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A Mixed N‐Heterocyclic Carbene/2,2′‐Bipyridine‐Supported Robust Ruthenium(II) Oxidation Precatalyst for Benzylic C−H Oxidation

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/adsc.201000686openalex-snapshot
A Novel Carbene Ruthenium Complex as Reusable and Selective Two‐Electron Catalyst for Alkene Epoxidation
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Chemie in Mikrostrukturreaktoren
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Ruthenium‐Catalyzed Selective and Efficient Oxygenation of Hydrocarbons with Water as an Oxygen Source
inferredcites →https://doi.org/10.1002/ange.201602644openalex-snapshot
Die Erschließung von Wirkstoffmetaboliten durch übergangsmetallkatalysierte C‐H‐Oxidation: die Leber als Inspiration für die Synthese
inferredcites →https://doi.org/10.1002/ange.201607861openalex-snapshot
A Ruthenium(III)–Oxyl Complex Bearing Strong Radical Character
inferredcites →https://doi.org/10.1002/anie.200300577openalex-snapshot
Chemistry in Microstructured Reactors
inferredcites →https://doi.org/10.1002/anie.200801170openalex-snapshot
Ruthenium‐Catalyzed Selective and Efficient Oxygenation of Hydrocarbons with Water as an Oxygen Source
inferredcites →https://doi.org/10.1002/anie.201602644openalex-snapshot
Accessing Drug Metabolites via Transition‐Metal Catalyzed C−H Oxidation: The Liver as Synthetic Inspiration
inferredcites →https://doi.org/10.1002/anie.201607861openalex-snapshot
A Ruthenium(III)–Oxyl Complex Bearing Strong Radical Character
inferredcites →https://doi.org/10.1002/cctc.201200590openalex-snapshot
PNNP‐Ligated RuII Complexes as Efficient Catalysts for Mild Benzylic CH Oxidation
inferredcites →https://doi.org/10.1002/cplu.201200268openalex-snapshot
Understanding Electronic Ligand Perturbation over Successive Metal‐Based Redox Potentials in Mononuclear Ruthenium–Aqua Complexes
inferredcites →https://doi.org/10.1002/ejoc.201200292openalex-snapshot
Dirhodium(II) Complexes of 2‐(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation
inferredcites →https://doi.org/10.1002/ejoc.201201300openalex-snapshot
N‐Heterocyclic Carbene Dirhodium(II) Complexes as Catalysts for Allylic and Benzylic Oxidations
inferredcites →https://doi.org/10.1016/b978-0-12-404582-8.00001-8openalex-snapshot
Homogeneous Multicopper Catalysts for Oxidation and Hydrocarboxylation of Alkanes
inferredcites →https://doi.org/10.1016/j.catcom.2014.02.007openalex-snapshot
One-pot oximation–Beckmann rearrangement of ketones and aldehydes to amides of industrial interest: Acetanilide, caprolactam and acetaminophen
inferredcites →https://doi.org/10.1016/j.molcata.2016.06.020openalex-snapshot
Metal-catalyzed C H activation/functionalization: The fundamentals
inferredcites →https://doi.org/10.1016/j.molcata.2016.06.027openalex-snapshot
Structure–activity comparison in palladium–N–heterocyclic carbene (NHC) catalyzed arene C H activation- functionalization
inferredcites →https://doi.org/10.1016/j.tet.2013.09.036openalex-snapshot
One-pot synthesis of multifunctionalized m-terphenyls
inferredcites →https://doi.org/10.1021/acs.organomet.6b00337openalex-snapshot
Dramatic Effect of Ancillary NHC Ligand in the Highly Selective Catalytic Oxidative Carbon–Carbon Multiple Bond Cleavage
inferredcites →https://doi.org/10.1021/ar2002045openalex-snapshot
Overcoming the “Oxidant Problem”: Strategies to Use O2 as the Oxidant in Organometallic C–H Oxidation Reactions Catalyzed by Pd (and Cu)
inferredcites →https://doi.org/10.1021/cr000018sopenalex-snapshot
Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities
inferredcites →https://doi.org/10.1021/cr050523vopenalex-snapshot
Recent Advances in Transition Metal Catalyzed Oxidation of Organic Substrates with Molecular Oxygen
inferredcites →https://doi.org/10.1021/cr100198wopenalex-snapshot
Direct C−H Transformation via Iron Catalysis
inferredcites →https://doi.org/10.1021/cr9411886openalex-snapshot
Activation of C−H Bonds by Metal Complexes
inferredcites →https://doi.org/10.1021/cs2005899openalex-snapshot
Cp* Iridium Precatalysts for Selective C–H Oxidation via Direct Oxygen Insertion: A Joint Experimental/Computational Study
inferredcites →https://doi.org/10.1021/ic00292a008openalex-snapshot
Redox properties and ligand loss chemistry in aqua/hydroxo/oxo complexes derived from cis- and trans-[(bpy)2RuII(OH2)2]2+
inferredcites →https://doi.org/10.1021/ic034782jopenalex-snapshot
Kinetics and Mechanism of the Oxidation of Alkylaromatic Compounds by a trans-Dioxoruthenium(VI) Complex
inferredcites →https://doi.org/10.1021/ic035298jopenalex-snapshot
Cumene Oxidation bycis-[RuIV(bpy)2(py)(O)]2+, Revisited
inferredcites →https://doi.org/10.1021/ic048170qopenalex-snapshot
Oxidations of NADH Analogues by cis-[RuIV(bpy)2(py)(O)]2+ Occur by Hydrogen-Atom Transfer Rather than by Hydride Transfer
inferredcites →https://doi.org/10.1021/ic201686copenalex-snapshot
Electronic Structure of Oxidized Complexes Derived from cis-[RuII(bpy)2(H2O)2]2+ and Its Photoisomerization Mechanism
inferredcites →https://doi.org/10.1021/ic300123dopenalex-snapshot
Topologically Unique Heterometallic CuII/Li Coordination Polymers Self-Assembled from N,N-bis(2-Hydroxyethyl)-2-aminoethanesulfonic Acid Biobuffer: Versatile Catalyst Precursors for Mild Hydrocarboxylation of Alkanes to Carboxylic Acids
inferredcites →https://doi.org/10.1021/ic400743hopenalex-snapshot
Alkali Metal Directed Assembly of Heterometallic V v /M (M = Na, K, Cs) Coordination Polymers: Structures, Topological Analysis, and Oxidation Catalytic Properties
inferredcites →https://doi.org/10.1021/ja00085a023openalex-snapshot
Catalytic Oxidation of Hydrocarbons with O2 or H2O2 Using a Sterically Hindered Ruthenium Complex
inferredcites →https://doi.org/10.1021/ja035276wopenalex-snapshot
Oxidation of C−H Bonds by [(bpy)2(py)RuIVO]2+Occurs by Hydrogen Atom Abstraction
inferredcites →https://doi.org/10.1021/ja066460vopenalex-snapshot
Synthesis, Characterization, and Reactivities of Manganese(V)−Oxo Porphyrin Complexes
inferredcites →https://doi.org/10.1021/ja1058247openalex-snapshot
Cp* Iridium Complexes Give Catalytic Alkane Hydroxylation with Retention of Stereochemistry
inferredcites →https://doi.org/10.1021/ja2037645openalex-snapshot
Formation of a Ruthenium(IV)-Oxo Complex by Electron-Transfer Oxidation of a Coordinatively Saturated Ruthenium(II) Complex and Detection of Oxygen-Rebound Intermediates in C–H Bond Oxygenation
inferredcites →https://doi.org/10.1021/ja207572zopenalex-snapshot
Photochemical Activation of Ruthenium(II)–Pyridylamine Complexes Having a Pyridine-N-Oxide Pendant toward Oxygenation of Organic Substrates
inferredcites →https://doi.org/10.1021/jacs.5b04787openalex-snapshot
Interplay of Experiment and Theory in Elucidating Mechanisms of Oxidation Reactions by a Nonheme RuIVO Complex
inferredcites →https://doi.org/10.1021/jacs.6b06252openalex-snapshot
Factors Controlling the Chemoselectivity in the Oxidation of Olefins by Nonheme Manganese(IV)-Oxo Complexes
inferredcites →https://doi.org/10.1021/jo0010126openalex-snapshot
Stoichiometric and Catalytic Oxidations of Alkanes and Alcohols Mediated by Highly Oxidizing Ruthenium−Oxo Complexes Bearing 6,6‘-Dichloro-2,2‘-bipyridine
inferredcites →https://doi.org/10.1021/jo00126a038openalex-snapshot
A Kinetic Study on the Reactivity of a cis-Dioxoruthenium(VI) Complex. Oxidation of Alcohols, Aromatic Hydrocarbons, and Alkenes by cis-[RuVI(Tet-Me6)O2]2+
inferredcites →https://doi.org/10.1021/ol0520020openalex-snapshot
Benzylic Oxidation Catalyzed by Dirhodium(II,III) Caprolactamate
inferredcites →https://doi.org/10.1021/ol7025284openalex-snapshot
Optimal TBHP Allylic Oxidation of Δ5-Steroids Catalyzed by Dirhodium Caprolactamate
inferredcites →https://doi.org/10.1021/ol900097yopenalex-snapshot
Aqueous Phase C−H Bond Oxidation Reaction of Arylalkanes Catalyzed by a Water-Soluble Cationic Ru(III) Complex [(pymox-Me2)2RuCl2]+BF4−
inferredcites →https://doi.org/10.1021/om301252wopenalex-snapshot
Cp* Iridium Precatalysts for Selective C–H Oxidation with Sodium Periodate As the Terminal Oxidant
inferredcites →https://doi.org/10.1021/om501163mopenalex-snapshot
Chelating Bis-N-heterocyclic Carbene–Palladium(II) Complexes for Oxidative Arene C–H Functionalization
inferredcites →https://doi.org/10.1038/446391aopenalex-snapshot
C–H activation
inferredcites →https://doi.org/10.1039/b105132fopenalex-snapshot
Alkane oxidation by a carboxylate-bridged dimanganese(III) complex.
inferredcites →https://doi.org/10.1039/b706709gopenalex-snapshot
Ruthenium catalyzed biomimetic oxidation in organic synthesis inspired by cytochrome P-450
inferredcites →https://doi.org/10.1039/c0cs00099jopenalex-snapshot
C–H oxidation by platinum group metal oxo or peroxo species
inferredcites →https://doi.org/10.1039/c2sc20118fopenalex-snapshot
Catalytic C–H oxidation by a triazamacrocyclic ruthenium complex
inferredcites →https://doi.org/10.1039/c39880001406openalex-snapshot
Ruthenium catalysed oxidation of alkanes with alkylhydroperoxides
inferredcites →https://doi.org/10.1039/c39910000021openalex-snapshot
Hydroxylation of methane by a sterically hindered ruthenium complex
inferredcites →https://doi.org/10.1039/c3cs60120jopenalex-snapshot
Methane as raw material in synthetic chemistry: the final frontier
inferredcites →https://doi.org/10.1039/c4dt03161jopenalex-snapshot
Templating an N-heterocyclic carbene (NHC)-cyclometalated Cp*Ir III -based oxidation precatalyst on a pendant coordination platform: assessment of the oxidative behavior via electrochemical, spectroscopic and catalytic probes
inferredcites →https://doi.org/10.1039/c4sc01050gopenalex-snapshot
Speciation and decomposition pathways of ruthenium catalysts used for selective C–H hydroxylation
inferredcites →https://doi.org/10.1039/c5cc04803fopenalex-snapshot
Mechanistic elucidation of C–H oxidation by electron rich non-heme iron( iv )–oxo at room temperature
inferredcites →https://doi.org/10.1039/c5cs00566copenalex-snapshot
To rebound or dissociate? This is the mechanistic question in C–H hydroxylation by heme and nonheme metal–oxo complexes
inferredcites →https://doi.org/10.1039/c5dt00809copenalex-snapshot
Mechanistic insights into the reactions of hydride transfer versus hydrogen atom transfer by a trans-dioxoruthenium( vi ) complex
inferredcites →https://doi.org/10.1039/c5np00122fopenalex-snapshot
Trends in applying C–H oxidation to the total synthesis of natural products
inferredcites →https://doi.org/10.1039/c6cc00157bopenalex-snapshot
A remote coordination booster enhances the catalytic efficiency by accelerating the generation of an active catalyst
inferredcites →https://doi.org/10.1039/c6dt03024fopenalex-snapshot
Characteristics and reactivity of ruthenium–oxo complexes
inferredcites →https://doi.org/10.1039/dt9910001901openalex-snapshot
Tuning the reactivities of ruthenium–oxo complexes with robust ligands. A ruthenium( IV )–oxo complex of 6,6′-dichloro-2,2′-bipyridine as an active oxidant for stoichiometric and catalytic organic oxidation

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Ruthenium‐Catalyzed Benzylic CH Functionalization
inferred← citeshttps://doi.org/10.1002/asia.201901215openalex-snapshot
Coordination Booster‐Catalyst Assembly: Remote Osmium Outperforming Ruthenium in Boosting Catalytic Activity
inferred← citeshttps://doi.org/10.1002/cctc.201900242openalex-snapshot
Remote ‘Imidazole’ Based Ruthenium(II) p ‐Cymene Precatalyst for Selective Oxidative Cleavage of C−C Multiple Bonds
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Metal-Carbon Bonds of Heavier Group 7 and 8 Metals (Tc, Re, Ru, Os): Mononuclear Tc/Re/Ru/Os Complexes With Metal-Carbon Bonds
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Cooperative strategies for controlling selectivity in oxidative cleavage of C C bonds: Insights from nanoscale Ni-NiO-ZnO catalysis
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Selective C(sp3)–H Oxyfunctionalizations in the Presence of Ru, Rh, and Pd Based Catalysts
inferred← citeshttps://doi.org/10.1016/j.ica.2019.119195openalex-snapshot
Ancillary ligands switch the activity of Ru–NHC-based oxidation precatalysts
inferred← citeshttps://doi.org/10.1016/j.jscs.2021.101397openalex-snapshot
Porous organic polymer immobilized copper nanoparticles as heterogeneous catalyst for efficient benzylic C–H bond oxidation
inferred← citeshttps://doi.org/10.1016/j.mcat.2020.111102openalex-snapshot
Efficient and selective oxidation of secondary benzylic C H bonds to ketones with O2 catalyzed by metalloporphyrins under solvent-free and additive-free conditions
inferred← citeshttps://doi.org/10.1016/j.mcat.2020.111276openalex-snapshot
Mn(III) active site in hydrotalcite efficiently catalyzes the oxidation of alkylarenes with molecular oxygen
inferred← citeshttps://doi.org/10.1016/j.molstruc.2023.136870openalex-snapshot
Ruthenium(II) carbonyl complexes bearing schiff-base ligands: Syntheses, characterization, and their catalytic activities for benzylic C-H oxidation
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Visible light-mediated oxidation of benzylic C H bonds using vitamin B2 as a photocatalyst
inferred← citeshttps://doi.org/10.1021/acs.chemrev.9b00634openalex-snapshot
N-Heterocyclic Carbene Complexes in C–H Activation Reactions
inferred← citeshttps://doi.org/10.1021/acs.joc.0c00025openalex-snapshot
Highly Active and Robust Ruthenium Complexes Based on Hemilability of Hybrid Ligands for C–H Oxidation
inferred← citeshttps://doi.org/10.1021/acsorginorgau.3c00005openalex-snapshot
Impact of Bidentate Pyridyl-Mesoionic Carbene Ligands: Structural, (Spectro)Electrochemical, Photophysical, and Theoretical Investigations on Ruthenium(II) Complexes
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Aerobic Oxidation of Fluorene to Fluorenone over Copper-Doped Co3O4 with a High Specific Surface Area
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Recent Advances in Ru-Catalyzed Olefin and C–H Bond Oxidation
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Aerobic oxidation of fluorene to fluorenone over Co–Cu bimetal oxides
inferred← citeshttps://doi.org/10.1039/d1ra06897kopenalex-snapshot
Site-selective unidirectional benzylic sp 3 C–H oxidation of dodecahydrotriphenylene with RuCl 3 –NaIO 4 : formation of benzylic ketones
inferred← citeshttps://doi.org/10.1039/d3gc03639aopenalex-snapshot
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Light enhanced cytotoxicity and antitumoral effect of a ruthenium-based photosensitizer inspired from natural alkaloids
inferred← citeshttps://doi.org/10.1070/rcr4918openalex-snapshot
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