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Tandem Living Insertion and Controlled Radical Polymerization for Polyolefin–Polyvinyl Block Copolymers

https://doi.org/10.1002/anie.202112742

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/ange.201814634openalex-snapshot

Emerging Palladium and Nickel Catalysts for Copolymerization of Olefins with Polar Monomers

inferredcites →https://doi.org/10.1002/ange.201900650openalex-snapshot

Olefine und polare Vinylmonomere: Überbrückung der Lücke für Materialien der nächsten Generation

inferredcites →https://doi.org/10.1002/ange.201910828openalex-snapshot

Dimethyl Dihydroacridines as Photocatalysts in Organocatalyzed Atom Transfer Radical Polymerization of Acrylate Monomers

inferredcites →https://doi.org/10.1002/ange.202107039openalex-snapshot

Distorted Sandwich α‐Diimine PdII Catalyst: Linear Polyethylene and Synthesis of Ethylene/Acrylate Elastomers

inferredcites →https://doi.org/10.1002/anie.201814634openalex-snapshot

Emerging Palladium and Nickel Catalysts for Copolymerization of Olefins with Polar Monomers

inferredcites →https://doi.org/10.1002/anie.201900650openalex-snapshot

Olefins and Vinyl Polar Monomers: Bridging the Gap for Next Generation Materials

inferredcites →https://doi.org/10.1002/anie.201910828openalex-snapshot

Dimethyl Dihydroacridines as Photocatalysts in Organocatalyzed Atom Transfer Radical Polymerization of Acrylate Monomers

inferredcites →https://doi.org/10.1002/anie.202107039openalex-snapshot

Distorted Sandwich α‐Diimine PdII Catalyst: Linear Polyethylene and Synthesis of Ethylene/Acrylate Elastomers

inferredcites →https://doi.org/10.1002/macp.200600125openalex-snapshot

Nitroxide‐Mediated Polymerization of Methyl Methacrylate Using an SG1‐Based Alkoxyamine: How the Penultimate Effect Could Lead to Uncontrolled and Unliving Polymerization

inferredcites →https://doi.org/10.1002/macp.201000420openalex-snapshot

Synthesis of Macro(alkoxyamines) via Hydroboration of Polyolefins with Subsequent Nitroxide Oxidation for Controlled NMP

inferredcites →https://doi.org/10.1002/marc.200700443openalex-snapshot

Chain Walking Ethylene Copolymerization with an ATRP Inimer for One‐Pot Synthesis of Hyperbranched Polyethylenes Tethered with ATRP Initiating Sites

inferredcites →https://doi.org/10.1002/marc.201100825openalex-snapshot

Synthesis of Hyperbranched Polyethylene Amphiphiles by Chain Walking Polymerization in Tandem with RAFT Polymerization and Supramolecular Self‐Assembly Vesicles

inferredcites →https://doi.org/10.1002/pola.10348openalex-snapshot

Polyolefin graft copolymers via living polymerization techniques: Preparation of poly(n‐butyl acrylate)‐graft‐polyethylene through the combination of Pd‐mediated living olefin polymerization and atom transfer radical polymerization

inferredcites →https://doi.org/10.1002/pola.21207openalex-snapshot

Nitroxide decomposition: Implications toward nitroxide design for applications in living free‐radical polymerization

inferredcites →https://doi.org/10.1002/pola.24639openalex-snapshot

Embedding multiple site‐specific functionalities into polymer chains via nitrone‐mediated radical coupling reactions

inferredcites →https://doi.org/10.1002/pola.28489openalex-snapshot

Synthesis and Characterization of Crystalline Styrene‐b‐(Ethylene‐co‐Butylene)‐b‐Styrene Triblock Copolymers

inferredcites →https://doi.org/10.1016/s0891-5849(87)80033-3openalex-snapshot

Spin Trapping: ESR parameters of spin adducts 1474 1528V

inferredcites →https://doi.org/10.1021/acs.macromol.0c00241openalex-snapshot

Catalytic Chain Transfer Polymerization to Functional Reactive End Groups for Controlled Free Radical Growth

inferredcites →https://doi.org/10.1021/acs.macromol.6b00345openalex-snapshot

Radical Generation and Termination in SARA ATRP of Methyl Acrylate: Effect of Solvent, Ligand, and Chain Length

inferredcites →https://doi.org/10.1021/acs.macromol.8b00348openalex-snapshot

Aqueous Metal-Free Atom Transfer Radical Polymerization: Experiments and Model-Based Approach for Mechanistic Understanding

inferredcites →https://doi.org/10.1021/acs.macromol.8b01719openalex-snapshot

Light as a Catalytic Switch for Block Copolymer Architectures: Metal–Organic Insertion/Light Initiated Radical (MILRad) Polymerization

inferredcites →https://doi.org/10.1021/ja00128a054openalex-snapshot

New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins

inferredcites →https://doi.org/10.1021/ja0573864openalex-snapshot

Tandem Chain Walking Polymerization and Atom Transfer Radical Polymerization for Efficient Synthesis of Dendritic Nanoparticles for Bioconjugation

inferredcites →https://doi.org/10.1021/ja061398nopenalex-snapshot

Redox Control within Single-Site Polymerization Catalysts

inferredcites →https://doi.org/10.1021/ja962516hopenalex-snapshot

Living Polymerization of α-Olefins Using NiII−α-Diimine Catalysts. Synthesis of New Block Polymers Based on α-Olefins

inferredcites →https://doi.org/10.1021/ja964144iopenalex-snapshot

Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and α-Olefins with Methyl Acrylate

inferredcites →https://doi.org/10.1021/ja984013copenalex-snapshot

Development of a Universal Alkoxyamine for “Living” Free Radical Polymerizations

inferredcites →https://doi.org/10.1021/jacs.0c10588openalex-snapshot

Dual Polymerization Pathway for Polyolefin-Polar Block Copolymer Synthesis via MILRad: Mechanism and Scope

inferredcites →https://doi.org/10.1021/jacs.5b13455openalex-snapshot

Mechanism of Photoinduced Metal-Free Atom Transfer Radical Polymerization: Experimental and Computational Studies

inferredcites →https://doi.org/10.1021/jacs.8b09039openalex-snapshot

Polyolefin–Polar Block Copolymers from Versatile New Macromonomers

inferredcites →https://doi.org/10.1021/jo00254a022openalex-snapshot

Correlation of radical structure with EPR spin adduct parameters: utility of the proton, carbon-13, and nitrogen-14 hyperfine splitting constants of aminoxyl adducts of PBN-nitronyl-13C for three-parameter scatter plots

inferredcites →https://doi.org/10.1021/ma050263jopenalex-snapshot

Synthesis of Block and Graft Copolymers with Linear Polyethylene Segments by Combination of Degenerative Transfer Coordination Polymerization and Atom Transfer Radical Polymerization

inferredcites →https://doi.org/10.1021/ma0717800openalex-snapshot

Role of Cu0 in Controlled/“Living” Radical Polymerization

inferredcites →https://doi.org/10.1021/ma401244topenalex-snapshot

Functional Polyolefins for Energy Applications

inferredcites →https://doi.org/10.1021/ma500034gopenalex-snapshot

Transition-Metal-Catalyzed Functional Polyolefin Synthesis: Effecting Control through Chelating Ancillary Ligand Design and Mechanistic Insights

inferredcites →https://doi.org/10.1021/ma701923qopenalex-snapshot

Synthesis of Multisegmented Degradable Polymers by Atom Transfer Radical Cross-Coupling

inferredcites →https://doi.org/10.1021/om030507topenalex-snapshot

Polymerization of Acrylates by Neutral Palladium Complexes. Isolation of Complexes at the Initial Steps

inferredcites →https://doi.org/10.1021/om9710125openalex-snapshot

Reactions of Cationic Palladium(II) Methyl and Vinyl Complexes with Alkynes

inferredcites →https://doi.org/10.1038/s41467-020-20645-8openalex-snapshot

Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight

inferredcites →https://doi.org/10.1039/b925390dopenalex-snapshot

Spin capturing with nitrones: radical coupling reactions with concurrent introduction of mid-chain functionality

inferredcites →https://doi.org/10.1039/c5py01493jopenalex-snapshot

Synthesis of thermally cleavable multisegmented polystyrene by an atom transfer nitroxide radical polymerization (ATNRP) mechanism

inferredcites →https://doi.org/10.1039/c6py01779gopenalex-snapshot

Aqueous SARA ATRP using inorganic sulfites

inferredcites →https://doi.org/10.1039/c7qm00321hopenalex-snapshot

Late transition metal catalyzed α-olefin polymerization and copolymerization with polar monomers

inferredcites →https://doi.org/10.1039/c8py01556bopenalex-snapshot

Metal–organic insertion light initiated radical (MILRad) polymerization: photo-initiated radical polymerization of vinyl polar monomers with various palladium diimine catalysts

inferredcites →https://doi.org/10.1039/c8sc00450aopenalex-snapshot

Catalytic synthesis of functionalized (polar and non-polar) polyolefin block copolymers

inferredcites →https://doi.org/10.1126/science.aaf3935openalex-snapshot

Organocatalyzed atom transfer radical polymerization driven by visible light

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4688240openalex-extracted

inferred← citeshttps://doi.org/10.1002/ange.202205931openalex-snapshot

One‐For‐All Polyolefin Functionalization: Active Ester as Gateway to Combine Insertion Polymerization with ROP, NMP, and RAFT

inferred← citeshttps://doi.org/10.1002/ange.202500761openalex-snapshot

“Pulsed” Chain Transfer Anionic Polymerization: A Green and Cost‐Effective Approach for Controlled Polymer Synthesis

inferred← citeshttps://doi.org/10.1002/anie.202205931openalex-snapshot

One‐For‐All Polyolefin Functionalization: Active Ester as Gateway to Combine Insertion Polymerization with ROP, NMP, and RAFT

inferred← citeshttps://doi.org/10.1002/anie.202500761openalex-snapshot

“Pulsed” Chain Transfer Anionic Polymerization: A Green and Cost‐Effective Approach for Controlled Polymer Synthesis

inferred← citeshttps://doi.org/10.1002/mame.202400358openalex-snapshot

Synthesis of Block Copolymers Utilizing Alkoxycarbonylation or Aminocarbonylation of Growing Chain End in Pd‐Catalyzed Living Polymerization of Olefins

inferred← citeshttps://doi.org/10.1002/marc.202300675openalex-snapshot

Block Copolymers of Polyolefins with Polyacrylates: Analyzing and Improving the Blocking Efficiencies Using MILRad/ATRP Approach

inferred← citeshttps://doi.org/10.1016/j.ccr.2024.216195openalex-snapshot

Development of well-defined olefin block (co)polymers achieved by late transition metal catalysts: Catalyst, synthesis and characterization

inferred← citeshttps://doi.org/10.1016/j.chempr.2024.05.016openalex-snapshot

Synthesis of polyethylene-polyacrylate block copolymers in continuous flow

inferred← citeshttps://doi.org/10.1016/j.eurpolymj.2024.113001openalex-snapshot

Current status and outlook for ATRP

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Polar polyethylene block copolymer synthesis via organometallic-mediated radical polymerization using Co(Salen) complexes

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Comparison of various ATRP techniques for synthesis of polar block copolymers with polyolefins

inferred← citeshttps://doi.org/10.1016/j.polymer.2024.126984openalex-snapshot

A New Radical Initiation for the Ring-Opening Polymerization of Tetrahydrofuran with a Radical Substitution Mechanism

inferred← citeshttps://doi.org/10.1016/j.polymer.2024.127000openalex-snapshot

The synthesis of asymmetrical anilinotropone nickel and palladium complexes for olefin polymerization

inferred← citeshttps://doi.org/10.1016/j.trechm.2022.12.007openalex-snapshot

‘Catalyst + X’ strategies for transition metal-catalyzed olefin-polar monomer copolymerization

inferred← citeshttps://doi.org/10.1021/acs.chemrev.2c00189openalex-snapshot

Linear Block Copolymer Synthesis

inferred← citeshttps://doi.org/10.1021/acs.chemrev.3c00212openalex-snapshot

Organic Synthesis Using Nitroxides

inferred← citeshttps://doi.org/10.1021/acs.macromol.2c00594openalex-snapshot

Tailor-Made Functional Polyolefins of Complex Architectures: Recent Advances, Applications, and Prospects

inferred← citeshttps://doi.org/10.1021/acs.macromol.2c02344openalex-snapshot

Dual-Site Polymeric Heterogeneous α-Diimine Ni Catalysts with Tailored Spatial Distribution for Ethylene Polymerization

inferred← citeshttps://doi.org/10.1021/acs.macromol.4c02684openalex-snapshot

Polyethylene-poly(methyl acrylate) Block Copolymers from PACE-SARA ATRP: Utilizing Polyolefin Active Ester Exchange-Based Macroinitiators in Atom Transfer Radical Polymerization

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Tailoring Branched Polyethylene with Polar Segments: A Strategic Approach to Multifunctional Polyolefin Materials

inferred← citeshttps://doi.org/10.1021/acscatal.2c04272openalex-snapshot

Advances on Controlled Chain Walking and Suppression of Chain Transfer in Catalytic Olefin Polymerization

inferred← citeshttps://doi.org/10.1021/jacs.5c13309openalex-snapshot

Leveraging Earth-Abundant Nickel for Orthogonal Polymerizations: Synthesizing Polar Polyolefin Block Copolymers

inferred← citeshttps://doi.org/10.1038/s41467-025-66962-8openalex-snapshot

Photoredox-controlled alternating copolymerization enables highly crystalline structures and block copolymers from thermoplastic to elastomer

inferred← citeshttps://doi.org/10.1039/d3py00714fopenalex-snapshot

Thermal control of multiblock sequence using anion-migrated ring-opening polymerization

inferred← citeshttps://doi.org/10.1039/d3sc03827kopenalex-snapshot

Alternating styrene–propylene and styrene–ethylene copolymers prepared by photocatalytic decarboxylation

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