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Insights on Artificial Interphases of Zn and Electrolyte: Protection Mechanisms, Constructing Techniques, Applicability, and Prospective

https://doi.org/10.1002/adfm.202213510
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What points at this work

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UIO‐66/Holey Graphene as a Surface Protective Layer for the Stabilization of Zn‐Metal Anode for High Performance Aqueous Zinc Ion Batteries
inferred← citeshttps://doi.org/10.1002/smll.74055openalex-snapshot
A Biomimetic Bidirectional Interphase Enabled by a Single Molecule for Ultra‐Stable Zn‐I 2 Batteries
inferred← citeshttps://doi.org/10.1002/smll.75316openalex-snapshot
Cellulose Tissue Separator With Aramid‐BaTiO 3 Composite Dielectric Coating Proactively Stabilizing Zinc Metal Anodes
inferred← citeshttps://doi.org/10.1002/smll.75735openalex-snapshot
Facilitated Zn 2+ Transport and Preferential Zn (100) Deposition Enabled by Amorphous ZrO x ‐C Hybrid Thin Film for High‐Performance Aqueous Zinc‐Ion Batteries
inferred← citeshttps://doi.org/10.1002/smm2.70034openalex-snapshot
Sputtered Ultra‐Thin TiO2 Interlayer for Highly Reversible Aqueous Zinc‐Ion Battery
inferred← citeshttps://doi.org/10.1002/smsc.202500466openalex-snapshot
Separator Design for High‐Performance Aqueous Zinc‐Ion Batteries: Recent Advances and Future Outlooks
inferred← citeshttps://doi.org/10.1002/smtd.202300965openalex-snapshot
Understanding the Role of Zinc Hydroxide Sulfate and its Analogues in Mildly Acidic Aqueous Zinc Batteries: A Review
inferred← citeshttps://doi.org/10.1002/smtd.202401936openalex-snapshot
Fast Kinetics Enabled by Ion Enrichment Layer for Dendrite−Free Zinc Anode
inferred← citeshttps://doi.org/10.1002/sus2.197openalex-snapshot
Three‐dimensional electrically conductive–hydrophobic layer for stable Zn metal anodes
inferred← citeshttps://doi.org/10.1002/sus2.70051openalex-snapshot
Highly Reversible and Safe Zinc‐Metal Anodes Enabled by a Functional and Antibacterial Interfacial Layer
inferred← citeshttps://doi.org/10.1002/tcr.70217openalex-snapshot
Artificial Solid Electrolyte Interphase Engineering Enables Stable Zinc Metal Anodes: Recent Advances and Perspectives
inferred← citeshttps://doi.org/10.1007/s11426-023-1940-1openalex-snapshot
Surficial modification enabling planar Al growth toward dendrite-free metal anodes for rechargeable aluminum batteries
inferred← citeshttps://doi.org/10.1007/s11581-026-07357-7openalex-snapshot
Synergistic engineering of CTAB-modified MoO2 microspheres for stable and kinetics-enhanced zinc-ion batteries
inferred← citeshttps://doi.org/10.1007/s11664-023-10789-wopenalex-snapshot
In Situ Constructing Solid Electrolyte Interphase and Optimizing Solvation Shell for a Stable Zn Anode
inferred← citeshttps://doi.org/10.1007/s11664-024-11397-yopenalex-snapshot
Glycine as a Bi-functional Electrolyte Additive for Favorable Zn Deposition
inferred← citeshttps://doi.org/10.1007/s11664-024-11466-2openalex-snapshot
Establishing a C,N,F-Solid Electrolyte Interphase and Poor-H2O Solvation Structure for Stabilizing Zinc Anodes
inferred← citeshttps://doi.org/10.1007/s11706-023-0668-2openalex-snapshot
Highly reversible and long-lived zinc anode assisted by polymer-based hydrophilic coating
inferred← citeshttps://doi.org/10.1007/s11708-025-1002-8openalex-snapshot
Surface electron reconfiguration of ceric dioxide artificial interface layer by cationic doping for dendrite-free zinc anode
inferred← citeshttps://doi.org/10.1007/s12274-023-5637-7openalex-snapshot
Roles of electrolyte additive in Zn chemistry
inferred← citeshttps://doi.org/10.1007/s12598-023-02541-4openalex-snapshot
Urea‐induced interfacial engineering enabling highly reversible aqueous zinc‐ion battery
inferred← citeshttps://doi.org/10.1007/s12598-024-02734-5openalex-snapshot
Application of carbon materials for Zn anode protection in aqueous Zn metal batteries
inferred← citeshttps://doi.org/10.1007/s12613-026-3369-xopenalex-snapshot
Carbon-based current collectors for stable aqueous Zn anodes
inferred← citeshttps://doi.org/10.1007/s13369-026-11133-0openalex-snapshot
Solid Electrolyte Interphase Membrane in Zinc-Ion Capacitors and Batteries: Formation Mechanism, Optimization Strategies, and Future Research Directions
inferred← citeshttps://doi.org/10.1007/s40820-025-01765-6openalex-snapshot
Aspartame Endowed ZnO-Based Self-Healing Solid Electrolyte Interface Film for Long-Cycling and Wide-Temperature Aqueous Zn-Ion Batteries
inferred← citeshttps://doi.org/10.1007/s41918-025-00271-yopenalex-snapshot
Recent Progress on Constructing Artificial Interfacial Layers for Zinc-Anodes-Stabilizing
inferred← citeshttps://doi.org/10.1016/j.apenergy.2026.127689openalex-snapshot
Research progress on in-situ strategies for modulating the anode/electrolyte interface in zinc-ion batteries
inferred← citeshttps://doi.org/10.1016/j.ccr.2026.217586openalex-snapshot
Rational design of artificial solid electrolyte interphases for stable zinc metal anodes: mechanistic insights, construction strategies, and practical implementation
inferred← citeshttps://doi.org/10.1016/j.cej.2024.149503openalex-snapshot
Zinc saponite protection layer with fast zinc-ion transfer kinetics to enable highly reversible Zn anode
inferred← citeshttps://doi.org/10.1016/j.cej.2024.153002openalex-snapshot
Improving zincophilicity and manipulating de-solvation effect enabling high-performance zinc metal anodes
inferred← citeshttps://doi.org/10.1016/j.cej.2024.153627openalex-snapshot
Defect engineering and in-situ electrochemical oxidation promote lattice reconstruction of VO2 for boosting the energy storage of aqueous zinc-ion batteries
inferred← citeshttps://doi.org/10.1016/j.cej.2025.160615openalex-snapshot
Challenges and strategies for zinc anodes in aqueous Zinc-Ion batteries
inferred← citeshttps://doi.org/10.1016/j.cej.2025.161633openalex-snapshot
Dual ions regulation strategy realizes long-life aqueous Zn-ion batteries
inferred← citeshttps://doi.org/10.1016/j.cej.2025.161688openalex-snapshot
Hollow and mesoporous nanospheres enable rapid ion migration on the zinc anode surface
inferred← citeshttps://doi.org/10.1016/j.cej.2025.163974openalex-snapshot
Progress and challenges of zinc ion capacitors: From basic principles to performance optimization strategies
inferred← citeshttps://doi.org/10.1016/j.cej.2025.164578openalex-snapshot
Lignocellulose aggregation effect facilitates zinc anode crystal plane optimization for dendrite-free zinc deposition
inferred← citeshttps://doi.org/10.1016/j.cej.2025.165509openalex-snapshot
Hyper-tolerant chloride/phosphate-rich interphase embracing aggressive zinc electrochemistry in hydrated eutectic electrolytes
inferred← citeshttps://doi.org/10.1016/j.cej.2025.167118openalex-snapshot
Organic-inorganic synergistic strategy: Sodium humate additive constructs high stability aqueous zinc ion energy storage systems
inferred← citeshttps://doi.org/10.1016/j.cej.2025.168861openalex-snapshot
Stable and high-capacity MnO2-organic aqueous “rocking chair” battery
inferred← citeshttps://doi.org/10.1016/j.cinorg.2024.100068openalex-snapshot
Synthesis and characterization of zinc cobalt sulphide nanofilms for optoelectronic applications
inferred← citeshttps://doi.org/10.1016/j.electacta.2025.146418openalex-snapshot
Revealing Zn stripping and plating behavior in ZnSO4, Zn(ClO4)2, and ZnCl2 as a function of current density and capacity in aqueous zinc ion batteries
inferred← citeshttps://doi.org/10.1016/j.ensm.2023.102882openalex-snapshot
Taurine-mediated dynamic bridging strategy for highly stable Zn metal anode
inferred← citeshttps://doi.org/10.1016/j.ensm.2024.103227openalex-snapshot
A mini review: How to select electrolyte additives for better Zn anode electrochemistry?
inferred← citeshttps://doi.org/10.1016/j.ensm.2024.103248openalex-snapshot
Strategies for pH regulation in aqueous zinc ion batteries
inferred← citeshttps://doi.org/10.1016/j.ensm.2024.103300openalex-snapshot
Carbon-based nanomaterials for stabilizing zinc metal anodes towards high-performance aqueous zinc-ion batteries
inferred← citeshttps://doi.org/10.1016/j.ensm.2024.103391openalex-snapshot
Ultrafast construction of porous zincophilic interphase within 10 s toward stable Zn metal anode through a selective zinc crystal growth
inferred← citeshttps://doi.org/10.1016/j.ensm.2024.103449openalex-snapshot
Blocking the passivation reaction via localized acidification and cation selective interface towards highly stable zinc anode
inferred← citeshttps://doi.org/10.1016/j.ensm.2024.103569openalex-snapshot
Bio-organic adenosine with bilateral asymmetric units remodels definitive interfacial for highly reversible Zn anode
inferred← citeshttps://doi.org/10.1016/j.ensm.2024.103628openalex-snapshot
Construction of stable Zn metal anode by inorganic functional protective layer toward long-life aqueous Zn-ion battery
inferred← citeshttps://doi.org/10.1016/j.ensm.2024.103629openalex-snapshot
Regulating solvation structure and enhancing anion-derived solid electrolyte interphase with N, N'-Dimethylpropyleneurea Co-solvent for long-term and dendrite-free Zn metal anodes
inferred← citeshttps://doi.org/10.1016/j.ensm.2024.103865openalex-snapshot
Achieving dendrite-free zinc deposition by large-size anion-reinforced solvated structures for highly reversible zinc anode
inferred← citeshttps://doi.org/10.1016/j.ensm.2025.104028openalex-snapshot
Regulation of Zn2+ desolvation kinetics via interfacial hydrogen-bond network for a highly reversible Zn metal anode
inferred← citeshttps://doi.org/10.1016/j.ensm.2025.104113openalex-snapshot
Bio-inspired biomass hydrogel interface with ion-selective responsive sieving mechanism for corrosion-resistant and dendrite-free zinc-iodine batteries
inferred← citeshttps://doi.org/10.1016/j.ensm.2025.104380openalex-snapshot
Tailored electronegative-driven MOF channels with bimetallic coordination for synergistic Zn2+ transport enabling dendrite-free Zn anodes
inferred← citeshttps://doi.org/10.1016/j.ensm.2025.104549openalex-snapshot
Interfacial triazine chemistry modulates zn deposition and suppresses shuttle effect for durable aqueous zinc bromine/iodine batteries over a wide-temperature-range
inferred← citeshttps://doi.org/10.1016/j.ensm.2025.104652openalex-snapshot
Crystallographic steering of Sn(200) layers via ionic liquid electrodeposition for ultrastable Zn metal anodes
inferred← citeshttps://doi.org/10.1016/j.ensm.2025.104683openalex-snapshot
Electrolytes for rechargeable calcium batteries: Addressing the constraints imposed by battery configuration and electrode materials
inferred← citeshttps://doi.org/10.1016/j.esci.2025.100410openalex-snapshot
Novel approaches to aqueous zinc-ion batteries: Challenges, strategies, and prospects
inferred← citeshttps://doi.org/10.1016/j.est.2025.116260openalex-snapshot
Anion-type solvation structure enables stable zinc‑iodine flow batteries
inferred← citeshttps://doi.org/10.1016/j.est.2025.116266openalex-snapshot
Suppressing intergranular corrosion and uniformizing Zn deposition for highly reversible anode toward high Zn utilization rate aqueous Zn ion battery
inferred← citeshttps://doi.org/10.1016/j.est.2025.116856openalex-snapshot
Ultra-stable and long-life zinc anodes enabled by porous cyclodextrin-based polymer coatings
inferred← citeshttps://doi.org/10.1016/j.est.2025.117155openalex-snapshot
Enhanced performance and stability of zinc-lon batteries via fucoidan-modified ZnSO4 electrolytes
inferred← citeshttps://doi.org/10.1016/j.est.2025.118638openalex-snapshot
Enhanced Zn2+ transfer kinetics and desolvation through a versatile silicon carbide ceramic coating for stable Zn anode in zinc-ion hybrid capacitors
inferred← citeshttps://doi.org/10.1016/j.est.2025.118875openalex-snapshot
Precise phase control of CuSn alloys on carbon felt via active screen plasma for highly reversible zinc metal anodes
inferred← citeshttps://doi.org/10.1016/j.jcis.2023.12.137openalex-snapshot
Nanosheet-structured ZnCo-LDH microsphere as active material for rechargeable zinc batteries
inferred← citeshttps://doi.org/10.1016/j.jcis.2024.05.014openalex-snapshot
Modulating solvated structure of Zn2+ and inducing surface crystallography by a simple organic molecule with abundant polar functional groups to synergistically stabilize zinc metal anodes for long-life aqueous zinc-ion batteries
inferred← citeshttps://doi.org/10.1016/j.jcis.2024.05.153openalex-snapshot
Engineering Sb/Zn4(OH)6SO4·5H2O interfacial layer by in situ chemically reacting for stable Zn anode
inferred← citeshttps://doi.org/10.1016/j.jechem.2024.08.061openalex-snapshot
Interfacial Zn2+-solvation regulator towards reversible and stable Zn anode
inferred← citeshttps://doi.org/10.1016/j.jechem.2024.09.053openalex-snapshot
Dual-phase interface engineering via parallel modulation strategy for highly reversible Zn metal batteries
inferred← citeshttps://doi.org/10.1016/j.jechem.2024.10.003openalex-snapshot
Stabilizing water and regulating interfacial electrostatic interaction with economical supporting salt for stable Zn metal anode
inferred← citeshttps://doi.org/10.1016/j.jiec.2025.07.057openalex-snapshot
Exfoliated LDH nanosheets for membrane-based wastewater treatment: surface engineering and performance
inferred← citeshttps://doi.org/10.1016/j.matt.2024.11.011openalex-snapshot
Regulating Zn2+ solvation structure in eutectic electrolytes for rechargeable zinc batteries
inferred← citeshttps://doi.org/10.1016/j.mtchem.2024.102059openalex-snapshot
Challenges and strategies for constructing stable zinc metal anodes in mild aqueous zinc-ion batteries
inferred← citeshttps://doi.org/10.1016/j.mtener.2024.101659openalex-snapshot
A HKUST-1 coating with copper metal active site enables stabilized zinc metal anode
inferred← citeshttps://doi.org/10.1016/j.mtener.2025.102042openalex-snapshot
Key issues in surface and interface of Zn anode and interfacial manipulation strategies toward high performance Zn-ion batteries
inferred← citeshttps://doi.org/10.1016/j.nanoen.2023.109053openalex-snapshot
Multifunctional fluorinated carbon dots artificial interface layer coupled with in-situ generated Zn2+ conductor interlayer enable ultra-stable Zn anode
inferred← citeshttps://doi.org/10.1016/j.nanoen.2024.109416openalex-snapshot
Advances in application of sustainable lignocellulosic materials for high-performance aqueous zinc-ion batteries
inferred← citeshttps://doi.org/10.1016/j.nanoen.2024.110430openalex-snapshot
A two-pronged approach:Bulk-phase substitution and second-phase synergism to enhance the anion redox stability of layered oxide cathode for sodium-ion batteries
inferred← citeshttps://doi.org/10.1016/j.nantod.2025.102806openalex-snapshot
Tuning planar and selective Zn evolution promoted by densely grown covalent organic framework towards high performance zinc batteries
inferred← citeshttps://doi.org/10.1021/acs.accounts.5c00226openalex-snapshot
Underscoring Covalent–Organic Frameworks As Nanoengines for Zinc Anode Protection Coating
inferred← citeshttps://doi.org/10.1021/acs.energyfuels.5c05783openalex-snapshot
Organic–Inorganic Nanoarchitectonics of Binder-Free Hybrid Protective Layer for Suppression of Dendrite Formation and Side Reactions with Stabilizing Zn Anodes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c05130openalex-snapshot
Disrupting the Crystal Growth of Corrosion Byproducts to Stabilize Aqueous Zn Metal Batteries
inferred← citeshttps://doi.org/10.1021/acs.langmuir.4c03380openalex-snapshot
Synergistic Long-Term Protection of Inorganic and Polymer Hybrid Coatings for Free-Dendrite Zinc Anodes
inferred← citeshttps://doi.org/10.1021/acs.langmuir.6c01156openalex-snapshot
Constructing a Zincophilic CNT@POF Coating on a Zn Anode for Dendrite-Free Aqueous Zinc-Ion Batteries
inferred← citeshttps://doi.org/10.1021/acs.nanolett.3c01481openalex-snapshot
Remodeling Zinc Deposition via Multisite Zincophilic Chlorophyll for Powerful Aprotic Zinc Batteries
inferred← citeshttps://doi.org/10.1021/acs.nanolett.3c03161openalex-snapshot
Understanding the Role of Titanium Metal–Organic Framework Nanosheets in Modulating Anode Chemistry for Aqueous Zinc-Ion Batteries
inferred← citeshttps://doi.org/10.1021/acs.nanolett.3c05034openalex-snapshot
In Situ Grown Coordination-Supramolecular Layer Holding 3D Charged Channels for Highly Reversible Zn Anodes
inferred← citeshttps://doi.org/10.1021/acs.nanolett.5c01125openalex-snapshot
Gradient Structured Separator Enables Stable Aqueous Zinc Metal Batteries
inferred← citeshttps://doi.org/10.1021/acs.nanolett.5c04178openalex-snapshot
Hybrid Coating with High Zn 2+ Selectivity Achieves Stable Zinc Anodes
inferred← citeshttps://doi.org/10.1021/acsaem.3c00605openalex-snapshot
Nitrogen-Doped Carbon Coated Na 3 V 2 (PO 4 ) 2 F 3 Derived from Polyvinylpyrrolidone as a High-Performance Cathode for Sodium-Ion Batteries
inferred← citeshttps://doi.org/10.1021/acsaem.5c00620openalex-snapshot
Recent Advances in Interfacial Engineering for High-Performance Zn Anodes: Challenges, Solutions, and Prospects
inferred← citeshttps://doi.org/10.1021/acsaem.6c00036openalex-snapshot
Functionalized Graphite Nanosheet Interfaces Enable (002)-Oriented Epitaxial Zinc Growth in Aqueous Zinc-Ion Batteries
inferred← citeshttps://doi.org/10.1021/acsami.4c02912openalex-snapshot
A Protective Layer of UIO-66/Reduced Graphene Oxide to Stabilize Zinc-Metal Anodes toward High-Performance Aqueous Zinc-Ion Batteries
inferred← citeshttps://doi.org/10.1021/acsami.4c05372openalex-snapshot
Improving Aqueous Zinc Ion Batteries with Alkali Metal Ions
inferred← citeshttps://doi.org/10.1021/acsami.5c00853openalex-snapshot
Suppressing Hydrogen Evolution and Dendrite Formation on a Zn Anode by Coating In2O3 with Tailored Affinity to H* and Zn*
inferred← citeshttps://doi.org/10.1021/acsami.5c06535openalex-snapshot
Artificial Protective Interfacial Layer Functionalized by In Situ Constructed Hydrophobic Polyphosphonitrile-Containing Polymer for Dendrite-Free Zinc Metal Anodes
inferred← citeshttps://doi.org/10.1021/acsami.5c19551openalex-snapshot
Gradient Interphase Engineering Enables Crystallographically Aligned Zinc Anodes for Dendrite-Free Electrochemistry
inferred← citeshttps://doi.org/10.1021/acsenergylett.4c00103openalex-snapshot
An Energetic Aqueous Mn Metal Anode
inferred← citeshttps://doi.org/10.1021/acsenergylett.4c00347openalex-snapshot
Retarding Deposition and Hydrogen Evolution Reaction Enables Stable and Reversible Zn Metal Anode
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