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Rigid and Flexible: A Highly Porous Metal–Organic Framework with Unusual Guest‐Dependent Dynamic Behavior

https://doi.org/10.1002/anie.200460712

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/1521-3757(20000616)112:12<2161::aid-ange2161>3.0.co;2-6openalex-snapshot

[{CuSiF6(4,4′-bipyridin)2}n], ein neues methanadsorbierendes poröses Koordinationspolymer

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A Breathing Hybrid Organic-Inorganic Solid with Very Large Pores and High Magnetic Characteristics

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Self-Assembly and Selective Guest Binding of Three-Dimensional Open-Framework Solids from a Macrocyclic Complex as a Trifunctional Metal Building Block

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Novel Flexible Frameworks of Porous Cobalt(II) Coordination Polymers That Show Selective Guest Adsorption Based on the Switching of Hydrogen-Bond Pairs of Amide Groups

inferredcites →https://doi.org/10.1002/1521-3773(20000616)39:12<2081::aid-anie2081>3.0.co;2-aopenalex-snapshot

A New, Methane Adsorbent, Porous Coordination Polymer [{CuSiF6(4,4′-bipyridine)2}n]

inferredcites →https://doi.org/10.1002/1521-3773(20020118)41:2<281::aid-anie281>3.0.co;2-yopenalex-snapshot

A Breathing Hybrid Organic–Inorganic Solid with Very Large Pores and High Magnetic Characteristics

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A Springlike 3D-Coordination Network That Shrinks or Swells in a Crystal-to-Crystal Manner upon Guest Removal or Readsorption

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Offene Metallcarboxylat‐Architekturen

inferredcites →https://doi.org/10.1002/ange.200300610openalex-snapshot

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inferredcites →https://doi.org/10.1002/ange.200390098openalex-snapshot

Porous Coordination‐Polymer Crystals with Gated Channels Specific for Supercritical Gases

inferredcites →https://doi.org/10.1002/anie.200300588openalex-snapshot

Metal Carboxylates with Open Architectures

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Functional Porous Coordination Polymers

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Hydrogen Sorption in Functionalized Metal−Organic Frameworks

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Establishing Microporosity in Open Metal−Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate)

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inferredcites →https://doi.org/10.1038/35010088openalex-snapshot

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inferredcites →https://doi.org/10.1038/46248openalex-snapshot

Design and synthesis of an exceptionally stable and highly porous metal-organic framework

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Dynamic channels of a porous coordination polymer responding to external stimuli

inferredcites →https://doi.org/10.1039/b200393gopenalex-snapshot

Metal-organic frameworks

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inferredcites →https://doi.org/10.1126/science.1067208openalex-snapshot

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inferred← citeshttps://doi.org/10.1002/anie.200500516openalex-snapshot

Supramolecular Coordination Assemblies of Dinuclear Fe III Complexes

inferred← citeshttps://doi.org/10.1002/anie.200502309openalex-snapshot

inferred← citeshttps://doi.org/10.1002/anie.200502844openalex-snapshot

A Microporous Metal–Organic Framework for Gas‐Chromatographic Separation of Alkanes

inferred← citeshttps://doi.org/10.1002/anie.200503023openalex-snapshot

A Homochiral Metal–Organic Material with Permanent Porosity, Enantioselective Sorption Properties, and Catalytic Activity

inferred← citeshttps://doi.org/10.1002/anie.200600105openalex-snapshot

Hydrogen Storage in the Giant‐Pore Metal–Organic Frameworks MIL‐100 and MIL‐101

inferred← citeshttps://doi.org/10.1002/anie.200600976openalex-snapshot

Metastable Sorption State of a Metal–Organic Porous Material Determined by In Situ Synchrotron Powder Diffraction

inferred← citeshttps://doi.org/10.1002/anie.200603270openalex-snapshot

A Flexible Porous Coordination Polymer Functionalized by Unsaturated Metal Clusters

inferred← citeshttps://doi.org/10.1002/anie.200604306openalex-snapshot

Assembly of Metal–Organic Frameworks (MOFs) Based on Indium‐Trimer Building Blocks: A Porous MOF with soc Topology and High Hydrogen Storage

inferred← citeshttps://doi.org/10.1002/anie.200604362openalex-snapshot

Observation of Cu2+–H2 Interactions in a Fully Desolvated Sodalite‐Type Metal–Organic Framework

inferred← citeshttps://doi.org/10.1002/anie.200700218openalex-snapshot

Exceptional Negative Thermal Expansion in Isoreticular Metal–Organic Frameworks

inferred← citeshttps://doi.org/10.1002/anie.200700242openalex-snapshot

Topotactic Linear Radical Polymerization of Divinylbenzenes in Porous Coordination Polymers

inferred← citeshttps://doi.org/10.1002/anie.200700999openalex-snapshot

Thermo‐to‐Photo‐Switching of the Chromic Behavior of Salicylideneanilines by Inclusion in a Porous Coordination Network

inferred← citeshttps://doi.org/10.1002/anie.200701252openalex-snapshot

Copper β‐Diketonate Molecular Squares and Their Host–Guest Reactions

inferred← citeshttps://doi.org/10.1002/anie.200702390openalex-snapshot

Two‐Step Adsorption/Desorption on a Jungle‐Gym‐Type Porous Coordination Polymer

inferred← citeshttps://doi.org/10.1002/anie.200704347openalex-snapshot

Self‐Assembly of a Homochiral Nanoscale Metallacycle from a Metallosalen Complex for Enantioselective Separation

inferred← citeshttps://doi.org/10.1002/anie.200704809openalex-snapshot

A Selective Instant Synthesis of a Coordination Network and Its Ab Initio Powder Structure Determination

inferred← citeshttps://doi.org/10.1002/anie.200802803openalex-snapshot

A Bistable Porous Coordination Polymer with a Bond‐Switching Mechanism Showing Reversible Structural and Functional Transformations

inferred← citeshttps://doi.org/10.1002/anie.200804836openalex-snapshot

Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core–Shell Single Crystals with an In‐Plane Rotational Epitaxial Relationship

inferred← citeshttps://doi.org/10.1002/anie.200901177openalex-snapshot

Nanoporous Nanorods Fabricated by Coordination Modulation and Oriented Attachment Growth

inferred← citeshttps://doi.org/10.1002/anie.200906583openalex-snapshot

Ion‐ and Liquid‐Assisted Grinding: Improved Mechanochemical Synthesis of Metal–Organic Frameworks Reveals Salt Inclusion and Anion Templating

inferred← citeshttps://doi.org/10.1002/anie.201001735openalex-snapshot

A Highly Porous Metal–Organic Framework with Open Nickel Sites

inferred← citeshttps://doi.org/10.1002/anie.201002259openalex-snapshot

Control of Interpenetration for Tuning Structural Flexibility Influences Sorption Properties

inferred← citeshttps://doi.org/10.1002/anie.201101924openalex-snapshot

Sequential Functionalization of Porous Coordination Polymer Crystals

inferred← citeshttps://doi.org/10.1002/anie.201104240openalex-snapshot

Enantiopure Metal–Organic Framework Thin Films: Oriented SURMOF Growth and Enantioselective Adsorption

inferred← citeshttps://doi.org/10.1002/anie.201106429openalex-snapshot

Metal–Organic Framework Regioisomers Based on Bifunctional Ligands

inferred← citeshttps://doi.org/10.1002/anie.201207908openalex-snapshot

Metal–Organic Framework Thin Films: Crystallite Orientation Dependent Adsorption

inferred← citeshttps://doi.org/10.1002/anie.201300057openalex-snapshot

Mixed‐Linker Hybrid Superpolyhedra for the Production of a Series of Large‐Pore Iron(III) Carboxylate Metal–Organic Frameworks

inferred← citeshttps://doi.org/10.1002/anie.201410252openalex-snapshot

“Heterogeneity within Order” in Metal–Organic Frameworks

inferred← citeshttps://doi.org/10.1002/anie.201604023openalex-snapshot

Precise Modulation of the Breathing Behavior and Pore Surface in Zr‐MOFs by Reversible Post‐Synthetic Variable‐Spacer Installation to Fine‐Tune the Expansion Magnitude and Sorption Properties

inferred← citeshttps://doi.org/10.1002/anie.201608463openalex-snapshot

Time‐Resolved In Situ X‐ray Diffraction Reveals Metal‐Dependent Metal–Organic Framework Formation

inferred← citeshttps://doi.org/10.1002/anie.201611338openalex-snapshot

Anisotropically Swelling Gels Attained through Axis‐Dependent Crosslinking of MOF Crystals

inferred← citeshttps://doi.org/10.1002/anie.201800820openalex-snapshot

Reversible Switching between Highly Porous and Nonporous Phases of an Interpenetrated Diamondoid Coordination Network That Exhibits Gate‐Opening at Methane Storage Pressures

inferred← citeshttps://doi.org/10.1002/anie.201905876openalex-snapshot

Lock‐and‐Key and Shape‐Memory Effects in an Unconventional Synthetic Path to Magnesium Metal–Organic Frameworks

inferred← citeshttps://doi.org/10.1002/anie.201909977openalex-snapshot

Tuning the Gate‐Opening Pressure in a Switching pcu Coordination Network, X‐pcu‐5‐Zn, by Pillar‐Ligand Substitution

inferred← citeshttps://doi.org/10.1002/anie.202003186openalex-snapshot

Structural‐Deformation‐Energy‐Modulation Strategy in a Soft Porous Coordination Polymer with an Interpenetrated Framework

inferred← citeshttps://doi.org/10.1002/anie.202011004openalex-snapshot

Configurational Entropy Driven High‐Pressure Behaviour of a Flexible Metal–Organic Framework (MOF)

inferred← citeshttps://doi.org/10.1002/anie.202105229openalex-snapshot

Capture and Separation of SO2 Traces in Metal–Organic Frameworks via Pre‐Synthetic Pore Environment Tailoring by Methyl Groups

inferred← citeshttps://doi.org/10.1002/anie.202218076openalex-snapshot

Understanding MOF Flexibility: An Analysis Focused on Pillared Layer MOFs as a Model System

inferred← citeshttps://doi.org/10.1002/anie.202300233openalex-snapshot

Metal‐Organic Framework Supported Copper Photoredox Catalysts for Iminyl Radical‐Mediated Reactions

inferred← citeshttps://doi.org/10.1002/anie.202309985openalex-snapshot

Shape‐Memory Effect Enabled by Ligand Substitution and CO2 Affinity in a Flexible SIFSIX Coordination Network

inferred← citeshttps://doi.org/10.1002/anie.202512244openalex-snapshot

Highly Selective Adsorption of Para‐Xylene, Ethylbenzene, and Explicit Exclusion of Ortho‐Xylene from Xylene Isomers Using a Pillar‐Layered MOF with Tuned Pore Channels

inferred← citeshttps://doi.org/10.1002/anie.202513518openalex-snapshot

Regioselective Separation and Extraction of Polyalkylthiophene by Metal–Organic Frameworks

inferred← citeshttps://doi.org/10.1002/anse.70098openalex-snapshot

129 Xe Nuclear Magnetic Resonance Spectroscopy of Metal–Organic Frameworks

inferred← citeshttps://doi.org/10.1002/aoc.70656openalex-snapshot

Chitosan‐Conjugated Folic Acid–Functionalized Zn‐MOF Nanocarrier for pH‐Responsive Targeted Capecitabine Delivery in Hepatocellular Carcinoma

inferred← citeshttps://doi.org/10.1002/asia.200600054openalex-snapshot

Interpenetrating Coordination Polymers from CuI or AgI and Flexible Ligands: 2D Polyrotaxanes and Interpenetrating Grids

inferred← citeshttps://doi.org/10.1002/asia.200600074openalex-snapshot

Polymerization in Coordination Nanospaces

inferred← citeshttps://doi.org/10.1002/asia.200600390openalex-snapshot

Microporous Magnesium and Manganese Formates for Acetylene Storage and Separation

inferred← citeshttps://doi.org/10.1002/asia.200800112openalex-snapshot

Storage and Sorption Properties of Acetylene in Jungle‐Gym‐Like Open Frameworks

inferred← citeshttps://doi.org/10.1002/asia.200800458openalex-snapshot

Control of Structure Dimensionality and Functional Studies of Flexible CuII Coordination Polymers

inferred← citeshttps://doi.org/10.1002/asia.200900020openalex-snapshot

Methane Sorption and Structural Characterization of the Sorption Sites in Zn2(bdc)2(dabco) by Single Crystal X‐ray Crystallography

inferred← citeshttps://doi.org/10.1002/asia.201501422openalex-snapshot

Supramolecular Porphyrin‐Based Metal–Organic Frameworks with Fullerenes: Crystal Structures and Preferential Intercalation of C70

inferred← citeshttps://doi.org/10.1002/asia.202101305openalex-snapshot

Coordination Flexibility Aided CO2‐specific Gating in an Iron Isonicotinate MOF

inferred← citeshttps://doi.org/10.1002/asia.202500966openalex-snapshot

Toward the Rational Design of Ion‐Conducting Ionic Liquid‐Incorporated Metal–Organic Framework Hybrids

inferred← citeshttps://doi.org/10.1002/bkcs.12145openalex-snapshot

Hierarchical Porous Carbon Materials Prepared by Direct Carbonization of Metal–Organic Frameworks as an Electrode Material for Supercapacitors

inferred← citeshttps://doi.org/10.1002/chem.200401201openalex-snapshot

Synthesis, X‐ray Crystal Structures, and Gas Sorption Properties of Pillared Square Grid Nets Based on Paddle‐Wheel Motifs: Implications for Hydrogen Storage in Porous Materials

inferred← citeshttps://doi.org/10.1002/chem.200500548openalex-snapshot

Rationally Designed, Polymeric, Extended Metal–Ciprofloxacin Complexes

inferred← citeshttps://doi.org/10.1002/chem.200501308openalex-snapshot

A Bridge between Pillared‐Layer and Helical Structures: A Series of Three‐Dimensional Pillared Coordination Polymers with Multiform Helical Chains

inferred← citeshttps://doi.org/10.1002/chem.200802093openalex-snapshot

Alkali Metal Cation (K+, Cs+) Induced Dissolution/Reorganization of Porous Metal Carboxylate Coordination Networks in Water

inferred← citeshttps://doi.org/10.1002/chem.200802292openalex-snapshot

Enhancement of H2 Adsorption in Coordination Framework Materials by Use of Ligand Curvature

inferred← citeshttps://doi.org/10.1002/chem.200900552openalex-snapshot

Temperature‐Dependent Guest‐Driven Single‐Crystal‐to‐Single‐Crystal Ligand Exchange in a Two‐Fold Interpenetrated CdII Grid Network

inferred← citeshttps://doi.org/10.1002/chem.200901929openalex-snapshot

Thermally Stable Porous Hydrogen‐Bonded Coordination Networks Displaying Dual Properties of Robustness and Dynamics upon Guest Uptake

inferred← citeshttps://doi.org/10.1002/chem.200902036openalex-snapshot

Facile Purification of Porous Metal Terephthalates with Ultrasonic Treatment in the Presence of Amides

inferred← citeshttps://doi.org/10.1002/chem.200902382openalex-snapshot

Synthesis of a Metal–Organic Framework Material, Iron Terephthalate, by Ultrasound, Microwave, and Conventional Electric Heating: A Kinetic Study

inferred← citeshttps://doi.org/10.1002/chem.201002341openalex-snapshot

Flexibility and Sorption Selectivity in Rigid Metal–Organic Frameworks: The Impact of Ether‐Functionalised Linkers

inferred← citeshttps://doi.org/10.1002/chem.201002818openalex-snapshot

Enhancing Gas Adsorption and Separation Capacity through Ligand Functionalization of Microporous Metal–Organic Framework Structures

inferred← citeshttps://doi.org/10.1002/chem.201003364openalex-snapshot

The Route to a Feasible Hydrogen‐Storage Material: MOFs versus Ammonia Borane

inferred← citeshttps://doi.org/10.1002/chem.201003376openalex-snapshot

A Highly Porous Metal–Organic Framework: Structural Transformations of a Guest‐Free MOF Depending on Activation Method and Temperature

inferred← citeshttps://doi.org/10.1002/chem.201003680openalex-snapshot

Selective CO2 Adsorption by a Triazacyclononane‐Bridged Microporous Metal–Organic Framework

inferred← citeshttps://doi.org/10.1002/chem.201100226openalex-snapshot

Rational Design of Zinc–Organic Coordination Polymers Directed by N‐Donor Co‐ligands

inferred← citeshttps://doi.org/10.1002/chem.201101383openalex-snapshot

Route to a Family of Robust, Non‐interpenetrated Metal–Organic Frameworks with pto‐like Topology

inferred← citeshttps://doi.org/10.1002/chem.201202899openalex-snapshot

Metal‐Ion Metathesis in Metal–Organic Frameworks: A Synthetic Route to New Metal–Organic Frameworks

inferred← citeshttps://doi.org/10.1002/chem.201502648openalex-snapshot

Versatile Tailoring of Paddle‐Wheel ZnII Metal–Organic Frameworks through Single‐Crystal‐to‐Single‐Crystal Transformations

inferred← citeshttps://doi.org/10.1002/chem.201503685openalex-snapshot

Influence of Solvent‐Like Sidechains on the Adsorption of Light Hydrocarbons in Metal–Organic Frameworks

inferred← citeshttps://doi.org/10.1002/chem.201600162openalex-snapshot

Porphyrin–Alkaline Earth MOFs with the Highest Adsorption Capacity for Methylene Blue

inferred← citeshttps://doi.org/10.1002/chem.201605507openalex-snapshot

Continuous One‐Step Synthesis of Porous M‐XF6‐Based Metal‐Organic and Hydrogen‐Bonded Frameworks

inferred← citeshttps://doi.org/10.1002/chem.201801157openalex-snapshot

Phase Transition Induced by Gas Adsorption in Metal‐Organic Frameworks

inferred← citeshttps://doi.org/10.1002/chem.201805028openalex-snapshot

Complex Phase Behaviour and Structural Transformations of Metal‐Organic Frameworks with Mixed Rigid and Flexible Bridging Ligands

inferred← citeshttps://doi.org/10.1002/chem.201903210openalex-snapshot

Effect of the Metal within Regioisomeric Paddle‐Wheel‐Type Metal–Organic Frameworks

inferred← citeshttps://doi.org/10.1002/chem.202001438openalex-snapshot

Competing Roles of Two Kinds of Ligand during Nonclassical Crystallization of Pillared‐Layer Metal‐Organic Frameworks Elucidated Using Microfluidic Systems

inferred← citeshttps://doi.org/10.1002/chem.202102640openalex-snapshot

Breathing‐Assisted Selective Adsorption of C 8 Alkyl Aromatics in Zn‐Based Metal‐Organic Frameworks

inferred← citeshttps://doi.org/10.1002/cjoc.201500625openalex-snapshot

Research Progress of Metal‐Organic Frameworks Based on Aromatic Polycarboxylic Acid

inferred← citeshttps://doi.org/10.1002/cphc.201300976openalex-snapshot

Targeted Manipulation of Metal–Organic Frameworks To Direct Sorption Properties

inferred← citeshttps://doi.org/10.1002/cplu.202000206openalex-snapshot

Cyclic Aliphatic Hydrocarbons as Linkers in Metal‐Organic Frameworks: New Frontiers for Ligand Design

inferred← citeshttps://doi.org/10.1002/cssc.202300069openalex-snapshot

Metal Doping to Control Gate Opening and Increase Methane Working Capacity in Isostructural Flexible Diamondoid Networks

inferred← citeshttps://doi.org/10.1002/cssc.202400885openalex-snapshot

Reticular Imine‐Linked Coordination Polymers Based on Paddlewheel Diruthenium/Dirhodium Nodes: Synthesis and Metal‐Site Dependent Photocatalytic Reduction of CO2

inferred← citeshttps://doi.org/10.1002/ejic.200500217openalex-snapshot

Multiple Regulated Assembly, Crystal Structures and Magnetic Properties of Porous Coordination Polymers with Flexible Ligands

inferred← citeshttps://doi.org/10.1002/ejic.200600713openalex-snapshot

Cadmium(II) and Zinc(II) Coordination Polymers with 1D Ladder and 2D Basket Weave Layer Structures Constructed from a New T‐Shaped Ligand

inferred← citeshttps://doi.org/10.1002/ejic.200700818openalex-snapshot

From Interwoven to Noninterpenetration: Crystal Structural Motifs of Two New Manganese–Organic Frameworks Mediated by the Substituted Group of the Bridging Ligand

inferred← citeshttps://doi.org/10.1002/ejic.200701284openalex-snapshot

Base‐Induced Formation of Two Magnesium Metal‐Organic Framework Compounds with a Bifunctional Tetratopic Ligand

inferred← citeshttps://doi.org/10.1002/ejic.200701335openalex-snapshot

Metal‐Organic Frameworks (MOFs) Composed of (Triptycenedicarboxylato)zinc

inferred← citeshttps://doi.org/10.1002/ejic.200800108openalex-snapshot

Solvent‐Mediated Ion Exchange and Structural Transformations of Cluster‐Based Coordination Polymers

inferred← citeshttps://doi.org/10.1002/ejic.200900144openalex-snapshot

Syntheses, Crystal Structures and Adsorption Properties of Ultramicroporous Coordination Polymers Constructed from Hexafluorosilicate Ions and Pyrazine

inferred← citeshttps://doi.org/10.1002/ejic.201000393openalex-snapshot

Systematic Hydrothermal Investigation of Metal Phosphonatobenzenesulfonates by High‐Throughput Methods

inferred← citeshttps://doi.org/10.1002/ejic.201000395openalex-snapshot

A Hydroscopic Self‐Catenated Net Formed by Borromean Layers Interlocked by Ferrocenyl Bridging Ligands

inferred← citeshttps://doi.org/10.1002/ejic.201000402openalex-snapshot

Construction of Metal‐Organic Frameworks with the Pyridine‐3,5‐dicarboxylate Anion and Bis(imidazole) Ligands: Synthesis, Structure, and Thermostability Studies

inferred← citeshttps://doi.org/10.1002/ejic.201000436openalex-snapshot

A Dynamically Entangled Coordination Polymer: Synthesis, Structure, Luminescence, Single‐Crystal‐to‐Single‐Crystal Reversible Guest Inclusion and Structural Transformation

inferred← citeshttps://doi.org/10.1002/ejic.201100227openalex-snapshot

Solvothermal Synthesis and Structural Characterisation of Metal‐Organic Frameworks with Paddle‐Wheel Zinc Carboxylate Clusters and Mixed Ligands

inferred← citeshttps://doi.org/10.1002/ejic.201500245openalex-snapshot

Zn‐MOFs Containing Pyridine and Bipyridine Carboxylate Organic Linkers and Open Zn2+ Sites

inferred← citeshttps://doi.org/10.1002/ejic.201600120openalex-snapshot

Exchange Method Using Acid‐Solvent Synergy for Metal–Organic Framework Synthesis (EASY‐MOFs) Based on a Typical Pillar‐Layered Parent Structure

inferred← citeshttps://doi.org/10.1002/ejic.201600134openalex-snapshot

Carboxylate–Hydrazone Mixed‐Linker Metal–Organic Frameworks: Synthesis, Structure, and Selective Gas Adsorption

inferred← citeshttps://doi.org/10.1002/ejic.201600645openalex-snapshot

Three‐Dimensional Co‐ and Mn‐MOFs Containing a C2h‐Symmetric Terphenyl‐3,3′‐dicarboxylate Linker and Their Magnetic Properties

inferred← citeshttps://doi.org/10.1002/ejic.201800124openalex-snapshot

Coordination Polymers with Intriguing Photoluminescence Behavior: The Promising Avenue for Greatest Long‐Lasting Phosphors

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