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Photochemical Carbopyridylation of Alkenes UsingN‐Alkenoxypyridinium Salts as Bifunctional Reagents

https://doi.org/10.1002/anie.201913320

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Synthesis of α‐Trifluoromethylthiolated and α‐Thiocyanated Ketones Using Umpoled Enolates

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Metal‐Free Oxidation/C(sp3)H Functionalization of Unactivated Alkynes Using Pyridine‐N‐Oxide as the External Oxidant

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Metallfreie oxidative Cyclisierung von Alkinyl‐Aryl‐Ethern zu Benzofuranonen

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Säurekatalysierte oxidative Radikaladdition von Ketonen an Olefine

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Combination of a Cyano Migration Strategy and Alkene Difunctionalization: The Elusive Selective Azidocyanation of Unactivated Olefins

inferredcites →https://doi.org/10.1002/ange.201704385openalex-snapshot

Visible‐Light‐Induced Carbo‐2‐pyridylation of Electron‐Deficient Alkenes with Pyridinium Salts

inferredcites →https://doi.org/10.1002/ange.201706896openalex-snapshot

Durch sichtbares Licht vermittelte Deaminierung zur Erzeugung von Alkylradikalen

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Photokatalyse mit sichtbarem Licht: Welche Bedeutung hat sie für die organische Synthese?

inferredcites →https://doi.org/10.1002/ange.201710397openalex-snapshot

Alkene 1,2‐Difunctionalization by Radical Alkenyl Migration

inferredcites →https://doi.org/10.1002/ange.201801305openalex-snapshot

Photocatalyzed ortho‐Alkylation of Pyridine N‐Oxides through Alkene Cleavage

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Alkoxyl Radicals Generated under Photoredox Catalysis: A Strategy for anti‐Markovnikov Alkoxylation Reactions

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Visible‐Light‐Induced Pyridylation of Remote C(sp3)−H Bonds by Radical Translocation of N‐Alkoxypyridinium Salts

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Mechanistische Studien in der Photokatalyse

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Visible‐Light‐Mediated Metal‐Free Difunctionalization of Alkenes with CO2 and Silanes or C(sp3)−H Alkanes

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Rapid Construction of Structurally Diverse Quinolizidines, Indolizidines, and Their Analogues via Ruthenium‐Catalyzed Asymmetric Cascade Hydrogenation/Reductive Amination

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Dual Photoredox/Copper Catalysis for the Remote C(sp3)−H Functionalization of Alcohols and Alkyl Halides by N‐Alkoxypyridinium Salts

inferredcites →https://doi.org/10.1002/ange.201813689openalex-snapshot

Deaminative (Carbonylative) Alkyl‐Heck‐type Reactions Enabled by Photocatalytic C−N Bond Activation

inferredcites →https://doi.org/10.1002/ange.201814452openalex-snapshot

Catalyst‐Free Deaminative Functionalizations of Primary Amines by Photoinduced Single‐Electron Transfer

inferredcites →https://doi.org/10.1002/ange.201901935openalex-snapshot

Evaluierung der Reaktionsbedingungs‐basierten Sensitivität chemischer Transformationen

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Metal‐Free Oxidation/C(sp3)H Functionalization of Unactivated Alkynes Using Pyridine‐N‐Oxide as the External Oxidant

inferredcites →https://doi.org/10.1002/anie.201304813openalex-snapshot

Metal‐Free Oxidative Cyclization of Alkynyl Aryl Ethers to Benzofuranones

inferredcites →https://doi.org/10.1002/anie.201605130openalex-snapshot

Combination of a Cyano Migration Strategy and Alkene Difunctionalization: The Elusive Selective Azidocyanation of Unactivated Olefins

inferredcites →https://doi.org/10.1002/anie.201704385openalex-snapshot

Visible‐Light‐Induced Carbo‐2‐pyridylation of Electron‐Deficient Alkenes with Pyridinium Salts

inferredcites →https://doi.org/10.1002/anie.201706896openalex-snapshot

Deaminative Strategy for the Visible‐Light‐Mediated Generation of Alkyl Radicals

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Visible‐Light Photocatalysis: Does It Make a Difference in Organic Synthesis?

inferredcites →https://doi.org/10.1002/anie.201710397openalex-snapshot

Alkene 1,2‐Difunctionalization by Radical Alkenyl Migration

inferredcites →https://doi.org/10.1002/anie.201801305openalex-snapshot

Photocatalyzed ortho‐Alkylation of Pyridine N‐Oxides through Alkene Cleavage

inferredcites →https://doi.org/10.1002/anie.201806522openalex-snapshot

Alkoxyl Radicals Generated under Photoredox Catalysis: A Strategy for anti‐Markovnikov Alkoxylation Reactions

inferredcites →https://doi.org/10.1002/anie.201809879openalex-snapshot

Visible‐Light‐Induced Pyridylation of Remote C(sp3)−H Bonds by Radical Translocation of N‐Alkoxypyridinium Salts

inferredcites →https://doi.org/10.1002/anie.201809984openalex-snapshot

Mechanistic Studies in Photocatalysis

inferredcites →https://doi.org/10.1002/anie.201811266openalex-snapshot

Visible‐Light‐Mediated Metal‐Free Difunctionalization of Alkenes with CO 2 and Silanes or C(sp 3 )−H Alkanes

inferredcites →https://doi.org/10.1002/anie.201812647openalex-snapshot

Rapid Construction of Structurally Diverse Quinolizidines, Indolizidines, and Their Analogues via Ruthenium‐Catalyzed Asymmetric Cascade Hydrogenation/Reductive Amination

inferredcites →https://doi.org/10.1002/anie.201813356openalex-snapshot

Dual Photoredox/Copper Catalysis for the Remote C(sp 3 )−H Functionalization of Alcohols and Alkyl Halides by N ‐Alkoxypyridinium Salts

inferredcites →https://doi.org/10.1002/anie.201813689openalex-snapshot

Deaminative (Carbonylative) Alkyl‐Heck‐type Reactions Enabled by Photocatalytic C−N Bond Activation

inferredcites →https://doi.org/10.1002/anie.201814452openalex-snapshot

Catalyst‐Free Deaminative Functionalizations of Primary Amines by Photoinduced Single‐Electron Transfer

inferredcites →https://doi.org/10.1002/anie.201901935openalex-snapshot

Rapid Assessment of the Reaction‐Condition‐Based Sensitivity of Chemical Transformations

inferredcites →https://doi.org/10.1002/chem.201001100openalex-snapshot

Recent Strategies for the Synthesis of Pyridine Derivatives

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Metal‐Free Oxidative Radical Addition of Carbonyl Compounds to α,α‐Diaryl Allylic Alcohols: Synthesis of Highly Functionalized Ketones

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Efficient One‐Pot Multifunctionalization of Alkynes en Route to α‐Alkoxyketones, α‐Thioketones, and α‐Thio Thioketals by using an Umpolung Strategy

inferredcites →https://doi.org/10.1002/chem.201804246openalex-snapshot

Deaminative Borylation of Aliphatic Amines Enabled by Visible Light Excitation of an Electron Donor–Acceptor Complex

inferredcites →https://doi.org/10.1016/b978-0-08-052349-1.00090-1openalex-snapshot

Stabilized Nucleophiles with Electron Deficient Alkenes and Alkynes

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Free Radical Chemistry Enabled by Visible Light-Induced Electron Transfer

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Photoredox Catalysis for the Generation of Carbon Centered Radicals

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Shining Light on Copper: Unique Opportunities for Visible-Light-Catalyzed Atom Transfer Radical Addition Reactions and Related Processes

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Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes: Bond Forming at a High-Valent Palladium Center

inferredcites →https://doi.org/10.1021/acs.accounts.6b00351openalex-snapshot

Merging Visible Light Photoredox and Gold Catalysis

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Dual Catalysis Strategies in Photochemical Synthesis

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Organic Photoredox Catalysis

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Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

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C–H Functionalization of Azines

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Photoredox Catalysis for Building C–C Bonds from C(sp 2 )–H Bonds

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inferredcites →https://doi.org/10.1021/acs.orglett.9b01155openalex-snapshot

Visible-Light Excitation of Quinolinone-Containing Substrates Enables Divergent Radical Cyclizations

inferredcites →https://doi.org/10.1021/acs.orglett.9b01329openalex-snapshot

Photocatalyzed Metal-Free Alkylheteroarylation of Unactivated Olefins via Direct Acidic C(sp3)–H Bond Activation

inferredcites →https://doi.org/10.1021/acscatal.8b03875openalex-snapshot

Photoredox-Catalyzed Generation of Acetonyl Radical in Flow: Theoretical Investigation and Synthetic Applications

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Heteroarene Phosphinylalkylation via a Catalytic, Polarity-Reversing Radical Cascade

inferredcites →https://doi.org/10.1021/acscatal.9b03367openalex-snapshot

Site-Selective C–H Acylation of Pyridinium Derivatives by Photoredox Catalysis

inferredcites →https://doi.org/10.1021/cr100371yopenalex-snapshot

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

inferredcites →https://doi.org/10.1021/cr300503ropenalex-snapshot

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One-Pot Synthesis of Benzene-Fused Medium-Ring Ketones: Gold Catalysis-Enabled Enolate Umpolung Reactivity

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Metal-Free, Visible Light-Photocatalyzed Synthesis of Benzo[b]phosphole Oxides: Synthetic and Mechanistic Investigations

inferredcites →https://doi.org/10.1021/jacs.6b05271openalex-snapshot

Intermolecular Hydropyridylation of Unactivated Alkenes

inferredcites →https://doi.org/10.1021/jacs.6b05344openalex-snapshot

A Radical Bidirectional Fragment Coupling Route to Unsymmetrical Ketones

inferredcites →https://doi.org/10.1021/jacs.7b02388openalex-snapshot

Hydroheteroarylation of Unactivated Alkenes Using N-Methoxyheteroarenium Salts

inferredcites →https://doi.org/10.1021/jacs.8b07023openalex-snapshot

Intermolecular Carboamination of Unactivated Alkenes

inferredcites →https://doi.org/10.1021/jacs.8b07103openalex-snapshot

Photoinduced Deaminative Borylation of Alkylamines

inferredcites →https://doi.org/10.1021/jacs.8b07578openalex-snapshot

Catalytic Alkene Difunctionalization via Imidate Radicals

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Site-Selective Functionalization of Pyridinium Derivatives via Visible-Light-Driven Photocatalysis with Quinolinone

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Visible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents

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Catalytic radical addition of ketones to alkenes by a metal–dioxygen redox system

inferredcites →https://doi.org/10.1039/b913880nopenalex-snapshot

Visible light photoredox catalysis: applications in organic synthesis

inferredcites →https://doi.org/10.1039/c7cc06287gopenalex-snapshot

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Metal-free photocatalytic trifluoromethylative pyridylation of unactivated alkenes

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inferredcites →https://doi.org/10.1039/c8sc03493aopenalex-snapshot

Metal-free, intermolecular carbopyridylation of alkenes via visible-light-induced reductive radical coupling

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What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Nucleophilic and Radical Heptafluoroisopropoxylation with Redox‐Active Reagents

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Visible‐Light‐Enabled Trifluoromethylative Pyridylation of Alkenes from Pyridines and Triflic Anhydride

inferred← citeshttps://doi.org/10.1002/anie.202008435openalex-snapshot

Photocatalytic Vicinal Aminopyridylation of Methyl Ketones by a Double Umpolung Strategy

inferred← citeshttps://doi.org/10.1002/anie.202010597openalex-snapshot

Regioselective C−H Functionalization of HeteroareneN‐Oxides Enabled by a Traceless Nucleophile

inferred← citeshttps://doi.org/10.1002/anie.202010958openalex-snapshot

C−H Methylation of Iminoamido Heterocycles with Sulfur Ylides**

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Visible‐Light‐Induced 1,3‐Aminopyridylation of [1.1.1]Propellane with N‐Aminopyridinium Salts

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Nucleophilic and Radical Heptafluoroisopropoxylation with Redox‐Active Reagents

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Remote C−H Pyridylation of Hydroxamates through Direct Photoexcitation of O‐Aryl Oxime Pyridinium Intermediates

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Regioselective Access to Vicinal Diamines by Metal‐Free Photosensitized Amidylimination of Alkenes with Oxime Esters

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Visible-Light-Triggered Iodinations Facilitated by Weak Electrostatic Interaction of N-Heterocyclic Carbenes

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Photoredox-Catalyzed Formal [4 + 2] Cycloaddition of Pyridinium Masked Enols with Unactivated Olefins

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c05038openalex-snapshot

Ph 3 N as an Organocatalytic Donor for Photoactivation of Pyridinium-Masked Enols in the Formal [4 + 2] Cycloaddition with Unactivated Olefins

inferred← citeshttps://doi.org/10.1021/acscatal.0c03726openalex-snapshot

Photochemical C–H Silylation and Hydroxymethylation of Pyridines and Related Structures: Synthetic Scope and Mechanisms

inferred← citeshttps://doi.org/10.1021/acscatal.0c04332openalex-snapshot

Visible-Light-Driven, Metal-Free Divergent Difunctionalization of Alkenes Using Alkyl Formates

inferred← citeshttps://doi.org/10.1021/acscatal.4c00523openalex-snapshot

Carbamoylarylation of Alkenes with N -Aryl Oxamic Acids Involving 1,4-Aryl Migration Via C(aryl)–N Bond Cleavage

inferred← citeshttps://doi.org/10.1021/jacs.0c04499openalex-snapshot

Visible-Light-Driven C4-Selective Alkylation of Pyridinium Derivatives with Alkyl Bromides

inferred← citeshttps://doi.org/10.1021/jacs.0c05025openalex-snapshot

Visible-Light-Enabled Ortho-Selective Aminopyridylation of Alkenes with N-Aminopyridinium Ylides

inferred← citeshttps://doi.org/10.1021/jacs.0c06827openalex-snapshot

ZnMe2-Mediated, Direct Alkylation of Electron-Deficient N-Heteroarenes with 1,1-Diborylalkanes: Scope and Mechanism

inferred← citeshttps://doi.org/10.1021/jacs.0c11896openalex-snapshot

α-Amino Acids and Peptides as Bifunctional Reagents: Carbocarboxylation of Activated Alkenes via Recycling CO 2

inferred← citeshttps://doi.org/10.1021/jacs.1c00549openalex-snapshot

Site-Selective Direct C–H Pyridylation of Unactivated Alkanes by Triplet Excited Anthraquinone

inferred← citeshttps://doi.org/10.1021/jacs.2c09244openalex-snapshot

Highly Selective Radical Relay 1,4-Oxyimination of Two Electronically Differentiated Olefins

inferred← citeshttps://doi.org/10.1021/jacs.4c01667openalex-snapshot

γ-Amino Alcohols via Energy Transfer Enabled Brook Rearrangement

inferred← citeshttps://doi.org/10.1021/jacs.6c06698openalex-snapshot

Tricomponent α-Carbonyl Alkylation by a Cobalt-Catalyzed Polar–Radical and Radical–Polar Crossover Cascade

inferred← citeshttps://doi.org/10.1038/s41467-021-26857-wopenalex-snapshot

Photo-induced catalytic halopyridylation of alkenes

inferred← citeshttps://doi.org/10.1038/s41467-025-60130-8openalex-snapshot

Direct synthesis of N-trifluoromethyl amides via photocatalytic trifluoromethylamidation

inferred← citeshttps://doi.org/10.1038/s41467-026-74339-8openalex-snapshot

Divergent C2 functionalization of N-Heteroarenes via nonclassical rearomatization

inferred← citeshttps://doi.org/10.1038/s41570-021-00266-5openalex-snapshot

Bifunctional reagents in organic synthesis

inferred← citeshttps://doi.org/10.1039/d0cc05621aopenalex-snapshot

Enantioselective dicarbofunctionalization of ( E )-alkenyloxindoles with pyridinium salts by chiral Lewis acid/photo relay catalysis

inferred← citeshttps://doi.org/10.1039/d0cs00493fopenalex-snapshot

Visible light photocatalysis in the late-stage functionalization of pharmaceutically relevant compounds

inferred← citeshttps://doi.org/10.1039/d0ob01453bopenalex-snapshot

The C–H functionalization of organic cations: an interesting and fresh journey

inferred← citeshttps://doi.org/10.1039/d0qo00827copenalex-snapshot

Metal-free reductive coupling of aliphatic aldehydes/ketones with 4-cyanopyridines: expanded scope and mechanistic studies

inferred← citeshttps://doi.org/10.1039/d0qo01218aopenalex-snapshot

Metal-free visible-light-induced photoredox-catalyzed intermolecular pyridylation/phosphinoylation of alkenes

inferred← citeshttps://doi.org/10.1039/d0sc06473dopenalex-snapshot

Trifluoromethanesulfonyl azide as a bifunctional reagent for metal-free azidotrifluoromethylation of unactivated alkenes

inferred← citeshttps://doi.org/10.1039/d1sc00776aopenalex-snapshot

Divergent reactivity of sulfinates with pyridinium salts based on one- versus two-electron pathways

inferred← citeshttps://doi.org/10.1039/d2cc00369dopenalex-snapshot

Recent advances in difunctionalization of alkenes using pyridinium salts as radical precursors

inferred← citeshttps://doi.org/10.1039/d2sc05654bopenalex-snapshot

Catalytic photochemical enantioselective α-alkylation with pyridinium salts

inferred← citeshttps://doi.org/10.1039/d3cc02422aopenalex-snapshot

Ferrocene catalyzed redox-neutral difunctionalization of alkenes using cycloketone oxime esters: access to distal imido-nitriles

inferred← citeshttps://doi.org/10.1039/d3gc00143aopenalex-snapshot

Visible-light-mediated β-acylative divergent alkene difunctionalization with Katritzky salt/CO 2

inferred← citeshttps://doi.org/10.1039/d3ob00799eopenalex-snapshot

C–H functionalization of pyridines

inferred← citeshttps://doi.org/10.1039/d3qo01671dopenalex-snapshot

Synthesis of 2-acyl benzofurans and indoles based on nucleophile-intercepted Meyer–Schuster rearrangement of o -hydroxyphenyl and o -aminophenyl propargylic alcohols

inferred← citeshttps://doi.org/10.1039/d3qo02045bopenalex-snapshot

Straightforward α-allylation of carbonyl compounds with alkenes via α-carbonyl radical intermediates

inferred← citeshttps://doi.org/10.1039/d4cc06305hopenalex-snapshot

A sequential Au( i )/TBAF-promoted rapid and selective functionalization of heteroarene N -oxides with alkynes

inferred← citeshttps://doi.org/10.1039/d4cc06801gopenalex-snapshot

Copper catalyzed C(sp 3 )–H/C(sp 3 )–H cross-coupling of arylacetic acid equivalents with methylarenes via α-carbonyl radicals

inferred← citeshttps://doi.org/10.1039/d4gc06330aopenalex-snapshot

Visible-light-induced 1,3-difunctionalization of allylboronic esters enabled by a 1,2-boron shift

inferred← citeshttps://doi.org/10.1039/d5cc03886copenalex-snapshot

Catalytic α-C–H functionalization of carbonyl compounds via SET-induced formation of α-carbonyl radicals

inferred← citeshttps://doi.org/10.1039/d5cc07355copenalex-snapshot

Recent advances in decorating the meta -position of pyridines through a temporary dearomatization strategy

inferred← citeshttps://doi.org/10.1039/d5cs00181aopenalex-snapshot

Navigating the functionalization of unactivated alkenes via visible light photocatalysis

inferred← citeshttps://doi.org/10.1039/d5cs00670hopenalex-snapshot

Intermolecular 1,2-difunctionalization of alkenes

inferred← citeshttps://doi.org/10.1039/d5np00030kopenalex-snapshot

Photo-/electro-chemical catalysis: a promising toolkit for late-stage functionalization of alkene-containing natural products

inferred← citeshttps://doi.org/10.1039/d5ra02290hopenalex-snapshot

Mechanism of EnT-mediated amino-sulfonylation of alkenes with N -sulfonyl ketimine: a DFT investigation

inferred← citeshttps://doi.org/10.1039/d5sc07904gopenalex-snapshot

Cis -difluoromethyl hetarylative dearomatization by a radical docking-migration cascade

inferred← citeshttps://doi.org/10.1055/a-2033-8155openalex-snapshot

Photoinduced Carboarylation of Alkenes by Using Bifunctional Reagents

inferred← citeshttps://doi.org/10.1055/a-2131-4126openalex-snapshot

Recent Uses of Photogenerated Oxygen-Centered Radicals in Intermolecular C–O Bond Formation

inferred← citeshttps://doi.org/10.1055/a-2427-7689openalex-snapshot

Visible-Light Organophotoredox-Catalyzed Phosphonoalkylation of Alkenes via Deaminative Three-Component Radical–Radical Coupling

inferred← citeshttps://doi.org/10.1055/a-2800-8016openalex-snapshot

Photo-Driven Difunctionalization of Unactivated Alkenes: Recent Advances in Radical-Mediated Strategies

inferred← citeshttps://doi.org/10.1055/sos-sd-234-00177openalex-snapshot

1.9 Oxygen-Centered Radicals

inferred← citeshttps://doi.org/10.3389/fchem.2023.1254632openalex-snapshot

Nucleophilic C4-selective (hetero) arylation of pyridines for facile synthesis of heterobiaryls

inferred← citeshttps://doi.org/10.3390/chemistry8060074openalex-snapshot

Covalent Organic Cage Directs EDA Complex Reactivity in Tetralone Synthesis

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