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Anion Effects on Spin Crossover Systems: From Supramolecular Chemistry to Magnetism

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Modified Bipyridines: 5,5′-Diamino-2,2′-bipyridine Metal Complexes Assembled into Multidimensional Networks via Hydrogen Bonding and π–π Stacking Interactions
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Anion Recognition and Sensing: The State of the Art and Future Perspectives
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Supramolecular Chemistry
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Crystal Engineering: A Holistic View
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Crystallographic Evidence for Reversible Symmetry Breaking in a Spin‐Crossover d7 Cobalt(II) Coordination Polymer
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Photomagnetic Response in Highly Conductive Iron(II) Spin‐Crossover Complexes with TCNQ Radicals
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Mechanochemistry for Synthesis
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Sublimable Spin‐Crossover Complexes: From Spin‐State Switching to Molecular Devices
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Stress‐Induced Domain Wall Motion in a Ferroelastic Mn3+ Spin Crossover Complex
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Ferroelectric and Spin Crossover Behavior in a Cobalt(II) Compound Induced by Polar‐Ligand‐Substituent Motion
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A Range of Spin‐Crossover Temperature T1/2>300 K Results from Out‐of‐Sphere Anion Exchange in a Series of Ferrous Materials Based on the 4‐(4‐Imidazolylmethyl)‐2‐(2‐imidazolylmethyl)imidazole (trim) Ligand, [Fe(trim)2]X2 (X=F, Cl, Br, I): Comparison of Experimental Results with Those Derived from…
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One‐Pot Mechanosynthesis with Three Levels of Molecular Self‐Assembly: Coordination Bonds, Hydrogen Bonds and Host–Guest Inclusion
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Lattice Effects on the Spin‐Crossover Profile of a Mononuclear Manganese(III) Cation
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Triazole‐Based One‐Dimensional Spin‐Crossover Coordination Polymers
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Guest Binding Subtly Influences Spin Crossover in an Fe II 4 L 4 Capsule
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Solvatomorphism‐Induced 45 K Hysteresis Width in a Spin‐Crossover Mononuclear Compound
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The First Conducting Spin‐Crossover Compound Combining a MnIII Cation Complex with Electroactive TCNQ Demonstrating an Abrupt Spin Transition with a Hysteresis of 50 K
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Abrupt Spin‐State Switching in Mn(III) Complexes with BPh4 Anion: Effect of Halide Substituents on Crystal Structure and Magnetic Properties.
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Synthesis of Functionalized Hexadentate Iminopyridine FeII Complexes – Toward Anion‐Dependent Spin Switching in Polar Media
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Magnetic Behavior and Liquid‐Crystal Properties in Spin‐Crossover Cobalt(II) Compounds with Long Alkyl Chains
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Spin Crossover at the Nanometre Scale
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Iron(III) Spin Crossover Compounds
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Structural and magnetic properties of homoleptic iron(III) complexes containing N-(8-quinolyl)-salicylaldimine [Fe(Qsal)2]+X− {X = I or (Qsal)FeCl3}
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Anion-π interactions: From concept to application
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Pressure effect studies on spin crossover systems
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Spin crossover in metallomesogens
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Thermo-, piezo-, photo- and chemo-switchable spin crossover iron(II)-metallocyanate based coordination polymers
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Spin crossover in soft matter
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Anion coordination chemistry: From recognition to supramolecular assembly
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Anion receptor chemistry: Highlights from 2016
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Spin crossover polymer composites, polymers and related soft materials
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Spin crossover and valence tautomerism conductors
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Anion Receptor Chemistry
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Advances in Anion Receptor Chemistry
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Recent advances in self-assembly of spin crossover materials and their applications
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Surfaces, thin films and patterning of spin crossover compounds
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Hydrogen-bonded 2D network structure and abrupt spin transition with thermal hysteresis of iron(III) complexes [FeIII(Him)2(3-MeOsalen)]·H2O·EtOH·X (Him = imidazole, 3-MeOsalen =N,N′-bis(3-methoxysalicylidene)ethylenediaminato, and X = PF6, AsF6, SbF6)
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Semiconducting spin-crossover cobalt (II) compound with non-integer charge distribution among TCNQ radicals
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Four new spin-crossover salts of [Fe(3-bpp)2]2+ (3-bpp=2,6-bis[1H-pyrazol-3-yl]pyridine)
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High-spin Fe(III) Schiff based complexes with photoactive ligands. Synthesis, EPR study and magnetic properties
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Photo-induced spin transition for iron(III) compounds with – interactions
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Anion receptor chemistry: highlights from 1999
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Communication between iron(II) building blocks in cooperative spin transition phenomena
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On the spin equilibrium in bis(2,2′,2″-terpyridine) cobalt(II) salts
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Towards an unified hydrogen-bond theory
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From Molecules to Interactions to Crystal Engineering: Mechanical Properties of Organic Solids
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Structural Origin of Magnetic Hysteresis in an Iron(III) Spin-Crossover Material
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High-Temperature Spin Crossover in Fe III N 4 O 2 Complexes Incorporating an [R-sal 2 323] Backbone
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Controlling Spin Switching with Anionic Supramolecular Frameworks
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Alternative Route Triggering Multistep Spin Crossover with Hysteresis in an Iron(II) Family Mediated by Flexible Anion Ordering
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Spin Crossover in Iron(III) Quinolylsalicylaldiminates: The Curious Case of [Fe(qsal-F) 2 ](Anion)
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Spin Crossover in [Fe(2-Picolylamine)3]2+ Adjusted by Organosulfonate Anions
inferredcites →https://doi.org/10.1021/acs.inorgchem.8b02408openalex-snapshot
Pressure Sensor with a Color Change at Room Temperature Based on Spin-Crossover Behavior
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Qualitative Guest Sensing via Iron(II) Triazole Complexes
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Atomically Thin Two-Dimensional Nanosheets with Tunable Spin-Crossover Properties
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Halogen Bonds in Crystal Engineering: Like Hydrogen Bonds yet Different
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Recent Advances in Understanding the Mechanism of Cocrystal Formation via Grinding
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Electrical Conductivity Modulation Coupled to a High-Spin−Low-Spin Conversion in the Molecular System [FeIII(qsal)2][Ni(dmit)2]3·CH3CN·H2O
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Prediction of the Spin Transition Temperature in FeII One-Dimensional Coordination Polymers: an Anion Based Database
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[FeII(TRIM)2]F2, the First Example of Spin Conversion Monitored by Molecular Vibrations
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Ship-in-a-Bottle Synthesis of Otherwise Labile Cyclic Trimers of Siloxanes in a Self-Assembled Coordination Cage
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Iron(III) Spin-Crossover Compounds with a Wide Apparent Thermal Hysteresis around Room Temperature
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The nature of halogen.cntdot..cntdot..cntdot.halogen interactions: are short halogen contacts due to specific attractive forces or due to close packing of nonspherical atoms?
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Coexistence of Conducting and Magnetic Electrons Based on Molecular π-Electrons in the Supramolecular Conductor (Me-3,5-DIP)[Ni(dmit)2]2
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Evidence of the Chemical Uniaxial Strain Effect on Electrical Conductivity in the Spin-Crossover Conducting Molecular System: [FeIII(qnal)2][Pd(dmit)2]5·Acetone
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Dynamic Interplay between Spin-Crossover and Host−Guest Function in a Nanoporous Metal−Organic Framework Material
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A critical account on π–π stacking in metal complexes with aromatic nitrogen-containing ligands †
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Spin crossover phenomena in Fe(ii) complexes
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Spin transition centres linked by the nitroprusside ion. The cooperative transition in bis(2,6-bis(pyrazol-3-yl)pyridine)iron(ii) nitroprusside
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[Fe(sal2-trien)][Ni(dmit)2]: towards switchable spin crossover molecular conductors
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Iron( ii ) complexes with a terpyridine embrace packing motif show remarkably consistent cooperative spin-transitions
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Trapping and manipulating excited spin states of transition metal compounds
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Anions in crystal engineering
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Molecular spin crossover phenomenon: recent achievements and prospects
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Structure:function relationships in molecular spin-crossover complexes
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Vortex grinding for mechanochemistry: application for automated supramolecular catalysis and preparation of a metal–organic framework
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A spin crossover ferrous complex with ordered magnetic ferric anions
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Anion driven modulation of magnetic intermolecular interactions and spin crossover properties in an isomorphous series of mononuclear iron(iii) complexes with a hexadentate Schiff base ligand
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Supramolecular concepts and new techniques in mechanochemistry: cocrystals, cages, rotaxanes, open metal–organic frameworks
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A face-capped [Fe4L4]8+ spin crossover tetrahedral cage
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Spin state modulation of iron spin crossover complexes via hydrogen-bonding self-assembly
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The anion–π interaction: naissance and establishment of a peculiar supramolecular bond
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Abrupt two-step and symmetry breaking spin crossover in an iron( iii ) complex: an exceptionally wide [LS–HS] plateau
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The relationship between the strength of hydrogen bonding and spin crossover behaviour in a series of iron( iii ) Schiff base complexes
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Counter anion dependent gradual spin transition in a 1D cobalt( ii ) coordination polymer
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Structural insights into the counterion effects on the manganese( iii ) spin crossover system with hexadentate Schiff-base ligands
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Reversible quantitative guest sensing via spin crossover of an iron( ii ) triazole
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Tunable cooperativity in a spin-crossover Hoffman-like metal–organic framework material by aromatic guests
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Structural distortions of the spin-crossover material [Co(pyterpy) 2 ](TCNQ) 2 mediated by supramolecular interactions
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Hydrogen-bonded networks of [Fe(bpp) 2 ] 2+ spin crossover complexes and dicarboxylate anions: structural and photomagnetic properties
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Organic synthesis by Twin Screw Extrusion (TSE): continuous, scalable and solvent-free
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Green and rapid synthesis of zirconium metal–organic frameworks via mechanochemistry: UiO-66 analog nanocrystals obtained in one hundred seconds
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Hysteretic spin crossover driven by anion conformational change
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An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors
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Cooperative spin-crossover transition from three-dimensional purely π-stacking interactions in a neutral heteroleptic azobisphenolate Fe III complex with a N 3 O 3 coordination sphere
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The molecular and supramolecular aspects in mononuclear manganese( iii ) Schiff-base spin crossover complexes
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Mechanochemistry as an emerging tool for molecular synthesis: what can it offer?
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Unravelling the spin-state of solvated [Fe(bpp) 2 ] 2+ spin-crossover complexes: structure–function relationship
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Solvatomorphism and anion effects in predominantly low spin iron( iii ) Schiff base complexes
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Functional metal–organic frameworks as effective sensors of gases and volatile compounds
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Post-synthetic anion exchange in iron( ii ) 1,2,4-triazole based spin crossover materials via mechanochemistry
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Structure–function correlations in mononuclear manganese( iii ) spin crossover systems with a big conjugated hexadentate Schiff-base ligand
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Bistable spin-crossover in a new series of [Fe(BPP-R) 2 ] 2+ (BPP = 2,6-bis(pyrazol-1-yl)pyridine; R = CN) complexes
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Stepwise spin-state switching in a manganese( iii ) complex
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The dynamic interplay between intramolecular and intermolecular interactions in mononuclear manganese( iii ) SCO complexes
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Spin crossover phenomena in long chain alkylated complexes
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Anion-driven supramolecular modulation of spin-crossover properties in mononuclear iron( iii ) Schiff-base complexes
inferredcites →https://doi.org/10.1039/d1sc02843jopenalex-snapshot
Optimization of crystal packing in semiconducting spin-crossover materials with fractionally charged TCNQ δ − anions (0 < δ < 1)
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Five- and six-coordinated complexes of cobalt(II) with 2,2',2'-terpyridyl: Unusual structure and magnetism
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Coordination of Pyridine-Substituted Pyrazoles and Their Influence on the Spin State of Iron(II)
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Supramolecular modulation of spin crossover profile in manganese(III)
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Modified Chesnut Model for Spin-Crossover Semiconductors [Fe(acpa) 2 ](TCNQ) n
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Importance of van der Waals interactions for ab initio studies of topological insulators
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Spin-Transition Polymers: From Molecular Materials Toward Memory Devices
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First Iron(II) Spin-crossover Complex with an N5S Coordination Sphere
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Definition of the halogen bond (IUPAC Recommendations 2013)
inferredcites →https://doi.org/10.3390/cryst9020081openalex-snapshot
High-Temperature Cooperative Spin Crossover Transitions and Single-Crystal Reflection Spectra of [FeIII(qsal)2](CH3OSO3) and Related Compounds
inferredcites →https://doi.org/10.3390/magnetochemistry7050072openalex-snapshot
New Spin-Crossover Compounds Containing the [Ni(mnt)] Anion (mnt = Maleonitriledithiolate)
inferredcites →https://doi.org/10.3390/molecules25214922openalex-snapshot
Magnetism, Conductivity and Spin-Spin Interactions in Layered Hybrid Structure of Anionic Radicals [Ni(dmit)2] Alternated by Iron(III) Spin-Crossover Complex [Fe(III)(3-OMe-Sal2trien)] and Ferric Moiety Precursors
inferredcites →https://doi.org/10.3390/s120404479openalex-snapshot
Pressure and Temperature Spin Crossover Sensors with Optical Detection
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Spin state switching in iron coordination compounds

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Exploring how interactions between components determine the cooperativity and magnetic properties of mononuclear Mn(III) spin crossover complexes
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Half the Step, Twice the Mystery─Kinetically Controlled Spin Crossover in an Anticooperative Pyridine-Coordinate Jäger -Type Iron(II) Complex
inferred← citeshttps://doi.org/10.1021/acs.cgd.5c00492openalex-snapshot
T 1/2 Tuning in a Synergistic BODIPY-Tetrazole Fe(II) Spin Crossover-Photoluminescence System via Counterion Variation
inferred← citeshttps://doi.org/10.1021/acs.cgd.6c00317openalex-snapshot
Manipulating Multi-Step Spin Crossover and Symmetry Breaking via Halogen and Anion Effects in Mononuclear Fe III Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.4c01675openalex-snapshot
Observation of TLIESST above Liquid Nitrogen Temperature and Disclosure of Hidden Hysteresis in Multiresponsive Hofmann-type Coordination Polymers
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c00639openalex-snapshot
Polyoxometalate Anion-Induced On–Off Spin-Crossover Property in Two Isomeric Cobalt(II) Complexes with Proton Conductivity
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c00885openalex-snapshot
Halogen-Driven Spin Dynamics: Exploring Correlation of Cooperativity and Spin Crossover in Solid-State Mononuclear Fe(III) Schiff-Base Complexes
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c05598openalex-snapshot
Dual Modulation of Spin-Crossover Behavior in [Fe(tpma)(xbim)] 2 + Complexes by Chemical and Mechanical Pressures
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.5c05953openalex-snapshot
Stimuli-Responsive Spin-State Switching in Supramolecular Helicates Bridging Solid–Solution Bistability
inferred← citeshttps://doi.org/10.1021/acs.inorgchem.6c01161openalex-snapshot
Tuning the Magnetic Properties of Heterotrimetallic Co–M–Co (M = Ni and Pd) Chain Complexes via Redox Modulation and Metal Ion Replacement
inferred← citeshttps://doi.org/10.1021/acscatal.3c05355openalex-snapshot
Iron(I) and Iron(II) Amido-imidazolin-2-imine Complexes as Catalysts for H/D Exchange in Hydrosilanes
inferred← citeshttps://doi.org/10.1039/d3cs00688copenalex-snapshot
Spin crossover iron complexes with spin transition near room temperature based on nitrogen ligands containing aromatic rings: from molecular design to functional devices
inferred← citeshttps://doi.org/10.1039/d4cc00673aopenalex-snapshot
Cyanometallic charge engineering in spin crossover metal–organic frameworks
inferred← citeshttps://doi.org/10.1039/d4cc00812jopenalex-snapshot
Triptycene-based diiron( ii ) mesocates: spin-crossover in solution
inferred← citeshttps://doi.org/10.1039/d4dt00911hopenalex-snapshot
Unlocking room-temperature bistable spin transition at the nanoscale: the synthesis of core@shell [Fe(NH 2 trz) 3 (NO 3 ) 2 ]@SiO 2 nanoparticles
inferred← citeshttps://doi.org/10.1039/d4dt01855aopenalex-snapshot
Mix and match – controlling the functionality of spin-crossover materials through solid solutions and molecular alloys
inferred← citeshttps://doi.org/10.1039/d4dt02901aopenalex-snapshot
The hydrate of a neutral iron( iii ) complex based on the pyruvic acid thiosemicarbazone ligand with abrupt spin-crossover with T 1/2 = 340 K and a wide hysteresis loop of 45 K
inferred← citeshttps://doi.org/10.1039/d4ra06111jopenalex-snapshot
Synthesis, mixed-spin-state structure and Langmuir–Blodgett deposition of amphiphilic Fe( iii ) quinolylsalicylaldiminate complexes
inferred← citeshttps://doi.org/10.1039/d4tc02203copenalex-snapshot
Variation in the zero-point energy difference via electrostatic interactions in Co( ii )-Cltpy-based spin-crossover molecular materials
inferred← citeshttps://doi.org/10.1039/d5ce00671fopenalex-snapshot
Recent advances in spin crossover Fe( ii ) tetrahedral metal–organic cages and their solid-state applications
inferred← citeshttps://doi.org/10.1039/d5dt00841gopenalex-snapshot
Halogen bond-enhanced spin dynamics: investigating co-crystallization effects on spin crossover in mononuclear Mn( iii ) Schiff-base complexes
inferred← citeshttps://doi.org/10.1039/d6cc03350dopenalex-snapshot
Leveraging supramolecular design towards spin-state control
inferred← citeshttps://doi.org/10.1039/d6ce00068aopenalex-snapshot
Crystal engineering of p -sulfocinnamic acid into mononuclear cationic Fe( ii ), Co( ii ) and Fe( iii ) complexes
inferred← citeshttps://doi.org/10.1039/d6ce00107fopenalex-snapshot
A beginner's guide to spin crossover
inferred← citeshttps://doi.org/10.1039/d6nj02094aopenalex-snapshot
The structural polymorphism of the potassium salt of Fe( iii ) 5Cl-salicyaldehyde–thiosemicarbazone as an additional option for SCO setting
inferred← citeshttps://doi.org/10.1093/bulcsj/uoag125openalex-snapshot
Spin-crossover systems with multifunctional behavior based on intermolecular interactions
inferred← citeshttps://doi.org/10.1515/revic-2026-0022openalex-snapshot
Spin crossover Fe(III) complexes with tetradentate Schiff base ligands
inferred← citeshttps://doi.org/10.3390/nano15020090openalex-snapshot
Various Sizes and Shapes of Mixed-Anion Fe(NH2trz)3(BF4)2−x(SiF6)x/2@SiO2 Nanohybrid Particles Undergoing Spin Crossover Just Above Room Temperature
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