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Polyolefin Characterization: Recent Advances in Separation Techniques

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Studies of the Comonomer Distributions in Low Density Polyethylenes Using Temperature Rising Elution Fractionation and Stepwise Crystallization by DSC
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Characterization of homogeneous ethylene/1‐octene copolymers made with a single‐site catalyst. CRYSTAF analysis and calibration
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Development of a universal separator: Characterization of macromolecular and particulate material by aqueous and nonaqueous flow FFF at ambient and elevated operating temperatures
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Crystallization analysis fractionation (CRYSTAF) of poly(ethylene-co-1-octene) made with single-site-type catalysts: A mathematical model for the dependence of composition distribution on molecular weight
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Polymer characterization by temperature gradient interaction chromatography
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Encyclopedia of Analytical Chemistry
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Temperature Rising Elution Fractionation and Crystallization Analysis Fractionation
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Modern Size‐Exclusion Liquid Chromatography
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Polymerisation von Äthylen und anderen Olefinen
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Infrared detection of polymers in gel permeation chromatography
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Development of automatic cross fractionation: Combination of crystallizability fractionation and molecular weight fractionation
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Mark–Houwink equation and GPC calibration for linear short‐chain branched polyolefines, including polypropylene and ethylene–propylene copolymers
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Temperature rising elution fractionation: A review
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Determination of short-chain branching distributions of ethylene copolymers by automated analytical temperature rising elution fractionation (Auto-ATREF)
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Sizes of long‐chain branches in a high‐pressure low‐density polyethylene as a function of molecular weight
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SEC–viscometer detector systems. II. Resolution correction and determination of interdetector volume
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Characterization of fractionated LLDPE by DSC, FTIR, and SEC
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Crystallization analysis fractionation: A new technique for the analysis of branching distribution in polyolefins
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Separation of polyolefins based on comonomer content using high‐temperature gradient adsorption liquid chromatography with a graphitic carbon column
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Characterization of ethylene‐propylene copolymers with high‐temperature gradient adsorption liquid chromatography and CRYSTAF
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Fractionnement par extraction du polythène
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Über hochpolymere Verbindungen, 33. Mitteilung: Beziehungen zwischen Viscosität und Molekulargewicht bei Poly‐styrolen
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A review on the development of liquid chromatography systems for polyolefins
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Polymères isotactiques.
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Segmental exchange polyacetal‐polyether in the cationic copolymerization of trioxane with dioxolane catalyzed by BF3 in the presence of polyethers
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Determination of long‐chain branching distribution in polyethylene by combination of gel permeation chromatography and viscometry
inferredcites →https://doi.org/10.1002/macp.1994.021950507openalex-snapshot
Fractionation of polypropylene according to molecular weight and tacticity
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Characterisation of the Chemical Composition Distribution of LLDPE Using Interactive Liquid Chromatography
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Mathematical Modeling of Temperature Rising Elution Fractionation (TREF) of Polyethylene and Ethylene/1‐Olefin Copolymers
inferredcites →https://doi.org/10.1002/marc.1988.030090803openalex-snapshot
Study on molecular weight dependence of short‐chain branching of linear low‐density polyethylene using the gel permeation chromatography/Fourier transform infrared method
inferredcites →https://doi.org/10.1002/masy.200751102openalex-snapshot
Development of an Automated Cross‐Fractionation Apparatus (TREF‐GPC) for a Full Characterization of the Bivariate Distribution of Polyolefins
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Separation and Characterization of Ethylene‐Propylene Copolymers by High‐Temperature Gradient HPLC Coupled to FTIR Spectroscopy
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Crystallization Elution Fractionation. A New Separation Process for Polyolefin Resins
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A Mathematical Model for the Kinetics of Crystallization in Crystaf
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Advances in Crystallization Elution Fractionation
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High Temperature Interaction Chromatography of Olefin Copolymers
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High Temperature Thermal Gradient Interaction Chromatography (HT‐TGIC) for Microstructure Analysis of Polyolefins
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Crystallization Elution Fractionation and Thermal Gradient Interaction Chromatography. Techniques Comparison
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Homogeneous Copolymers of Ethylene with α‐olefins Synthesized with Metallocene Catalysts and Their Use as Standards for TREF Calibration
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Advances in Thermal Gradient Interaction Chromatography and Crystallization Techniques for Composition Analysis in Polyolefins
inferredcites →https://doi.org/10.1002/masy.201300060openalex-snapshot
Characterization of Chemical Composition along the Molar Mass Distribution in Polyolefin Copolymers by GPC Using a Modern Filter‐ B ased IR Detector
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Analyzing TREF data by stockmayer's bivariate distribution
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The fractionation of polyethylene
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A universal calibration for gel permeation chromatography
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Determination of polymer branching with gel‐permeation chromatography. I. Theory
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Long‐chain branching in low‐density polyethylene
inferredcites →https://doi.org/10.1002/pol.1982.180200307openalex-snapshot
Determination of branching distributions in polyethylene and ethylene copolymers
inferredcites →https://doi.org/10.1002/pola.20292openalex-snapshot
The discovery of metallocene catalysts and their present state of the art
inferredcites →https://doi.org/10.1002/polb.1988.090261011openalex-snapshot
The cocrystallization of polymers: Polyethylene and its copolymers
inferredcites →https://doi.org/10.1002/polb.20441openalex-snapshot
Crystallization analysis fractionation
inferredcites →https://doi.org/10.1002/polc.5070210114openalex-snapshot
A method for high‐temperature exclusion chromatography of polyethylenes
inferredcites →https://doi.org/10.1007/3-540-53135-1_4openalex-snapshot
Temperature rising elution fractionation
inferredcites →https://doi.org/10.1007/978-1-4615-2992-7openalex-snapshot
New Advances in Polyolefins
inferredcites →https://doi.org/10.1007/978-1-4615-2992-7_11openalex-snapshot
Development of High Performance TREF for Polyolefin Analysis
inferredcites →https://doi.org/10.1007/978-3-642-75799-0openalex-snapshot
Gradient HPLC of Copolymers and Chromatographic Cross-Fractionation
inferredcites →https://doi.org/10.1007/978-94-009-5472-4_6openalex-snapshot
History of Crystalline Polypropylene
inferredcites →https://doi.org/10.1007/s00216-010-4335-yopenalex-snapshot
Separation of short-chain branched polyolefins by high-temperature gradient adsorption liquid chromatography
inferredcites →https://doi.org/10.1007/s00216-011-4817-6openalex-snapshot
Improved SEC-FTIR method for the characterization of multimodal high-density polyethylenes
inferredcites →https://doi.org/10.1007/s002890050174openalex-snapshot
Successive self-nucleation/annealing (SSA): A novel technique to study molecular segregation during crystallization
inferredcites →https://doi.org/10.1016/0021-9673(93)83286-2openalex-snapshot
Characterization of high-molecular-mass polyethylenes by gel permeation chromatography—low-angle laser-light scattering
inferredcites →https://doi.org/10.1016/0032-3861(67)90084-5openalex-snapshot
Stereoregular polymers and stereospecific polymerizations
inferredcites →https://doi.org/10.1016/0032-3861(92)90276-3openalex-snapshot
Evaluation of the heterogeneity in linear low-density polyethylene comonomer unit distribution by differential scanning calorimetry characterization of thermally treated samples
inferredcites →https://doi.org/10.1016/0032-3861(95)99010-ropenalex-snapshot
Temperature rising elution fractionation of linear polyolefins
inferredcites →https://doi.org/10.1016/0040-6031(94)85048-8openalex-snapshot
Evaluation of the comonomer distribution in ethylene copolymers using DSC fractionation
inferredcites →https://doi.org/10.1016/b978-1-4831-9883-5.50018-0openalex-snapshot
STEREOSPECIFIC POLYMERIZATION OF α-OLEFINS
inferredcites →https://doi.org/10.1016/b978-1-4832-3245-4.50006-6openalex-snapshot
Theoretical Considerations
inferredcites →https://doi.org/10.1016/j.chroma.2007.03.116openalex-snapshot
Characterization of high molecular weight polyethylenes using high temperature asymmetrical flow field-flow fractionation with on-line infrared, light scattering, and viscometry detection
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Optimisation of ambient and high temperature asymmetric flow field-flow fractionation with dual/multi-angle light scattering and infrared/refractive index detection
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Characterization of branched ultrahigh molar mass polymers by asymmetrical flow field-flow fractionation and size exclusion chromatography
inferredcites →https://doi.org/10.1016/j.chroma.2012.08.005openalex-snapshot
Filter-based infrared detectors for high temperature size exclusion chromatography analysis of polyolefins: Calibration with a small number of standards and error analysis
inferredcites →https://doi.org/10.1016/j.eurpolymj.2010.11.016openalex-snapshot
Characterization of polyolefins by comprehensive high-temperature two-dimensional liquid chromatography (HT 2D-LC)
inferredcites →https://doi.org/10.1016/j.jmr.2006.09.004openalex-snapshot
On-line coupling of high temperature GPC and 1H NMR for the analysis of polymers
inferredcites →https://doi.org/10.1016/j.polymer.2004.07.035openalex-snapshot
Triple-detector GPC characterization and processing behavior of long-chain-branched polyethylene prepared by solution polymerization with constrained geometry catalyst
inferredcites →https://doi.org/10.1016/j.polymer.2005.04.036openalex-snapshot
SEC-MALS method for the determination of long-chain branching and long-chain branching distribution in polyethylene
inferredcites →https://doi.org/10.1016/j.polymer.2005.11.001openalex-snapshot
High-temperature gradient HPLC for the separation of polyethylene–polypropylene blends
inferredcites →https://doi.org/10.1016/j.progpolymsci.2005.03.001openalex-snapshot
Thermal fractionation of polymers
inferredcites →https://doi.org/10.1016/s0021-9673(01)95722-xopenalex-snapshot
Gel permeation chromatography—Fourier transform infrared study of some synthetic polymers
inferredcites →https://doi.org/10.1016/s0021-9673(02)02062-9openalex-snapshot
Elution behavior of polyethylene in polar mobile phases on a non-polar sorbent
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SEC–FTIR characterization of semi-crystalline HDPE and PP
inferredcites →https://doi.org/10.1016/s0032-3861(00)00664-9openalex-snapshot
Characterization of the combined molecular weight and composition distribution of industrial ethylene/α-olefin copolymers
inferredcites →https://doi.org/10.1016/s0032-3861(01)00392-5openalex-snapshot
New approaches using MW-sensitive detectors in GPC–TREF for polyolefin characterization
inferredcites →https://doi.org/10.1016/s0032-3861(01)00574-2openalex-snapshot
Quantifying short chain branching microstructures in ethylene 1-olefin copolymers using size exclusion chromatography and Fourier transform infrared spectroscopy (SEC–FTIR)
inferredcites →https://doi.org/10.1016/s0065-3055(08)60307-xopenalex-snapshot
Ziegler-Natta Catalysis
inferredcites →https://doi.org/10.1016/s0167-2991(06)80431-3openalex-snapshot
Microstructure Characterization of Polyolefins. TREF and CRYSTAF
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Chromatography of Polymers
inferredcites →https://doi.org/10.1021/ma00193a045openalex-snapshot
Thermodynamic and structural properties of ethylene copolymers
inferredcites →https://doi.org/10.1021/ma070732copenalex-snapshot
Separation of Ethylene−Vinyl Acetate Copolymers by High-Temperature Gradient Liquid Chromatography
inferredcites →https://doi.org/10.1021/ma100010eopenalex-snapshot
Development of Comprehensive Two-Dimensional High Temperature Liquid Chromatography × Gel Permeation Chromatography for Characterization of Polyolefins.
inferredcites →https://doi.org/10.1021/ma200304eopenalex-snapshot
A New Technique for Characterizing Comonomer Distribution in Polyolefins: High-Temperature Thermal Gradient Interaction Chromatography (HT-TGIC)
inferredcites →https://doi.org/10.1021/ma2026989openalex-snapshot
Multidimensional Analysis of the Complex Composition of Impact Polypropylene Copolymers: Combination of TREF, SEC-FTIR-HPer DSC, and High Temperature 2D-LC
inferredcites →https://doi.org/10.1021/ma900979nopenalex-snapshot
Separation of Linear Polyethylene from Isotactic, Atactic, and Syndiotactic Polypropylene by High-Temperature Adsorption Liquid Chromatography
inferredcites →https://doi.org/10.1039/tf9555100848openalex-snapshot
Theory of crystallization in copolymers
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A New Separation Concept Based on a Coupling of Concentration and Flow Nonuniformities
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Copolymer Compositional Drift across Molecular Weight Measured by LC-FTIR
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Determination of the Distribution of Molar Mass and Comonomer Content of Medium Density Polyethylene: Comparison of Procedures with Alternative Sequence of Fractionation
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Structural Distribution of Linear Low-Density Polyethylenes
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Gel Permeation Chromatography/Fourier Transform Infrared Interface for Polymer Analysis
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What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Effect of Chain Microstructure on Mechanical Properties of Metallocene Lldpe Resins by Using Tref×Ht-Gpc and Tref×Ssa Methods
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Fractionation of Polymers
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Molecular Structural Characterization of Polyethylene
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Selective experimental parameters for preparative TREF of propylene‐ethylene random copolymers: Limiting undercooling of PP
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Separation of Polypropylene Polymers by Crystallization and Adsorption Techniques
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Characterization of the Chemical Composition Distribution of Ethylene/1‐Alkene Copolymers with HPLC and CRYSTAF—Comparison of Results
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Liquid Chromatography at Critical Conditions of Poly(propylene)
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Exploring the Compositional Heterogeneity of Vis‐Broken Impact Poly(propylene) Copolymers by Advanced Fractionation Methods
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An Advanced Technique for Linear Low‐Density Polyethylene Composition Determination: TGA–IST16–GC–MS Coupling
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Chemical Composition of Hexene‐Based Linear Low‐Density Polyethylene by Infrared Spectroscopy and Chemometrics
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45 Years of Polymer HPLC: A Short Review
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Cloud Point Temperature Measurements on Polyolefins: Identification of Potential New Mobile Phases for Interactive Liquid Chromatography of Polyolefins
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Elution Behavior of Polypropylene with Different Tacticity – An Overview
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High‐Temperature Solvent Gradient Liquid Chromatography of Model Long Chain Branched Polyethylenes
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Analysis of Propylene‐1‐Butene Copolymer Composition by GPC with Online Detectors
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Effect of Heterogeneous Short Chain Branching Distribution on Acceleration or Retardation of the Rate of Crystallization from Melts of Ethylene Copolymers Synthesized with Ziegler‐Natta Catalysts
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Studies on the Application of Filter‐Based IR Detector for Polyolefin Characterization with HT‐SEC
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Characterization and Morphological Distribution of Ethylene Content in Impact Propylene Copolymers
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Development of an Integrated On‐Line 2D Analytical TREF‐High Throughput SEC Technique for Polyolefins Characterization
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Assessment of the Cocrystallization of Ethylene/1‐Octene Copolymer Blends by CRYSTAF and TREF
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Multidimensional analytical protocols for the fractionation and analysis of complex polyolefins
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Molecular heterogeneity of ethylene-propylene rubbers: New insights through advanced crystallization-based and chromatographic techniques
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Structure of Polymers
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Synthesis, Characterization and Applications of Polyolefin Based Eco-Friendly Polymer Composites
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High-Temperature Separations: Polyolefins and Other Materials
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Introduction
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Crystallization-Based Fractionation Techniques
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Column-Based Chromatographic Techniques
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Preparative solution crystallization fractionation: a simple and rapid fractionation method for the chemical composition separation of complex ethylene-propylene copolymers
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Application of two-dimensional chromatography to the characterization of macromolecules and biomacromolecules
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On the multimodality of preparative TREF fractionation as detected by advanced analytical methods
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Comparison of chain structures between high-speed extrusion coating polyethylene resins by preparative temperature rising elution fractionation and cross-fractionation
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Molecular chain heterogeneity of a branched polyethylene resin using cross-fractionation techniques
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Solvent gradient fractionation and chain microstructure of complex branched polyethylene resin
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Microstructure characterization of one high-speed extrusion coating polyethylene resin fractionated by solvent gradient fractionation
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Comparison of chain structures between special polyethylene resins for natural gas pipes by preparative temperature rising elution fractionation and cross-fractionation
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Characterization of polyolefins
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Porous graphite as platform for the separation and characterization of synthetic polymers – an overview
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Retention of polypropylene stereoisomers in solvent gradient interaction chromatography on porous graphitic carbon as influenced by temperature and mobile phase composition
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Improving temperature gradient interaction chromatography of polyolefins by simultaneous use of different stationary phases
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Use graphene coated silica core shell particles to provide rapid, precise, and equivalent chemical composition distribution analysis for polyolefin materials by high temperature thermal gradient interaction chromatography
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Successive Self-nucleation and Annealing (SSA): Correct design of thermal protocol and applications
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Investigation of the molecular architecture influence on the solid-liquid transition of ethylene/1-octene copolymers in butylal
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Advanced characterization of recycled polyolefins: A holistic approach to study their microstructure and contaminations
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Investigation of sample preparation for high temperature gel permeation chromatography using a low solvent consumption method
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Quantifying the content of various types of polypropylene in high density polyethylene blends
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Advances in High-Temperature Interaction Chromatography of Polyolefins: A Tutorial on Solvent and Temperature Gradient
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Comparative Effects on Recrystallization of Melt-Memory and Liquid–Liquid Phase Separation in Ziegler–Natta and Metallocene Ethylene Copolymers with Bimodal Comonomer Composition Distribution
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Influence of Chain Microstructure on Liquid–Liquid Phase Structure and Crystallization of Dual Reactor Ziegler–Natta Made Impact Propylene–Ethylene Copolymers
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Preparative Temperature Rising Elution Fractionation of One Poly(1-butene) Copolymer and Its Chain Microstructure Characterization
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Fabrication of Graphene-Coated Silica Particles for Polymer Chromatography to Quantify Chemical Composition Distribution of Polyolefin Materials
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Quantification of Chemical Composition Distribution of Polyolefin Materials for Improved Accuracy and Speed
inferred← citeshttps://doi.org/10.1021/acs.macromol.4c00290openalex-snapshot
Nonlinear Ziegler–Natta-Homopolyethylene with Enhanced Crystallinity: Physical and Macromolecular Characteristics
inferred← citeshttps://doi.org/10.1021/acsapm.1c00742openalex-snapshot
Non-Negligible Effect of Additives in the Application of Successive Self-Nucleation and Annealing Fractionation for Microstructure Characterization of Matrix Resin in Additive-Containing Samples
inferred← citeshttps://doi.org/10.1021/ie502423hopenalex-snapshot
Studying Binary Solvent Mixtures as Mobile Phase for Thermal Gradient Interactive Chromatography (TGIC) of Poly(ethylene-stat-1-octene)
inferred← citeshttps://doi.org/10.1021/jasms.0c00291openalex-snapshot
Characterization of Polyethylene Branching by Thermal Analysis-Photoionization Mass Spectrometry
inferred← citeshttps://doi.org/10.1038/s43586-025-00410-1openalex-snapshot
Size-exclusion chromatography with multi-angle static light scattering
inferred← citeshttps://doi.org/10.1080/1023666x.2026.2634666openalex-snapshot
Optimum pTREF conditions to unravel chemical composition heterogeneity of LLDPE
inferred← citeshttps://doi.org/10.22063/poj.2016.1323openalex-snapshot
Quantification of identical and unique segments in ethylene-propylene copolymers using two dimensional liquid chromatography with infra-red detection
inferred← citeshttps://doi.org/10.3139/9781569906125.002openalex-snapshot
Structure of Polymers
inferred← citeshttps://doi.org/10.70675/3213b628zc9b4z4269z9b7bze89158c0581aopenalex-snapshot
Characterization of polyethylenes : from thermal fractionation techniques to spectrometry
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