10.1021/acs.cgd.5c00876openalex-snapshot

π–π Stacked Stable Supramolecular Nanocage π-Skeleton and Its Derivatives for Ammonia Synthesis at Normal Temperature and Pressure

inferred← citeshttps://doi.org/10.1021/acs.chemmater.4c02267openalex-snapshot

Highly Stable Bismuth-Based Layered Oxides Modified by Phytic Acid for Anhydrous and Water-Assisted Proton Conductivity

inferred← citeshttps://doi.org/10.1021/acs.energyfuels.4c00802openalex-snapshot

NH3 Synthesis via Electrocatalytic N2 Reduction Reaction on the Defective Surfaces of Nb2Mo2C3Tx MXenes: Theoretical and Experimental Studies

inferred← citeshttps://doi.org/10.1021/acs.est.6c05691openalex-snapshot

Unveiling the Promoting Mechanism of Humic Acid in Photocatalysis via Bismuth Heavy-Atom Effect

inferred← citeshttps://doi.org/10.1021/acs.iecr.6c00834openalex-snapshot

ZnAl2O4–ZnO–Bi2O3 Integrated Ni2P for Enhancing Charge Transfer during Efficient Alkaline Hydrogen Evolution Reaction

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.1c03938openalex-snapshot

Simple Bottom-Up Synthesis of Bismuthene Nanostructures with a Suitable Morphology for Competitive Performance in the Electrocatalytic Nitrogen Reduction Reaction

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6c00320openalex-snapshot

Steam-Reformed Dispersive Sites with Cu 0 –Cu + Interface for Electroreduction of Nitrate to Ammonia

inferred← citeshttps://doi.org/10.1021/acs.jpclett.2c00918openalex-snapshot

Unveiling the Role of Charge Transfer in Enhanced Electrochemical Nitrogen Fixation at Single-Atom Catalysts on BX Sheets (X = As, P, Sb)

inferred← citeshttps://doi.org/10.1021/acsabm.4c00036openalex-snapshot

ZnAl2O4:Er3+ Upconversion Nanophosphor for SPECT Imaging and Luminescence Modulation via Defect Engineering

inferred← citeshttps://doi.org/10.1021/acsami.3c15403openalex-snapshot

Enhancing Electrocatalytic Water Oxidation of NiFe-LDH Nanosheets via Bismuth-Induced Electronic Structure Engineering

inferred← citeshttps://doi.org/10.1021/acsami.4c00162openalex-snapshot

Crystal-Phase and Surface-Structure Engineering of Bi2O3 for Enhanced Electrochemical N2 Fixation to NH3

inferred← citeshttps://doi.org/10.1021/acsami.4c18683openalex-snapshot

Two-Dimensional BiSb Alloy Nanosheets for the Electrochemical Conversion of Nitrogen-to-Ammonia in Neutral Electrolytes

inferred← citeshttps://doi.org/10.1021/acsami.5c06917openalex-snapshot

Surface Entropy-Reduction Tailored Few-Atom Layer Metal on High-Entropy Alloy for Tandem Electrocatalytic Nitrate Reduction to Ammonia

inferred← citeshttps://doi.org/10.1021/acsanm.4c05946openalex-snapshot

Advancements in Electrocatalytic Nitrogen Reduction Reaction: A Review on the Role of Catalyst Electronic Structure and Design Strategies

inferred← citeshttps://doi.org/10.1021/acsanm.5c05454openalex-snapshot

Composites of Bi 2 WO 6 Quantum Dots and WO 3 Nanosheets Rich in Oxygen Vacancies for N 2 Electroreduction

inferred← citeshttps://doi.org/10.1021/acscatal.2c02629openalex-snapshot

Progress of Experimental and Computational Catalyst Design for Electrochemical Nitrogen Fixation

inferred← citeshttps://doi.org/10.1021/acscatal.2c05724openalex-snapshot

Constructing Robust Bi Active Sites In Situ on α-Bi2O3 for Efficient and Selective Photoreduction of CO2 to CH4 via Directional Transfer of Electrons

inferred← citeshttps://doi.org/10.1021/acscatal.5c04422openalex-snapshot

Revealing the Role of Interfacial Water in pH-Dependent Hydroxylamine Electrosynthesis over Bi-Based Catalysts

inferred← citeshttps://doi.org/10.1021/acscatal.5c07782openalex-snapshot

Critical Role of Surface Hydroxyls on Bismuth in Steering CO 2 Electroreduction to Formate

inferred← citeshttps://doi.org/10.1021/acscatal.5c08588openalex-snapshot

Low-Temperature Electrocatalytic Ammonia Production: Study on the Nitrogen-Reducing Activity of Vanadium Sulfide Catalysts

inferred← citeshttps://doi.org/10.1021/acsenergylett.4c00399openalex-snapshot

Spectroelectrochemical Identification of CuO Impurities Catalyzing Water Reduction on CuBi 2 O 4 Photocathodes

inferred← citeshttps://doi.org/10.1021/acsenergylett.4c02823openalex-snapshot

Unleashing High Yield Urea Production by Pulse Electrodeposition of Bi/Cu via Co-reduction of N2 and CO2

inferred← citeshttps://doi.org/10.1021/acsnano.1c07820openalex-snapshot

Constructing Heterogeneous Structure in Metal–Organic Framework-Derived Hierarchical Sulfur Hosts for Capturing Polysulfides and Promoting Conversion Kinetics

inferred← citeshttps://doi.org/10.1021/acsnano.1c07973openalex-snapshot

Mo 2 C-MoO 2 Heterostructure Quantum Dots for Enhanced Electrocatalytic Nitrogen Reduction to Ammonia

inferred← citeshttps://doi.org/10.1021/acsnano.2c07260openalex-snapshot

Emerging p-Block-Element-Based Electrocatalysts for Sustainable Nitrogen Conversion

inferred← citeshttps://doi.org/10.1021/acssuschemeng.4c05358openalex-snapshot

Electrocatalytic Ammonia Production from Nitrogen with Enhanced Faradaic Efficiency Using Nanostructured Bi2MoO6

inferred← citeshttps://doi.org/10.1021/jacs.4c08564openalex-snapshot

Urea Synthesis via Coelectrolysis of CO 2 and Nitrate over Heterostructured Cu–Bi Catalysts

inferred← citeshttps://doi.org/10.1021/jacs.6c16565openalex-snapshot

Industrial-Scale Electrosynthesis of Amino Acids from the Air via a Molecular Ligand-Engineered Bismuth Catalyst

inferred← citeshttps://doi.org/10.1038/s41929-026-01524-9openalex-snapshot

A high-flux membrane electrode assembly for CO2 electroreduction to 4.5 M formate with over 8,000 h stability

inferred← citeshttps://doi.org/10.1039/d1cc01451jopenalex-snapshot

Electrochemical nitrogen reduction: recent progress and prospects

inferred← citeshttps://doi.org/10.1039/d2nj02510hopenalex-snapshot

Single s-block and p-block metal sites for photocatalytic degradation of organic pollutants and hydrogen evolution

inferred← citeshttps://doi.org/10.1039/d2qm01061eopenalex-snapshot

Theoretical and experimental progress of metal electrocatalysts for the nitrogen reduction reaction

inferred← citeshttps://doi.org/10.1039/d2qm01131jopenalex-snapshot

Polyoxometalate-derived bimetallic catalysts for the nitrogen reduction reaction

inferred← citeshttps://doi.org/10.1039/d2ta07781gopenalex-snapshot

Heterogeneous crystalline–amorphous interface for boosted electrocatalytic nitrogen reduction to ammonia

inferred← citeshttps://doi.org/10.1039/d2ta10036copenalex-snapshot

Metal–support interactions for heterogeneous catalysis: mechanisms, characterization techniques and applications

inferred← citeshttps://doi.org/10.1039/d3nr01019hopenalex-snapshot

WO x nanoparticles coupled with nitrogen-doped porous carbon toward electrocatalytic N 2 reduction

inferred← citeshttps://doi.org/10.1039/d3nr05982kopenalex-snapshot

A Cu hollow fiber with coaxially grown Bi nanosheet arrays as an integrated gas-penetrable electrode enables high current density and durable formate electrosynthesis

inferred← citeshttps://doi.org/10.1039/d3qi00225jopenalex-snapshot

The β-PdBi 2 monolayer for efficient electrocatalytic NO reduction to NH 3 : a computational study

inferred← citeshttps://doi.org/10.1039/d3qi00517hopenalex-snapshot

Synergetic effect between non-metals and dual metal catalysts for nitrogen reduction reaction

inferred← citeshttps://doi.org/10.1039/d3qm00267eopenalex-snapshot

Accelerating the development of electrocatalysts for electrochemical nitrogen fixation through theoretical and computational approaches

inferred← citeshttps://doi.org/10.1039/d3ta02408copenalex-snapshot

An isolated bimetallic Fe–Ru single-atom catalyst for efficient electrochemical nitrogen reduction

inferred← citeshttps://doi.org/10.1039/d3ta06254fopenalex-snapshot

ZnO–CoS heterostructure quantum dots for enhanced electrocatalytic nitrogen reduction to ammonia

inferred← citeshttps://doi.org/10.1039/d4cc00140kopenalex-snapshot

A p-block dopant enables energy-efficient hydrogen production from biomass

inferred← citeshttps://doi.org/10.1039/d4cc03443kopenalex-snapshot

Nanostructure impact on electrocatalysis in gold nanodimers via electrochemiluminescence microscopy

inferred← citeshttps://doi.org/10.1039/d4cs00563eopenalex-snapshot

Advanced systems for enhanced CO 2 electroreduction

inferred← citeshttps://doi.org/10.1039/d4ee02450hopenalex-snapshot

A novel high-performance all-liquid formic acid redox fuel cell: simultaneously generating electricity and restoring the capacity of flow batteries

inferred← citeshttps://doi.org/10.1039/d4ta02863eopenalex-snapshot

Electronic delocalization engineering of bismuth-based materials for catalytic electrochemical CO 2 and N 2 conversion

inferred← citeshttps://doi.org/10.1039/d4ta07286copenalex-snapshot

Unveiling high-yield dinitrogen-to-green ammonia production via highly defective Cu 4 Bi 5 S 10 /Mn 4 V 2 O 9 electrocatalysts in alkaline H-cell and stack-cell reactors

inferred← citeshttps://doi.org/10.1039/d5cc02478aopenalex-snapshot

Boosting small-molecule reduction with bismuth-based nanostructured reactors

inferred← citeshttps://doi.org/10.1039/d5nj02277kopenalex-snapshot

Ambient NH 3 synthesis via electrochemical reduction of N 2 over Fe–MnO 2 layered nanoflower catalysts

inferred← citeshttps://doi.org/10.1039/d5ta00172bopenalex-snapshot

Sustainable ammonia production from nitrate reduction assisted by methanol oxidation using Co@CF bifunctional electrocatalysts

inferred← citeshttps://doi.org/10.1039/d5ta02526eopenalex-snapshot

Bi/ZIF-8 catalysts: the important role of ZIF-8 for enhanced electrochemical N 2 -to-NH 3 conversion using a neutral electrolyte

inferred← citeshttps://doi.org/10.1039/d5ta07478aopenalex-snapshot

Coupled defect chemistry and redox dynamics in a bismuth gahnite system for self-adaptive tribological interfaces

inferred← citeshttps://doi.org/10.1039/d6dt00112bopenalex-snapshot

Synthetic method analysis of Ir 0.85 Bi 0.15 solid-solution nanoparticles with excellent hydrazine-decomposition activity

inferred← citeshttps://doi.org/10.1039/d6ra05930aopenalex-snapshot

Photoelectrochemical nitrate reduction to ammonia on CuFeO 2 photocathodes modified with metallic cocatalysts

inferred← citeshttps://doi.org/10.1073/pnas.2115504119openalex-snapshot

High-ammonia selective metal–organic framework–derived Co-doped Fe/Fe 2 O 3 catalysts for electrochemical nitrate reduction

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