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Recent advances in the recovery of germanium during the zinc refining process

https://doi.org/10.1016/j.cej.2022.137445
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Outgoing claims: the papers this work cites, builds on, or argues with.

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Zinc and germanium in the sedimentary rocks of Gale Crater on Mars indicate hydrothermal enrichment followed by diagenetic fractionation
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Extracting and Refining Germanium
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inferredcites →https://doi.org/10.1007/s11771-013-1698-1openalex-snapshot
Extraction of germanium(IV) from acid leaching solution with mixtures of P204 and TBP
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Permeation and modeling studies on Ge(IV) facilitated transport using trioctylamine through supported liquid membrane
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Electrolytic and chemical precipitation of germanium dioxide from oxalate solution
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Germanium crystal chemistry in hematite and goethite from the Apex Mine, Utah, and some new data on germanium in aqueous solution and in stottite
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Some typical behaviours of the β-dodecenyl 8-hydroxyquinoline through its reactions with germanium(IV)
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Liquid-liquid extraction of germanium by LIX 63
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Leaching of zinc and germanium from zinc oxide dust in sulfuric acid-ozone media
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Germanium nanoparticles supported by 3D ordered macroporous nickel frameworks as high-performance free-standing anodes for Li-ion batteries
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Microwave-assisted leaching—a review
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The effect of organic acids on LIX®63 stability under harsh strip conditions and isolation of a diketone degradation product
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inferredcites →https://doi.org/10.1016/j.hydromet.2008.03.005openalex-snapshot
Difference in dissolution between germanium and zinc during the oxidative pressure leaching of sphalerite
inferredcites →https://doi.org/10.1016/j.hydromet.2008.03.006openalex-snapshot
Behavior of tannins in germanium recovery by tannin process
inferredcites →https://doi.org/10.1016/j.hydromet.2014.11.016openalex-snapshot
Recovery of germanium from synthetic leach solution of zinc refinery residues by synergistic solvent extraction using LIX 63 and Ionquest 801
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Recovery of germanium from leach solutions of fly ash using solvent extraction with various extractants
inferredcites →https://doi.org/10.1016/j.hydromet.2018.11.007openalex-snapshot
Selective extraction of zinc, gallium, and germanium from zinc refinery residue using two stage acid and alkaline leaching
inferredcites →https://doi.org/10.1016/j.hydromet.2019.03.001openalex-snapshot
Recovery of gallium from strong acidic sulphate leach solutions of zinc refinery residues using a novel phosphate ester extractant
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Pb-based aggregate, Ge-galena coexistence, and Ge-anglesite coprecipitate—Limitations and an improvement of germanium recovery from secondary zinc oxide via H2SO4 leaching
inferredcites →https://doi.org/10.1016/j.hydromet.2021.105599openalex-snapshot
Efficient extracting germanium and gallium from zinc residue by sulfuric and tartaric complex acid
inferredcites →https://doi.org/10.1016/j.hydromet.2021.105605openalex-snapshot
Recovery of germanium and indium from leaching solution of germanium dross using solvent extraction with TOA, TBP and D2EHPA
inferredcites →https://doi.org/10.1016/j.jclepro.2021.126217openalex-snapshot
Review on resources and recycling of germanium, with special focus on characteristics, mechanism and challenges of solvent extraction
inferredcites →https://doi.org/10.1016/j.jclepro.2021.128223openalex-snapshot
Recovery of a critical metal from electronic wastes: Germanium extraction with organic acid
inferredcites →https://doi.org/10.1016/j.jece.2017.09.048openalex-snapshot
Recovery of germanium from waste Optical Fibers by hydrometallurgical method
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Recovery of pure germanium oxide from Zener diodes using a recyclable ionic liquid Cyphos IL 104
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Removal of phenols from aqueous solutions by emulsion liquid membranes
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GeTe Thermoelectrics
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Selective separation of aromatic hydrocarbons through supported liquid membranes based on ionic liquids
inferredcites →https://doi.org/10.1016/j.mineng.2003.11.014openalex-snapshot
Review of germanium processing worldwide
inferredcites →https://doi.org/10.1016/j.mineng.2018.07.022openalex-snapshot
Low environmental impact process for germanium recovery from an industrial residue
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Recovery of Ge(IV) from synthetic leaching solution of secondary zinc oxide by solvent extraction using tertiary amine (N235) as extractant and trioctyl phosphate (TOP) as modifier
inferredcites →https://doi.org/10.1016/j.mineng.2019.04.020openalex-snapshot
Occurrence state and sulfuric-acid leaching behavior of germanium in secondary zinc oxide
inferredcites →https://doi.org/10.1016/j.mineng.2019.04.021openalex-snapshot
Selective separation of Germanium(IV) from simulated industrial leachates containing heavy metals by non-dispersive ionic extraction
inferredcites →https://doi.org/10.1016/j.mineng.2020.106682openalex-snapshot
Extraction behavior of germanium from synthetic leaching solution of secondary zinc oxide in tertiary amine (N235)-trioctyl phosphate (TOP) system
inferredcites →https://doi.org/10.1016/j.minpro.2017.04.005openalex-snapshot
Extraction of Ga and Ge from zinc refinery residues in H2C2O4 solutions containing H2O2
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Potential connections between the interaction and extraction performance of mixed extractant systems: A short review
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The aqueous geochemistry of gallium, germanium, indium and scandium
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Metallogenesis of germanium—A review
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Recent advances in germanium nanocrystals: Synthesis, optical properties and applications
inferredcites →https://doi.org/10.1016/j.seppur.2017.11.013openalex-snapshot
Selective extraction and separation of germanium by catechol based resins
inferredcites →https://doi.org/10.1016/j.seppur.2019.03.068openalex-snapshot
Selective recovery of germanium from iron-rich solutions using a supported ionic liquid phase (SILP)
inferredcites →https://doi.org/10.1016/j.ultsonch.2015.12.006openalex-snapshot
Comparison of ultrasonic-assisted and regular leaching of germanium from by-product of zinc metallurgy
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An X-ray absorption fine structure spectroscopy study of germanium-organic ligand complexes in aqueous solution
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Hydrometallurgical process for recovery of Zn, Pb, Ga and Ge from Zn refinery residues
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Sustainable Inorganic Chemistry: Metal Separations for Recycling
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Binding and Precipitation of Germanium(IV) by Penta-O-galloyl-β- d -glucose
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Extraction Behaviors of Heavy Rare Earths with Organophosphoric Extractants: The Contribution of Extractant Dimer Dissociation, Acid Ionization, and Complexation. A Quantum Chemistry Study
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Enhanced Third Harmonic Generation in Single Germanium Nanodisks Excited at the Anapole Mode
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Recovery of Germanium via H2SO4/MnO2 Leaching–NaAc Leaching/Na2CO3 Precipitation–Tri(octyl-decyl) Amine Stepwise Solvent Extraction
inferredcites →https://doi.org/10.1021/acssuschemeng.8b04882openalex-snapshot
Thermodynamics, Kinetics Model, and Reaction Mechanism of Low-Vacuum Phosphate Reduction Process for Germanium Recovery from Optical Fiber Scraps
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Extraction of Germanium by the AOT Microemulsion with N235 System
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GERMANIUM. XXXIX. THE POLYMORPHISM OF GERMANIUM DIOXIDE 1
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Academic and industry research progress in germanium nanodevices
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The reactions of elemental germanium with 3,5-di-tert-butyl-1,2-benzoquinone
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Mechanochemistry: opportunities for new and cleaner synthesis
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An environment-friendly approach to produce nanostructured germanium anodes for lithium-ion batteries
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Microwave chemistry
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GERMANIUM SOLVENT EXTRACTION FROM SULFURIC ACID SOLUTIONS (AND CO-EXTRACTION OF GERMANIUM AND GALLIUM)
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A Review on Germanium Resources and its Extraction by Hydrometallurgical Method
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Microwave-assisted and regular leaching of germanium from the germanium-rich lignite ash
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Extractive Metallurgy
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Facilitated transport of germanium from acidic medium through supported liquid membrane using Cyanex 301 as mobile carrier

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Multi‐Site Chelation Enabled by 3D‐Printed TiO 2 Hydrogel Monoliths for Dynamic Ge(IV) Recovery in Fixed Beds
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Recovery of germanium from zinc smelting leachates: a review
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Elemental distributions of solid waste collected from the germanium extraction process
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Hydrochloric Acid Leaching Kinetics Study of Germanium Concentrate
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Experimental Study on Zinc Germanium Leaching of High-Silicon Zinc Oxide Dust
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Major obstacles hindering gallium and germanium leaching in the zinc refining process
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Mild in situ growth of a hydroxyl-rich magnetic amorphous TiO2/graphene oxide composite for selective Ge(IV) capture from acidic solutions
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Enhanced gallium and germanium recovery from zinc pressure leachate via zinc powder cementation
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Behavior of germanium recovery by adsorption from a coupling perspective: Macro-scale performance and microstructural evolution
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Efficient extraction and separation of germanium from highly acidic media using a trialkylphosphine oxide - isooctanol system and stripping with HNO3
inferred← citeshttps://doi.org/10.1016/j.ijpe.2024.109231openalex-snapshot
Ensuring the sustainable supply of semiconductor material: A case of germanium in China
inferred← citeshttps://doi.org/10.1016/j.jclepro.2022.135399openalex-snapshot
A novel solvent extraction system to recover germanium from H2SO4 leaching liquor of secondary zinc oxide: Extraction behavior and mechanism
inferred← citeshttps://doi.org/10.1016/j.jclepro.2026.147999openalex-snapshot
Co-extraction and stepwise purification of germanium and chlorine from zinc oxide leaching solution
inferred← citeshttps://doi.org/10.1016/j.jclepro.2026.149183openalex-snapshot
From co-extraction to decoupled separation: Structural thermodynamics governing the dual recovery of germanium(IV) and chloride in an amine extraction system
inferred← citeshttps://doi.org/10.1016/j.jece.2025.115344openalex-snapshot
One-step room-temperature synthesis of amorphous TiO2-based adsorbent for enhanced Ge(IV) recovery
inferred← citeshttps://doi.org/10.1016/j.jece.2025.120982openalex-snapshot
Novel insights into synergistic mechanisms of germanium extraction via tertiary amine system: Protonation processes and tartaric acid behavior
inferred← citeshttps://doi.org/10.1016/j.jece.2026.122181openalex-snapshot
TOC-inhibited synergistic solvent extraction system for high-efficiency germanium recovery from sulfuric acid solutions: Extraction behavior and reaction mechanism
inferred← citeshttps://doi.org/10.1016/j.jece.2026.122241openalex-snapshot
Recovery of germanium from high‑chloride germanium-bearing wastewater by ion exchange: A behavior investigation
inferred← citeshttps://doi.org/10.1016/j.jenvman.2024.121699openalex-snapshot
Preparation and evaluation of germanium concentrate by ultrasonic purification of tannin germanium residue
inferred← citeshttps://doi.org/10.1016/j.jenvman.2025.128125openalex-snapshot
Thermodynamic analysis and extraction and recovery of germanium from germanium-containing materials: A review
inferred← citeshttps://doi.org/10.1016/j.jenvman.2026.129140openalex-snapshot
Enrichment of germanium from waste germanium-bearing dust via reduction volatilization using calcium sulfate as an additive
inferred← citeshttps://doi.org/10.1016/j.jhazmat.2024.133766openalex-snapshot
An original strategy and evaluation of a reaction mechanism for recovering valuable metals from zinc oxide dust containing intractable germanide
inferred← citeshttps://doi.org/10.1016/j.jscs.2023.101738openalex-snapshot
Study on the mechanism of ultrasonic enhanced removal of zinc and germanium from lead residue
inferred← citeshttps://doi.org/10.1016/j.jscs.2023.101740openalex-snapshot
Research on the mechanism of lead sulfate adsorption of germanium and ultrasonic inhibition during the leaching process of zinc oxide dust containing germanium
inferred← citeshttps://doi.org/10.1016/j.jscs.2023.101803openalex-snapshot
Kinetics and mechanism of ultrasonic enhanced separation of zinc from tannin germanium residue
inferred← citeshttps://doi.org/10.1016/j.mineng.2024.108763openalex-snapshot
Application of copper for sufficient metal extraction from zinc leaching residue: Process optimization and copper reuse
inferred← citeshttps://doi.org/10.1016/j.mineng.2025.109196openalex-snapshot
Selective leaching of Ga and Ge from zinc powder replacement residue and determining influential role of magnetic field with an ultrasonic field
inferred← citeshttps://doi.org/10.1016/j.mineng.2025.109758openalex-snapshot
Selective separation and recovery of gallium and germanium from complex polymetallic sulfate solutions
inferred← citeshttps://doi.org/10.1016/j.mineng.2025.109951openalex-snapshot
Ultrasound-induced entropy enhancement of tannic acid for selective germanium extraction from complex solutions
inferred← citeshttps://doi.org/10.1016/j.mineng.2026.110542openalex-snapshot
“Electrostatically friendly” aminomethyl functionalized tannic acid: Investigation on Ge adsorption performance and mechanism
inferred← citeshttps://doi.org/10.1016/j.mtsust.2026.101366openalex-snapshot
Evaluating high-yield synthesis methods for gallium and germanium: A bibliometric, systematic and life cycle assessment aligned with SDGs
inferred← citeshttps://doi.org/10.1016/j.psep.2026.109472openalex-snapshot
From hazardous waste to strategic resources: A critical review on detoxification and resource valorization of secondary zinc oxide
inferred← citeshttps://doi.org/10.1016/j.seppur.2023.123338openalex-snapshot
Unraveling the steric hindrance roles of the phenolic hydroxyl position on the selective Ge(IV) recovery from zinc residue leachate
inferred← citeshttps://doi.org/10.1016/j.seppur.2023.125467openalex-snapshot
Migration behavior of germanium and its related elements in zinc hydrometallurgy process
inferred← citeshttps://doi.org/10.1016/j.seppur.2023.125572openalex-snapshot
Strong magnetic and ultrasonic fields enhanced the leaching of Ga and Ge from zinc powder replacement residue
inferred← citeshttps://doi.org/10.1016/j.seppur.2023.125802openalex-snapshot
Full-components utilization: Study on simultaneous preparation of sodalite and separation of yttrium from coal gangue by chlorination roasting process
inferred← citeshttps://doi.org/10.1016/j.seppur.2023.126166openalex-snapshot
Selective separation of zinc from germanium-bearing iron cake via a roasting–leaching process
inferred← citeshttps://doi.org/10.1016/j.seppur.2024.126475openalex-snapshot
Separation behavior of trace impurities during deep purification of zone-fused germanium tailings via vacuum distillation
inferred← citeshttps://doi.org/10.1016/j.seppur.2024.127734openalex-snapshot
A perspective on molecular recognition technology for recovering critical metals from minerals and processing wastes
inferred← citeshttps://doi.org/10.1016/j.seppur.2024.128015openalex-snapshot
Separation of silicon and germanium from the chlorination distillation residue based on co-precipitation of sodium-aluminum–silicon
inferred← citeshttps://doi.org/10.1016/j.seppur.2024.128590openalex-snapshot
Selective extraction of germanium from iron-bearing ammonia leaching residue via low-temperature molten NaOH leaching
inferred← citeshttps://doi.org/10.1016/j.seppur.2024.129770openalex-snapshot
An improvement for enrichment and purification of germanium using carbonyl acid extractants
inferred← citeshttps://doi.org/10.1016/j.seppur.2024.131266openalex-snapshot
A feasible strategy for the multi-stage separation of valuable metals from zinc hydrometallurgy leaching solution
inferred← citeshttps://doi.org/10.1016/j.seppur.2025.134054openalex-snapshot
Extraction of germanium and fixation of arsenic from lignite using pyrolysis
inferred← citeshttps://doi.org/10.1016/j.seppur.2025.134156openalex-snapshot
Co-extraction and enrichment of Ge, Sb and as from coal measure germanium-containing dust by reductive volatilization
inferred← citeshttps://doi.org/10.1016/j.seppur.2025.134399openalex-snapshot
Unconventional technologies for the separation of germanium and gallium from solutions: A review
inferred← citeshttps://doi.org/10.1016/j.seppur.2025.134602openalex-snapshot
Stoichiometry and growth mechanism of Tannin-Germanium complexes in precipitation processes
inferred← citeshttps://doi.org/10.1016/j.seppur.2025.135101openalex-snapshot
Efficient separation process of niobium and titanium: In-situ chlorination-cascade condensation assisted by molten salt
inferred← citeshttps://doi.org/10.1016/j.seppur.2025.136109openalex-snapshot
Study on volatilization characteristics and atmosphere regulation mechanism of germanium during lignite pyrolysis
inferred← citeshttps://doi.org/10.1016/j.seppur.2025.136192openalex-snapshot
Microfluidic chelation of germanium from post-indium extraction waste streams: Coordinative immobilization, process optimization, and environmental risk mitigation
inferred← citeshttps://doi.org/10.1016/j.seppur.2026.137655openalex-snapshot
From resources to single-crystal germanium: A review on recovery and purification
inferred← citeshttps://doi.org/10.1016/j.seppur.2026.139973openalex-snapshot
Separation of germanium from low-grade zinc mine tailings using membrane solvent extraction with Tributyl phosphate (TBP)
inferred← citeshttps://doi.org/10.1016/j.seppur.2026.140254openalex-snapshot
Molecular recognition-driven selective recovery of germanium from acidic zinc leaching solution: COUPLED zinc separation and DFT-supported mechanism elucidation
inferred← citeshttps://doi.org/10.1016/j.susmat.2023.e00806openalex-snapshot
Sequential fabrication of multiple Ge nanomembranes from a single wafer: Towards sustainable recycling of Ge substrates
inferred← citeshttps://doi.org/10.1016/s1003-6326(25)67009-9openalex-snapshot
Mechanism of ultrasound enhanced selective oxygen pressure leaching of Ga and Ge from zinc powder replacement residue
inferred← citeshttps://doi.org/10.1021/acs.langmuir.4c01167openalex-snapshot
Mechanism of Germanium Adsorption by Iron Hydroxide Colloids during the Leaching Process of Secondary Zinc Oxide
inferred← citeshttps://doi.org/10.1021/acs.langmuir.4c02307openalex-snapshot
Mechanism and Kinetic Study on Ultrasonically Enhanced Reduction Leaching of Zinc Suboxide
inferred← citeshttps://doi.org/10.1021/acsapm.4c01489openalex-snapshot
Selective Capture of Germanium from Water by a Hydrotalcite-Based Ion-Imprinted Polymer: Performance and Mechanism
inferred← citeshttps://doi.org/10.1021/acsapm.6c01425openalex-snapshot
A Selective and Efficient Germanium(IV) Adsorbent Based on Pyrogallol-Formaldehyde Cross-Linking
inferred← citeshttps://doi.org/10.1021/acsomega.5c03602openalex-snapshot
Latest Research Progress in High-Purity Material Purification Technology
inferred← citeshttps://doi.org/10.1021/acssuschemeng.5c03443openalex-snapshot
Ultrasonic-Persulfate Synergetic Unlocking the Efficient Extraction of Targeted Zn, In, and Ge in Zinc Slag: From Experimental Evaluation to DFT Study
inferred← citeshttps://doi.org/10.1021/acssusresmgt.5c00485openalex-snapshot
Targeted Recovery of Germanium from Coal Fly Ash Using Quaternary Ammonium Salt Extractant
inferred← citeshttps://doi.org/10.1039/d6ra01890dopenalex-snapshot
Leaching kinetics and mechanisms in efficient chlorination leaching of germanium-rich fume dust
inferred← citeshttps://doi.org/10.1080/00084433.2024.2357514openalex-snapshot
Dissociation of germanium-containing insoluble mineral phases in zinc oxide dust Dissociation des phases minérales insolubles contenant du germanium dans la poussière d’oxyde de zinc
inferred← citeshttps://doi.org/10.1080/10426507.2023.2193747openalex-snapshot
The potential – pH diagram for germanium
inferred← citeshttps://doi.org/10.1088/1742-6596/2860/1/012036openalex-snapshot
Kinetics Study on Microwave Alkaline Roasting-Water Dissolving of Germanium from Zinc Oxide Dust
inferred← citeshttps://doi.org/10.1088/1742-6596/2860/1/012037openalex-snapshot
Study on the Sulfuric-Leaching Kinetics of Germanium from Zinc Oxide Dust Assisted by Microwave Roasting
inferred← citeshttps://doi.org/10.1515/ijcre-2023-0011openalex-snapshot
Leaching behavior of germanium presented in different phases from zinc oxide dust under atmospheric acid leaching conditions
inferred← citeshttps://doi.org/10.1515/ijcre-2023-0042openalex-snapshot
Physical effect of ultrasonic on leaching system of zinc oxide dust containing germanium
inferred← citeshttps://doi.org/10.2139/ssrn.5149023openalex-snapshot
Recover Crystalline Germanium Thin Films from Waste Optical Fiber by Leaching-Electrodeposition Process
inferred← citeshttps://doi.org/10.2139/ssrn.5366333openalex-snapshot
Efficient Extraction of Germanium from Highly Acidic Media by Trialkylphosphine Oxide and Isooctanol Extraction System and Acid Stripping
inferred← citeshttps://doi.org/10.2139/ssrn.5800450openalex-snapshot
Ultrasonic-Assisted Synergistic Oxalic Acid Enhanced Leaching of Ge Encapsulated by PbS/PbSO₄ from Leaching Residues
inferred← citeshttps://doi.org/10.2139/ssrn.6717080openalex-snapshot
Germanium extraction from germanium-bearing lignite via microwave plasma pyrolysis
inferred← citeshttps://doi.org/10.2139/ssrn.6909267openalex-snapshot
Kinetic and mass transfer mechanisms of germanium(IV) extraction from sulfuric acid solutions containing tartaric acid using a N235-TBP composite solvent
inferred← citeshttps://doi.org/10.2139/ssrn.6970152openalex-snapshot
Mechanistic insights into tannin-metal ion interactions during complexation-precipitation for germanium recovery
inferred← citeshttps://doi.org/10.25259/ajc_288_2024openalex-snapshot
Selective extraction of germanium from lead slag washing wastewater by tannic acid coordination and precipitation method
inferred← citeshttps://doi.org/10.3390/met13050852openalex-snapshot
The States and Properties of Germanium in Sulfuric Acid Solution
inferred← citeshttps://doi.org/10.3390/met16060644openalex-snapshot
Microfluidic-Intensified Two-Stage Tannin Precipitation of Germanium to Reduce Tannin Consumption
inferred← citeshttps://doi.org/10.3390/molecules30081695openalex-snapshot
Challenges and Opportunities in Hydrometallurgical Recovery of Germanium from Coal By-Products
inferred← citeshttps://doi.org/10.3390/pr14050757openalex-snapshot
Synergistic SO2/H2SO4-Driven Co-Recovery of Zinc and Germanium from Industrial Dust: A Closed-Loop Strategy for Critical Metal Recycling
inferred← citeshttps://doi.org/10.3390/separations13080235openalex-snapshot
A Review of Germanium Recovery from Zinc Smelting Residues: From Enrichment to High-Purity Preparation
Editorial review for independent work. ICSAC — the Institute for Complexity Science and Advanced Computing — runs a structured editorial panel for researchers publishing outside journals, and publishes on CiteStamp rails. Submission is free and goes through ORCID: icsacinstitute.org/submit.