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Optimal Pore Chemistry in an Ultramicroporous Metal–Organic Framework for Benchmark Inverse CO 2 /C 2 H 2 Separation

https://doi.org/10.1002/anie.202106769

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Pore Chemistry of Metal–Organic Frameworks

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Metal–Organic Frameworks for Separation

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CO2 Capture in Metal–Organic Framework Adsorbents: An Engineering Perspective

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Robust Ultramicroporous Metal–Organic Frameworks with Benchmark Affinity for Acetylene

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Host–Guest Interaction Modulation in Porous Coordination Polymers for Inverse Selective CO2/C2H2Separation

inferredcites →https://doi.org/10.1002/anie.201107906openalex-snapshot

Inverse and High CO2/C2H2 Sorption Selectivity in Flexible Organic–Inorganic Ionic Crystals

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Separation of Acetylene from Carbon Dioxide and Ethylene by a Water‐Stable Microporous Metal–Organic Framework with Aligned Imidazolium Groups inside the Channels

inferredcites →https://doi.org/10.1002/anie.201806732openalex-snapshot

Robust Ultramicroporous Metal–Organic Frameworks with Benchmark Affinity for Acetylene

inferredcites →https://doi.org/10.1002/anie.202000323openalex-snapshot

Mixed Metal–Organic Framework with Multiple Binding Sites for Efficient C 2 H 2 /CO 2 Separation

inferredcites →https://doi.org/10.1002/anie.202009446openalex-snapshot

Efficient Trapping of Trace Acetylene from Ethylene in an Ultramicroporous Metal–Organic Framework: Synergistic Effect of High‐Density Open Metal and Electronegative Sites

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Efficient Separation of Acetylene and Carbon Dioxide in a Decorated Zeolite

inferredcites →https://doi.org/10.1002/anie.202016673openalex-snapshot

Host–Guest Interaction Modulation in Porous Coordination Polymers for Inverse Selective CO2/C2H2Separation

inferredcites →https://doi.org/10.1002/smll.202005360openalex-snapshot

Fine‐Tuning Pore Dimension in Hybrid Ultramicroporous Materials Boosting Simultaneous Trapping of Trace Alkynes from Alkenes

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Optimized pore environment for efficient high selective C2H2/C2H4 and C2H2/CO2 separation in a metal-organic framework

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Recent Progress Towards Light Hydrocarbon Separations Using Metal–Organic Frameworks

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Inverse Adsorption Separation of CO 2 /C 2 H 2 Mixture in Cyclodextrin-Based Metal–Organic Frameworks

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inferredcites →https://doi.org/10.1021/jacs.9b00232openalex-snapshot

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inferredcites →https://doi.org/10.1038/nature03852openalex-snapshot

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What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Spin crossover in metal–organic framework for improved separation of C2H2/CH4 at room temperature

inferred← citeshttps://doi.org/10.1016/j.jssc.2023.124461openalex-snapshot

Tuning the CO2 selective adsorption performance in MOFs by incorporating functional groups on the isophthalate skeleton

inferred← citeshttps://doi.org/10.1016/j.jssc.2025.125574openalex-snapshot

Benchmark molecular sieving of CO2 over C2H2 in an ultramicroporous metal-organic framework through gating mechanism

inferred← citeshttps://doi.org/10.1016/j.matt.2022.07.029openalex-snapshot

Machine-learning-assisted exploration of anion-pillared metal organic frameworks for gas separation

inferred← citeshttps://doi.org/10.1016/j.memsci.2023.121853openalex-snapshot

Unexpected high CO2 over C2H2 separation performance by high-silica CHA zeolite membranes

inferred← citeshttps://doi.org/10.1016/j.mtcomm.2026.115654openalex-snapshot

How accurate are the estimates of the Ideal Adsorbed Solution Theory (IAST) for mixture adsorption equilibrium?

inferred← citeshttps://doi.org/10.1016/j.seppur.2021.119608openalex-snapshot

Inverse CO2/C2H2 separation in a pillared-layer framework featuring a chlorine-modified channel by quadrupole-moment sieving

inferred← citeshttps://doi.org/10.1016/j.seppur.2022.120446openalex-snapshot

Enhancing CH4/N2 separation performance within aluminum-based Metal-Organic Frameworks: Influence of the pore structure and linker polarity

inferred← citeshttps://doi.org/10.1016/j.seppur.2022.121340openalex-snapshot

A nickel-based metal-organic framework for efficient SF6/N2 separation with record SF6 uptake and SF6/N2 selectivity

inferred← citeshttps://doi.org/10.1016/j.seppur.2022.122318openalex-snapshot

Thermodynamic and kinetic synergetic separation of CO2/C2H2 in an ultramicroporous metal-organic framework

inferred← citeshttps://doi.org/10.1016/j.seppur.2022.122617openalex-snapshot

Nickel-based metal–organic framework for efficient capture of CF4 with a high CF4/N2 selectivity

inferred← citeshttps://doi.org/10.1016/j.seppur.2023.124930openalex-snapshot

Controllable C2H2/CO2 inverse adsorption and separation in pillar-layered Zn-1,2,4-triazolate-dicarboxylate frameworks induced by the ligand aromaticity

inferred← citeshttps://doi.org/10.1016/j.seppur.2023.125349openalex-snapshot

Mixed matrix membrane with amorphous metal-based complexes displays high CO2 separation performance

inferred← citeshttps://doi.org/10.1016/j.seppur.2024.126764openalex-snapshot

Regulating the Si/Al ratio of GIS zeolite with bulky primary particles for selective CO2 capture from hydrocarbons

inferred← citeshttps://doi.org/10.1016/j.seppur.2024.129468openalex-snapshot

Efficient molecular sieving separation of C2H2/CO2 by a flexible interpenetrated metal-organic framework

inferred← citeshttps://doi.org/10.1016/j.seppur.2025.131827openalex-snapshot

A comprehensive review of reduction technologies for tetrafluoromethane (CF4): Progress, challenges and future directions

inferred← citeshttps://doi.org/10.1016/j.seppur.2026.136952openalex-snapshot

Molecular trap construction via pore environment optimization in ultramicroporous MOFs for efficient C2H2 separation

inferred← citeshttps://doi.org/10.1016/j.seppur.2026.139458openalex-snapshot

Tuning local pore geometry in isostructural flexible MOFs via metal substitution for one-step polymer-grade C2H2 separation from CO2/C2H2 mixtures

inferred← citeshttps://doi.org/10.1021/acs.cgd.4c00068openalex-snapshot

Solvent-Driven Switchable Structural Deformations in a Flexible Metal–Organic Framework with Pyrrolo-Pyrrole–Based Linker

inferred← citeshttps://doi.org/10.1021/acs.cgd.4c00349openalex-snapshot

Nanoporous Metal–Organic Framework Based on Furan-2,5-Dicarboxylic Acid with High Potential in Selective Adsorption and Separation of Gas Mixtures

inferred← citeshttps://doi.org/10.1021/acs.cgd.4c00868openalex-snapshot

Soft Crystal Design for Discriminatory Gate Effect on Inverse Selective CO2/C2H2 Separation

inferred← citeshttps://doi.org/10.1021/acs.cgd.5c01505openalex-snapshot

Polyoxometalate-Zr-Organic Cage Hybrid Ionic Salts Exhibiting Rapid Photochromic Behavior

inferred← citeshttps://doi.org/10.1021/acs.chemmater.2c02004openalex-snapshot

Metal–Organic Framework-Based Single-Molecule SF6 Trap for Record SF6 Capture

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.1c02552openalex-snapshot

A Copper-Based Metal–Organic Framework for C2H2/CO2 Separation

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c01634openalex-snapshot

Efficient Separation of Trace SO2 from SO2/CO2/N2 Mixtures in a Th-Based MOF

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c02250openalex-snapshot

Precise Introduction of Single Vanadium Site into Indium–Organic Framework for CO 2 Capture and Photocatalytic Fixation

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.2c03236openalex-snapshot

Fe-MOF with U-Shaped Channels for C2H2/CO2 and C2H2/C2H4 Separation

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c00954openalex-snapshot

Boosting the C2H2/CO2 Separation Performance of Metal–Organic Frameworks through Fluorine Substitution

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c02435openalex-snapshot

pH-Stable Zn(II) Coordination Polymer as a Multiresponsive Turn-On and Turn-Off Fluorescent Sensor for Aqueous Medium Detection of Al(III) and Cr(VI) Oxo-Anions

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c00592openalex-snapshot

Host–Host Interactions Enhanced the Structural Rigidity in a 6-Fold Interpenetrated Diamondoid Metal–Organic Framework Exhibiting C 2 H 2 /C 2 H 4 Separation

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c01422openalex-snapshot

Mechanistical Insights into the Ultrasensitive Detection of Radioactive and Chemotoxic UO22+ Ions by a Porous Anionic Co-Metal–Organic Framework

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c01518openalex-snapshot

C 2 H 2 /CO 2 Separation by a Carborane Hybrid 2D Metal–Organic Framework

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c03662openalex-snapshot

A Distinct Microporous Metal–Organic Framework with Multiple Accessible Adsorption Sites for Separation of C2H2/CO2/CH4 Mixtures

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c05964openalex-snapshot

Precise Pore Engineering of a Pillar-Layered MOF via the Dual-Ligand Strategy for C 2 H 2 /CO 2 Separation

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6c01035openalex-snapshot

Breathing Effect of Flexible Metal–Organic Frameworks Drives C 2 H 2 /CO 2 Separation

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6c02002openalex-snapshot

Symmetry Engineering of Metal–Organic Frameworks via Ligand Desymmetrization Design for Acetylene Purification

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6c02528openalex-snapshot

Spatial–Electrostatic Potential Synergistically Driven in Isoreticular Metal–Organic Frameworks for Inverse CO2/C2H2 Separation

inferred← citeshttps://doi.org/10.1021/acs.jpcc.4c00483openalex-snapshot

Unveiling CO 2 Dynamics in Perfluorinated Cerium-Based Metal–Organic Frameworks with UiO-66 and MIL-140 Topologies by Solid State NMR

inferred← citeshttps://doi.org/10.1021/acs.jpcc.6c04011openalex-snapshot

Quantifying C2H2/CO2 Gas Sorption in s-Block Metal–Organic Frameworks via FTIR Spectroscopy and Periodic DFT Calculations

inferred← citeshttps://doi.org/10.1021/acs.langmuir.1c02009openalex-snapshot

Tuning the Selectivity between C2H2 and CO2 in Molecular Porous Materials

inferred← citeshttps://doi.org/10.1021/acs.langmuir.3c00474openalex-snapshot

Highly Efficient CO2/C2H2 Separation by Porous Graphene via Quadrupole Gating Mechanism

inferred← citeshttps://doi.org/10.1021/acsami.2c06744openalex-snapshot

Efficient One-Step Purification of C1and C2Hydrocarbons over CO2in a New CO2-Selective MOF with a Gate-Opening Effect

inferred← citeshttps://doi.org/10.1021/acsami.2c07640openalex-snapshot

Increased CO 2 Affinity and Adsorption Selectivity in MOF-801 Fluorinated Analogues

inferred← citeshttps://doi.org/10.1021/acsami.2c19779openalex-snapshot

Pore Environment Optimization of Microporous Metal–Organic Frameworks with Huddled Pyrazine Pillars for C2H2/CO2 Separation

inferred← citeshttps://doi.org/10.1021/acsami.3c07066openalex-snapshot

Multifunctional Roles of Dihydrotetrazine-Decorated Zr-MOFs in Photoluminescence and Colorimetrism for Discrimination of Arsenate and Phosphate Ions in Water

inferred← citeshttps://doi.org/10.1021/acsami.3c16849openalex-snapshot

Separation of High-Purity C 2 H 2 from Binary C 2 H 2 /CO 2 Using Robust Al-Based MOFs Comprising Nitrogen-Containing Heterocyclic Dicarboxylate

inferred← citeshttps://doi.org/10.1021/acsami.4c11234openalex-snapshot

Dihydrotetrazine-Functionalized Zirconium-Based Metal–Organic Frameworks for High-Capacity Oil Denitrogenation

inferred← citeshttps://doi.org/10.1021/acsami.6c05311openalex-snapshot

Tetrazole-Decorated Ultramicroporous MOF Exhibiting Inverse CO 2 Selectivity for Hydrocarbon Purification

inferred← citeshttps://doi.org/10.1021/acscentsci.4c02155openalex-snapshot

Plastic Pores for Switchable and Optimized Adsorption Behaviors

inferred← citeshttps://doi.org/10.1021/acsmaterialslett.2c00129openalex-snapshot

Stable Bimetallic Metal–Organic Framework with Dual-Functional Pyrazolate-Carboxylate Ligand: Rational Construction and C2H2/CO2 Separation

inferred← citeshttps://doi.org/10.1021/acsmaterialslett.4c01434openalex-snapshot

Installing Methyl Group Guards in a Metal–Organic Framework Featuring Multiple N/O Active Sites for Efficient C2H2/CO2 Separation under Moist Conditions

inferred← citeshttps://doi.org/10.1021/acsmaterialslett.4c02504openalex-snapshot

Rapid Synthesis of Ultramicroporous Potassium-Pyrenetetracarboxylate Framework with Confined-Space-Charge-Driving CO2 Capture

inferred← citeshttps://doi.org/10.1021/acsomega.6c02924openalex-snapshot

Metal-Dependent Adsorption Mechanism in Perfluorinated MIL-140A Metal–Organic Frameworks

inferred← citeshttps://doi.org/10.1021/acssuschemeng.2c03359openalex-snapshot

Robust Nickel Aspartate Framework for Shape Recognition of Hexane Isomers

inferred← citeshttps://doi.org/10.1021/acssuschemeng.4c08179openalex-snapshot

Facile Preparation of Mixed-Matrix Membrane for Highly Selective Separation of CO 2 via a Defected Zr-MOF Fluorination-Modified Strategy

inferred← citeshttps://doi.org/10.1021/cbe.4c00035openalex-snapshot

Deciphering Mechanisms of CO 2 -Selective Recognition over Acetylene within Porous Materials

inferred← citeshttps://doi.org/10.1021/jacs.1c07191openalex-snapshot

Efficient C2H2/CO2 Separation in Ultramicroporous Metal–Organic Frameworks with Record C2H2 Storage Density

inferred← citeshttps://doi.org/10.1021/jacs.2c05309openalex-snapshot

Efficient Adsorption of Acetylene over CO 2 in Bioinspired Covalent Organic Frameworks

inferred← citeshttps://doi.org/10.1021/jacs.3c01705openalex-snapshot

Exclusive Recognition of CO 2 from Hydrocarbons by Aluminum Formate with Hydrogen-Confined Pore Cavities

inferred← citeshttps://doi.org/10.1021/jacs.3c03265openalex-snapshot

Immobilization of the Polar Group into an Ultramicroporous Metal–Organic Framework Enabling Benchmark Inverse Selective CO2/C2H2 Separation with Record C2H2 Production

inferred← citeshttps://doi.org/10.1021/jacs.3c12032openalex-snapshot

Isoreticular Contraction of Cage-like Metal–Organic Frameworks with Optimized Pore Space for Enhanced C2H2/CO2 and C2H2/C2H4 Separations

inferred← citeshttps://doi.org/10.1021/jacs.4c01092openalex-snapshot

Precise Modulation of CO2 Sorption in Ti8Ce2–Oxo Clusters: Elucidating Lewis Acidity of the Ce Metal Sites and Structural Flexibility

inferred← citeshttps://doi.org/10.1021/jacs.4c03476openalex-snapshot

CO2-Based Stable Porous Metal–Organic Frameworks for CO2 Utilization

inferred← citeshttps://doi.org/10.1021/jacs.4c15141openalex-snapshot

Mobile Constituent-Boosted Dynamic Separation of C 2 H 2 /C 2 H 4 /CO 2 Ternary Mixtures in Metal–Organic Frameworks

inferred← citeshttps://doi.org/10.1021/prechem.2c00003openalex-snapshot

Synergistic and Antisynergistic Intracrystalline Diffusional Influences on Mixture Separations in Fixed-Bed Adsorbers

inferred← citeshttps://doi.org/10.1038/s41467-022-32677-3openalex-snapshot

Ultramicroporous material based parallel and extended paraffin nano-trap for benchmark olefin purification

inferred← citeshttps://doi.org/10.1038/s41467-023-39319-2openalex-snapshot

Temperature-dependent rearrangement of gas molecules in ultramicroporous materials for tunable adsorption of CO2 and C2H2

inferred← citeshttps://doi.org/10.1038/s41467-025-57972-7openalex-snapshot

Benchmarking selective capture of trace CO2 from C2H2 using an amine-functionalized adsorbent

inferred← citeshttps://doi.org/10.1039/9781839166617-00062openalex-snapshot

Flexible Properties: Adsorptive Storage and Separation

inferred← citeshttps://doi.org/10.1039/d1cc06261aopenalex-snapshot

Recent progress on porous MOFs for process-efficient hydrocarbon separation, luminescent sensing, and information encryption

inferred← citeshttps://doi.org/10.1039/d2cs00442aopenalex-snapshot

Fluorinated metal–organic frameworks for gas separation

inferred← citeshttps://doi.org/10.1039/d2dt04088copenalex-snapshot

Low-concentration CO 2 capture using metal–organic frameworks – current status and future perspectives

inferred← citeshttps://doi.org/10.1039/d2me00036aopenalex-snapshot

Recent advances in software tools for adsorption science and engineering

inferred← citeshttps://doi.org/10.1039/d2ta03159kopenalex-snapshot

Metal–organic frameworks based on infinite secondary building units: recent progress and future outlooks

inferred← citeshttps://doi.org/10.1039/d2ta04835copenalex-snapshot

Recent advances in microporous metal–organic frameworks as promising adsorbents for gas separation

inferred← citeshttps://doi.org/10.1039/d2ta07473gopenalex-snapshot

Controllable inverse C 2 H 2 /CO 2 separation in ultra-stable Zn-organic frameworks for efficient removal of trace CO 2 from acetylene

inferred← citeshttps://doi.org/10.1039/d2ta08934copenalex-snapshot

Ultramicroporous iron-isonicotinate MOFs combining size-exclusion kinetics and thermodynamics for efficient CO 2 /N 2 gas separation

inferred← citeshttps://doi.org/10.1039/d2ta09746jopenalex-snapshot

Cooperative CO 2 adsorption mechanism in a perfluorinated Ce IV -based metal organic framework

inferred← citeshttps://doi.org/10.1039/d3mh00697bopenalex-snapshot

One-step ethylene purification from ternary mixtures by an ultramicroporous material with synergistic binding centers

inferred← citeshttps://doi.org/10.1039/d3qi00314kopenalex-snapshot

Design of a robust rod-packing scandium–organic framework for C 2 H x /CO 2 separation, CO 2 storage, and catalytic CO 2 cycloaddition

inferred← citeshttps://doi.org/10.1039/d3qm00430aopenalex-snapshot

Recent progress in metal–organic frameworks for the separation of gaseous hydrocarbons

inferred← citeshttps://doi.org/10.1039/d3ra04940jopenalex-snapshot

Recent advances in the chemistry and applications of fluorinated metal–organic frameworks (F-MOFs)

inferred← citeshttps://doi.org/10.1039/d4ce01097copenalex-snapshot

Sonochemical synthesis of Zr-based metal–organic cages and their adsorption performance towards tartrazine

inferred← citeshttps://doi.org/10.1039/d4dt02209bopenalex-snapshot

Metal–organic frameworks with a sulfur-rich heterocycle: synthesis, gas adsorption properties, and metal exchange

inferred← citeshttps://doi.org/10.1039/d4qi02531hopenalex-snapshot

Efficient inverse CO 2 /C 2 H 2 separation driven by difference in rare thermodynamic affinities in a porous MOF

inferred← citeshttps://doi.org/10.1039/d4sc01525hopenalex-snapshot

Increased CO 2 /N 2 selectivity by stepwise fluorination in isoreticular ultramicroporous metal–organic frameworks

inferred← citeshttps://doi.org/10.1039/d5me00060bopenalex-snapshot

Discovery of metal–organic frameworks for inverse CO 2 /C 2 H 2 separation by synergizing molecular simulation and machine learning

inferred← citeshttps://doi.org/10.1039/d5nr03256copenalex-snapshot

Fluorinated Zr-MOF-modified separators for Li–S batteries with enhanced electrochemical performance

inferred← citeshttps://doi.org/10.1039/d5sc03281dopenalex-snapshot

A cation gating–breathing synergetic mechanism in K-MER-2.0 zeolite enables unprecedented selective CO 2 separation from hydrocarbon gas streams

inferred← citeshttps://doi.org/10.1039/d5sc03670dopenalex-snapshot

Structural determination of MCOFs: status, challenges and perspectives

inferred← citeshttps://doi.org/10.1039/d6cc04161bopenalex-snapshot

A carboxylic acid-containing Zr-MOF demonstrating exceptional CO 2 /N 2 separation performance under humid conditions

inferred← citeshttps://doi.org/10.1039/d6ce00699jopenalex-snapshot

Structural diversity and blue photoluminescence of Mg( ii ) and Cd( ii ) coordination polymers assembled with tetrafluoroterephthalate linkers

inferred← citeshttps://doi.org/10.1039/d6ta03830aopenalex-snapshot

CO 2 -selective metal–organic frameworks for one-step C 2 H 2 purification

inferred← citeshttps://doi.org/10.1246/bcsj.20210237openalex-snapshot

An Ultramicroporous Metal-Organic Framework with Record High Selectivity for Inverse CO2/C2H2 Separation

inferred← citeshttps://doi.org/10.3390/cleantechnol5010001openalex-snapshot

CO2-Selective Capture from Light Hydrocarbon Mixtures by Metal-Organic Frameworks: A Review

inferred← citeshttps://doi.org/10.6023/a26010036openalex-snapshot

A Low-Cost and Highly Stable K 2 Zn 3 [Fe(CN) 6 ] 2 Framework for Efficient CO 2 /C 2 H 2 Separation ★

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