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Reduction kinetics of aqueous U(VI) in acidic chloride brines to uraninite by methane, hydrogen or C-graphite under hydrothermal conditions: Implications for the genesis of unconformity-related uranium ore deposits

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Transition State Theory
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Review: Nucleation in solutions revisited
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The extreme diversity of uranium deposits
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Characterization of graphite alteration in an uranium deposit by micro-Raman spectroscopy, X-ray diffraction, transmission electron microscopy and scanning electron microscopy
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Petrogenesis of the Proterozoic Athabasca Basin, northern Saskatchewan, Canada, and its relation to diagenesis, hydrothermal uranium mineralization and paleohydrogeology
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Radiolysis evidenced by H2-O2 and H2-bearing fluid inclusions in three uranium deposits
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Micrometer scale carbon isotopic study of bitumen associated with Athabasca uranium deposits: Constraints on the genetic relationship with petroleum source-rocks and the abiogenic origin hypothesis
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The yield and isotopic composition of radiolytic H2, a potential energy source for the deep subsurface biosphere
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Isotopic signatures of CH4 and higher hydrocarbon gases from Precambrian Shield sites: A model for abiogenic polymerization of hydrocarbons
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Thermodynamic constraints on hydrogen generation during serpentinization of ultramafic rocks
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From evaporated seawater to uranium-mineralizing brines: Isotopic and trace element study of quartz–dolomite veins in the Athabasca system
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An experimental and ab initio study on the abiotic reduction of uranyl by ferrous iron
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Effect of graphite zone in the formation of unconformity-related uranium deposits: Insights from reactive mass transport modeling
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Reduction of UO22+ by H2
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Abiogenic Fischer?Tropsch synthesis of hydrocarbons in alkaline igneous rocks; fluid inclusion, textural and isotopic evidence from the Lovozero complex, N.W. Russia
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Alteration, HFSE mineralisation and hydrocarbon formation in peralkaline igneous systems: Insights from the Strange Lake Pluton, Canada
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Biogenic and petroleum-related ore-forming processes in Dongsheng uranium deposit, NW China
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A reassessment of the potential for reduction of dissolved CO 2 to hydrocarbons during serpentinization of olivine
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Fischer-Tropsch synthesis of hydrocarbons during sub-solidus alteration of the Strange Lake peralkaline granite, Quebec/Labrador, Canada
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Kinetics of pyrite formation by the H2S oxidation of iron (II) monosulfide in aqueous solutions between 25 and 125°C: The rate equation
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Surface catalysis of uranium(VI) reduction by iron(II)
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Fluid inclusion evidence of the differential migration of H2 and O2in the McArthur River unconformity-type uranium deposit (Saskatchewan, Canada). Possible role on post-ore modifications of the host rocks
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A detailed fluid inclusion study in silicified breccias from the Kombolgie sandstones (Northern Territory, Australia): inferences for the genesis of middle-Proterozoic unconformity-type uranium deposits
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Chemical Reduction of U(VI) by Fe(II) at the Solid−Water Interface Using Natural and Synthetic Fe(III) Oxides
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Reduction of Uranyl(VI) by Iron(II) in Solutions: An Ab Initio Study
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Aqueous Uranyl Complexes 1. Raman Spectroscopic Study of the Hydrolysis of Uranyl(VI) in Solutions of Trifluoromethanesulfonic Acid and/or Tetramethylammonium Hydroxide at 25°C and 0.1 MPa
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Radiolytic H 2 in continental crust: Nuclear power for deep subsurface microbial communities
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Some geological implications of equilibrium between graphite and a C‐H‐O gas phase at high temperatures and pressures
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Pyrite formation linked with hydrogen evolution under anaerobic conditions
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Abiogenic formation of alkanes in the Earth's crust as a minor source for global hydrocarbon reservoirs
inferredcites →https://doi.org/10.1038/ngeo1338openalex-snapshot
Giant uranium deposits formed from exceptionally uranium-rich acidic brines
inferredcites →https://doi.org/10.1063/1.555976openalex-snapshot
Summary of the Apparent Standard Partial Molal Gibbs Free Energies of Formation of Aqueous Species, Minerals, and Gases at Pressures 1 to 5000 Bars and Temperatures 25 to 1000 °C
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Evolution of the first metabolic cycles.
inferredcites →https://doi.org/10.1111/gfl.12009openalex-snapshot
Synchrotron XRF and XANES investigation of uranium speciation and element distribution in fluid inclusions from unconformity‐related uranium deposits
inferredcites →https://doi.org/10.1111/j.1365-3121.2010.00947.xopenalex-snapshot
Brine-rock interaction in the Athabasca basement (McArthur River U deposit, Canada): consequences for fluid chemistry and uranium uptake
inferredcites →https://doi.org/10.1111/j.1468-8123.2010.00289.xopenalex-snapshot
Fluid flows and metal deposition near basement /cover unconformity: lessons and analogies from Pb–Zn–F–Ba systems for the understanding of Proterozoic U deposits
inferredcites →https://doi.org/10.1111/j.1468-8123.2010.00314.xopenalex-snapshot
Geochemistry of H2‐ and CH4‐enriched hydrothermal fluids of Socorro Island, Revillagigedo Archipelago, Mexico. Evidence for serpentinization and abiogenic methane
inferredcites →https://doi.org/10.1111/j.1525-1314.1993.tb00155.xopenalex-snapshot
C‐O‐H‐S fluid composition and oxygen fugacity in graphitic metapelites
inferredcites →https://doi.org/10.1126/science.1151194openalex-snapshot
Abiogenic Hydrocarbon Production at Lost City Hydrothermal Field
inferredcites →https://doi.org/10.1127/0935-1221/2013/0025-2319openalex-snapshot
Experimental study of uranyl(VI) chloride complex formation in acidic LiCl aqueous solutions under hydrothermal conditions (T = 21 C?350 °C, Psat) using Raman spectroscopy
inferredcites →https://doi.org/10.1130/0091-7613(1996)024<0351:rocdso>2.3.co;2openalex-snapshot
Reduction of CO2 during serpentinization of olivine at 300 °C and 500 bar
inferredcites →https://doi.org/10.1139/e77-235openalex-snapshot
Hydrogen—a reducing agent in some uranium deposits
inferredcites →https://doi.org/10.1139/e89-042openalex-snapshot
Stable isotope constraints on the role of graphite in the genesis of unconformity-type uranium deposits
inferredcites →https://doi.org/10.1139/e93-055openalex-snapshot
Pétrographie et minéralogie des halos d'altération autour du gisement de Cigar Lake et leurs relations avec les minéralisations
inferredcites →https://doi.org/10.1146/annurev.pc.32.100181.001111openalex-snapshot
Transition State Theory
inferredcites →https://doi.org/10.1180/minmag.1981.044.336.13openalex-snapshot
Uraninite-albite veins from the Mistamisk Valley of the Labrador Trough, Quebec
inferredcites →https://doi.org/10.1306/819a4202-16c5-11d7-8645000102c1865dopenalex-snapshot
Free Hydrogen in Genesis of Petroleum
inferredcites →https://doi.org/10.13140/2.1.1033.1847openalex-snapshot
DIAGENETIC FLUIDS IN PALEO- AND MESO-PROTEROZOIC SEDIMENTARY BASINS AND THEIR IMPLICATIONS FOR LONG PROTRACTED FLUID HISTORIES.
inferredcites →https://doi.org/10.1346/ccmn.2006.0540302openalex-snapshot
Mineralogy and Geochemistry of the Host-Rock Alterations Associated with the Shea Creek Unconformity-Type Uranium Deposits (Athabasca Basin, Saskatchewan, Canada). Part 2. Regional-Scale Spatial Distribution of the Athabasca Group Sandstone Matrix Minerals
inferredcites →https://doi.org/10.1351/pac199365061343openalex-snapshot
The cradle chemistry of life: On the origin of natural products in a pyrite-pulled chemoautotrophic origin of life
inferredcites →https://doi.org/10.2113/100.8.1657openalex-snapshot
URANIUM IN IRON OXIDE-COPPER-GOLD (IOCG) SYSTEMS
inferredcites →https://doi.org/10.2113/econgeo.107.1.147openalex-snapshot
Tectonic Deformation and Fluid Flow: Implications for the Formation of Unconformity-Related Uranium Deposits
inferredcites →https://doi.org/10.2113/gscanmin.43.3.1005openalex-snapshot
EFFECTS OF CATIONIC SUBSTITUTIONS AND ALTERATION IN URANINITE, AND IMPLICATIONS FOR THE DATING OF URANIUM DEPOSITS
inferredcites →https://doi.org/10.2113/gsecongeo.100.8.1529openalex-snapshot
Mixing of Sodic and Calcic Brines and Uranium Deposition at McArthur River, Saskatchewan, Canada: A Raman and Laser-Induced Breakdown Spectroscopic Study of Fluid Inclusions
inferredcites →https://doi.org/10.2113/gsecongeo.100.8.1547openalex-snapshot
Alteration Mineralogy and Stable Isotope Geochemistry of Paleoproterozoic Basement-Hosted Unconformity-Type Uranium Deposits in the Athabasca Basin, Canada
inferredcites →https://doi.org/10.2113/gsecongeo.73.8.1450openalex-snapshot
On the genesis of Rabbit Lake and other unconformity-type uranium deposits in northern Saskatchewan, Canada
inferredcites →https://doi.org/10.2113/gsecongeo.76.8.2236openalex-snapshot
The possible role of sulfate reduction kinetics in the formation of hydrothermal uranium deposits
inferredcites →https://doi.org/10.2113/gsecongeo.84.6.1627openalex-snapshot
Fluid inclusion evidence on the origin of some Australian unconformity-related uranium deposits
inferredcites →https://doi.org/10.2113/gsecongeo.94.7.993openalex-snapshot
Precipitation kinetics of uranium by sedimentary organic matter under diagenetic and hydrothermal conditions
inferredcites →https://doi.org/10.2138/am.2007.2277openalex-snapshot
Significance of aluminum phosphate-sulfate minerals associated with U unconformity-type deposits: The Athabasca basin, Canada
inferredcites →https://doi.org/10.2138/rmg.2013.75.15openalex-snapshot
Laboratory Simulations of Abiotic Hydrocarbon Formation in Earth's Deep Subsurface
inferredcites →https://doi.org/10.2172/138894openalex-snapshot
EQ3/6, a software package for geochemical modeling of aqueous systems: Package overview and installation guide (Version 7.0)
inferredcites →https://doi.org/10.2475/ajs.295.6.639openalex-snapshot
The formation of unconformity-type uranium ore deposits; 2, Coupled hydrochemical modeling
inferredcites →https://doi.org/10.3133/wri994259openalex-snapshot
User's guide to PHREEQC (Version 2): A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations
inferredcites →https://doi.org/10.3406/bulmi.1984.7746openalex-snapshot
Simulation des équilibres chimiques dans le système C-O-H. Conséquences méthodologiques pour les inclusions fluides
inferredcites →https://doi.org/10.3749/9780921294726.ch03openalex-snapshot
CHAPTER 3: GEOCHEMICAL CHARACTERISTICS OF URANIUM AND THORIUM AND ANALYTICAL METHODOLOGIES
inferredcites →https://doi.org/10.3749/9780921294795openalex-snapshot
Recent and Not-so-recent Developments in Uranium Deposits and Implications for Exploration
inferredcites →https://doi.org/10.5382/av100.13openalex-snapshot
Iron Oxide Copper-Gold Deposits
inferredcites →https://doi.org/10.5382/sp.15.2.15openalex-snapshot
Geological Evolution and Exploration Geochemistry of the Boomerang Lake Unconformity-type Uranium Prospect, Northwest Territories, Canada
inferredcites →https://doi.org/10.70675/e9570cf8zacb2z4a58zb06fz353a44668a40openalex-snapshot
Etude expérimentale et modélisation, en fonction du pH et de la concentration en NaCl, du système ternaire U(VI)-NaCl-H2O à T = 155°C et pression de vapeur saturante

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

inferred← citeshttps://doi.org/10.2139/ssrn.4474232openalex-extracted
Graphite Does Not Function as a Direct Reducing Agent for Unconformity-Related Uranium Mineralization – Evidence from the Graphitic Metapelite-Hosted Gryphon Uranium Deposit, Northern Saskatchewan, Canada
inferred← citeshttps://doi.org/10.1002/9781394264841.ch3openalex-snapshot
The Unconformity‐related Uranium Mineral System of the Athabasca Basin (Canada)
inferred← citeshttps://doi.org/10.1007/s00126-023-01171-1openalex-snapshot
Spatial variations in fluid composition along structures hosting unconformity-related uranium deposits in the Athabasca Basin, Canada: implications for ore-controlling factors
inferred← citeshttps://doi.org/10.1007/s00126-024-01304-0openalex-snapshot
Relationship between U and Ni-Co-As mineralization in the Midwest polymetallic U deposit, Athabasca Basin (Canada) – constraints from mineralogical, geochemical, and fluid inclusion studies
inferred← citeshttps://doi.org/10.1007/s00126-025-01402-7openalex-snapshot
Structural network at the basement/cover interface reveals fluid overpressure associated with uranium mineralization in the Eastern Athabasca Basin (Saskatchewan, Canada)
inferred← citeshttps://doi.org/10.1007/s12517-022-10302-3openalex-snapshot
Uranium and graphite mineralization in metamorphic rocks in the Kangding complex (Datian area), southwestern Yangtze Platform, Western China
inferred← citeshttps://doi.org/10.1007/s12583-021-1532-xopenalex-snapshot
Classification of Sandstone-Related Uranium Deposits
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2018.05.042openalex-snapshot
Formation of U-rich mineralizing fluids through basinal brine migration within basement-hosted shear zones: A large-scale study of the fluid chemistry around the unconformity-related Cigar Lake U deposit (Saskatchewan, Canada)
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2023.121432openalex-snapshot
Re-evaluation of equilibrium relationships involving U6+/U4+ and Fe3+/Fe2+ in hydrothermal fluids and their implications for U mineralization
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2023.121764openalex-snapshot
Coupling of thermal convection and basin-basement fluid mixing is critical for the formation of unconformity-related uranium deposits: Insights from reactive transport modeling
inferred← citeshttps://doi.org/10.1016/j.chemgeo.2024.122456openalex-snapshot
Geochemical modeling of U-Ni-Co-As transport and deposition in acidic basinal brines: Implications for unconformity-related U-(Ni-Co-As) mineralization in the Athabasca Basin (Canada)
inferred← citeshttps://doi.org/10.1016/j.gca.2020.04.011openalex-snapshot
Evaluation of rammelsbergite (NiAs2) as a novel mineral for 187Re-187Os dating and implications for unconformity-related U deposits
inferred← citeshttps://doi.org/10.1016/j.gca.2025.03.031openalex-snapshot
Basin-scale production of hyperacidic brines is critical for the formation of high-grade and large-tonnage uranium deposits in sedimentary basins
inferred← citeshttps://doi.org/10.1016/j.jhazmat.2023.131222openalex-snapshot
Concurrent reductive decontamination of chromium (VI) and uranium (VI) in groundwater by Fe(0)-based autotrophic bioprocess
inferred← citeshttps://doi.org/10.1016/j.molliq.2023.123862openalex-snapshot
Recent advances in various adsorbents for the extraction of uranium from saline lakes: A review
inferred← citeshttps://doi.org/10.1016/j.oregeorev.2015.09.001openalex-snapshot
The Ranger uranium deposit, northern Australia: Timing constraints, regional and ore-related alteration, and genetic implications for unconformity-related mineralisation
inferred← citeshttps://doi.org/10.1016/j.oregeorev.2019.103085openalex-snapshot
Metallogeny of the Zoujiashan uranium deposit in the Mesozoic Xiangshan volcanic-intrusive complex, southeast China: Insights from chemical compositions of hydrothermal apatite and metal elements of individual fluid inclusions
inferred← citeshttps://doi.org/10.1016/j.oregeorev.2020.103579openalex-snapshot
Uranium deposits of Franceville basin (Gabon): Role of organic matter and oil cracking on uranium mineralization
inferred← citeshttps://doi.org/10.1016/j.oregeorev.2020.103794openalex-snapshot
Geochemical evolution and timing of uranium mineralization in the Khetri Copper Belt, western India
inferred← citeshttps://doi.org/10.1016/j.oregeorev.2025.106611openalex-snapshot
Characterization of primary geochemical halos for the Hetaoba volcanic-related uranium deposits in Duolun County, Inner Mongolia
inferred← citeshttps://doi.org/10.1016/j.oregeorev.2026.107406openalex-snapshot
Multistage pyrites and association with uranium mineralization in the Yingqian granite-related uranium deposit, South China
inferred← citeshttps://doi.org/10.1016/j.oreoa.2023.100028openalex-snapshot
Graphite does not function as a direct reducing agent for unconformity-related uranium mineralization – Evidence from the graphitic metapelite-hosted Gryphon uranium deposit, northern Saskatchewan, Canada
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Radiolytic (H2, O2) and other Trace Gases (CO2, CH4, C2H6, N2) in Fluid Inclusions from Unconformity-related U Deposits
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Independent and synergistic bio-reductions of uranium (VI) driven by zerovalent iron in aquifer
inferred← citeshttps://doi.org/10.1021/acsearthspacechem.3c00083openalex-snapshot
Iron and Sulfur Secondary Phases as Proxies of Aqueous Alteration on Chondrite Parent Bodies
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Deep Geological Controls on Formation of the Highest‐Grade Uranium Deposits in the World: Magnetotelluric Imaging of Unconformity‐Related Systems From the Athabasca Basin, Canada
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Ferrous Iron (Fe +2 ) Released From Iron‐Rich Chlorite as a Reductant for Unconformity‐Related Uranium Mineralization: Insights From Reactive Fluid Flow Modeling
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Deciphering the conditions of tochilinite and cronstedtite formation in CM chondrites from low temperature hydrothermal experiments
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inferred← citeshttps://doi.org/10.1144/geochem2021-023openalex-snapshot
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The role of graphite in the formation of unconformity-related uranium deposits of the Athabasca Basin, Canada: A case study of Raman spectroscopy of graphite from the world-class Phoenix uranium deposit
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inferred← citeshttps://doi.org/10.3390/min5040518openalex-snapshot
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Hydratation et évolution isotopique précoce des astéroïdes carbonés : approches expérimentale et isotopique
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