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Enantiomer‐Differentiation Induced by an Enantiomeric Excess during Chromatography with Achiral Phases
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
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Chiral Lanthanide Shift Reagents
inferredcites →https://doi.org/10.1002/ange.19710831307openalex-snapshot
Neuartige asymmetrische Cyclisierung zu optisch aktiven Steroid‐CD‐Teilstücken
inferredcites →https://doi.org/10.1002/ange.19710832303openalex-snapshot
Methoden der asymmetrischen Synthese – enantioselektive katalytische Hydrierung
inferredcites →https://doi.org/10.1002/ange.19820940904openalex-snapshot
Spezifikation des sterischen Verlaufs von asymmetrischen Synthesen
inferredcites →https://doi.org/10.1002/ange.19820940912openalex-snapshot
Isocyanate als universelle Reagentien bei der Derivatbildung für die gaschromatographische Enantiomerentrennung
inferredcites →https://doi.org/10.1002/ange.19840961004openalex-snapshot
Gaschromatographische Enantiomerentrennung an metallkomplexfreien Stationärphasen
inferredcites →https://doi.org/10.1002/bip.1967.360050308openalex-snapshot
Asymmetric selection in the copolymerization of N‐carboxy‐ L ‐ and D ‐alanine anhydride
inferredcites →https://doi.org/10.1002/bip.1976.360151015openalex-snapshot
Étude expérimentale de l'auto‐association des molécules modèles dipeptidiques. II. Association stéréosélective des molécules énantiomères
inferredcites →https://doi.org/10.1002/bscb.19770860805openalex-snapshot
On the Classification of Pairwise Relations Between Isomeric Structures
inferredcites →https://doi.org/10.1002/cber.19821150432openalex-snapshot
Liquid chromatography on triacetylcellulose, 4. Determination of enantiomeric purity in spite of incomplete chromatographic separation
inferredcites →https://doi.org/10.1002/hlca.19560390316openalex-snapshot
Reaktionen mit Mikroorganismen. 1. Mitteilung. Die stereospezifische Reduktion von (±)‐Δ4‐9‐Methyl‐octalindion‐(3,8)
inferredcites →https://doi.org/10.1002/hlca.19820650143openalex-snapshot
The Stereochemical Outcomes – the Isoborneol/Borneol Ratios – in Lithium, Sodium and Potassium/Ammonia Reductions without a Proton Source of the Enantiomers and the Racemate of Camphor Differ Strongly
inferredcites →https://doi.org/10.1002/ijch.197600002openalex-snapshot
An Epistemological Note on Chirality
inferredcites →https://doi.org/10.1002/macp.1965.020850124openalex-snapshot
Asymmetric selection in the copolymerization of N‐carboxy‐ L ‐ and ‐ D ‐alanine anhydride
inferredcites →https://doi.org/10.1002/polc.5070230227openalex-snapshot
Stereoregulation in N‐carboxy anhydride polymerization
inferredcites →https://doi.org/10.1007/bf00928403openalex-snapshot
Experiments of the amplification of optical activity
inferredcites →https://doi.org/10.1007/bfb0046191openalex-snapshot
Discriminating interactions between chiral molecules
inferredcites →https://doi.org/10.1016/0040-4020(76)80131-7openalex-snapshot
Enantiomeric recognition and interactions
inferredcites →https://doi.org/10.1016/0040-4020(76)85164-2openalex-snapshot
An NMR study of optical isomers in solution
inferredcites →https://doi.org/10.1016/0040-4020(77)80097-5openalex-snapshot
Enantioselective effects in the association behaviour of optically active alcohols
inferredcites →https://doi.org/10.1016/b978-0-12-377850-5.50007-6openalex-snapshot
Nomenclature for Stereo-Differentiating Reactions
inferredcites →https://doi.org/10.1016/b978-0-12-507701-9.50011-5openalex-snapshot
Separation of Enantiomers by Liquid Chromatographic Methods
inferredcites →https://doi.org/10.1016/s0021-9673(01)87863-8openalex-snapshot
Unexpected pehnomenon in the high-performance liquid chromatographic anlaysis of racemic 14C-labelled nicotine: Separation of enantiomers in a totally achiral system
inferredcites →https://doi.org/10.1016/s0021-9673(01)92750-5openalex-snapshot
Self-amplification of optical activity by chromatography on an achiral adsorbent
inferredcites →https://doi.org/10.1016/s0040-4020(01)96602-5openalex-snapshot
Diastereoisomeric interactions and selective reactions in solutions of enantiomers
inferredcites →https://doi.org/10.1016/s0040-4020(01)97323-5openalex-snapshot
Interactions diastereoisomeres d'antipodes en phase liquide
inferredcites →https://doi.org/10.1016/s0040-4020(01)97710-5openalex-snapshot
Stereoselective hydrolysis of leucine oligomers
inferredcites →https://doi.org/10.1016/s0040-4039(01)81836-0openalex-snapshot
Selective reactions of enantiomeric-mixtures
inferredcites →https://doi.org/10.1016/s0040-4039(01)88364-7openalex-snapshot
Interactions d'enantiomeres en solution ; influence sur le pouvoir rotatoire : Purete optique et purete enantiomerique.
inferredcites →https://doi.org/10.1021/cen-v055n003.p034-bopenalex-snapshot
Asymmetric Organic Reactions
inferredcites →https://doi.org/10.1021/ja00344a003openalex-snapshot
La coupe du roi and its relevance to stereochemistry. Combination of two homochiral molecules to give an achiral product
inferredcites →https://doi.org/10.1021/ja00356a019openalex-snapshot
Mechanism of coupling of methylidene to ethylene at a homogeneous (triphenylphosphine)nitrosyl(.eta.-cyclopentadienyl)rhenium(+) [(.eta.-C5H5)Re(NO)(PPh3)]+ center. Remarkable enantiomer self-recognition
inferredcites →https://doi.org/10.1021/ja00357a047openalex-snapshot
Hydrogen bonding in optically active and racemic 2-butanol
inferredcites →https://doi.org/10.1021/ja00527a015openalex-snapshot
Aqueous lanthanide shift reagents. 8. Chiral interactions and stereochemical assignments of chemically and isotopically chiral ligands
inferredcites →https://doi.org/10.1021/ja01035a060openalex-snapshot
Diastereomeric solute-solute interactions of enantiomers in achiral solvents. Nonequivalence of the nuclear magnetic resonance spectra of racemic and optically active dihydroquinine
inferredcites →https://doi.org/10.1021/jo00427a033openalex-snapshot
Enhancement of optical activity by fractional sublimation. An alternative to fractional crystallization and a warning
inferredcites →https://doi.org/10.1021/jo00925a003openalex-snapshot
Asymmetric synthesis of bicyclic intermediates of natural product chemistry
inferredcites →https://doi.org/10.1021/jo01281a037openalex-snapshot
Separation of an enantiomorph and its racemate by sublimation
inferredcites →https://doi.org/10.1038/180513a0openalex-snapshot
Late-glacial Finds of Lepidurus arcticus (Pallas) in the British Isles
inferredcites →https://doi.org/10.1038/182198b0openalex-snapshot
Motion of the Nodal Line of the Second Russian Earth Satellite (1957β) and Flattening of the Earth
inferredcites →https://doi.org/10.1051/jcp/1977740129openalex-snapshot
Étude expérimentale de l’auto-association des molécules modèles dipeptidiques
inferredcites →https://doi.org/10.1070/rc1978v047n09abeh002277openalex-snapshot
Optical Isomers in Solution Investigated by Nuclear Magnetic Resonance
inferredcites →https://doi.org/10.1248/yakushi1947.95.1_33openalex-snapshot
Stereochemical Studies. XXXII. Asymmetric Synthesis of Intermediates for the Total Synthesis of Steroids and Terpenes with L-Proline Enamine Method
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Enantiomeric enrichment of non-racemic mixtures of binaphthol with non-chiral packings
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Nichtlineare Effekte bei asymmetrischen Synthesen und stereoselektiven Reaktionen
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TADDOLe, ihre Derivate und Analoga – vielseitige chirale Hilfsstoffe
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TADDOLs, Their Derivatives, and TADDOL Analogues: Versatile Chiral Auxiliaries
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Separation of Enantiomers by Gas Chromatography on Chiral Stationary Phases
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Die chromatographische Abtrennung des überschüssigen Enantiomers unter achiralen Bedingungen
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Enantioselektive Addition von Organometallreagentien an Carbonylverbindungen: Übertragung, Vervielfältigung und Verstärkung der Chiralität
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Enantioselektive Protonierung eines einfachen Enols: Aminoalkohol‐katalysierte Ketonbildung aus dem photochemisch erzeugten 2‐Methylinden‐3‐ol
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Remarkable Amplification of the Self‐Disproportionation of Enantiomers on Achiral‐Phase Chromatography Columns
inferred← citeshttps://doi.org/10.1002/ange.201504589openalex-snapshot
An Enantioselective Synthesis of Spirobilactams through Copper‐Catalyzed Intramolecular Double N‐Arylation and Phase Separation
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Chromatographic Separation of the Excess Enantiomer under Achiral Conditions
inferred← citeshttps://doi.org/10.1002/anie.199100491openalex-snapshot
Enantioselective Addition of Organometallic Reagents to Carbonyl Compounds: Chirality Transfer, Multiplication, and Amplification
inferred← citeshttps://doi.org/10.1002/anie.199104161openalex-snapshot
Enantioselective Protonation of a Simple Enol: Aminoalcohol‐Catalyzed Ketonization of a Photochemically Produced 2‐Methylinden‐3‐ol
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Remarkable Amplification of the Self‐Disproportionation of Enantiomers on Achiral‐Phase Chromatography Columns
inferred← citeshttps://doi.org/10.1002/anie.201504589openalex-snapshot
An Enantioselective Synthesis of Spirobilactams through Copper‐Catalyzed Intramolecular Double N‐Arylation and Phase Separation
inferred← citeshttps://doi.org/10.1002/asia.201101029openalex-snapshot
Formal Synthesis of (−)‐Cephalotaxine Based on a Tandem Hydroamination/Semipinacol Rearrangement Reaction
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Electrophilic Thiocyanation of Tryptamine Derivatives: Divergent Synthesis of SCN‐Containing Indole Compounds
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Enantiorecognition on solid chiral selectors using microbatch technology: an example of limitation in case of strong association in the racemate
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Possible Case of Halogen Bond‐Driven Self‐Disproportionation of Enantiomers (SDE) via Achiral Chromatography
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Rhodium‐Catalyzed Enantioselective Synthesis of Highly Fluorescent and CPL‐Active Dispiroindeno[2,1‐c]fluorenes
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ChemInform Abstract: Enantiomer‐Differentiation Induced by an Enantiomeric Excess During Chromatography with Achiral Phases
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Contributions to the theory and practice of the chromatographic separation of enantiomers
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Single Enantiomer Versus Racemate: Chiral Distinction in the Proton Pump Inhibitors Omeprazole and Esomeprazole
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Experimental studies of competition between enantiomers in chiral liquid chromatography through their system peaks
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The self‐disproportionation of enantiomers (SDE): The effect of scaling down, potential problems versus prospective applications, possible new occurrences, and unrealized opportunities?
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Nucleophilic additions to N‐glycosylnitrones part IV Asymmetric synthesis of N‐hydroxy‐α‐aminophosphonic and α‐aminophosphonic acids
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Semicorrin metal complexes as enantioselective catalysts. Part 2. Enantioselective cyclopropane formation from olefins with diazo compounds catalyzed by chiral (semicorrinato)copper complexes
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Diastereoface Selectivity During Pthalimidonitrene Additions to (E)‐and (Z)‐configurated α, β‐unsaturated esters, induced by a chiral center in the γ‐position
inferred← citeshttps://doi.org/10.1002/hlca.200490172openalex-snapshot
Determination of the Dimerization Equilibrium Constants of Omeprazole and Pirkle's Alcohol through Optical‐Rotation Measurements
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Purification of Enantiomeric Mixtures in Enantioselective Synthesis: Overlooked Errors and Scientific Basis of Separation in Achiral Environment
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Enantiomeric Enrichments via the Self‐Disproportionation of Enantiomers (SDE) by Achiral, Gravity‐Driven Column Chromatography: a Case Study Using N‐(1‐Phenylethyl)acetamide for Optimizing the Enantiomerically Pure Yield and Magnitude of the SDE
inferred← citeshttps://doi.org/10.1002/ijch.201600015openalex-snapshot
On the Centenary of Emanuel Gil‐Av, Former Professor of the Weizmann Institute of Science and Pioneer of Enantioselective Chromatography
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Self‐disproportionation of Enantiomers (SDE) of Chiral Nonracemic Amides via Achiral Chromatography
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Enantioseparations in Achiral Environments and Chromatographic Systems
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Enantioselective Syntheses of Substituted γ‐Butyrolactones
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HPLC‐Trennung verschiedener α‐substituierter γ‐Lactone und 1,3‐Dioxolan‐4‐one an ChiraSpher
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On the preparation of β‐amino acids from α‐amino acids using the Arndt‐Eistert reaction: Scope, limitations and stereoselectivity. Application to carbohydrate peptidation. Stereoselective α‐alkylations of some β‐amino acids
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Self and nonself recognition of chiral catalysts: The origin of nonlinear effects in the amino‐alcohol catalyzed asymmetric addition of diorganozincs to aldehydes
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Self-disproportionation of Enantiomers of Enantiomerically Enriched Compounds
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Salient Features of Enantioselective Gas Chromatography: The Enantiomeric Differentiation of Chiral Inhalation Anesthetics as a Representative Methodological Case in Point
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Chiroptical Detectors for the Study of Unusual Phenomena in Chiral Chromatography
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Other direct chiral resolution methods
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Enantiomeric Analysis of 2-Phenylpropionic Acid NSAID’s in Biological Fluids by HPLC
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Pitfalls in the Enantioselective Analysis of Chiral Drugs
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The Analytical Separation of Enantiomers by Gas Chromatography on Chiral Stationary Phases
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Asymmetric Synthesis : I - Fundamentals and Recent Advances II - Some Aspects of Asymmetric Catalysis with Transition - Metal Complexes
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Other direct chiral resolution methods
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Effect of solute association on the apparent adsorption isotherm. A model of the separation of non-racemic mixtures of enantiomers in achiral chromatographic systems
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Partial separation of lactic acid enantiomers by HPLC using (S)-(+)mandelic acid as chiral mobile-phase additive
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Computer simulation of three scenarios for the separation of non-racemic mixtures by chromatography on achiral stationary phases
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Enantiomer separation by gas chromatography on chiral stationary phases
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Resolution of non-racemic mixtures in achiral chromatographic systems: A model for, the enantioselective effects observed
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Enantiomeric enrichment of partially resolved 4-hydroxy-2-carboxymethylcyclopentanone de derivatives by achiral phase chromatography
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Practical Aspects of Asymmetric Synthesis
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Fluorine-Containing Pharmaceuticals and the Phenomenon of the Self-Disproportionation of Enantiomers
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Racemates: Properties and methods of resolution
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General model for the achiral chromatography of enantiomers forming dimers: application to binaphthol
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Elaborate treatment of retention in chemoselective chromatography—The retention increment approach and non-linear effects
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Separation of non-racemic mixtures of enantiomers by achiral chromatography
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Altering the mobile phase composition to enhance self-disproportionation of enantiomers in achiral chromatography
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Effect of temperature on chromatographic separation driven by enantiomer self-disproportionation
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Equilibrium theory-based framework for descripting separation of enantiomers by frontal achiral chromatography
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Effect of modification of silica surface on the extent of enantiomer self-disproportionation
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Gas chromatographic enantioseparation of derivatized α-amino acids on chiral stationary phases—Past and present
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Self-disproportionation of enantiomers of (R)-ethyl 3-(3,5-dinitrobenzamido)-4,4,4-trifluorobutanoate on achiral silica gel stationary phase
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Self-disproportionation of enantiomers of heterocyclic compounds having a tertiary trifluoromethyl alcohol center on chromatography with a non-chiral system
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First catalytic enantioselective synthesis of the cocaine abuse therapeutic agent (S)-(+)-1-(4-{2-[bis(4-fluorophenyl)methoxy]ethyl}piperazin-1-yl)-2-phenyl-2-propanol
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Nonlinear effects in enantioselective chromatography: prediction of unusual elution profiles of enantiomers in non-racemic mixtures on an achiral stationary phase doped with small amounts of a chiral selector
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Rational application of self-disproportionation of enantiomers via sublimation—a novel methodological dimension for enantiomeric purifications
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A question of policy: should tests for the self-disproportionation of enantiomers (SDE) be mandatory for reports involving scalemates?
inferred← citeshttps://doi.org/10.1016/s0021-9673(00)00505-7openalex-snapshot
Separation of enantiomers by gas chromatography
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Chiroptical detection during liquid chromatography 7
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Separation of binaphthol enantiomers through achiral chromatography
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Practice and theory of enantioselective complexation gas chromatography
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Enantiomer analysis by complexation gas chromatography
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Enantioselective determination of chiral organochlorine compounds in biota by gas chromatography on modified cyclodextrins
inferred← citeshttps://doi.org/10.1016/s0021-9673(98)00339-2openalex-snapshot
Enantiomeric enrichment of non-racemic antihistamines by achiral high-performance liquid chromatography
inferred← citeshttps://doi.org/10.1016/s0040-4020(01)86998-2openalex-snapshot
Photoreactivity of α-tetrasubstituted arylketones: Production and asymmetric tautomerization of arylenols
inferred← citeshttps://doi.org/10.1016/s0040-4020(01)87689-4openalex-snapshot
Asymmetric oxidation of sulfides mediated by chiral titanium complexes : mechanistic and synthetic aspects
inferred← citeshttps://doi.org/10.1016/s0378-4347(00)82761-9openalex-snapshot
Determination of 3,4-methylenedioxyamphetamine and 3,4-methylenedioxymethamphetamine enantiomers in whole blood
inferred← citeshttps://doi.org/10.1016/s0378-4347(99)00409-0openalex-snapshot
Quantitative determination of isoflurane enantiomers in blood samples during and after surgery via headspace gas chromatography–mass spectrometry
inferred← citeshttps://doi.org/10.1016/s1460-1567(96)80024-9openalex-snapshot
Chapter 2 Analytical methods
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Self-induced chiral recognition in the association of enantiomeric mixtures on silica gel chromatography
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Crystalline Architectures as Templates of Relevance to the Origins of Homochirality
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Symmetry-Assisted Synthesis of C2-Symmetric trans-α,α‘-Bis(hydroxymethyl)pyrrolidine and -piperidine Derivatives via Double Sharpless Asymmetric Dihydroxylation of α,ω-Terminal Dienes
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Chiral recognition in dipeptides containing 1‐aminocyclopropane carboxylic acid or α‐aminoisobutyric acid: NMR studies in solution
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Enantioselective catalytic Diels–Alder reaction of ethyl 2-benzoylacrylate with chiral bis(oxazoline)– or mono(oxazoline)–magnesium complex
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A study of asymmetric protonation with chiral β-hydroxy sulfoxides. Asymmetric synthesis of (–)-epibatidine
inferred← citeshttps://doi.org/10.1039/a707196eopenalex-snapshot
Synthesis, enzymic resolution and enantiomeric enhancement of bis(hydroxymethyl)[7]thiaheterohelicenes
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The racemate cage. Influence of p1,n1 salt occurrence on enantiomer separation processes. The case of trans-chrysanthemic acid
inferred← citeshttps://doi.org/10.1039/b814905dopenalex-snapshot
NMR and molecular modeling of the dimeric self-association of the enantiomers of 1,1′-bi-2-naphthol and 1-phenyl-2,2,2-trifluoroethanol in the solution state and their relevance to enantiomer self-disproportionation on achiral-phase chromatography (ESDAC)
inferred← citeshttps://doi.org/10.1039/b917564dopenalex-snapshot
Separation of non-racemic mixtures of enantiomers: an essential part of optical resolution
inferred← citeshttps://doi.org/10.1039/c2cs35006hopenalex-snapshot
Self-disproportionation of enantiomers via achiral chromatography: a warning and an extra dimension in optical purifications
inferred← citeshttps://doi.org/10.1039/c4ob00831fopenalex-snapshot
The self-disproportionation of the enantiomers (SDE) of methyl n-pentyl sulfoxide via achiral, gravity-driven column chromatography: a case study
inferred← citeshttps://doi.org/10.1039/c4ra13928copenalex-snapshot
A comprehensive examination of the self-disproportionation of enantiomers (SDE) of chiral amides via achiral, laboratory-routine, gravity-driven column chromatography
inferred← citeshttps://doi.org/10.1039/c6cs00703aopenalex-snapshot
Chiral sulfoxides: advances in asymmetric synthesis and problems with the accurate determination of the stereochemical outcome
inferred← citeshttps://doi.org/10.1080/10826079208018806openalex-snapshot
Resolution of Enantiomers with Achiral Phase Chromatography
inferred← citeshttps://doi.org/10.1093/chromsci/bmx031openalex-snapshot
Chromatographic Enantioseparations in Achiral Environments: Myth or Truth?
inferred← citeshttps://doi.org/10.1515/9783110867855.132openalex-snapshot
3 Techniques used in the analysis of optically active compounds. 3.5 Gas chromatography
inferred← citeshttps://doi.org/10.1515/9783110867855.62openalex-snapshot
3 Techniques used in the analysis of optically active compounds. 3.3 General aspects of chromatography
inferred← citeshttps://doi.org/10.24820/ark.5550190.p009.829openalex-snapshot
Self-disproportionation of enantiomers (SDE) of chiral sulfur-containing compounds via achiral chromatography
inferred← citeshttps://doi.org/10.2533/chimia.2008.148openalex-snapshot
Studying Chemistry at the University of Zurich in the Sixties and Seventies of the Last Century: A Personal View
inferred← citeshttps://doi.org/10.3390/molecules26092757openalex-snapshot
Recommended Tests for the Self-Disproportionation of Enantiomers (SDE) to Ensure Accurate Reporting of the Stereochemical Outcome of Enantioselective Reactions
inferred← citeshttps://doi.org/10.3390/sym11050680openalex-snapshot
A General Phenomenon of Spontaneous Amplification of Optical Purity under Achiral Chromatographic Conditions
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