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Recent Perspectives on Rearrangement Reactions of Ylides via Carbene Transfer Reactions

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Auf der Suche nach neuer Reaktivität (Nobel-Vortrag) Copyright© The Nobel Foundation 2002. – Wir danken der Nobel-Stiftung, Stockholm, für die Genehmigung zum Druck einer deutschen Fassung des Vortrags. Abdruck in veränderter Fassung mit freundlicher Genehmigung aus „Coelacanths and Catalysis“: K.…
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Searching for New Reactivity (Nobel Lecture) Copyright© The Nobel Foundation 2002. We thank the Nobel Foundation, Stockholm, for permission to print this lecture. Adapted with the permission of the editors from “Coelacanths and Catalysis”: K. B. Sharpless, Tetrahedron 1994, 50, 4235.
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Hemin Catalyzed Dealkylative Intercepted [2, 3]‐Sigmatropic Rearrangement Reactions of Sulfonium Ylides with 2, 2, 2‐Trifluorodiazoethane
inferredcites →https://doi.org/10.1002/ajoc.201800091openalex-snapshot
Ammonium Ylide Mediated Cyclization Reactions
inferredcites →https://doi.org/10.1002/ajoc.201900099openalex-snapshot
Doyle‐Kirmse Rearrangement Reactions of Difluoroacetates
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Die Belluš‐Claisen‐Umlagerung
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Bis hin zu einer Symphonie der Reaktivität: Kaskaden mit Katalysen und sigmatropen Umlagerungen
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Highly Diastereoselective and Enantioselective Olefin Cyclopropanation Using Engineered Myoglobin‐Based Catalysts
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Myoglobin‐Catalyzed Olefination of Aldehydes
inferredcites →https://doi.org/10.1002/ange.201607278openalex-snapshot
Biocatalytic Synthesis of Allylic and Allenyl Sulfides through a Myoglobin‐Catalyzed Doyle–Kirmse Reaction
inferredcites →https://doi.org/10.1002/ange.201705317openalex-snapshot
Copper‐Catalyzed Enantio‐, Diastereo‐, and Regioselective [2,3]‐Rearrangements of Iodonium Ylides
inferredcites →https://doi.org/10.1002/ange.201707092openalex-snapshot
Enantioselektive [2,3]‐sigmatrope Umlagerungen – metallgebundene oder freie Ylide als Zwischenstufen?
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Durch blaues Licht induzierte Carbentransferreaktionen von Diazoalkanen
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The Belluš–Claisen Rearrangement
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Toward a Symphony of Reactivity: Cascades Involving Catalysis and Sigmatropic Rearrangements
inferredcites →https://doi.org/10.1002/anie.201409928openalex-snapshot
Highly Diastereoselective and Enantioselective Olefin Cyclopropanation Using Engineered Myoglobin‐Based Catalysts
inferredcites →https://doi.org/10.1002/anie.201508817openalex-snapshot
Myoglobin‐Catalyzed Olefination of Aldehydes
inferredcites →https://doi.org/10.1002/anie.201607278openalex-snapshot
Biocatalytic Synthesis of Allylic and Allenyl Sulfides through a Myoglobin‐Catalyzed Doyle–Kirmse Reaction
inferredcites →https://doi.org/10.1002/anie.201705317openalex-snapshot
Copper‐Catalyzed Enantio‐, Diastereo‐, and Regioselective [2,3]‐Rearrangements of Iodonium Ylides
inferredcites →https://doi.org/10.1002/anie.201707092openalex-snapshot
Enantioselective [2,3]‐Sigmatropic Rearrangements: Metal‐Bound or Free Ylides as Reaction Intermediates?
inferredcites →https://doi.org/10.1002/anie.201811991openalex-snapshot
Blue‐Light‐Induced Carbene‐Transfer Reactions of Diazoalkanes
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Stereogenic‐Only‐at‐Metal Asymmetric Catalysts
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Über Umlagerung von Phenol‐allyläthern in C‐Allyl‐phenole
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Umsetzung von Allylhalogeniden mit Diazomethan unter Kupfersalz‐Katalyse
inferredcites →https://doi.org/10.1002/cber.19681010333openalex-snapshot
Reaktionen des Diazomethans mit Diallylsulfid und Allyläthern unter Kupfersalz‐Katalyse
inferredcites →https://doi.org/10.1002/chem.200701885openalex-snapshot
Iron(III) Corroles and Porphyrins as Superior Catalysts for the Reactions of Diazoacetates with Nitrogen‐ or Sulfur‐Containing Nucleophilic Substrates: Synthetic Uses and Mechanistic Insights
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Trapping Reactive Metal–Carbene Complexes by a Bis‐Pocket Porphyrin: X‐ray Crystal Structures of RuCHCO 2 Et and trans ‐[Ru(CHR)(CO)] Species and Highly Selective Carbenoid Transfer Reactions
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Unifying Metal and Brønsted Acid Catalysis—Concepts, Mechanisms, and Classifications
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Photochemical, Metal‐Free Sigmatropic Rearrangement Reactions of Sulfur Ylides
inferredcites →https://doi.org/10.1002/cjoc.20030210732openalex-snapshot
Catalytic Asymmetric [2, 3]‐Sigmatropic Rearrangement of Sulfur Ylides Generated from Carbenoids and Allenic 2‐Methylphenyl Sulfide
inferredcites →https://doi.org/10.1002/tcr.201500009openalex-snapshot
Recent Advances in the Base‐Induced Sommelet–Hauser Rearrangement of Amino Acid Derived Ammonium Ylides
inferredcites →https://doi.org/10.1007/128_047openalex-snapshot
[2,3]Sigmatropic Rearrangements of Propargylic and Allenic Systems
inferredcites →https://doi.org/10.1007/128_2006_103openalex-snapshot
[2,3]-Sigmatropic Rearrangements of Allylic Sulfur Compounds
inferredcites →https://doi.org/10.1007/s41061-018-0193-4openalex-snapshot
Sulfur-Based Ylides in Transition-Metal-Catalysed Processes
inferredcites →https://doi.org/10.1016/0040-4020(60)85008-9openalex-snapshot
Stereo-selectivity in the reaction of carbomethoxycarbene with cis-butene
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Catalytic [2,3]-sigmatropic rearrangement of sulfur ylide derived from metal carbene
inferredcites →https://doi.org/10.1016/j.copbio.2017.06.005openalex-snapshot
Exploiting and engineering hemoproteins for abiological carbene and nitrene transfer reactions
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Cross-coupling reactions catalysed by palladium pincer complexes. A review of recent advances
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Catalysis of the Claisen rearrangement
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Intramolecular generation and rearrangement of oxonium ylides: methodology studies and their application in synthesis
inferredcites →https://doi.org/10.1016/j.tet.2016.11.045openalex-snapshot
Transition metal-catalyzed [2,3]-sigmatropic rearrangements of ylides: An update of the most recent advances
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Sulfonium ylide formation and subsequent C S bond cleavage of aromatic isopropyl sulfide catalyzed by hemin in aqueous solvent
inferredcites →https://doi.org/10.1016/s0021-9258(19)85701-0openalex-snapshot
3-Trifluoromethyl-3-phenyldiazirine. A new carbene generating group for photolabeling reagents.
inferredcites →https://doi.org/10.1016/s0040-4039(97)00639-4openalex-snapshot
Co(III)-salen catalyzed carbenoid reaction: Stereoselective [2,3]sigmatropic rearrangement of S-ylides derived from allyl aryl sulfides
inferredcites →https://doi.org/10.1021/acs.accounts.6b00586openalex-snapshot
Steering Asymmetric Lewis Acid Catalysis Exclusively with Octahedral Metal-Centered Chirality
inferredcites →https://doi.org/10.1021/acs.joc.9b01753openalex-snapshot
Visible Light Induced Metal-Free Carbene N -Carbazolation
inferredcites →https://doi.org/10.1021/acs.joc.9b02605openalex-snapshot
Metal-Free Insertion Reactions of Silanes with Aryldiazoacetates
inferredcites →https://doi.org/10.1021/acs.orglett.6b03836openalex-snapshot
Gold-Catalyzed [2,3]-Sigmatropic Rearrangement: Reaction of Aryl Allyl Alcohols with Diazo Compounds
inferredcites →https://doi.org/10.1021/acs.orglett.7b02139openalex-snapshot
Trifluoromethylthiolation-Based Bifunctionalization of Diazocarbonyl Compounds by Rhodium Catalysis
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Mechanisms of Rh-Catalyzed Oxyaminofluorination and Oxyaminotrifluoromethylthiolation of Diazocarbonyl Compounds with Electrophilic Reagents
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gem-Difluoroallylation of Aryl Diazoesters via Catalyst-Free, Blue-Light-Mediated Formal Doyle–Kirmse Reaction
inferredcites →https://doi.org/10.1021/acs.orglett.9b01092openalex-snapshot
Rhodium-Catalyzed Carbene Transfer Reactions for Sigmatropic Rearrangement Reactions of Selenium Ylides
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Norcaradiene Synthesis via Visible-Light-Mediated Cyclopropanation Reactions of Arenes
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Photochemical Doyle–Kirmse Reaction: A Route to Allenes
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Enantioselective Synthesis of Fluoroalkyl-Substituted syn-Diamines by the Asymmetric gem-Difunctionalization of 2,2,2-Trifluorodiazoethane
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Catalytic Stereoselective [2,3]-Rearrangement Reactions
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Rhodium-Catalyzed Oxy-Aminofluorination of Diazoketones with Tetrahydrofurans and N -Fluorobenzenesulfonimide
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Novel Multicomponent Reactions via Trapping of Protic Onium Ylides with Electrophiles
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Conservation of orbital symmetry
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Ylide formation from the reaction of carbenes and carbenoids with heteroatom lone pairs
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[2,3]-Wittig sigmatropic rearrangements in organic synthesis
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Claisen Rearrangement over the Past Nine Decades
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Small-Molecule H-Bond Donors in Asymmetric Catalysis
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Catalytic C–C Bond-Forming Multi-Component Cascade or Domino Reactions: Pushing the Boundaries of Complexity in Asymmetric Organocatalysis
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Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates
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The Claisen Rearrangement.
inferredcites →https://doi.org/10.1021/cr960411ropenalex-snapshot
Asymmetric Ylide Reactions: Epoxidation, Cyclopropanation, Aziridination, Olefination, and Rearrangement
inferredcites →https://doi.org/10.1021/ed079p572openalex-snapshot
The Nobel Prize in Chemistry for 2001
inferredcites →https://doi.org/10.1021/ja00148a005openalex-snapshot
.alpha.-Diazo Ketones as Photochemical DNA Cleavers: A Mimic for the Radical Generating System of Neocarzinostatin Chromophore
inferredcites →https://doi.org/10.1021/ja01531a008openalex-snapshot
Photochemical Experiments in Rigid Media at Low Temperatures. II. The Reactions of Methylene, Cyclopentadienylene and Diphenylmethylene
inferredcites →https://doi.org/10.1021/ja043768iopenalex-snapshot
Asymmetric [2,3]-Rearrangement of Glycine-Derived Allyl Ammonium Ylids
inferredcites →https://doi.org/10.1021/ja055021dopenalex-snapshot
Highly Stereoselective [2,3]-Sigmatropic Rearrangement of Sulfur Ylide Generated through Cu(I) Carbene and Sulfides
inferredcites →https://doi.org/10.1021/ja303023nopenalex-snapshot
Highly Stereoselective C–C Bond Formation by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement between Donor/Acceptor Carbenoids and Chiral Allylic Alcohols
inferredcites →https://doi.org/10.1021/ja3061529openalex-snapshot
Scope and Mechanistic Analysis of the Enantioselective Synthesis of Allenes by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement between Donor/Acceptor Carbenoids and Propargylic Alcohols
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Dynamics and a Unified Understanding of Competitive [2,3]- and [1,2]-Sigmatropic Rearrangements Based on a Study of Ammonium Ylides
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Cooperative Catalysis with Chiral Brønsted Acid-Rh 2 (OAc) 4 : Highly Enantioselective Three-Component Reactions of Diazo Compounds with Alcohols and Imines
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Ultrafast UV−Vis and IR Studies of p-Biphenylyl Acetyl and Carbomethoxy Carbenes
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Enantioselective C−C Bond Formation by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement between Donor/Acceptor Carbenoids and Allylic Alcohols
inferredcites →https://doi.org/10.1021/ja972095jopenalex-snapshot
Enantiocontrol in the Generation and Diastereoselective Reactions of Catalytically Generated Oxonium and Iodonium Ylides. Metal-Stabilized Ylides as Reaction Intermediates
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Ligand-Controlled Regiodivergence in the Copper-Catalyzed [2,3]- and [1,2]-Rearrangements of Iodonium Ylides
inferredcites →https://doi.org/10.1021/jacs.7b12486openalex-snapshot
Chiral Nickel(II) Complex Catalyzed Enantioselective Doyle–Kirmse Reaction of α-Diazo Pyrazoleamides
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Highly effective catalytic methods for ylide generation from diazo compounds. Mechanism of the rhodium- and copper-catalyzed reactions with allylic compounds
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Catalytic Asymmetric [2,3]-Sigmatropic Rearrangement of Sulfur Ylides Generated from Copper(I) Carbenoids and Allyl Sulfides
inferredcites →https://doi.org/10.1021/jo048328oopenalex-snapshot
Microwave- and Photoirradiation-Induced Staudinger Reactions of Cyclic Imines and Ketenes Generated from α-Diazoketones. A Further Investigation into the Stereochemical Process
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Ruthenium Porphyrin Catalyzed Tandem Sulfonium/Ammonium Ylide Formation and [2,3]-Sigmatropic Rearrangement. A Concise Synthesis of (±)-Platynecine
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The mechanism of the Stevens and Sommelet−Hauser Rearrangements. A Theoretical Study
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One-Carbon Ring Expansion of Azetidines via Ammonium Ylide [1,2]-Shifts: A Simple Route to Substituted Pyrrolidines
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Asymmetric Copper-Catalyzed [2,3]-Sigmatropic Rearrangements of Alkyl- and Aryl-Substituted Allyl Sulfides
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Synthesis of Novel α-Substituted and α,α-Disubstituted Amino Acids by Rearrangement of Ammonium Ylides Generated from Metal Carbenoids
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Tandem Formation and [2,3] Rearrangement of Methylene Ammonium Ylides Derived from Amines and the Simmons−Smith Reagent
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Catalytic Thia-Sommelet−Hauser Rearrangement: Application to the Synthesis of Oxindoles
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Silica-Immobilized Chiral Dirhodium(II) Catalyst for Enantioselective Carbenoid Reactions
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Stereoselective Synthesis of Highly Substituted Cyclohexanes by a Rhodium-Carbene Initiated Domino Sequence
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Catalytic asymmetric trifluoromethylthiolation via enantioselective [2,3]-sigmatropic rearrangement of sulfonium ylides
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Highly stereoselective synthesis of cyclopentanes bearing four stereocentres by a rhodium carbene-initiated domino sequence
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Bond cleavage, fragment modification and reassembly in enantioselective three-component reactions
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Enantioselective three-component aminomethylation of α-diazo ketones with alcohols and 1,3,5-triazines
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Catalytic enantioselective rearrangements and cycloadditions involving ylides from diazo compounds
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Sigmatropic rearrangements of ‘onium’ ylids
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Highly efficient [2,3]-sigmatropic rearrangement of sulfur ylide derived from Rh( ii ) carbene and sulfides in water
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[3,3]-Sigmatropic rearrangements: recent applications in the total synthesis of natural products
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Combining transition metal catalysis and organocatalysis: a broad new concept for catalysis
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Asymmetric synthesis of highly functionalized cyclopentanes by a rhodium- and scandium-catalyzed five-step domino sequence
inferredcites →https://doi.org/10.1039/c2sc00907bopenalex-snapshot
Synergistic catalysis: A powerful synthetic strategy for new reaction development
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Myoglobin-catalyzed intermolecular carbene N–H insertion with arylamine substrates
inferredcites →https://doi.org/10.1039/c5sc00080gopenalex-snapshot
Intermolecular carbene S–H insertion catalysed by engineered myoglobin-based catalysts
inferredcites →https://doi.org/10.1039/c6cc02641aopenalex-snapshot
The Rh( ii )-catalyzed formal N–S bond insertion reaction of aryldiazoacetates into N-phenyl-sulfenyl phthalimide
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Aqueous hemin catalyzed sulfonium ylide formation and subsequent [2,3]-sigmatropic rearrangements
inferredcites →https://doi.org/10.1039/c7cc02484copenalex-snapshot
Hemin-catalyzed sulfonium ylide formation and subsequently reactant-controlled chemoselective rearrangements
inferredcites →https://doi.org/10.1039/c7cc02801fopenalex-snapshot
Enabling iron catalyzed Doyle–Kirmse rearrangement reactions with in situ generated diazo compounds
inferredcites →https://doi.org/10.1039/c7qo01131hopenalex-snapshot
Copper-catalyzed carbene insertion into the sulfur–sulfur bond of benzenesulfonothioate
inferredcites →https://doi.org/10.1039/c7sc02867aopenalex-snapshot
Copper-catalyzed cyanothiolation to incorporate a sulfur-substituted quaternary carbon center
inferredcites →https://doi.org/10.1039/c8cc04609copenalex-snapshot
Blue light-promoted cross-coupling of aryldiazoacetates and diazocarbonyl compounds
inferredcites →https://doi.org/10.1039/c8cc08821gopenalex-snapshot
Dealkylative intercepted rearrangement reactions of sulfur ylides
inferredcites →https://doi.org/10.1039/c8gc02860eopenalex-snapshot
Recent advances in the Suzuki–Miyaura cross-coupling reaction using efficient catalysts in eco-friendly media
inferredcites →https://doi.org/10.1039/c8ob02703jopenalex-snapshot
Recent developments in photochemical reactions of diazo compounds
inferredcites →https://doi.org/10.1039/c8sc01165fopenalex-snapshot
Blue light-promoted photolysis of aryldiazoacetates
inferredcites →https://doi.org/10.1039/c9cc00927bopenalex-snapshot
Visible light mediated, metal-free carbene transfer reactions of diazoalkanes with propargylic alcohols
inferredcites →https://doi.org/10.1039/c9cc03809dopenalex-snapshot
Solvent-dependent, rhodium catalysed rearrangement reactions of sulfur ylides
inferredcites →https://doi.org/10.1039/c9cc06830aopenalex-snapshot
Rhodium catalysed synthesis of seleno-ketals via carbene transfer reactions of diazoesters
inferredcites →https://doi.org/10.1039/c9cc08888aopenalex-snapshot
Photochemical fluoro-amino etherification reactions of aryldiazoacetates with NFSI under stoichiometric conditions
inferredcites →https://doi.org/10.1039/c9sc04069bopenalex-snapshot
Photochemical ring expansion reactions: synthesis of tetrahydrofuran derivatives and mechanism studies
inferredcites →https://doi.org/10.1055/s-0034-1378393openalex-snapshot
Rearrangements of Nitrile-Stabilized Ammonium Ylides
inferredcites →https://doi.org/10.1055/s-0037-1611700openalex-snapshot
Palladium-Catalyzed C–H Bond Monofluorination of 2-Arylbenzo[d]oxazinone Using Nitrate as Crucial Promoter
inferredcites →https://doi.org/10.1055/s-0037-1611874openalex-snapshot
Sustainable Carbene Transfer Reactions with Iron and Light
inferredcites →https://doi.org/10.1070/rcr4519openalex-snapshot
Photochemical transformations of diazocarbonyl compounds: expected and novel reactions
inferredcites →https://doi.org/10.1126/science.1231434openalex-snapshot
Olefin Cyclopropanation via Carbene Transfer Catalyzed by Engineered Cytochrome P450 Enzymes
inferredcites →https://doi.org/10.2174/138527209788167231openalex-snapshot
Developments in the Photochemistry of Diazo Compounds

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Alkynyl Sulfonium Salts Can Be Employed as Chalcogen‐Bonding Catalysts and Generate Alkynyl Radicals under Blue‐Light Irradiation
inferred← citeshttps://doi.org/10.1002/ange.202216923openalex-snapshot
Copper‐Catalyzed Enantioselective Doyle–Kirmse Reaction of Azide‐Ynamides via α‐Imino Copper Carbenes
inferred← citeshttps://doi.org/10.1002/ange.202307249openalex-snapshot
Asymmetric Catalytic Ring‐Expansion of 3‐Methyleneazetidines with α‐Diazo Pyrazoamides towards Proline‐Derivatives
inferred← citeshttps://doi.org/10.1002/ange.202312793openalex-snapshot
A Carbene Relay Strategy for Cascade Insertion Reactions
inferred← citeshttps://doi.org/10.1002/ange.202400805openalex-snapshot
Stereoselective Synthesis of Polysubstituted Conjugated Dienes Enabled by Photo‐Driven Sequential Sigmatropic Rearrangement
inferred← citeshttps://doi.org/10.1002/ange.202511703openalex-snapshot
Transition Metal‐Free Formal C─H/C─H Coupling of Arylacetamides and Sulfoxides: An Interrupted Pummerer/[2,3]‐sigmatropic Rearrangement Sequence
inferred← citeshttps://doi.org/10.1002/ange.202521012openalex-snapshot
Alkinyltriazene in photochemischen metallfreien Doyle‐Kirmse‐Umlagerungen
inferred← citeshttps://doi.org/10.1002/ange.4468205openalex-snapshot
Schwefel‐gesteuerter Aufbau von Vinylcyclopropanen ausgehend von 1,3‐Dienen
inferred← citeshttps://doi.org/10.1002/ange.8959071openalex-snapshot
Migration at Boron Cage for Selective B–H Functionalization of nido ‐Carboranes
inferred← citeshttps://doi.org/10.1002/ange.9568677openalex-snapshot
Skeletal Rearrangement of Indazoles to Indoles With α‐Trifluoromethyl Diazosilanes
inferred← citeshttps://doi.org/10.1002/anie.202116071openalex-snapshot
Alkynyl Sulfonium Salts Can Be Employed as Chalcogen‐Bonding Catalysts and Generate Alkynyl Radicals under Blue‐Light Irradiation
inferred← citeshttps://doi.org/10.1002/anie.202216923openalex-snapshot
Copper‐Catalyzed Enantioselective Doyle–Kirmse Reaction of Azide‐Ynamides via α‐Imino Copper Carbenes
inferred← citeshttps://doi.org/10.1002/anie.202307249openalex-snapshot
Asymmetric Catalytic Ring‐Expansion of 3‐Methyleneazetidines with α‐Diazo Pyrazoamides towards Proline‐Derivatives
inferred← citeshttps://doi.org/10.1002/anie.202312793openalex-snapshot
A Carbene Relay Strategy for Cascade Insertion Reactions
inferred← citeshttps://doi.org/10.1002/anie.202400805openalex-snapshot
Stereoselective Synthesis of Polysubstituted Conjugated Dienes Enabled by Photo‐Driven Sequential Sigmatropic Rearrangement
inferred← citeshttps://doi.org/10.1002/anie.202511703openalex-snapshot
Transition Metal‐Free Formal C─H/C─H Coupling of Arylacetamides and Sulfoxides: An Interrupted Pummerer/[2,3]‐sigmatropic Rearrangement Sequence
inferred← citeshttps://doi.org/10.1002/anie.202521012openalex-snapshot
Alkynyltriazenes in Photochemical Metal‐Free Doyle–Kirmse Rearrangements
inferred← citeshttps://doi.org/10.1002/anie.4468205openalex-snapshot
Sulfur‐Directed Construction of Vinyl Cyclopropanes from 1,3‐Dienes
inferred← citeshttps://doi.org/10.1002/anie.8959071openalex-snapshot
Migration at Boron Cage for Selective B–H Functionalization of nido ‐Carboranes
inferred← citeshttps://doi.org/10.1002/anie.9568677openalex-snapshot
Skeletal Rearrangement of Indazoles to Indoles With α‐Trifluoromethyl Diazosilanes
inferred← citeshttps://doi.org/10.1002/aoc.7678openalex-snapshot
Mn‐Catalyzed Three‐Component Coupling Reactions of Carboxylic Acids, Diazo Compounds, and Tertiary Amines for the Synthesis of β ‐Amino Esters
inferred← citeshttps://doi.org/10.1002/chem.202102671openalex-snapshot
Alkene Synthesis by Photo‐Wolff‐Kischner Reaction of Sulfur Ylides and N ‐Tosylhydrazones
inferred← citeshttps://doi.org/10.1002/chem.202200170openalex-snapshot
Cu(I)/Chiral Bisoxazoline‐Catalyzed Enantioselective Doyle‐Kirmse Reaction of Allenyl Sulfides with α‐Diazoesters
inferred← citeshttps://doi.org/10.1002/chem.202200822openalex-snapshot
Cesium‐Fluoride‐Promoted Synthesis of Stable Organocesium Reagents and Their Ambident Reactivities with Arynes
inferred← citeshttps://doi.org/10.1002/chem.202401522openalex-snapshot
Polycyclic Pyrazolidines by Tandem Diazomalonate Dipolar Cycloadditions and CpRu‐Catalyzed Carbene Additions
inferred← citeshttps://doi.org/10.1002/cjoc.70266openalex-snapshot
Electrochemical Iodination‐Triggered Skeletal Rearrangement of Acryl Imides via Cascade Substitutions to Access α,β‐Dihydroxyl Amides
inferred← citeshttps://doi.org/10.1002/ejoc.202400712openalex-snapshot
Generation and Application of Sulfur Ylides in Light‐Mediated Transformations
inferred← citeshttps://doi.org/10.1002/ejoc.202401438openalex-snapshot
Three‐Component α‐Thienylation/Oxylation Cascade of IIII/SVI‐Ylides via Photoinduced EDA Complex Activation
inferred← citeshttps://doi.org/10.1002/ejoc.202500329openalex-snapshot
Diazo Compounds Under Visible Light: Stereoselective Synthesis of Cyclic Architectures
inferred← citeshttps://doi.org/10.1002/ejoc.70619openalex-snapshot
Rhodium‐Catalyzed Carbene Transfer to Isocyanides Using Zinc Carbenoids
inferred← citeshttps://doi.org/10.1007/7081_2023_62openalex-snapshot
Heterocycles from Onium Ylides
inferred← citeshttps://doi.org/10.1007/s43630-021-00062-6openalex-snapshot
Visible-light-promoted nitrone synthesis from nitrosoarenes under catalyst- and additive-free conditions
inferred← citeshttps://doi.org/10.1016/b978-0-323-96025-0.00029-6openalex-snapshot
Nitrogen- and Sulfur-Based Stevens and Related Rearrangements
inferred← citeshttps://doi.org/10.1016/b978-0-443-31482-7.00049-7openalex-snapshot
Electrophilic Metallo-Carbenes
inferred← citeshttps://doi.org/10.1016/j.cclet.2021.03.010openalex-snapshot
Visible light and base promoted O-H insertion/cyclization of para-quinone methides with aryl diazoacetates: An approach to 2,3-dihydrobenzofuran derivatives
inferred← citeshttps://doi.org/10.1016/j.cclet.2021.10.066openalex-snapshot
Facile synthesis of (β-chlorodifluoroethyl)phosphonates via chlorination reaction of difluoroalkyl diazo derivatives with HCl
inferred← citeshttps://doi.org/10.1016/j.chempr.2023.02.017openalex-snapshot
Catalytic enantioselective synthesis of chiral sulfonium ylides with S-stereogenic center
inferred← citeshttps://doi.org/10.1016/j.gresc.2024.02.001openalex-snapshot
Metal-free and visible-light-mediated method enables the synthesis of olefins from ketones
inferred← citeshttps://doi.org/10.1016/j.gresc.2025.08.001openalex-snapshot
Skeletal recasting of benzo[c][1,2]dithiol-3-ones for the construction of 3-hydroxybenzo[b]thiophenes
inferred← citeshttps://doi.org/10.1016/j.inoche.2023.110792openalex-snapshot
A novel Ag3L2 coordination cage derived from a tripodal oxazoline ligand: synthesis, structure and catalysis
inferred← citeshttps://doi.org/10.1016/j.isci.2023.108605openalex-snapshot
Electro-oxidative quinylation of sulfides to sulfur ylides in batch and continuous flow
inferred← citeshttps://doi.org/10.1016/j.jcat.2024.115294openalex-snapshot
A stable Copper-Modified silica microsphere catalyst for the synthesis of N-substituted carbazoles and organosilanes
inferred← citeshttps://doi.org/10.1016/j.jinorgbio.2024.112688openalex-snapshot
Repurposing myoglobin into a carbene transferase for a [2,3]-sigmatropic Sommelet-Hauser rearrangement
inferred← citeshttps://doi.org/10.1016/j.tetlet.2021.152985openalex-snapshot
Stereoselective construction of fused cyclopropane from ynamide and its application to synthesis of small drug candidate molecules
inferred← citeshttps://doi.org/10.1016/j.tetlet.2025.155547openalex-snapshot
Synthesis and reactivity of 4-N-alkylpyridiniumyl/4-N-alkylquinoliniumyl diazoalkanes
inferred← citeshttps://doi.org/10.1021/acs.accounts.1c00075openalex-snapshot
Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations
inferred← citeshttps://doi.org/10.1021/acs.accounts.1c00664openalex-snapshot
Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds
inferred← citeshttps://doi.org/10.1021/acs.chemrev.3c00869openalex-snapshot
Visible Light-Induced Reactions of Diazo Compounds and Their Precursors
inferred← citeshttps://doi.org/10.1021/acs.joc.0c01678openalex-snapshot
Gold-Catalyzed Sigmatropic Rearrangement Reactions via Carbene Transfer Reactions
inferred← citeshttps://doi.org/10.1021/acs.joc.0c01974openalex-snapshot
Blue Light-Promoted Formal [4+1]-Annulation of Diazoacetates with o-Aminoacetophenones: Synthesis of Polysubstituted Indolines and Computational Study
inferred← citeshttps://doi.org/10.1021/acs.joc.0c02500openalex-snapshot
Visible-Light-Promoted Polysubstituted Olefins Synthesis Involving Sulfur Ylides as Carbene Trapping Reagents
inferred← citeshttps://doi.org/10.1021/acs.joc.2c01499openalex-snapshot
Visible-Light-Initiated Multicomponent Reactions of α-Diazoesters to Access Organophosphorus Compounds
inferred← citeshttps://doi.org/10.1021/acs.joc.2c02267openalex-snapshot
Visible Light-Induced Coupling Cyclization Reaction of α-Diazosulfonium Triflates with α-Oxocarboxylic Acids or Alkynes
inferred← citeshttps://doi.org/10.1021/acs.joc.2c02328openalex-snapshot
Rhodium-Catalyzed Formal C═O Bond Insertion and Sequential Acyl 1,4-N-to-O Migratory Rearrangement
inferred← citeshttps://doi.org/10.1021/acs.joc.2c03074openalex-snapshot
TfOH-Catalyzed Regioselective S–H Insertion of Cyclic Thioamide Derivatives with Diazo Compounds at Room Temperature
inferred← citeshttps://doi.org/10.1021/acs.joc.3c00735openalex-snapshot
Modulating Escape Channels of Cycloheptatrienyl Rhodium Carbenes To Form Semibullvalene
inferred← citeshttps://doi.org/10.1021/acs.joc.4c00705openalex-snapshot
Modular Synthesis of Tetrasubstituted Vinyl Sulfides via One-Pot Sequential Carbene Transfer Reaction from Thiols with α-Diazo Carbonyl Compounds
inferred← citeshttps://doi.org/10.1021/acs.joc.4c02698openalex-snapshot
Substituent-Controlled Regiodivergent Rearrangement of Gramine Ammonium Ylide
inferred← citeshttps://doi.org/10.1021/acs.joc.5c01645openalex-snapshot
Visible-Light-Induced Multifunctionalization Reaction of o -Alkenyl Aromatic Isocyanides, Sulfur Ylide, and Fluorinated Alcohols: Direct Synthesis of 3-Fluoroalkyl-Substituted Indoles
inferred← citeshttps://doi.org/10.1021/acs.joc.5c02888openalex-snapshot
Silver-Catalyzed [3 + 2] Cyclization Reaction of α-Azidovinyl Acids with RCF 2 -Imidoyl Sulfoxonium Ylides: Synthesis of Polyfluoroalkyl-Substituted 2 H -Pyrrole Derivatives
inferred← citeshttps://doi.org/10.1021/acs.organomet.1c00574openalex-snapshot
Effects of Axial Solvent Coordination to Dirhodium Complexes on the Reactivity and Selectivity in C–H Insertion Reactions: A Computational Study
inferred← citeshttps://doi.org/10.1021/acs.orglett.0c03493openalex-snapshot
Chemoselective Rearrangement Reactions of Sulfur Ylide Derived from Diazoquinones and Allyl/Propargyl Sulfides
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c01580openalex-snapshot
Copper(II) Acetate-Induced Oxidation of Hydrazones to Diazo Compounds under Flow Conditions Followed by Dirhodium-Catalyzed Enantioselective Cyclopropanation Reactions
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c01982openalex-snapshot
Borane-Catalyzed Carbazolation Reactions of Aryldiazoacetates
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c02555openalex-snapshot
Oxime Ether Synthesis through O–H Functionalization of Oximes with Diazo Esters under Blue LED Irradiation
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c03406openalex-snapshot
A Selective C–C Bond Cleavage Strategy Promoted by Visible Light
inferred← citeshttps://doi.org/10.1021/acs.orglett.1c03662openalex-snapshot
Visible-Light-Mediated Strategies to Assemble Alkyl 2-Carboxylate-2,3,3-Trisubstituted β-Lactams and 5-Alkoxy-2,2,4-Trisubstituted Furan-3(2H)-ones Using Aryldiazoacetates and Aryldiazoketones
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c01424openalex-snapshot
Rhodium-Catalyzed Enal Transfer withN-Methoxypyridazinium Salts
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c01757openalex-snapshot
Iron-Catalyzed Fluoromethylene Transfer from a Sulfonium Reagent
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c03907openalex-snapshot
Difluorocarbene-Triggered Acyl Rearrangement Reaction: A Strategy for the Direct Introduction of the gem-Difluoromethylene Group
inferred← citeshttps://doi.org/10.1021/acs.orglett.2c04218openalex-snapshot
Photoinduced Synthesis of Functionalized Oxacyclic Spirooxindoles Via Ring Expansion
inferred← citeshttps://doi.org/10.1021/acs.orglett.3c00404openalex-snapshot
Synthesis of Alkynyl Hydrazones from Unprotected Hydrazine and Their Reactivity as Diazo Precursors
inferred← citeshttps://doi.org/10.1021/acs.orglett.3c04296openalex-snapshot
Photoinduced [3+2] Cycloaddition of Alkyl–Acceptor Diazoalkanes: Diversity-Oriented Synthesis of Pyrazolines Containing a Quaternary Center
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c00545openalex-snapshot
Doyle–Kirmse Reaction on Alkynyl Hydrazone Carboxylates: Synthesis of 1,4-Allenyne and 1,5-Enyne Thioaryl Carboxylates
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c03117openalex-snapshot
The Reactivity of Acceptor-Acceptor Diazo Pyrazolones with Allyl Thioethers under Visible Light: Access to Homoallyl Sulfides, Spiropyrazolones - Pesticide Analogues and Photoflow Synthesis
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c03656openalex-snapshot
Oxy-pyridinium Ylides Mediated 1,4-Pyridyl/Aryl Translocation
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c03998openalex-snapshot
Dual Photoredox/Copper-Catalyzed Three-Component Alkylcyanation of Alkenes and 1,4-Alkylcyanation of 1,3-Enynes Employing Sulfoxonium Ylides as the Carbon Radical Precursors
inferred← citeshttps://doi.org/10.1021/acs.orglett.4c04444openalex-snapshot
Copper-Catalyzed [2,3]-Sigmatropic Rearrangement of Azide–Ynamides via Selenium Ylides
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c00825openalex-snapshot
Catalytic Asymmetric Rearrangement of Azoalkene-Derived Sulfonium Ylides via Remote Chirality Control
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c01059openalex-snapshot
Silver-Catalyzed Doyle–Kirmse Reaction of Allyl Sulfides with Vinyl Triftosylhydrazones
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c01416openalex-snapshot
Metal-Catalyzed Fluoroacetyl Carbene Transfer from Sulfonium Salts
inferred← citeshttps://doi.org/10.1021/acs.orglett.5c04395openalex-snapshot
The Ylide Dance: Base-Induced Furan Synthesis via Formal [3+2] Annulation of Phenacyl- and Alkenyl Sulfonium Salts
inferred← citeshttps://doi.org/10.1021/acs.orglett.6c01121openalex-snapshot
Metallo Protic N -Allyl Enammonium Ylide 3-Aza-Cope Rearrangement Enabled by Resonance-Assisted H-Bonding: Direct Access to Functionalized Pyrroles
inferred← citeshttps://doi.org/10.1021/acscatal.0c04768openalex-snapshot
Metal Bound or Free Ylides as Reaction Intermediates in Metal-Catalyzed [2,3]-Sigmatropic Rearrangements? It Depends
inferred← citeshttps://doi.org/10.1021/acscatal.1c05413openalex-snapshot
Tunable Aziridinium Ylide Reactivity: Noncovalent Interactions Enable Divergent Product Outcomes
inferred← citeshttps://doi.org/10.1021/acscatal.2c00638openalex-snapshot
Photoredox-Catalyzed and Copper(II) Salt-Assisted Radical Addition/Hydroxylation Reaction of Alkenes, Sulfur Ylides, and Water
inferred← citeshttps://doi.org/10.1021/acscatal.3c06173openalex-snapshot
Tunable Divergent Reactivity of Aziridinium Ylides in the Synthesis of Complex Piperidines and Azetidines
inferred← citeshttps://doi.org/10.1021/acscatal.4c03569openalex-snapshot
Rhodium(II)-Catalyzed Strain-Enabled Stereoselective Synthesis of Skipped Dienes
inferred← citeshttps://doi.org/10.1021/acscatal.5c09031openalex-snapshot
Transition-Metal Catalyzed Carbene Transformations via Ring Strain-Release Processes
inferred← citeshttps://doi.org/10.1021/acscatal.6c02636openalex-snapshot
Visible-Light-Induced Enantioselective Three-Component Reactions via Free Carbenes
inferred← citeshttps://doi.org/10.1021/acssuschemeng.1c01976openalex-snapshot
Lightening Diazo Compounds?
inferred← citeshttps://doi.org/10.1021/jacs.1c01972openalex-snapshot
A New Ligand Design Based on London Dispersion Empowers Chiral Bismuth–Rhodium Paddlewheel Catalysts
inferred← citeshttps://doi.org/10.1021/jacs.1c07074openalex-snapshot
Detection of Ylide Formation between an Alkylidenecarbene and Acetonitrile by Femtosecond Transient Absorption Spectroscopy
inferred← citeshttps://doi.org/10.1021/jacs.2c01208openalex-snapshot
Direct Observation of the Dynamics of Ylide Solvation by Hydrogen-bond Donors Using Time-Resolved Infrared Spectroscopy
inferred← citeshttps://doi.org/10.1021/jacs.3c07469openalex-snapshot
BN Analogue of Butadiyne: A Platform for Dinitrogen Release and Reduction
inferred← citeshttps://doi.org/10.1021/jacs.4c09847openalex-snapshot
In Situ Observation of Elusive Dirhodium Carbenes and Studies on the Innate Role of Carboxamidate Ligands in Dirhodium Paddlewheel Complexes: A Combined Experimental and Computational Approach
inferred← citeshttps://doi.org/10.1021/jacs.5c03567openalex-snapshot
Dirhodium Complexes Heterochiral-at-the-Metal Centers: An Alternative Type of Paddlewheel Catalyst for Asymmetric Synthesis
inferred← citeshttps://doi.org/10.1021/jacs.6c02960openalex-snapshot
Enzyme-Catalyzed Stereoselective C(sp3)–S Bond Formation via a Dichotomic Carbene Transfer Mechanism
inferred← citeshttps://doi.org/10.1021/jacs.6c04476openalex-snapshot
The Catalytic Enantioselective Sommelet–Hauser Rearrangement
inferred← citeshttps://doi.org/10.1021/jacs.6c13015openalex-snapshot
Total Synthesis and Structural Confirmation of Curcusone I
inferred← citeshttps://doi.org/10.1021/jacsau.4c00970openalex-snapshot
Photoinduced C–Cl Bond Activation of Polychloroalkanes with Triplet Carbenes: Synthetic Applications and Mechanistic Studies
inferred← citeshttps://doi.org/10.1021/jacsau.4c01045openalex-snapshot
Machine-Learning-Aided Engineering Hemoglobin as Carbene Transferase for Catalyzing Enantioselective Olefin Cyclopropanation
inferred← citeshttps://doi.org/10.1038/s41467-021-24716-2openalex-snapshot
Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation
inferred← citeshttps://doi.org/10.1038/s41467-021-27167-xopenalex-snapshot
Modular and stereoselective synthesis of tetrasubstituted vinyl sulfides leading to a library of AIEgens
inferred← citeshttps://doi.org/10.1038/s41467-025-56445-1openalex-snapshot
Fe(OTf)3 or Photosensitizer-free blue light activated diazo-thioglycoside donors for Iterative and stereoselective glycosylations
inferred← citeshttps://doi.org/10.1038/s41467-025-59328-7openalex-snapshot
Ligand-controlled divergent asymmetric C(sp3)−H and C(sp3)−O insertion via vinyl cations
inferred← citeshttps://doi.org/10.1038/s41467-025-60805-2openalex-snapshot
[2,3]-Sigmatropic rearrangement with [1.1.1]propellane
inferred← citeshttps://doi.org/10.1039/d1cc06041dopenalex-snapshot
Rhodium-catalyzed denitrogenative gem -difunctionalization of pyridotriazoles with thioesters: formal carbene insertion into C(O)–S bonds
inferred← citeshttps://doi.org/10.1039/d1cc06521aopenalex-snapshot
Unlocking novel reaction pathways of diazoalkanes with visible light
inferred← citeshttps://doi.org/10.1039/d1cs00305dopenalex-snapshot
Transition metal-catalysed carbene- and nitrene transfer to carbon monoxide and isocyanides
inferred← citeshttps://doi.org/10.1039/d1nj01678dopenalex-snapshot
Recent quinone diazide based transformations via metal–carbene formation
inferred← citeshttps://doi.org/10.1039/d1ob01129dopenalex-snapshot
Doyle–Kirmse reaction using 3,3-difluoroallyl sulfide and N -sulfonyl-1,2,3-triazole: an efficient access to gem -difluoroallylated multifunctional quaternary carbon
inferred← citeshttps://doi.org/10.1039/d1qo00920fopenalex-snapshot
Rationalization of the mechanism and chemoselectivity of versatile Au-catalyzed reactions of diazoesters with allyl-functionalized sulfides, selenides, amines, or ethers by DFT
inferred← citeshttps://doi.org/10.1039/d1qo01102bopenalex-snapshot
Synthesis of trisubstituted hydroxylamines by a visible light-promoted multicomponent reaction
inferred← citeshttps://doi.org/10.1039/d1sc00495fopenalex-snapshot
Rhodium-catalyzed cascade reactions of triazoles with organoselenium compounds – a combined experimental and mechanistic study
inferred← citeshttps://doi.org/10.1039/d2gc00903jopenalex-snapshot
Visible-light-driven multicomponent reactions to access S -alkyl phosphorothioates using elemental sulfur as the sulfur source
inferred← citeshttps://doi.org/10.1039/d2ob00218copenalex-snapshot
Catalytic rearrangements of onium ylides in aromatic systems
inferred← citeshttps://doi.org/10.1039/d2ob01679fopenalex-snapshot
A copper-catalyzed three-component reaction of dithioacetals with diazo ketones and ketimines
inferred← citeshttps://doi.org/10.1039/d2qo00311bopenalex-snapshot
Metal-free visible-light-induced multi-component reactions of α-diazoesters leading to S -alkyl dithiocarbamates
inferred← citeshttps://doi.org/10.1039/d2qo01647hopenalex-snapshot
Copper-catalyzed dearomative 1,4-carboxylate rearrangement of 2-carbonateindoles
inferred← citeshttps://doi.org/10.1039/d2sc00721eopenalex-snapshot
Organometallic catalysis in aqueous and biological environments: harnessing the power of metal carbenes
inferred← citeshttps://doi.org/10.1039/d2sc03806dopenalex-snapshot
Recent advances in metal-catalysed asymmetric sigmatropic rearrangements
inferred← citeshttps://doi.org/10.1039/d2sc04720aopenalex-snapshot
Photochemical synthesis of 1,2,4-triazoles via addition reaction of triplet intermediates to diazoalkanes and azomethine ylide intermediates
inferred← citeshttps://doi.org/10.1039/d2sc06152jopenalex-snapshot
Copper-catalyzed enantioselective diyne cyclization via C(sp 2 )–O bond cleavage
inferred← citeshttps://doi.org/10.1039/d3cc00160aopenalex-snapshot
Catalytic [2,3]-sigmatropic rearrangement of sulfonium ylides derived from azoalkenes: non-carbenoid Doyle–Kirmse reaction
inferred← citeshttps://doi.org/10.1039/d3cc00988bopenalex-snapshot
Visible light-mediated photolysis of organic molecules: the case study of diazo compounds
inferred← citeshttps://doi.org/10.1039/d3cc04137aopenalex-snapshot
Insights into the multifaceted applications of vinyl sulfoxonium ylides
inferred← citeshttps://doi.org/10.1039/d3cs01129aopenalex-snapshot
Visible photons as ideal reagents for the activation of coloured organic compounds
inferred← citeshttps://doi.org/10.1039/d3ob00971hopenalex-snapshot
Rhodium( ii )-catalyzed synthesis of 2-aminoquinoline derivatives from 2-quinolones and N -sulfonyl-1,2,3-triazoles
inferred← citeshttps://doi.org/10.1039/d3qo01607bopenalex-snapshot
Transition-metal catalyzed reactions of diazo compounds and N , N -dialkylnitrosoamines
inferred← citeshttps://doi.org/10.1039/d3sc04749kopenalex-snapshot
A highly diastereoselective strain-release Doyle–Kirmse reaction: access to functionalized difluoro(methylene)cyclopropanes
inferred← citeshttps://doi.org/10.1039/d4cc03272aopenalex-snapshot
Metal-free visible-light-mediated aerobic nitrooxylation for the synthesis of nitrate esters with t -BuONO
inferred← citeshttps://doi.org/10.1039/d4cc06346eopenalex-snapshot
Rhodium/selenium dual catalysis for accessing 2-aminopyrroles from N -sulfonyl-1,2,3-triazoles
inferred← citeshttps://doi.org/10.1039/d4gc05690fopenalex-snapshot
Visible-light-induced oxytrifluoromethylthiolation of α-diazo esters
inferred← citeshttps://doi.org/10.1039/d4qo00652fopenalex-snapshot
A visible light-induced photoredox-catalyzed assembly-point di/trifunctionalization of diazomethyl radicals
inferred← citeshttps://doi.org/10.1039/d4qo01103aopenalex-snapshot
Rhodium-catalyzed 1,4-hydroxyl migration of alkenyl alcohols
inferred← citeshttps://doi.org/10.1039/d5cc04404aopenalex-snapshot
Heme-based catalysis for sustainable carbene transfer chemistry: computational mechanistic investigations
inferred← citeshttps://doi.org/10.1039/d5cc06578jopenalex-snapshot
Construction of oxindole spiro medium-sized S-heterocycles via ring expansion [2,3]-sigmatropic rearrangement
inferred← citeshttps://doi.org/10.1039/d5cc07429kopenalex-snapshot
Diazo compounds: beyond carbenes as radical precursors in light-driven organic transformations
inferred← citeshttps://doi.org/10.1039/d5nj04942copenalex-snapshot
A visible light-promoted C–H insertion reaction of diazoamides with 1,3-diketones
inferred← citeshttps://doi.org/10.1039/d5ob00087dopenalex-snapshot
Cascade reaction of α-aryl vinyl and propargyl sulfonium salts with carbon nucleophiles: synthesis of functionalized benzyl and homoallyl thioethers
inferred← citeshttps://doi.org/10.1039/d5qo00012bopenalex-snapshot
Silver-catalyzed tandem cyclization of sulfur ylides with terminal alkynes: direct synthesis of vinylcyclopropanes
inferred← citeshttps://doi.org/10.1039/d5qo00663eopenalex-snapshot
Acrolein triftosylhydrazone: a versatile vinylcarbene reagent
inferred← citeshttps://doi.org/10.1039/d5qo01266jopenalex-snapshot
New mode of sulfur ylides reactivity: stereoelectronic control provides C–C bond insertion before cyclopropanation/epoxidation directly affording homologated three-membered rings
inferred← citeshttps://doi.org/10.1039/d6dt01202gopenalex-snapshot
Strategic ligand design for modulating axial sites in dirhodium catalysts: towards enhanced asymmetric cyclopropanation
inferred← citeshttps://doi.org/10.1039/d6qo00454gopenalex-snapshot
A visible-light-induced, N-heterocyclic carbene-catalyzed four-component reaction of aroyl fluorides, diazo esters, cyclic ethers, and H 2 O
inferred← citeshttps://doi.org/10.1039/d6ra06430bopenalex-snapshot
Sigmatropic rearrangements of ynamides in stereoselective synthesis of complex molecular architectures: a comprehensive review
inferred← citeshttps://doi.org/10.1055/a-1677-5971openalex-snapshot
Alkylation Reactions with Alkylsulfonium Salts
inferred← citeshttps://doi.org/10.1055/a-1730-2540openalex-snapshot
Copper-Catalyzed Allylation of Amines with Cyclopropyldiphenylsulfonium Trifluoromethanesulfonate
inferred← citeshttps://doi.org/10.1055/a-1914-7261openalex-snapshot
Recent Advances in the Generation of Onium Ylides for Sommelet–Hauser Rearrangements
inferred← citeshttps://doi.org/10.1055/a-2119-5390openalex-snapshot
Recent Advances in the Asymmetric Doyle–Kirmse Reaction
inferred← citeshttps://doi.org/10.1055/a-2136-3609openalex-snapshot
Acetate/Alkoxide/Halide Shuttle Systems Mediated by Lewis Acid Catalysts for Insertion Reaction of a One-Carbon Unit into Carbon–Carbon or Carbon–Halogen Bonds
inferred← citeshttps://doi.org/10.1055/a-2201-7197openalex-snapshot
Photocatalytic [2,3]-Sigmatropic Rearrangement Reactions of Ethyl Diazoacetate
inferred← citeshttps://doi.org/10.1055/a-2515-0351openalex-snapshot
Doyle–Kirmse Reaction of S-Allyl and S-Propargyl Phosphorothioates
inferred← citeshttps://doi.org/10.1055/s-0040-1720451openalex-snapshot
Melding of Experiment and Theory Illuminates Mechanisms of Metal-Catalyzed Rearrangements: Computational Approaches and Caveats
inferred← citeshttps://doi.org/10.1071/ch22168openalex-snapshot
Aryl/aryl diazoalkanes in rhodium(II)-catalyzed rearrangements of sulfur ylides
inferred← citeshttps://doi.org/10.1093/bulcsj/uoaf028openalex-snapshot
Carboxylation of ammonium ylides with CO2 for the synthesis of α-amino acids: integrating experimental and computational approaches
inferred← citeshttps://doi.org/10.1360/ssc-2022-0207openalex-snapshot
Progress in N,N′-dioxide/metal complex-catalyzed asymmetricreactions of ylides
inferred← citeshttps://doi.org/10.2174/1385272826666220509143140openalex-snapshot
A Critical Review on Recent Advances in Base-Assisted Smiles Rearrangement
inferred← citeshttps://doi.org/10.26434/chemrxiv-2024-5s3ztopenalex-snapshot
Reactivity of Acceptor-Acceptor Diazo-Pyrazolones with Allyl Thioethers under Visible Light: Access to Homoallyl and Bis-Homoallyl Sulfides, Spiropyrazolones-Pesticide Analogues and Photo-Flow Synthesis
inferred← citeshttps://doi.org/10.33774/chemrxiv-2021-c6gz7openalex-snapshot
Effects of Axial Solvent Coordination to Dirhodium Complexes on Reactivity and Selectivity in C–H Insertion Reactions: A Computational Study
inferred← citeshttps://doi.org/10.33774/chemrxiv-2021-c6gz7-v2openalex-snapshot
Effects of Axial Solvent Coordination to Dirhodium Complexes on Reactivity and Selectivity in C–H Insertion Reactions: A Computational Study
inferred← citeshttps://doi.org/10.3390/molecules28020807openalex-snapshot
Reshuffle Bonds by Ball Milling: A Mechanochemical Protocol for Charge-Accelerated Aza-Claisen Rearrangements
inferred← citeshttps://doi.org/10.4274/haseki.galenos.2023.9237openalex-snapshot
Comparison of Fatigue Levels, Muscle Strength, Balance, and Exercise Performance of Young Adults with a History of Mild COVID-19 and Healthy Adults
inferred← citeshttps://doi.org/10.47749/t/unicamp.2022.1246274openalex-snapshot
Novas transformações envolvendo diazo compostos
inferred← citeshttps://doi.org/10.59429/ace.v7i2.1869openalex-snapshot
Sigmatropic rearrangements in the synthesis of heterocyclic compounds and their functionalization
inferred← citeshttps://doi.org/10.6023/cjoc202405016openalex-snapshot
Rh(III)-Catalyzed Aminoalkylation of Alkenes with Diazo Compounds toward Functionalized Isoindolinones
inferred← citeshttps://doi.org/10.70675/c8b09b07z4bc0z40ddz9e0az80e3fdc52dd3openalex-snapshot
Ingénierie de métalloenzymes pour la catalyse abiologique
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