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Regioselectively Functionalized Pyridines from Sustainable Resources

https://doi.org/10.1002/anie.201301919

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Direct Synthesis of Imines from Alcohols and Amines with Liberation of H 2

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Selective Ruthenium‐Catalyzed Three‐Component Synthesis of Pyrroles

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Direct Synthesis of Pyrroles by Dehydrogenative Coupling of β‐Aminoalcohols with Secondary Alcohols Catalyzed by Ruthenium Pincer Complexes

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Recent Strategies for the Synthesis of Pyridine Derivatives

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α,ω‐Functionalized C19 Monomers

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Poly(vinyl pyridine)s: Simple reactive polymers with multiple applications

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Pyridines and their Benzo Derivatives: Synthesis

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De novo synthesis of substituted pyridines

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What points at this work

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Cu(II) Metal–Organic Framework as a Recyclable Heterogeneous Catalyst for Substituted Pyridine Synthesis from Cyclic Ketones with Propargylamine

inferred← citeshttps://doi.org/10.1021/acs.joc.0c02764openalex-snapshot

Sustainable Four-Component Annulation for the Synthesis of 2,3,4,6-Tetraarylpyridines

inferred← citeshttps://doi.org/10.1021/acs.joc.0c03038openalex-snapshot

Cu-Catalyzed Pyridine Synthesis via Oxidative Annulation of Cyclic Ketones with Propargylamine

inferred← citeshttps://doi.org/10.1021/acs.joc.1c00714openalex-snapshot

Catalytic Acceptorless Dehydrogenation of Amino Alcohols and 2-Hydroxybenzyl Alcohols for Annulation Reaction under Neutral Conditions

inferred← citeshttps://doi.org/10.1021/acs.joc.2c02867openalex-snapshot

Zn(II)-Catalyzed Multicomponent Sustainable Synthesis of Pyridines in Air

inferred← citeshttps://doi.org/10.1021/acs.joc.4c02910openalex-snapshot

Divergent Synthesis of Polysubstituted 1,2-Dihydropyridines and Pyridines through Manganese-Mediated Radical Cascade Cyclization of Tertiary Enamides

inferred← citeshttps://doi.org/10.1021/acs.joc.5b01065openalex-snapshot

Regioselective Pd-Catalyzed Synthesis of 2,3,6-Trisubstituted Pyridines from Isoxazolinones

inferred← citeshttps://doi.org/10.1021/acs.joc.5b01975openalex-snapshot

Synthesis of a-Alkylated Ketones via Tandem Acceptorless Dehydrogenation/a-Alkylation from Secondary and Primary Alcohols Catalyzed by Metal–Ligand Bifunctional Iridium Complex [Cp*Ir(2,2′-bpyO)(H2O)]

inferred← citeshttps://doi.org/10.1021/acs.joc.5c01531openalex-snapshot

Microwave-Driven Solventless Nickel Metalloradical-Catalyzed [2 + 2 + 1 + 1] Cascade Annulation of Polysubstituted Pyridines

inferred← citeshttps://doi.org/10.1021/acs.joc.7b01501openalex-snapshot

Divergent Synthesis of Functionalized Quinolines from Aniline and Two Distinct Amino Acids

inferred← citeshttps://doi.org/10.1021/acs.joc.8b01668openalex-snapshot

Direct Biomimetic Synthesis of β-Carboline Alkaloids from Two Amino Acids

inferred← citeshttps://doi.org/10.1021/acs.joc.8b03070openalex-snapshot

Dehydrogenative Synthesis of Quinolines, 2-Aminoquinolines, and Quinazolines Using Singlet Diradical Ni(II)-Catalysts

inferred← citeshttps://doi.org/10.1021/acs.joc.9b01343openalex-snapshot

Metal–Ligand Cooperative Approach To Achieve Dehydrogenative Functionalization of Alcohols to Quinolines and Quinazolin-4(3H)-ones under Mild Aerobic Conditions

inferred← citeshttps://doi.org/10.1021/acs.joc.9b03315openalex-snapshot

One-Pot Amberlyst 15-Controlled Cyclocondensation of Piperidines and Arylaldehydes: Synthesis of 3,5-Diarylmethylpyridines

inferred← citeshttps://doi.org/10.1021/acs.organomet.2c00667openalex-snapshot

Mechanistic Elucidation of an Alcohol Oxidation Reaction Promoted by a Nickel Azophenolate Complex

inferred← citeshttps://doi.org/10.1021/acs.organomet.7b00774openalex-snapshot

A Versatile Ru(II)-NNP Complex Catalyst for the Synthesis of Multisubstituted Pyrroles and Pyridines

inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00300openalex-snapshot

Synthesis, Characterization, and Catalytic Studies of Unsymmetrical Chiral NCC Pincer Pd(II) and Ni(II) Complexes Bearing (Imidazolinyl)aryl NHC Ligands

inferred← citeshttps://doi.org/10.1021/acs.organomet.8b00359openalex-snapshot

NNN-Ruthenium Catalysts for the Synthesis of Pyridines, Quinolines, and Pyrroles by Acceptorless Dehydrogenative Condensation

inferred← citeshttps://doi.org/10.1021/acs.orglett.5b00266openalex-snapshot

Synthesis of Pyrazoles from 1,3-Diols via Hydrogen Transfer Catalysis

inferred← citeshttps://doi.org/10.1021/acs.orglett.5b01733openalex-snapshot

Base-Promoted N-Pyridylation of Heteroarenes Using N -Propargyl Enaminones as Equivalents of Pyridine Scaffolds

inferred← citeshttps://doi.org/10.1021/acs.orglett.5b03699openalex-snapshot

Hydrogen-Transfer-Mediated Direct β-Alkylation of Aryl-1,8-naphthyridines with Alcohols under Transition Metal Catalyst Free Conditions

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c00099openalex-snapshot

Visible-Light-Induced Decarboxylative Annulation of α,β-Unsaturated Acids with Amines and α-Keto Acids for 2,4-Diarylquinoline Synthesis

inferred← citeshttps://doi.org/10.1021/acs.orglett.6b00326openalex-snapshot

Iron-Catalyzed Cyclization of Ketoxime Carboxylates and Tertiary Anilines for the Synthesis of Pyridines

inferred← citeshttps://doi.org/10.1021/acs.orglett.6c02844openalex-snapshot

From Esters to Benzodiazepines: A Two-Step Nickel–Iridium Catalytic Pathway via Amide Intermediates

inferred← citeshttps://doi.org/10.1021/acs.orglett.7b01232openalex-snapshot

Oxidative Trimerization of Amino Acids: Selective Synthesis of 2,3,5-Trisubstituted Pyridines

inferred← citeshttps://doi.org/10.1021/acs.orglett.7b03726openalex-snapshot

Ligand-Controlled Copper(I)-Catalyzed Cross-Coupling of Secondary and Primary Alcohols to α-Alkylated Ketones, Pyridines, and Quinolines

inferred← citeshttps://doi.org/10.1021/acs.orglett.8b02256openalex-snapshot

Nickel-Catalyzed Hydrogen-Borrowing Strategy for α-Alkylation of Ketones with Alcohols: A New Route to Branched gem-Bis(alkyl) Ketones

inferred← citeshttps://doi.org/10.1021/acscatal.3c00067openalex-snapshot

Relay C–H Functionalization Enables De Novo Synthesis of Pyridines and Pyridones

inferred← citeshttps://doi.org/10.1021/acscatal.5b02638openalex-snapshot

A Ruthenium Catalyst with Unprecedented Effectiveness for the Coupling Cyclization of γ-Amino Alcohols and Secondary Alcohols

inferred← citeshttps://doi.org/10.1021/acscatal.5c01416openalex-snapshot

Iridium-Catalyzed Monoamination of Polyols toward Amino Alcohols or Amino Acids

inferred← citeshttps://doi.org/10.1021/acscatal.6b00175openalex-snapshot

Ruthenium-Catalyzed Amination of Secondary Alcohols Using Borrowing Hydrogen Methodology

inferred← citeshttps://doi.org/10.1021/acscatal.8b02208openalex-snapshot

Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes

inferred← citeshttps://doi.org/10.1021/acscatal.8b02814openalex-snapshot

Acceptorless Dehydrogenative Synthesis of Pyrimidines from Alcohols and Amidines Catalyzed by Supported Platinum Nanoparticles

inferred← citeshttps://doi.org/10.1021/acscatal.8b02869openalex-snapshot

Homogeneous Catalysis by Cobalt and Manganese Pincer Complexes

inferred← citeshttps://doi.org/10.1021/acscombsci.6b00042openalex-snapshot

Synthesis of High-Load, Hybrid Silica-Immobilized Heterocyclic Benzyl Phosphate (Si–OHBP) and Triazolyl Phosphate (Si–OHTP) Alkylating Reagents

inferred← citeshttps://doi.org/10.1021/acscombsci.8b00140openalex-snapshot

Synthesis of D-Ring Annulated Pyridosteroids from β-Formyl Enamides and Their Biological Evaluations

inferred← citeshttps://doi.org/10.1021/acsomega.2c00773openalex-snapshot

Iridium-Catalyzed C–H Borylation of CF3-Substituted Pyridines

inferred← citeshttps://doi.org/10.1021/acsorginorgau.3c00048openalex-snapshot

Diazines and Triazines as Building Blocks in Ligands for Metal-Mediated Catalytic Transformations

inferred← citeshttps://doi.org/10.1021/acssuschemeng.2c01222openalex-snapshot

Single-Molecular Mn(I)-Complex-Catalyzed Tandem Double Dehydrogenation Cross-Coupling of (Amino)Alcohols under Solventless Conditions with the Liberation of H2 and H2O

inferred← citeshttps://doi.org/10.1021/cr5002782openalex-snapshot

Bond Activation and Catalysis by Ruthenium Pincer Complexes

inferred← citeshttps://doi.org/10.1021/ja412444dopenalex-snapshot

Rh(III)-Catalyzed Decarboxylative Coupling of Acrylic Acids with Unsaturated Oxime Esters: Carboxylic Acids Serve as Traceless Activators

inferred← citeshttps://doi.org/10.1021/jacs.4c13266openalex-snapshot

A Catalytic Version of the Knorr Pyrrole Synthesis Permits Access to Pyrroles and Pyridines

inferred← citeshttps://doi.org/10.1021/jacs.5b04349openalex-snapshot

A Highly Active and Easily Accessible Cobalt Catalyst for Selective Hydrogenation of C═O Bonds

inferred← citeshttps://doi.org/10.1021/jacs.5b06400openalex-snapshot

Ruthenium-Catalyzed Formal Dehydrative [4 + 2] Cycloaddition of Enamides and Alkynes for the Synthesis of Highly Substituted Pyridines: Reaction Development and Mechanistic Study

inferred← citeshttps://doi.org/10.1021/jacs.5b09510openalex-snapshot

A Sustainable Multicomponent Pyrimidine Synthesis

inferred← citeshttps://doi.org/10.1021/jacs.6b06448openalex-snapshot

General and Mild Cobalt-Catalyzed C-Alkylation of Unactivated Amides and Esters with Alcohols

inferred← citeshttps://doi.org/10.1021/jacs.6b10433openalex-snapshot

Sustainable Synthesis of Quinolines and Pyrimidines Catalyzed by Manganese PNP Pincer Complexes

inferred← citeshttps://doi.org/10.1021/jacs.7b10496openalex-snapshot

Direct Asymmetric Ruthenium-Catalyzed Reductive Amination of Alkyl–Aryl Ketones with Ammonia and Hydrogen

inferred← citeshttps://doi.org/10.1021/jacs.8b08385openalex-snapshot

Acceptorless Dehydrogenative Coupling Using Ammonia: Direct Synthesis of N-Heteroaromatics from Diols Catalyzed by Ruthenium

inferred← citeshttps://doi.org/10.1021/ol501183zopenalex-snapshot

Ruthenium-Catalyzed Cyclization of Ketoxime Acetates with DMF for Synthesis of Symmetrical Pyridines

inferred← citeshttps://doi.org/10.1021/ol501493hopenalex-snapshot

A Novel Straightforward Synthesis of 2,4-Disubstituted-1,3,5-triazines via Aerobic Copper-Catalyzed Cyclization of Amidines with DMF

inferred← citeshttps://doi.org/10.1021/ol503752kopenalex-snapshot

Aza-Annulation of Enynyl Azides: A New Approach to Substituted Pyridines

inferred← citeshttps://doi.org/10.1038/ncomms12641openalex-snapshot

Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes

inferred← citeshttps://doi.org/10.1038/ncomms13201openalex-snapshot

Single-catalyst high-weight% hydrogen storage in an N-heterocycle synthesized from lignin hydrogenolysis products and ammonia

inferred← citeshttps://doi.org/10.1038/s41467-018-04143-6openalex-snapshot

Catalytic condensation for the formation of polycyclic heteroaromatic compounds

inferred← citeshttps://doi.org/10.1038/s41467-023-36220-wopenalex-snapshot

Rational design of N-heterocyclic compound classes via regenerative cyclization of diamines

inferred← citeshttps://doi.org/10.1039/c3dt53052copenalex-snapshot

Synthesis and catalytic alcohol oxidation and ketone transfer hydrogenation activity of donor-functionalized mesoionic triazolylidene ruthenium( ii ) complexes

inferred← citeshttps://doi.org/10.1039/c3ob42589dopenalex-snapshot

An efficient ruthenium-catalyzed dehydrogenative synthesis of 2,4,6-triaryl-1,3,5-triazines from aryl methanols and amidines

inferred← citeshttps://doi.org/10.1039/c4cy01018copenalex-snapshot

The synthesis of pyrroles via acceptorless dehydrogenative condensation of secondary alcohols and 1,2-amino alcohols mediated by a robust and reusable catalyst based on nanometer-sized iridium particles

inferred← citeshttps://doi.org/10.1039/c4ob01565gopenalex-snapshot

Iridium-catalyzed C–H borylation of pyridines

inferred← citeshttps://doi.org/10.1039/c4ra00039kopenalex-snapshot

Ruthenium/Yb(OTf) 3 -cocatalyzed dehydrogenative synthesis of 14-substituted-14-H-dibenzo[a,j]xanthenes from β-naphthol and alcohols

inferred← citeshttps://doi.org/10.1039/c4ra10880aopenalex-snapshot

Metal-free synthesis of substituted pyridines from aldehydes and NH 4 OAc under air

inferred← citeshttps://doi.org/10.1039/c5cc01708dopenalex-snapshot

Ruthenium pincer-catalyzed synthesis of substituted γ-butyrolactones using hydrogen autotransfer methodology

inferred← citeshttps://doi.org/10.1039/c6gc03137dopenalex-snapshot

Synthesis of symmetrical pyridines by iron-catalyzed cyclization of ketoxime acetates and aldehydes

inferred← citeshttps://doi.org/10.1039/c7cc07427aopenalex-snapshot

Cobalt-catalyzed acceptorless dehydrogenative coupling of aminoalcohols with alcohols: direct access to pyrrole, pyridine and pyrazine derivatives

inferred← citeshttps://doi.org/10.1039/c7ob02471aopenalex-snapshot

Synthesis of polysubstituted pyridines from oxime acetates using NH 4 I as a dual-function promoter

inferred← citeshttps://doi.org/10.1039/c8cc05307copenalex-snapshot

Cu-Catalyzed switchable synthesis of functionalized pyridines and pyrroles

inferred← citeshttps://doi.org/10.1039/c8cc05877fopenalex-snapshot

Phosphine free Mn-complex catalysed dehydrogenative C–C and C–heteroatom bond formation: a sustainable approach to synthesize quinoxaline, pyrazine, benzothiazole and quinoline derivatives

inferred← citeshttps://doi.org/10.1039/c8gc00318aopenalex-snapshot

A nitrogen-ligated nickel-catalyst enables selective intermolecular cyclisation of β- and γ-amino alcohols with ketones: access to five and six-membered N-heterocycles

inferred← citeshttps://doi.org/10.1039/c9dt04040dopenalex-snapshot

Cooperative ruthenium complex catalyzed multicomponent synthesis of pyrimidines

inferred← citeshttps://doi.org/10.1039/c9ra06625jopenalex-snapshot

TBHP-mediated oxidative synthesis of substituted pyrimido[4,5- d ]pyrimidines from N -uracil amidines and methylarenes under metal free conditions

inferred← citeshttps://doi.org/10.1039/d0nj03619fopenalex-snapshot

Direct synthesis of 2-substituted benzimidazoles via dehydrogenative coupling of aromatic-diamine and primary alcohol catalyzed by a Co complex

inferred← citeshttps://doi.org/10.1039/d0ob02593copenalex-snapshot

Metal-free [3 + 2 + 1] annulation of allylic alcohols, ketones, and ammonium acetate: radical-involving synthesis of 2,3-diarylpyridine derivatives

inferred← citeshttps://doi.org/10.1039/d0qo01577fopenalex-snapshot

Recent advances in sustainable synthesis of N-heterocycles following acceptorless dehydrogenative coupling protocol using alcohols

inferred← citeshttps://doi.org/10.1039/d1cy01945gopenalex-snapshot

Direct synthesis of ring-fused quinolines and pyridines catalyzed by NN H Y -ligated manganese complexes (Y = NR 2 or SR)

inferred← citeshttps://doi.org/10.1039/d1ob01154eopenalex-snapshot

Nickel catalyzed sustainable synthesis of benzazoles and purines via acceptorless dehydrogenative coupling and borrowing hydrogen approach

inferred← citeshttps://doi.org/10.1039/d2cc00247gopenalex-snapshot

Sustainable catalysis with fluxional acridine-based PNP pincer complexes

inferred← citeshttps://doi.org/10.1039/d2cs00093hopenalex-snapshot

Manganese-catalyzed hydrogenation, dehydrogenation, and hydroelementation reactions

inferred← citeshttps://doi.org/10.1039/d2qo00825dopenalex-snapshot

Disarming the alkoxide trap to access a practical FeCl 3 system for borrowing-hydrogen N -alkylation

inferred← citeshttps://doi.org/10.1039/d3cy00327bopenalex-snapshot

Sustainable synthesis of azobenzenes, quinolines and quinoxalines via oxidative dehydrogenative couplings catalysed by reusable transition metal oxide–Bi( iii ) cooperative catalysts

inferred← citeshttps://doi.org/10.1039/d3dt03149gopenalex-snapshot

Role of ancillary ligands in selectivity towards acceptorless dehydrogenation versus dehydrogenative coupling of alcohols and amines catalyzed by cationic ruthenium( ii )–CNC pincer complexes

inferred← citeshttps://doi.org/10.1039/d4dt01481bopenalex-snapshot

Chromium-catalyzed sustainable C–C and C–N bond formation: C -alkylation and Friedländer quinoline synthesis using alcohols

inferred← citeshttps://doi.org/10.1039/d4nj01648copenalex-snapshot

Cu( ii )-catalyzed annulation of α,β-unsaturated ketoxime acetates with 3-formylchromones for the synthesis of functionalized 2,4-diarylpyridines

inferred← citeshttps://doi.org/10.1039/d5cc07355copenalex-snapshot

Recent advances in decorating the meta -position of pyridines through a temporary dearomatization strategy

inferred← citeshttps://doi.org/10.1055/sos-sd-115-00035openalex-snapshot

15.1.4 Pyridines (Update 2016)

inferred← citeshttps://doi.org/10.1071/ch19255openalex-snapshot

H2-Generation from Alcohols by the MOF-Based Noble Metal-Free Photocatalyst Ni/CdS/TiO2@MIL-101*

inferred← citeshttps://doi.org/10.1093/bulcsj/uoag054openalex-snapshot

Design and polymerization behavior of carbocyclic-fused (imino)pyridine-ligated late-transition-metal catalysts

inferred← citeshttps://doi.org/10.1126/sciadv.adz3401openalex-snapshot

Electrochemical C4 alkylation of pyridine derivatives: Enhanced regioselectivity via silane assistance

inferred← citeshttps://doi.org/10.1515/psr-2017-0017openalex-snapshot

Dehydrogenation of alcohols and polyols from a hydrogen production perspective

inferred← citeshttps://doi.org/10.20517/cs.2025.03openalex-snapshot

One-pot synthesis of N-containing heterocycles from bioethanol via dehydrogenative dual-cross-condensation

inferred← citeshttps://doi.org/10.24959/ophcj.23.289263openalex-snapshot

The Synthesis of Diverse Annulated Pyridines with 6-Membered Functionalized Saturated Cycles for Medical Chemistry Research

inferred← citeshttps://doi.org/10.3390/catal10070773openalex-snapshot

Recent Progress with Pincer Transition Metal Catalysts for Sustainability

inferred← citeshttps://doi.org/10.3390/inorganics7080097openalex-snapshot

Iridium Catalyzed Synthesis of Tetrahydro-1H-Indoles by Dehydrogenative Condensation

inferred← citeshttps://doi.org/10.3762/bjoc.17.163openalex-snapshot

Recent advances in the tandem annulation of 1,3-enynes to functionalized pyridine and pyrrole derivatives

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