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High-resolution 29Si CP/MAS solid state NMR spectroscopy and DFT investigation on the role of geminal and single silanols in grafting chromium species over Phillips Cr/silica catalyst

https://doi.org/10.1016/j.apcata.2017.05.011
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

inferredcites →https://doi.org/10.1002/9783527610044openalex-snapshot
Handbook of Heterogeneous Catalysis
inferredcites →https://doi.org/10.1002/masy.19930660110openalex-snapshot
Polyhedral oligometallasilsesquioxanes as models for silica‐supported catalysts
inferredcites →https://doi.org/10.1002/mren.201000053openalex-snapshot
Comprehensive Investigation of Catalyst Structure and Polymerization Conditions for Chain Branching in Ethylene Polymerization with Phillips‐Type Catalysts
inferredcites →https://doi.org/10.1002/mren.201400072openalex-snapshot
Novel SiO2‐Supported Chromium Oxide(Cr)/Vanadium Oxide(V) Bimetallic Catalysts for Production of Bimodal Polyethylene
inferredcites →https://doi.org/10.1002/pol.1970.150080929openalex-snapshot
Ethylene polymerization catalysis over chromium oxide
inferredcites →https://doi.org/10.1006/jcat.2001.3443openalex-snapshot
Molecular-Level Insight into Cr/Silica Phillips-Type Catalysts: Polymerization-Active Mononuclear Chromium Sites
inferredcites →https://doi.org/10.1006/jcat.2001.3499openalex-snapshot
Molecular-Level Insight into Cr/Silica Phillips-Type Catalysts: Polymerization-Active Dinuclear Chromium Sites
inferredcites →https://doi.org/10.1007/12_2013_222openalex-snapshot
Phillips Cr/Silica Catalyst for Ethylene Polymerization
inferredcites →https://doi.org/10.1007/bf00767380openalex-snapshot
IR study of the interaction of hydroxyl groups of silica gel with Cr species of Phillips' type catalysts
inferredcites →https://doi.org/10.1016/0021-9517(81)90261-xopenalex-snapshot
The state of Cr(VI) on the Cr/Silica polymerization catalyst
inferredcites →https://doi.org/10.1016/0021-9517(82)90179-8openalex-snapshot
Hydrogenation of olefins and polymerization of ethene over chromium oxide/silica catalysts III. Hydrogenation of olefins and H/D exchange
inferredcites →https://doi.org/10.1016/0021-9517(82)90232-9openalex-snapshot
The state of Cr(VI) on the Phillips polymerization catalyst II. The reaction between silica and CrO2Cl2
inferredcites →https://doi.org/10.1016/0021-9517(82)90234-2openalex-snapshot
The state of Cr(VI) on the Phillips polymerization catalyst IV. Saturation coverage
inferredcites →https://doi.org/10.1016/0021-9517(92)90124-zopenalex-snapshot
A silicon-29 magic angle spinning NMR study of a Phillips (chromia/silica) catalyst
inferredcites →https://doi.org/10.1016/0022-328x(96)06295-xopenalex-snapshot
The Union Carbide catalyst (Cp2Cr + SiO2), studied by solid-state NMR
inferredcites →https://doi.org/10.1016/0039-6028(89)90337-3openalex-snapshot
Kinetics of dissociative chemisorption on strained edge-shared surface defects on dehydroxylated silica
inferredcites →https://doi.org/10.1016/0167-2584(87)90016-8openalex-snapshot
Novel aspects of mid and far IR fourier spectroscopy applied to surface and adsorption studies on SiO2
inferredcites →https://doi.org/10.1016/0304-5102(81)87012-5openalex-snapshot
Why do homogeneous analogs of phillips (CrO3/SiO2) and union carbide (Chromocene/SiO2) polyethylene catalysts fail? Some answers from ir investigations
inferredcites →https://doi.org/10.1016/j.apcata.2004.10.023openalex-snapshot
Photo-stability of surface chromate species on Phillips CrO /SiO2 catalysts isothermally calcined at various temperatures, probed by high resolution X-ray photoelectron spectroscopy
inferredcites →https://doi.org/10.1016/j.apcata.2006.06.051openalex-snapshot
DRIFTS and DRS studies of Phillips ethylene polymerization catalysts
inferredcites →https://doi.org/10.1016/j.apcata.2016.12.001openalex-snapshot
Manipulating polymerization chemistry of Cr/silica catalysts through calcination
inferredcites →https://doi.org/10.1016/j.ccr.2009.09.031openalex-snapshot
On silsesquioxanes’ accuracy as molecular models for silica-grafted complexes in heterogeneous catalysis
inferredcites →https://doi.org/10.1016/j.jcat.2003.12.019openalex-snapshot
A surface science model for the Phillips ethylene polymerization catalyst: thermal activation and polymerization activity
inferredcites →https://doi.org/10.1016/j.jcat.2008.11.024openalex-snapshot
Evidence for a chromasiloxane ring size effect in Phillips (Cr/SiO2) polymerization catalysts
inferredcites →https://doi.org/10.1016/j.jcat.2012.05.014openalex-snapshot
Spectroscopic and structural characterization of Cr(II)/SiO2 active site precursors in model Phillips polymerization catalysts
inferredcites →https://doi.org/10.1016/j.molcata.2004.05.001openalex-snapshot
High resolution X-ray photoelectron spectroscopic analysis of transformation of surface chromium species on Phillips CrOx/SiO2 catalysts isothermally calcined at various temperatures
inferredcites →https://doi.org/10.1016/j.molcata.2010.07.002openalex-snapshot
Experimental and theoretical studies on ethylene polymerization using SiO2-supported silyl chromate type catalysts prepared by a green method
inferredcites →https://doi.org/10.1016/j.molcata.2012.01.021openalex-snapshot
A novel SiO2-supported inorganic and organic hybrid chromium-based catalyst for ethylene polymerization
inferredcites →https://doi.org/10.1016/s0021-9517(79)80021-4openalex-snapshot
Hydrogenation of olefins and polymerization of ethene over chromium oxide/silica catalystsI. Preparation and structure of the catalyst
inferredcites →https://doi.org/10.1016/s0039-6028(87)80150-4openalex-snapshot
Novel aspects of mid and far IR Fourier spectroscopy applied to surface and adsorption studies on SiO2
inferredcites →https://doi.org/10.1016/s0167-2991(06)81511-9openalex-snapshot
Chapter 3 The surface chemistry of silica
inferredcites →https://doi.org/10.1016/s0360-0564(08)60258-8openalex-snapshot
Supported Chromium Catalysts for Ethylene Polymerization
inferredcites →https://doi.org/10.1016/s0360-0564(10)53003-7openalex-snapshot
A Review of the Phillips Supported Chromium Catalyst and Its Commercial Use for Ethylene Polymerization
inferredcites →https://doi.org/10.1016/s0927-7757(00)00556-2openalex-snapshot
The surface chemistry of amorphous silica. Zhuravlev model
inferredcites →https://doi.org/10.1016/s1381-1169(01)00121-2openalex-snapshot
Investigation of the physico-chemical state and aggregation mechanism of surface Cr species on a Phillips CrOx/SiO2 catalyst by XPS and EPMA
inferredcites →https://doi.org/10.1021/ar00144a004openalex-snapshot
Paired interacting orbitals: a way of looking at chemical interactions
inferredcites →https://doi.org/10.1021/cr010386bopenalex-snapshot
Incompletely Condensed Silsesquioxanes: Versatile Tools in Developing Silica-Supported Olefin Polymerization Catalysts
inferredcites →https://doi.org/10.1021/cr040083sopenalex-snapshot
The Structure of Active Centers and the Ethylene Polymerization Mechanism on the Cr/SiO 2 Catalyst: A Frontier for the Characterization Methods
inferredcites →https://doi.org/10.1021/cr940044oopenalex-snapshot
Surface Chemistry and Spectroscopy of Chromium in Inorganic Oxides
inferredcites →https://doi.org/10.1021/j100121a040openalex-snapshot
An IR and NMR study of the chemisorption of titanium tetrachloride on silica
inferredcites →https://doi.org/10.1021/j100577a005openalex-snapshot
Chemistry of silica supported chromium ions. I. Characterization of the samples
inferredcites →https://doi.org/10.1021/j100717a028openalex-snapshot
Proton nuclear magnetic resonance technique for determining the surface hydroxyl content of hydrated silica gel
inferredcites →https://doi.org/10.1021/j150644a041openalex-snapshot
Silicon-29 nuclear magnetic resonance study of hydroxyl sites on dehydrated silica gel surfaces, using silylation as a probe
inferredcites →https://doi.org/10.1021/ja00344a012openalex-snapshot
Silicon-29 NMR study of dehydrated/rehydrated silica gel using cross polarization and magic-angle spinning
inferredcites →https://doi.org/10.1021/ja0122243openalex-snapshot
Silsesquioxane Models for Geminal Silica Surface Silanol Sites. A Spectroscopic Investigation of Different Types of Silanols
inferredcites →https://doi.org/10.1021/ja102842dopenalex-snapshot
Handbook of Transition Metal Polymerization Catalysts
inferredcites →https://doi.org/10.1021/jp209680ropenalex-snapshot
Chromium Oxide Species Supported on Silica: A Representative Periodic DFT Model
inferredcites →https://doi.org/10.1039/c39900001614openalex-snapshot
Polyhedral oligometallasilasesquioxanes as models for silica-supported catalysts: chromium attached to two vicinal siloxy groups
inferredcites →https://doi.org/10.1039/ft9969200453openalex-snapshot
29 Si magic-angle spinning NMR study of Phillips catalysts: multi-exponential spin–lattice relaxation resulting from adsorption of paramagnetic chromium species onto a silica surface
inferredcites →https://doi.org/10.1073/pnas.1220240110openalex-snapshot
Surface structural-chemical characterization of a single-site d 0 heterogeneous arene hydrogenation catalyst having 100% active sites
inferredcites →https://doi.org/10.1134/s0023158406020121openalex-snapshot
Theoretical investigation of novel silsesquioxane-supported Phillips-type catalyst by density functional theory (DFT) method

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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inferred← citeshttps://doi.org/10.1002/macp.202000010openalex-snapshot
CrV Bimetallic Phillips Catalyst Prepared by Citric Acid‐Assisted Impregnation on Ethylene Polymerization
inferred← citeshttps://doi.org/10.1007/978-3-030-11714-6_11openalex-snapshot
Computational Modelling of Structure and Catalytic Properties of Silica-Supported Group VI Transition Metal Oxide Species
inferred← citeshttps://doi.org/10.1016/j.biombioe.2021.106243openalex-snapshot
Rough-surface hydroxyl-group-rich hollow mesoporous silica nanospheres with nanocellulose as a template to improve the oxidation stability of bio-oil
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Nanocellulose as template to prepare rough-hydroxy rich hollow silicon mesoporous nanospheres (R-nCHMSNs) for drug delivery
inferred← citeshttps://doi.org/10.1016/j.jcat.2017.10.026openalex-snapshot
Planar model system of the Phillips (Cr/SiO2) catalyst based on a well-defined thin silicate film
inferred← citeshttps://doi.org/10.1016/j.jcat.2022.07.011openalex-snapshot
A porous V/SiO2 sphere composite for the selective oxidation of benzyl alcohol to benzaldehyde in aqueous phase through peroxymonosulfate activation
inferred← citeshttps://doi.org/10.1016/j.jcat.2025.116493openalex-snapshot
Cr(II)/SiO2 Phillips catalysts for olefin polymerization: How calcination and support morphology control site accessibility and polymer microstructure
inferred← citeshttps://doi.org/10.1016/j.micromeso.2024.113222openalex-snapshot
Should we still be using HCl in the synthesis of SBA-15 and Al-SBA-15?
inferred← citeshttps://doi.org/10.1021/acs.chemmater.1c04016openalex-snapshot
Modeling the Structural Heterogeneity of Vicinal Silanols and Its Effects on TiCl4 Grafting onto Amorphous Silica
inferred← citeshttps://doi.org/10.1021/acs.chemrev.1c00995openalex-snapshot
Two-Dimensional Ultrathin Silica Films
inferred← citeshttps://doi.org/10.1021/acscatal.1c04998openalex-snapshot
Computational Insights into the Multisite Nature of the Phillips CrOx/SiO2 Catalyst for Ethylene Polymerization: The Perspective of Chromasiloxane Ring Size and F Modification
inferred← citeshttps://doi.org/10.1021/acssuschemeng.0c04148openalex-snapshot
Boron Nitride and Oxide Supported on Dendritic Fibrous Nanosilica for Catalytic Oxidative Dehydrogenation of Propane
inferred← citeshttps://doi.org/10.1021/acssuschemeng.3c03585openalex-snapshot
Ligand-Aided Glycolysis of PET Using Functionalized Silica-Supported Fe 2 O 3 Nanoparticles
inferred← citeshttps://doi.org/10.3389/fctls.2022.935174openalex-snapshot
Modelling complex molecular interactions in catalytic materials for energy storage and conversion in nuclear magnetic resonance
inferred← citeshttps://doi.org/10.3390/catal11070842openalex-snapshot
Comparison of Support Effects on Phillips and Metallocene Catalysts
inferred← citeshttps://doi.org/10.3390/polym16050681openalex-snapshot
Mechanistic Insights of Ethylene Polymerization on Phillips Chromium Catalysts
inferred← citeshttps://doi.org/10.3390/polym18111304openalex-snapshot
A Complex Study of Nuclear Magnetic Resonance for Olefin Polymerization Catalyst
inferred← citeshttps://doi.org/10.70675/1cb9bc88za679z48b1z8e0az0c79e5f3d45fopenalex-snapshot
Development of high-field (DNP)-NMR methods to detect quadrupolar nuclei on surfaces
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