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Metal‐Free Electrochemical Carboxylation of Organic Halides in the Presence of Catalytic Amounts of an Organomediator

https://doi.org/10.1002/anie.202210201

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Electrochemical Desaturative β‐Acylation of Cyclic N‐Aryl Amines

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Cathodic Radical Cyclisation of Aryl Halides Using a Strongly‐Reducing Catalytic Mediator in Flow

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Electrochemical Desaturative β‐Acylation of Cyclic N‐Aryl Amines

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Cathodic Radical Cyclisation of Aryl Halides Using a Strongly‐Reducing Catalytic Mediator in Flow

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Electrocarboxylation of Aryl Epoxides with CO2for the Facile and Selective Synthesis of β‐Hydroxy Acids

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What points at this work

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Organic Transformations Utilizing 1,5,7‐Triazabicyclo[4.4.0]Dec‐5‐Ene (TBD): A Tale of Two Nitrogens

inferred← citeshttps://doi.org/10.1002/ejoc.202501217openalex-snapshot

Electrochemically Generated Carbanions in Organic Synthesis

inferred← citeshttps://doi.org/10.1002/open.202400426openalex-snapshot

Transition Metal‐Free Direct Electrochemical Carboxylation of Organic Halides Using a Sacrificial Magnesium Anode: Straightforward Synthesis of Carboxylic Acids

inferred← citeshttps://doi.org/10.1007/s11426-024-2036-0openalex-snapshot

Electrochemical conversion of organic compounds and inorganic small molecules

inferred← citeshttps://doi.org/10.1007/s11426-024-2154-8openalex-snapshot

Organo-electroreduction enables arylcarboxylation of styrenes

inferred← citeshttps://doi.org/10.1007/s11426-025-2639-8openalex-snapshot

A general electrochemical CO2 fixation to aromatic carboxylic acids via the CO2·− intermediate using a non-transition metal electrode

inferred← citeshttps://doi.org/10.1007/s11426-026-3468-7openalex-snapshot

Recent advances in organic synthesis with CO2

inferred← citeshttps://doi.org/10.1007/s11426-026-3575-7openalex-snapshot

Electron-shuttle catalysis in organic transformations

inferred← citeshttps://doi.org/10.1007/s41061-025-00496-xopenalex-snapshot

CO2 Fixation into Useful Aromatic Carboxylic Acids via C (sp2)–X Bonds Functionalization

inferred← citeshttps://doi.org/10.1016/bs.acat.2023.07.009openalex-snapshot

Overview of outer-sphere electron transfer mediators for electrosynthesis

inferred← citeshttps://doi.org/10.1016/j.checat.2022.10.017openalex-snapshot

Tandem strategy for electrochemical CO2 reduction reaction

inferred← citeshttps://doi.org/10.1016/j.checat.2025.101263openalex-snapshot

Anodic reactions matter for cathodic electrocarboxylation with CO2

inferred← citeshttps://doi.org/10.1016/j.checat.2025.101359openalex-snapshot

Electroreductively driven C–H functionalization of arenes

inferred← citeshttps://doi.org/10.1016/j.crgsc.2023.100377openalex-snapshot

Site-selective electrochemical carboxylation of aromatic C(sp2)–H bonds with CO2

inferred← citeshttps://doi.org/10.1016/j.esci.2024.100255openalex-snapshot

Catalyst-free electrochemical SNAr of electron-rich fluoroarenes using carboxylic acids

inferred← citeshttps://doi.org/10.1016/j.isci.2025.111748openalex-snapshot

Efficient photoelectrochemical system for electrocarboxylation of 1,4-dibromobenzene with CO2 using dye-sensitized photovoltaics

inferred← citeshttps://doi.org/10.1016/j.jcat.2024.115371openalex-snapshot

Recent progress in the development of electrode materials for electrochemical carboxylation with CO2

inferred← citeshttps://doi.org/10.1016/j.tchem.2024.100080openalex-snapshot

Repurposing HER catalysis toward metal hydride-mediated electro-reductive transformations

inferred← citeshttps://doi.org/10.1016/j.tetlet.2024.155354openalex-snapshot

Synthesis of (2,3-dihydrobenzofuran-3-yl)acetic acids from salicylic aldehydes: Trimethylsilyl as traceless activating group

inferred← citeshttps://doi.org/10.1021/acs.accounts.4c00417openalex-snapshot

Recent Advances in Electrochemical Carboxylation with CO 2

inferred← citeshttps://doi.org/10.1021/acs.accounts.4c00652openalex-snapshot

Electroreductive Cross-Coupling Reactions: Carboxylation, Deuteration, and Alkylation

inferred← citeshttps://doi.org/10.1021/acs.accounts.6c00268openalex-snapshot

Organic Electrochemical Transformations of Resource Small Molecules

inferred← citeshttps://doi.org/10.1021/acs.chemrev.3c00158openalex-snapshot

Electrochemical Late-Stage Functionalization

inferred← citeshttps://doi.org/10.1021/acs.chemrev.4c00808openalex-snapshot

Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations

inferred← citeshttps://doi.org/10.1021/acs.joc.3c00037openalex-snapshot

Selective Electroreductive Hydroboration of Olefins with B2pin2

inferred← citeshttps://doi.org/10.1021/acs.joc.4c02566openalex-snapshot

Alkylthiolation of Aryl Halides under Electrochemical Conditions

inferred← citeshttps://doi.org/10.1021/acs.joc.5c02460openalex-snapshot

Electroreductive C(sp 3 )–C(sp 3 ) Cross-Coupling Reactions

inferred← citeshttps://doi.org/10.1021/acs.orglett.3c01033openalex-snapshot

Revisiting the Electrochemical Carboxylation of Naphthalene with CO2: Selective Monocarboxylation of 2-Substituted Naphthalenes

inferred← citeshttps://doi.org/10.1021/acs.orglett.3c02989openalex-snapshot

Cobalt-Promoted Electroreductive Cross-Coupling of Prop-2-yn-1-yl Acetates with Chloro(vinyl)silanes

inferred← citeshttps://doi.org/10.1021/acs.orglett.3c03735openalex-snapshot

Electroreductive Carboxylation of Propargylic Acetates with CO2: Access to Tetrasubstituted 2,3-Allenoates

inferred← citeshttps://doi.org/10.1021/acs.orglett.4c00920openalex-snapshot

Electroreductive Arylcarboxylation of Styrenes with CO2 and Aryl Halides via a Radical–Polar Crossover Mechanism

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c01099openalex-snapshot

Electrochemical Deaminative Carboxylation of Aryltriazenes with CO2 to Aryl Carboxylic Acids

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c02243openalex-snapshot

Electrochemical Ni-Catalyzed α-Selective Hydrocarboxylation of Styrenes with CO2

inferred← citeshttps://doi.org/10.1021/acs.orglett.5c03380openalex-snapshot

1,3,5-Triazine-Mediated Electrochemical Carboxylation of Aryl Thianthrenium Salts with CO 2

inferred← citeshttps://doi.org/10.1021/acs.orglett.6c00031openalex-snapshot

Dual Non-C1 Synthon Role of CO 2 in Controlled Electrochemical Defluorination

inferred← citeshttps://doi.org/10.1021/jacs.5c00259openalex-snapshot

Electrochemical Benzylic C–H Carboxylation

inferred← citeshttps://doi.org/10.1021/jacsau.4c00974openalex-snapshot

Excited Organic Radicals in Photoredox Catalysis

inferred← citeshttps://doi.org/10.1038/s41467-023-42106-8openalex-snapshot

Metal-free electrochemical dihydroxylation of unactivated alkenes

inferred← citeshttps://doi.org/10.1038/s41467-023-42699-0openalex-snapshot

Organomediated electrochemical fluorosulfonylation of aryl triflates via selective C–O bond cleavage

inferred← citeshttps://doi.org/10.1038/s41467-024-47168-wopenalex-snapshot

Electroreduction of unactivated alkenes using water as hydrogen source

inferred← citeshttps://doi.org/10.1038/s41467-025-57060-wopenalex-snapshot

Metallaphotoredox-catalyzed alkynylcarboxylation of alkenes with CO2 and alkynes for expedient access to β-alkynyl acids

inferred← citeshttps://doi.org/10.1038/s41557-026-02249-9openalex-snapshot

Deep reduction in electrosynthesis

inferred← citeshttps://doi.org/10.1038/s41929-024-01118-3openalex-snapshot

Nickel-electrocatalysed C(sp3)–C(sp3) cross-coupling of unactivated alkyl halides

inferred← citeshttps://doi.org/10.1039/d2im00056copenalex-snapshot

Multicomponent catalyst design for CO 2 /N 2 /NO x electroreduction

inferred← citeshttps://doi.org/10.1039/d2sc07045fopenalex-snapshot

Electrosynthesis of bridged or fused sulfonamides through complex radical cascade reactions: divergence in medium-sized ring formation

inferred← citeshttps://doi.org/10.1039/d3gc00344bopenalex-snapshot

Electrochemical dual α,β-C(sp 3 )–H functionalization of cyclic N -aryl amines

inferred← citeshttps://doi.org/10.1039/d3gc02814copenalex-snapshot

Electrochemical nickel-catalysed defluoroalkylation of gem -difluoroalkenes with alkyl halides

inferred← citeshttps://doi.org/10.1039/d3qo00280bopenalex-snapshot

Indirect electrochemical reductive cyclization of o -halophenylacrylamides mediated by phenanthrene

inferred← citeshttps://doi.org/10.1039/d3qo01913fopenalex-snapshot

Self-detachable protecting group function of CO 2 in the electrochemical reduction of aryl azides

inferred← citeshttps://doi.org/10.1039/d4cs01142bopenalex-snapshot

Organo-mediator enabled electrochemical transformations

inferred← citeshttps://doi.org/10.1039/d4gc01238kopenalex-snapshot

CO 2 -mediated isomerization of enamides

inferred← citeshttps://doi.org/10.1039/d4gc02829eopenalex-snapshot

Advances in photochemical/electrochemical synthesis of heterocyclic compounds from carbon dioxide

inferred← citeshttps://doi.org/10.1039/d4gc03452jopenalex-snapshot

Electroreductive deoxygenative carboxylation of alkyl oxalates with CO 2

inferred← citeshttps://doi.org/10.1039/d4gc05731gopenalex-snapshot

Electrochemical lactamization with CO 2

inferred← citeshttps://doi.org/10.1039/d4nj02533dopenalex-snapshot

Electrochemical formylation of aryl halides by using DMF as a formyl source

inferred← citeshttps://doi.org/10.1039/d4qo00846dopenalex-snapshot

Electroreduction strategy: a sustainable tool for the generation of aryl radicals

inferred← citeshttps://doi.org/10.1039/d4qo00999aopenalex-snapshot

Modern photo- and electrochemical approaches to aryl radical generation

inferred← citeshttps://doi.org/10.1039/d4sc03049dopenalex-snapshot

Electroreductive deuteroarylation of alkenes enabled by an organo-mediator

inferred← citeshttps://doi.org/10.1039/d5cc06533jopenalex-snapshot

Organomediator enabled electrochemically regioselective 1,2-arylalkylation of alkenes with aryl and alkyl halides

inferred← citeshttps://doi.org/10.1039/d5nj04770fopenalex-snapshot

Development and fabrication of a sustainable and recyclable COF-366-LP@Cu modified SPE electrode for the enantioselective electro-carboxylation of 1-phenylethan-1-ols to synthesize ( S )-2-phenylpropanoic acid derivatives under mild reaction conditions

inferred← citeshttps://doi.org/10.1039/d5qo00484eopenalex-snapshot

Organo-mediator enabled electrochemical 1,4-aryl migration of N -aryl-2-iodobenzamides/ N -sulfonyl-2-iodoanilines to access biaryls

inferred← citeshttps://doi.org/10.1039/d6gc03050eopenalex-snapshot

Ni@ETS-10-catalyzed carboxylation of aryl and alkyl halides with CO 2 in water: a green strategy for CO 2 utilization

inferred← citeshttps://doi.org/10.1039/d6gc03816fopenalex-snapshot

Electrochemical controlled divergent carboxylation and hydrocarboxylation of α-oxoalkenone dithioacetals with carbon dioxide

inferred← citeshttps://doi.org/10.1055/a-2373-0471openalex-snapshot

Reductive Electrophilic Cross-Coupling for Constructing C(sp3)–C(sp3) Bonds

inferred← citeshttps://doi.org/10.1055/s-0041-1738439openalex-snapshot

Nickel-Catalyzed Electrochemical Cyclizative Carboxylation of Alkene-Tethered Carbamoyl Chlorides with Carbon Dioxide

inferred← citeshttps://doi.org/10.1055/s-0043-1763748openalex-snapshot

Recent Advances and Challenges in Electrocatalytic Carboxylation of CO2

inferred← citeshttps://doi.org/10.1055/s-0043-1763755openalex-snapshot

Carboxylation of Alkenes with CO2 via Photocatalytic Cleavage of C=C Double Bonds

inferred← citeshttps://doi.org/10.1055/sos-sd-120-00360openalex-snapshot

20.2.10.2 Arenecarboxylic Acids (Update 2024)

inferred← citeshttps://doi.org/10.1360/tb-2024-0186openalex-snapshot

Fundamental science for carbon dioxide valorization and its transformation pathways

inferred← citeshttps://doi.org/10.20517/cs.2024.32openalex-snapshot

Electrochemical conversion of CO2 via C−X bond formation: recent progress and perspective

inferred← citeshttps://doi.org/10.2174/1385272827666230915162055openalex-snapshot

Synthesis of Carboxylic Acid by Electrochemical Fixation of Carbon Dioxide: A Review of Electrochemical Carboxylation from Past to Latest

inferred← citeshttps://doi.org/10.26434/chemrxiv-2024-s20btopenalex-snapshot

Paired Electrolysis Enables Reductive Heck Coupling of Unacti-vated (Hetero)Aryl Halides and Alkenes

inferred← citeshttps://doi.org/10.26599/pom.2026.9140126openalex-snapshot

Polyoxometalate@copper catalyst for electrocatalytic coupling of halo-(hetero)aromatic hydrocarbons and carbon dioxide for synthesis of (hetero)aromatic acid

inferred← citeshttps://doi.org/10.3390/catal13121489openalex-snapshot

Recent Advances in Catalyst Design for Carboxylation Using CO2 as the C1 Feedstock

inferred← citeshttps://doi.org/10.3390/catal16020191openalex-snapshot

Electrochemistry Carboxylation of Bromothiazoles with CO2: An Environmentally Friendly Synthesis of Thiazole Carboxylic Acids

inferred← citeshttps://doi.org/10.3390/molecules28020857openalex-snapshot

Electroreductively Induced Radicals for Organic Synthesis

inferred← citeshttps://doi.org/10.3866/pku.whxb202307008openalex-snapshot

Electrocarboxylation of Benzylic Phosphates and Phosphinates with Carbon Dioxide

inferred← citeshttps://doi.org/10.6023/cjoc202200057openalex-snapshot

Electrocarboxylation of Aryl Epoxides with CO2 to Selectively Synthesize β-Hydroxy Acids

inferred← citeshttps://doi.org/10.6023/cjoc202208004openalex-snapshot

Recent Progress in Electrochemical Fixation of CO2 to Construct Carboxylic Acid Derivatives

inferred← citeshttps://doi.org/10.6023/cjoc202310024openalex-snapshot

Recent Progress in Electrochemical Modification of Amino Acids and Peptides

inferred← citeshttps://doi.org/10.6023/cjoc202311030openalex-snapshot

Research Progress in Preparation of Carboxylic Acids by Electrochemical Mediated Oxidative Carboxylation and Reductive Carboxylation of Carbon Dioxide

inferred← citeshttps://doi.org/10.6023/cjoc202500015openalex-snapshot

Asymmetric Cross-Coupling of Epoxide Radical Anions Catalyzed by Copper Metal Photoredox

inferred← citeshttps://doi.org/10.6023/cjoc202602005openalex-snapshot

Direct Synthesis of β -Hydroxyesters via Cobalt-Catalyzed Carbonylation of Epoxides

inferred← citeshttps://doi.org/10.61558/2993-074x.3442openalex-snapshot

Recent Advance in Electrochemical Dehalogenative Deuteration

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