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Effect of the internal/external donor pair in high‐yield catalysts for propylene polymerization, 1. Catalyst‐cocatalyst interactions
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What this work says
Outgoing claims: the papers this work cites, builds on, or argues with.
inferredcites →https://doi.org/10.1002/apmc.1984.051200104openalex-snapshot
High yield catalysts in olefin polymerization. General outlook on theoretical aspects and industrial uses
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Polymerization of propene in the presence of MgCl2‐supported Ziegler‐Natta catalysts, 1. The role of ethyl benzoate as “internal” and “external” base
inferredcites →https://doi.org/10.1002/macp.1986.021870508openalex-snapshot
Polymerization of propene in the presence of MgCl2‐supported Ziegler‐Natta catalysts, 2. Effects of the co‐catalyst composition
inferredcites →https://doi.org/10.1002/macp.1988.021890708openalex-snapshot
Influence of internal and external donors on activity and stereospecificity of ziegler‐natta catalysts
inferredcites →https://doi.org/10.1002/macp.1989.021900404openalex-snapshot
Synthesis of polypropylene with improved MgCl2‐supported Ziegler‐Natta catalysts, including silane compounds as external bases
inferredcites →https://doi.org/10.1002/pola.1987.080251206openalex-snapshot
Modification of olefin polymerization catalysts. I. Mechanism of the interaction between AIEt3 and silyl ethers
inferredcites →https://doi.org/10.1002/pola.1988.080261109openalex-snapshot
Superactive and stereospecific catalysts. II. Kinetics of propylene polymerizations
inferredcites →https://doi.org/10.1007/978-1-4757-9095-5_21openalex-snapshot
Polymerization of Propylene with Magnesium Chloride-Supported Catalysts
inferredcites →https://doi.org/10.1007/bfb0037612openalex-snapshot
The catalytic system Ti-complex/MgCl2
inferredcites →https://doi.org/10.1016/0025-326x(88)90430-4openalex-snapshot
Organochlorine contaminants in surficial sediments of Manukau Harbour, New Zealand
inferredcites →https://doi.org/10.1016/0032-3861(80)90034-8openalex-snapshot
Studies on highly active coordination catalysts for polymerization of α-olefins: 1. X-ray diffractomeric investigations of the catalyst supports
inferredcites →https://doi.org/10.1016/0032-3861(81)90022-7openalex-snapshot
Studies on highly active coordination catalysts for polymerization of α-olefins: 2. Thermal investigations of the support system anhydrous magnesium chloride-ethyl benzoate
inferredcites →https://doi.org/10.1016/0304-5102(89)80180-4openalex-snapshot
Mechanistic aspects in propene polymerization using mgcl2-supported ziegler-natta catalysts: behaviour of silane as an external lewis base
What points at this work
Incoming claims: where this work appears in other papers’ reference lists and arguments.
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Polypropylene
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Ziegler‐Natta Catalysts
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Ziegler–Natta Catalysts
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Stereospecific α‐Olefin Polymerization with Heterogeneous Catalysts
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Stereospecific α‐Olefin Polymerization with Heterogeneous Catalysts
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From Heterogeneous Z iegler – N atta to Homogeneous Single‐Center Group 4 Organometallic Catalysts: A Primer on the Coordination Polymerization of Olefins
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Early Transition Metal Catalysts for Olefin Polymerization
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Kinetic study of a highly active MgCl2‐supported Ziegler–Natta catalyst in liquid pool propylene polymerization. II. The influence of alkyl aluminum and alkoxysilane on catalyst activation and deactivation
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Propene polymerization with MgCl2‐supported TiCl4/dioctylphthalate catalyst. I. Catalyst behavior
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Propene polymerization with MgCl2‐supported TiCl4/dioctylphthalate catalyst. II. Effects of polymerization conditions on the microstructure of isotactic polymer
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Copolymerization of ethylene–propylene using high‐activity bi‐supported Ziegler–Natta TiCl4 catalyst
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XPS and EXAFS characterization of Ziegler–Natta catalyst systems
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MgCl2‐supported catalyst containing mixed internal donors for propylene polymerization
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Propylene polymerization over MgCl2‐supported TiCl4 catalysts bearing different amounts of a diether internal electron donor: Extrapolation to the role of internal electron donor on active site
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Study of the Effect of Internal Donors Composition in the Titanium–Magnesium Catalysts on the Molecular Weight Distribution of Polyethylene, Polypropylene, and Polyhexene
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Internal Donors in Ziegler–Natta Systems: is Reduction by AlR3 a Requirement for Donor Clean‐Up?
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Effect of the internal/external donor pair in high‐yield catalysts for propylene polymerization, 2. Polymerization results
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Use of different alkoxysilanes as external donors in MgCl2‐supported Ziegler‐Natta catalysts to obtain propene/1‐butene copolymers with different microstructure
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Magnesium chloride‐supported catalysts for Ziegler‐Natta propene polymerization: Ethyl formate as internal base
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Investigation of the kinetics of ethylene polymerization with supported titanium‐magnesium catalysts of various composition
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New synthesis of a highly active δ‐MgCl2 for MgCl2/TiCl4/AlEt3 catalytic systems
inferred← citeshttps://doi.org/10.1002/macp.1997.021980419openalex-snapshot
Propene polymerization with MgCl2‐supported catalysts: effects of using a diether as external donor
inferred← citeshttps://doi.org/10.1002/macp.200390005openalex-snapshot
Stereospecific Nature of Active Sites on TiCl4/MgCl2 Ziegler–Natta Catalyst in the Presence of an Internal Electron Donor
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A novel MgCl2‐supported Ziegler‐Natta catalyst composition: Stereospecific polymerization of propene without external donor
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Heterogeneous Ziegler‐Natta catalysts: On going progress for the polyolefin industry
inferred← citeshttps://doi.org/10.1002/masy.19950890106openalex-snapshot
Stereoregularity and regioregularity of active centers in propene polymerization
inferred← citeshttps://doi.org/10.1002/masy.19950890107openalex-snapshot
A mechanistic approach to MgCl2 supported stereospecific propene polymerization: A new model of active sites
inferred← citeshttps://doi.org/10.1002/masy.19950890110openalex-snapshot
Recent advances in propylene polymerization with MgCl2 supported catalysts
inferred← citeshttps://doi.org/10.1002/pen.11513openalex-snapshot
Modification of a Ziegler‐Natta catalyst with a metallocene catalyst and its olefin polymerization behavior
inferred← citeshttps://doi.org/10.1002/pi.1487openalex-snapshot
Plausible guard effect on the active sites of heterogeneous Ziegler–Natta catalyst by coordinating monomers and growing polymer chains in the initial stage of propene polymerization
inferred← citeshttps://doi.org/10.1002/pi.942openalex-snapshot
Active sites deterioration of MgCl2‐supported catalyst induced by the electron donor extraction by alkylaluminium
inferred← citeshttps://doi.org/10.1002/pola.10962openalex-snapshot
The discovery and progress of MgCl2‐supported TiCl4 catalysts
inferred← citeshttps://doi.org/10.1002/pola.1994.080321606openalex-snapshot
Investigation on the particle growth mechanism in propylene polymerization with MgCl2‐supported ziegler–natta catalysts
inferred← citeshttps://doi.org/10.1002/tcr.10077openalex-snapshot
Establishment of De Facto Standard Catalysts in the Polypropylene Industry
inferred← citeshttps://doi.org/10.1007/978-3-030-03476-4_1openalex-snapshot
Recent Developments in Supported Polyolefin Catalysts: A Review
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The Impact of the Cocatalyst on the Polymerisation Behaviour of Supported Metallocenes
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Advances in Propylene Polymerization with MgCl2 Supported Catalysts
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Effects of Electron Donors in Super High Activity Catalysts for Polypropylene
inferred← citeshttps://doi.org/10.1007/bf03218409openalex-snapshot
Ethylene polymerization using (n-BuCp)2ZrCl2 catalyst activated with a cross-linked MAO-supported cocatalyst
inferred← citeshttps://doi.org/10.1007/s10965-019-1794-5openalex-snapshot
Polypropylene synthesis in liquid monomer with titanium–magnesium catalyst: effect of different alkoxysilanes as external donors
inferred← citeshttps://doi.org/10.1007/s10965-021-02737-1openalex-snapshot
Internal donors on supported Ziegler Natta catalysts for isotactic polypropylene: a brief tutorial review
inferred← citeshttps://doi.org/10.1007/s10975-005-0065-0openalex-snapshot
Mechanism of olefin polymerization on supported Ziegler-Natta catalysts based on data on the number of active centers and propagation rate constants
inferred← citeshttps://doi.org/10.1016/0014-3057(92)90217-popenalex-snapshot
Magnesium dichloride supported titanium catalyst system: dimethoxypropane as an external lewis base
inferred← citeshttps://doi.org/10.1016/0014-3057(94)00149-9openalex-snapshot
Studies on tetraisobutylaluminoxane as a cocatalyst in a supported titanium system for propylene polymerization
inferred← citeshttps://doi.org/10.1016/0014-3057(94)90161-9openalex-snapshot
Infrared characterization of MgCl2 supported Ziegler-Natta catalysts with monoester and diester as a modifier
inferred← citeshttps://doi.org/10.1016/0032-3861(94)90392-1openalex-snapshot
Microstructural analysis of polypropylenes polymerized with Ziegler-Natta catalysts without external donors
inferred← citeshttps://doi.org/10.1016/0032-3861(95)95929-uopenalex-snapshot
External silane donors in Ziegler—Natta catalysis: a two-site model simulation of the effects of various alkoxysilane compounds
inferred← citeshttps://doi.org/10.1016/0032-3861(96)81138-4openalex-snapshot
Studies on magnesium dichloride-2,2-dimethoxypropane — titanium tetrachloride catalyst system for propylene polymerization
inferred← citeshttps://doi.org/10.1016/0304-5102(93)80065-3openalex-snapshot
Role of electron donor in propylene polymerization using magnesium chloride-supported titanium tetrachloride catalyst
inferred← citeshttps://doi.org/10.1016/b978-088415497-6/50023-1openalex-snapshot
Studies in supported titanium catalyst system using magnesium dichloride-alcohol adduct
inferred← citeshttps://doi.org/10.1016/j.cattod.2023.114494openalex-snapshot
Operando spectroscopies and heterogeneous olefin polymerization catalysis: A rare marriage with a lot of potential beyond usual understanding
inferred← citeshttps://doi.org/10.1016/j.jcat.2020.04.017openalex-snapshot
Revisiting the identity of δ-MgCl2: Part II. Morphology and exposed surfaces studied by vibrational spectroscopies and DFT calculation
inferred← citeshttps://doi.org/10.1016/j.mcat.2024.113850openalex-snapshot
Effect of internal and external electron donors on stereospecific polymerization of isoprene with TiCl4/MgCl2 type Ziegler-Natta catalysts
inferred← citeshttps://doi.org/10.1016/j.molcata.2007.04.002openalex-snapshot
Design of novel malonates as internal donors for MgCl2-supported TiCl4 type polypropylene catalysts and their mechanistic aspects, Part 1
inferred← citeshttps://doi.org/10.1016/j.molcata.2008.11.002openalex-snapshot
DRIFTS study of the interaction of the AlEt3 cocatalyst with the internal donor ethyl benzoate in supported Ziegler–Natta catalysts
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DRIFTS study of the interaction of the internal donor in TiCl4/di-n-butyl phthalate/MgCl2 catalysts with AlEt3 cocatalyst
inferred← citeshttps://doi.org/10.1016/s0014-3057(03)00069-7openalex-snapshot
A qualitative model for polymerisation of propylene with a MgCl2-supported TiCl4 Ziegler–Natta catalyst
inferred← citeshttps://doi.org/10.1016/s0014-3057(97)00183-3openalex-snapshot
The role of phenyltriethoxysilane as an internal donor for the propylene polymerization over BuMgCl-based titanium catalyst
inferred← citeshttps://doi.org/10.1016/s0079-6700(97)00003-8openalex-snapshot
Ziegler-Natta catalysts for olefin polymerizations
inferred← citeshttps://doi.org/10.1016/s1381-1169(00)00124-2openalex-snapshot
27Al MAS NMR study of the interaction of supported Ziegler–Natta catalysts with organoaluminium co-catalyst in the presence of donors
inferred← citeshttps://doi.org/10.1016/s1381-1169(01)00414-9openalex-snapshot
Formation, deactivation and transformation of stereospecific active sites on TiCl4/dibutylphthalate/Mg(OEt)2 catalyst induced by short time reaction with Al-alkyl cocatalyst
inferred← citeshttps://doi.org/10.1016/s1381-1169(02)00465-xopenalex-snapshot
Study on aminosilane compounds as external electron donors in isospecific propylene polymerization
inferred← citeshttps://doi.org/10.1016/s1381-1169(99)00024-2openalex-snapshot
27Al NMR MAS study of the surface Al complexes formed in reaction of organoaluminium compounds with supported TiCl4/MgCl2 catalyst
inferred← citeshttps://doi.org/10.1016/s1381-1169(99)00208-3openalex-snapshot
Effect of different donors on kinetics of Zn catalysts and molecular weight of the obtained polypropylene
inferred← citeshttps://doi.org/10.1016/s1381-1169(99)00275-7openalex-snapshot
Hartree–Fock and density functional theory analysis of propylene insertion in Al(CH3)3/TiCl3/TiO2 (red.) in the presence of a Lewis base
inferred← citeshttps://doi.org/10.1021/acs.iecr.3c03551openalex-snapshot
Influence of Cocatalysts on the Performance of Postphthalate Supported Ziegler–Natta Catalysts in Gas-Phase Propylene Polymerization
inferred← citeshttps://doi.org/10.1021/acs.jpcc.0c03814openalex-snapshot
Monitoring the Kinetics of Internal Donor Clean-up from Ziegler–Natta Catalytic Surfaces: An Integrated Experimental and Computational Study
inferred← citeshttps://doi.org/10.1021/acs.jpcc.8b00903openalex-snapshot
Spectroscopic Evidences for TiCl4/Donor Complexes on the Surface of MgCl2-Supported Ziegler–Natta Catalysts
inferred← citeshttps://doi.org/10.1021/acs.jpcc.8b01500openalex-snapshot
MgCl 2 -Supported Ziegler–Natta Catalysts: a DFT-D “Flexible-Cluster” Approach to Internal Donor Adducts
inferred← citeshttps://doi.org/10.1021/acscatal.1c01735openalex-snapshot
Electronic Properties of Ti Sites in Ziegler–Natta Catalysts
inferred← citeshttps://doi.org/10.1021/acscatal.1c03067openalex-snapshot
Formation of Highly Active Ziegler–Natta Catalysts Clarified by a Multifaceted Characterization Approach
inferred← citeshttps://doi.org/10.1021/acscatal.4c01601openalex-snapshot
End-to-End High-Throughput Approach for Data-Driven Internal Donor Development in Heterogeneous Ziegler–Natta Propylene Polymerization
inferred← citeshttps://doi.org/10.1021/acscatal.4c07916openalex-snapshot
Data Driven Modeling of Ziegler–Natta Polypropylene Catalysts: Revisiting the Role of the Internal Donor
inferred← citeshttps://doi.org/10.1021/acscatal.7b01232openalex-snapshot
Demystifying Ziegler–Natta Catalysts: The Origin of Stereoselectivity
inferred← citeshttps://doi.org/10.1021/jp308658copenalex-snapshot
Investigating Alkoxysilane Coverage and Dynamics on the (104) and (110) Surfaces of MgCl2-Supported Ziegler–Natta Catalysts
inferred← citeshttps://doi.org/10.1021/jp406977hopenalex-snapshot
Periodic Hybrid DFT Approach (Including Dispersion) to MgCl2-Supported Ziegler–Natta Catalysts. 2. Model Electron Donor Adsorption on MgCl2 Crystal Surfaces
inferred← citeshttps://doi.org/10.1021/jp501390eopenalex-snapshot
Investigating Phthalate and 1,3-Diether Coverage and Dynamics on the (104) and (110) Surfaces of MgCl2-Supported Ziegler–Natta Catalysts
inferred← citeshttps://doi.org/10.1021/ma071294copenalex-snapshot
Key Elements in the Structure and Function Relationship of the MgCl2/TiCl4/Lewis Base Ziegler−Natta Catalytic System
inferred← citeshttps://doi.org/10.1021/ma9514232openalex-snapshot
Polymerization Stereochemistry with Ziegler−Natta Catalysts Containing Dialkylpropane Diethers: A Tool for Understanding Internal/External Donor Relationships
inferred← citeshttps://doi.org/10.1080/03602559.1997.10399446openalex-snapshot
Studies of a Supported Titanium Catalyst System Using Magnesium Dichloride–Alcohol Adduct
inferred← citeshttps://doi.org/10.1080/10601329408545297openalex-snapshot
Magnesium-Ethoxide-Based Titanium Catalysts for Polymerization of Propylene
inferred← citeshttps://doi.org/10.1088/2053-1591/ab726dopenalex-snapshot
Temperature effect on propylene polymerization behavior over Ziegler-Natta catalyst with different cocatalyst systems
inferred← citeshttps://doi.org/10.1134/s0023158407030093openalex-snapshot
State of various stereoregulating electron-donating compounds in titanium-magnesium catalysts for propylene polymerization: A diffuse reflectance IR spectroscopic study
inferred← citeshttps://doi.org/10.1134/s0023158408060037openalex-snapshot
Supported titanium-magnesium catalysts for propylene polymerization
inferred← citeshttps://doi.org/10.1134/s0023158411020042openalex-snapshot
State of titanium in supported titanium-magnesium catalysts for propylene polymerization
inferred← citeshttps://doi.org/10.1134/s2070050411020024openalex-snapshot
Titanium-magnesium catalysts for propylene polymerization: The effect of donors
inferred← citeshttps://doi.org/10.1360/ssc-2019-0037openalex-snapshot
Progress on coordination polymerization mechanism of olefins catalyzed by heterogeneous TiCl4/MgCl2 type Ziegler-Natta catalyst
inferred← citeshttps://doi.org/10.23880/ppej-16000172openalex-snapshot
Tuning of Ziegler Natta Catalyst using Emulsion Technique
inferred← citeshttps://doi.org/10.3390/ma15030909openalex-snapshot
Effect of Internal Donors on Raman and IR Spectroscopic Fingerprints of MgCl2/TiCl4 Nanoclusters Determined by Machine Learning and DFT
inferred← citeshttps://doi.org/10.3390/molecules30102176openalex-snapshot
Probing the Interaction of Diester Internal Donors (ID) with AlEt3 on Ziegler-Natta Surfaces: A Comparison Between Binary (MgCl2/ID) and Ternary (MgCl2/ID/TiCl4) Formulations
inferred← citeshttps://doi.org/10.3724/sp.j.1105.2011.10367openalex-snapshot
STUDIES ON AMINOSILANE COMPOUNDS AS EXTERNAL ELECTRON DONORS IN 1-BUTENE POLYMERIZATION
inferred← citeshttps://doi.org/10.58837/chula.the.2020.49openalex-snapshot
Effect of cocatalyst combination in titanium-based ziegler-natta catalyst on olefin polymerization
inferred← citeshttps://doi.org/10.6092/unina/fedoa/10484openalex-snapshot
Molecular Kinetics of Catalytic Olefin Polymerization: an Integrated Quenched-Flow and High-Temperature Cryoprobe NMR Approach
inferred← citeshttps://doi.org/10.70675/23205870z22e6z433dza686z5e68f7cdfd1copenalex-snapshot
Studies on propylene gas phase polymerization modifiers
inferred← citeshttps://doi.org/10.9767/bcrec.15.1.5227.55-65openalex-snapshot
Facile Investigation of Ti3+ State in Ti-based Ziegler-Natta Catalyst with A Combination of Cocatalysts Using Electron Spin Resonance (ESR)
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