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Total Synthesis of the Meroterpenoid Manginoid A as Fueled by a Challenging Pinacol Coupling and Bicycle‐forming Etherification

https://doi.org/10.1002/anie.202016178

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Enantioselective Cu‐Catalyzed 1,4‐Addition of Grignard Reagents to Cyclohexenone Using Taddol‐Derived Phosphine–Phosphite Ligands and 2‐Methyl‐THF as a Solvent

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Samariumdiiodid‐vermittelte Reaktionen in der Totalsynthese

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Allylic CH Alkylation of Unactivated α‐Olefins: Serial Ligand Catalysis Resumed

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Total Synthesis and Anticancer Activity of (+)‐Hypercalin C and Congeners

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Total Synthesis of 1‐Hydroxytaxinine

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Total Synthesis of (−)‐Pepluanol B: Conformational Control of the Eight‐Membered‐Ring System

inferredcites →https://doi.org/10.1002/anie.200502485openalex-snapshot

Soluble Lanthanide Salts (LnCl 3 ⋅2 LiCl) for the Improved Addition of Organomagnesium Reagents to Carbonyl Compounds

inferredcites →https://doi.org/10.1002/anie.200803247openalex-snapshot

Enantioselective Cu‐Catalyzed 1,4‐Addition of Grignard Reagents to Cyclohexenone Using Taddol‐Derived Phosphine–Phosphite Ligands and 2‐Methyl‐THF as a Solvent

inferredcites →https://doi.org/10.1002/anie.200902151openalex-snapshot

Samarium Diiodide Mediated Reactions in Total Synthesis

inferredcites →https://doi.org/10.1002/anie.201101654openalex-snapshot

Allylic CH Alkylation of Unactivated α‐Olefins: Serial Ligand Catalysis Resumed

inferredcites →https://doi.org/10.1002/anie.201812909openalex-snapshot

Total Synthesis and Anticancer Activity of (+)‐Hypercalin C and Congeners

inferredcites →https://doi.org/10.1002/anie.201906872openalex-snapshot

Total Synthesis of 1‐Hydroxytaxinine

inferredcites →https://doi.org/10.1002/anie.201915876openalex-snapshot

Total Synthesis of (−)‐Pepluanol B: Conformational Control of the Eight‐Membered‐Ring System

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Michael reactions withtrans-3-isopropenyl-2-phenylthiocyclopentan-1-one andtrans-3-isopropenyl-2-phenylsulfonylcyclopentan-1-one

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Synthesis of 1,4-dimethylhydroazulene derivatives fromtrans-3-isopropenyl-2-(2-methoxycarbonylethyl)cyclopentanone

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Hypercohones D–G, New Polycyclic Polyprenylated Acylphloroglucinol Type Natural Products from Hypericum cohaerens

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Pharmacological characterization of the selective 11β-hydroxysteroid dehydrogenase 1 inhibitor, BI 135585, a clinical candidate for the treatment of type 2 diabetes

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Mangiterpenes A–C and 2′,3′-seco-manginoid C, four sesquiterpene/monoterpene–shikimate–conjugated spirocyclic meroterpenoids from Guignardia mangiferae

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Chiral phosphine–phosphite ligands in the enantioselective 1,4-addition of Grignard reagents to α,β-unsaturated carbonyl compounds

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Enantioselective rhodium(I)-triethylamine catalyzed addition of potassium isopropenyl trifluoroborate to enones

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Construction of bicyclic systems containing an oxygen bridge by isomerization of cyclic epoxy alcohols

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An IMDA approach to tigliane and daphnane diterpenoids: Generation of the tetracyclic ring system of the tiglianes

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Asymmetric Total Synthesis of (−)-Guignardones A and B

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Manginoids A–G: Seven Monoterpene–Shikimate-Conjugated Meroterpenoids with a Spiro Ring System from Guignardia mangiferae

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Asymmetric Synthesis and Biological Activities of Pactamycin-Inspired Aminocyclopentitols

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Asymmetric Synthesis and Structure Revision of Guignardone H and I: Development of a Chiral 1,3-Diketone Possessing C2 Symmetry

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Samarium(II)-Iodide-Mediated Cyclizations in Natural Product Synthesis

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Cross-Coupling Reactions Using Samarium(II) Iodide

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Reactions of SmI2 with Alkyl Halides and Ketones: Inner-Sphere vs Outer-Sphere Electron Transfer in Reactions of Sm(II) Reductants

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Stereocontrol in homogeneous catalytic hydrogenation via hydroxyl group coordination

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The endiandric acid cascade. Electrocyclizations in organic synthesis. I. Stepwise, stereocontrolled total synthesis of endiandric acids A and B

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General Allylic C–H Alkylation with Tertiary Nucleophiles

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Catalytic Intermolecular Allylic C—H Alkylation

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General Strategy for the Asymmetric Synthesis of the Picrotoxanes

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Catalytic Asymmetric Total Synthesis of (−)-Actinophyllic Acid

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11-Step Total Synthesis of (−)-Maoecrystal V

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11β-HSD1 plays a critical role in trabecular bone loss associated with systemic glucocorticoid therapy

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What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.1016/j.phytochem.2021.112860zenodo-depositor-declared

Terpene−Shikimate conjugated meroterpenoids from the endophytic fungus Guignardia mangiferae

inferred← citeshttps://doi.org/10.1002/ange.202104182openalex-snapshot

Enantioselective Total Syntheses of Manginoids A and C and Guignardones A and C

inferred← citeshttps://doi.org/10.1002/ange.202304033openalex-snapshot

Ketyl Radical Anion Mediated Radical Polymerization and Anionic Ring‐Opening Polymerization to Give Polymers with Low Molecular Weight Distribution

inferred← citeshttps://doi.org/10.1002/anie.202104182openalex-snapshot

Enantioselective Total Syntheses of Manginoids A and C and Guignardones A and C

inferred← citeshttps://doi.org/10.1002/anie.202304033openalex-snapshot

Ketyl Radical Anion Mediated Radical Polymerization and Anionic Ring‐Opening Polymerization to Give Polymers with Low Molecular Weight Distribution

inferred← citeshttps://doi.org/10.1002/ejoc.202500457openalex-snapshot

Decarboxylative Michael Additions of Substituted Malonic Acid Half‐Oxyesters to Methylidene Malonates

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Metal-Mediated Reductive C–C Coupling of π Bonds

inferred← citeshttps://doi.org/10.1016/j.phytochem.2022.113289openalex-snapshot

Proposal for structural revision of several disubstituted tricycloalternarenes

inferred← citeshttps://doi.org/10.1016/j.tetlet.2023.154361openalex-snapshot

Synthesis of the 5/6 fused-spiro tricyclic framework of manginoid A

inferred← citeshttps://doi.org/10.1021/acs.joc.3c01895openalex-snapshot

Synthesis of the 5–6–7 Tricyclic Core of Daphnicyclidin-Type Alkaloids via a Tiffeneau–Demjanov Ring Enlargement Strategy

inferred← citeshttps://doi.org/10.1021/acs.joc.5c02900openalex-snapshot

Rapid Construction of Tricyclic Carbon Framework for Convergent Synthesis of Manginoid Meroterpenoids

inferred← citeshttps://doi.org/10.1021/acs.orglett.1c01157openalex-snapshot

Synthesis of Desacyl Furanmonogones A and B

inferred← citeshttps://doi.org/10.1021/acs.orglett.1c03844openalex-snapshot

Soft Enolization of 3-Substituted Cycloalkanones Exhibits Significantly Improved Regiocontrol vs Hard Enolization Conditions

inferred← citeshttps://doi.org/10.1021/acs.orglett.3c02232openalex-snapshot

Bioinspired Total Synthesis of Hyperireflexolides A and B

inferred← citeshttps://doi.org/10.1021/acs.orglett.4c03643openalex-snapshot

Efforts toward the Total Synthesis of Thuggacin A

inferred← citeshttps://doi.org/10.1021/jacs.2c08760openalex-snapshot

Gram-Scale Enantioselective Synthesis of (+)-Lucidumone

inferred← citeshttps://doi.org/10.1021/jacs.2c12470openalex-snapshot

Concise Synthesis of (−)-GA 18 Methyl Ester

inferred← citeshttps://doi.org/10.1021/jacsau.6c00404openalex-snapshot

Total Syntheses of (+)-Hyperbeanols A–C, (+)-Hyperpatulol A, and (−)-Hypercohone G, as Well as Structure Revision of Hyperpatulol A, and Hyperbeanol B

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Highly selective aldehyde coupling on the heterointerface of molybdenum selenide and graphdiyne

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Combining the best of both worlds: radical-based divergent total synthesis

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