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Development of ansa-Metallocene Catalysts for Isotactic Olefin Polymerization

https://doi.org/10.1007/12_2013_215

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Donor/Acceptor Metallocenes: A New Structure Principle in Catalyst Design

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Stopped-flow polymerizations of ethene and propene in the presence of the catalyst systemrac-Me2Si(2-methyl-4-phenyl-1-indenyl)2ZrCl2/methylaluminoxane

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C1-symmetric metallocenes for olefin polymerisation, 1. Catalytic performance of [Me2C(3-tertBuCp)(Flu)]ZrCl2in ethene/norbornene copolymerisation

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Mechanism of dimethylzirconocene activation with methylaluminoxane: NMR monitoring of intermediates at high Al/Zr ratios

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Polymerization of Propene and Butene with a Chiral Zirconocene and Methylalumoxane as Cocatalyst

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High Molecular Weight Polypropylene through Specifically DesigneZirconocene Catalysts

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Monomer–Dimer Equilibria in Homo‐ and Heterodinuclear Cationic Alkylzirconium Complexes and Their Role in Polymerization Catalysis

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C1‐Symmetric Heterocyclic Zirconocenes as Catalysts for Propylene Polymerization, 2

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Metallocene Catalysts for 1‐Butene Polymerization

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Mathematical Modeling of Homopolymerization on Supported Metallocene Catalysts

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New polymers by homogenous zirconocene/aluminoxane catalysts

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Propene polymerization using homogeneous MAO‐activated metallocene catalysts: Me2Si(Benz[e]Indenyl)2ZrCl2/MAO vs. Me2Si(2‐Me‐Benz[e]Indenyl)2ZrCl2/MAO

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Efficient and selective catalysts for olefin polymerizations-insights and challenges

inferredcites →https://doi.org/10.1016/0022-328x(85)80104-2openalex-snapshot

ansa-Metallocene derivatives

inferredcites →https://doi.org/10.1016/0022-328x(91)80182-jopenalex-snapshot

Reversible and irreversible deactivation of propene polymerization using homogeneous Cp2ZrCl2/methylaluminoxane Ziegler—Natta catalysts

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The microstructure of propylene homo- and copolymers obtained with a Cp2ZrCl2 and methylaluminoxane catalyst system

inferredcites →https://doi.org/10.1016/b0-08-045047-4/00065-0openalex-snapshot

Olefin Polymerizations with Group IV Metal Catalysts

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Group 4 metallocene polymerisation catalysts: quantification of ring substituent steric effects

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Constrained geometry complexes—Synthesis and applications

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Frontiers of mechanistic studies of coordination polymerization and oligomerization of α-olefins

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ansa-Metallocene derivatives IV. Synthesis and molecular structures of chiral ansa-titanocene derivatives with bridged tetrahydroindenyl ligands

inferredcites →https://doi.org/10.1016/s0065-3055(08)60307-xopenalex-snapshot

Ziegler-Natta Catalysis

inferredcites →https://doi.org/10.1021/cr040670dopenalex-snapshot

“Bound but Not Gagged”Immobilizing Single-Site α-Olefin Polymerization Catalysts

inferredcites →https://doi.org/10.1021/cr980462jopenalex-snapshot

Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships

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Propene Polymerization with Silica-Supported Metallocene/MAO Catalysts

inferredcites →https://doi.org/10.1021/cr9804691openalex-snapshot

Selectivity in Propene Polymerization with Metallocene Catalysts

inferredcites →https://doi.org/10.1021/cr9902401openalex-snapshot

Heterogeneous Single-Site Catalysts for Olefin Polymerization

inferredcites →https://doi.org/10.1021/ja00226a056openalex-snapshot

Syndiospecific propylene polymerizations with Group IVB metallocenes

inferredcites →https://doi.org/10.1021/ja00254a052openalex-snapshot

Asymmetric hydrooligomerization of propylene

inferredcites →https://doi.org/10.1021/ja00255a068openalex-snapshot

Crystal structures and stereospecific propylene polymerizations with chiral hafnium metallocene catalysts

inferredcites →https://doi.org/10.1021/ja00333a041openalex-snapshot

Mechanisms of stereochemical control in propylene polymerizations with soluble Group 4B metallocene/methylalumoxane catalysts

inferredcites →https://doi.org/10.1021/ja020646mopenalex-snapshot

Activation of Dimethyl Zirconocene by Methylaluminoxane (MAO)Size Estimate for Me-MAO - Anions by Pulsed Field-Gradient NMR

inferredcites →https://doi.org/10.1021/ja028070oopenalex-snapshot

Direct Observation of Insertion Events atrac-(C2H4(1-indenyl)2)Zr(MeB(C6F5)3)−Polymeryl Intermediates: Distinction between Continuous and Intermittent Propagation Modes

inferredcites →https://doi.org/10.1021/ja042839aopenalex-snapshot

Reactivity of Secondary Metal−Alkyls in Catalytic Propene Polymerization: How Dormant Are “Dormant Chains”?

inferredcites →https://doi.org/10.1021/ja909157ropenalex-snapshot

Reactive Intermediates Formed During Olefin Polymerization by Methylalumoxane-Activated ansa -Zirconocene Catalysts: Identification of a Chain-Carrying Intermediate by NMR Methods

inferredcites →https://doi.org/10.1021/ja961157nopenalex-snapshot

Zr−Alkyl Isomerization in ansa-Zirconocene-Catalyzed Olefin Polymerizations. Contributions to Stereoerror Formation and Chain Termination1

inferredcites →https://doi.org/10.1021/ja964142yopenalex-snapshot

Relationship between Regiospecificity and Type of Stereospecificity in Propene Polymerization with Zirconocene-Based Catalysts1

inferredcites →https://doi.org/10.1021/ma00008a015openalex-snapshot

A possible model for the stereospecificity in the syndiospecific polymerization of propene with group 4a metallocenes

inferredcites →https://doi.org/10.1021/ma000691jopenalex-snapshot

Propene Polymerization with Catalyst Mixtures Containing Different ansa-Zirconocenes: Chain Transfer to Alkylaluminum Cocatalysts and Formation of Stereoblock Polymers

inferredcites →https://doi.org/10.1021/ma9608986openalex-snapshot

Dimethylzirconocene−Methylaluminoxane Catalyst for Olefin Polymerization: NMR Study of Reaction Equilibria

inferredcites →https://doi.org/10.1021/ma9710444openalex-snapshot

Ethene−Norbornene Copolymerization with Homogeneous Metallocene and Half-Sandwich Catalysts: Kinetics and Relationships between Catalyst Structure and Polymer Structure. 4. Development of Molecular Weights

inferredcites →https://doi.org/10.1021/om00014a041openalex-snapshot

Unsymmetric ansa-Zirconocene Complexes with Chiral Ethylene Bridges: Influence of Bridge Conformation and Monomer Concentration on the Stereoselectivity of the Propene Polymerization Reaction

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The Influence of Aromatic Substituents on the Polymerization Behavior of Bridged Zirconocene Catalysts

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ansa-Zirconocene Polymerization Catalysts with Anelated Ring Ligands - Effects on Catalytic Activity and Polymer Chain Length

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Ethylidene(1-.eta.5-tetramethylcyclopentadienyl)(1-.eta.5-indenyl)dichlorozirconium: synthesis, molecular structure, and polymerization catalysis

inferredcites →https://doi.org/10.1021/om0492092openalex-snapshot

Propene Polymerization Using ansa-Metallocenium Ions: Excess Activator Effects on Polymerization Activity and Polymer Microstructure

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The Chemistry of Catalyst Activation: The Case of Group 4 Polymerization Catalysts

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Chiral-at- ansa -Bridged Group 4 Metallocene Complexes {(R1R2C)-(3,6- t Bu2Flu)(3-R3-5-Me-C5H2)}MCl2: Synthesis, Structure, Stereochemistry, and Use in Highly Isoselective Propylene Polymerization

inferredcites →https://doi.org/10.1021/om300311kopenalex-snapshot

Novel Effective Racemoselective Method for the Synthesis of ansa-Zirconocenes and Its Use for the Preparation of C2-Symmetric Complexes Based on 2-Methyl-4-aryltetrahydro(s)indacene as Catalysts for Isotactic Propylene Polymerization and Ethylene–Propylene Copolymerization

inferredcites →https://doi.org/10.1021/om800486popenalex-snapshot

Ligand Mobility and Solution Structures of the Metallocenium Ion Pairs [Me2C(Cp)(fluorenyl)MCH2SiMe3+···X−] (M = Zr, Hf; X = MeB(C6F5)3, B(C6F5)4)

inferredcites →https://doi.org/10.1021/om980893sopenalex-snapshot

Fluxional η3-Allyl Derivatives of ansa-Scandocenes and an ansa-Yttrocene. Measurements of the Barriers for the η3 to η1 Process as an Indicator of Olefin Binding Energy to d0 Metallocenes

inferredcites →https://doi.org/10.1023/a:1019115801193openalex-snapshot

Chain transfer reactions in propylene polymerization with zirconocene catalysts

inferredcites →https://doi.org/10.1073/pnas.0602704103openalex-snapshot

Metallocene-catalyzed alkene polymerization and the observation of Zr-allyls

inferredcites →https://doi.org/10.1126/science.267.5195.217openalex-snapshot

Oscillating Stereocontrol: A Strategy for the Synthesis of Thermoplastic Elastomeric Polypropylene

inferredcites →https://doi.org/10.1351/pac200577050801openalex-snapshot

Chemical structure and physical properties of cyclic olefin copolymers (IUPAC Technical Report)

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Molekül- und Kristallstruktur von 1.1-Dimethylsilylentitanocendichlorid, (CH3)2Si(C5H4)2TiCl2 / Molecular and Crystal Structure of l,r-Dimethylsilylene Titanocene Dichloride, (CH3)2Si(C5H4)2TiCl2

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Polypropylene handbook

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Oligomerization and Polymerization

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Universität Konstanz

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Boryl‐ and Silyl‐Substituted Mixed Sandwich Compounds of Scandium

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Zirconium‐Allyl Complexes as Resting States in Zirconocene‐Catalyzed α‐Olefin Polymerization

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Contributions to the Ziegler–Natta Catalysis: An Anthology

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Chiral templated synthesis of methylalumoxane and its catalytic properties in alkene oligomerization

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1H NMR Characterization of rac-Et(2-MeInd)2ZrMe2 Activation by Diisobutylaluminum Aryloxide (2,6-tBu2PhO-)AliBu2

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