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New insights into the aquatic photochemistry of fluoroquinolone antibiotics: Direct photodegradation, hydroxyl-radical oxidation, and antibacterial activity changes

https://doi.org/10.1016/j.scitotenv.2015.04.099
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Environmental Organic Chemistry
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Primary photoproducts and half-lives
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Environmental photochemistry of fluoroquinolones in soil and in aqueous soil suspensions under solar light
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The kinetics of environmental aquatic photochemistry. Theory and practice
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The degradation of endocrine disruptor di-n-butyl phthalate by UV irradiation: A photolysis and product study
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Photolysis of Enrofloxacin in aqueous systems under simulated sunlight irradiation: Kinetics, mechanism and toxicity of photolysis products
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Tetracycline photolysis in natural waters: Loss of antibacterial activity
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Sunlight-induced degradation of soil-adsorbed veterinary antimicrobials Marbofloxacin and Enrofloxacin
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Different photolysis kinetics and photooxidation reactivities of neutral and anionic hydroxylated polybrominated diphenyl ethers
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Photolytic degradation of norfloxacin, enrofloxacin and ciprofloxacin in various aqueous media
inferredcites →https://doi.org/10.1016/j.chemosphere.2013.03.044openalex-snapshot
The distribution and partitioning of common antibiotics in water and sediment of the Pearl River Estuary, South China
inferredcites →https://doi.org/10.1016/j.chemosphere.2013.09.119openalex-snapshot
Occurrence and behavior of antibiotics in water and sediments from the Huangpu River, Shanghai, China
inferredcites →https://doi.org/10.1016/j.chemosphere.2014.04.052openalex-snapshot
Concentration-dependent photodegradation kinetics and hydroxyl-radical oxidation of phenicol antibiotics
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Photodegradation of salicylic acid in aquatic environment: Effect of different forms of nitrogen
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Light-induced catalytic transformation of ofloxacin by solar Fenton in various water matrices at a pilot plant: Mineralization and characterization of major intermediate products
inferredcites →https://doi.org/10.1016/j.watres.2010.03.002openalex-snapshot
Photolytic and photocatalytic decomposition of aqueous ciprofloxacin: Transformation products and residual antibacterial activity
inferredcites →https://doi.org/10.1016/j.watres.2012.07.043openalex-snapshot
Photodegradation of fluoroquinolones in surface water and antimicrobial activity of the photoproducts
inferredcites →https://doi.org/10.1016/j.watres.2012.10.025openalex-snapshot
Direct photochemistry of three fluoroquinolone antibacterials: Norfloxacin, ofloxacin, and enrofloxacin
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Photochemical degradation of sunscreen agent 2-phenylbenzimidazole-5-sulfonic acid in different water matrices
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Predicting photoreaction rates in surface waters
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Photochemistry of nitrite and nitrate in aqueous solution: a review
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Role of Dissolved Organic Matter, Nitrate, and Bicarbonate in the Photolysis of Aqueous Fipronil
inferredcites →https://doi.org/10.1021/es0353053openalex-snapshot
Photochemical Fate of Sulfa Drugs in the Aquatic Environment: Sulfa Drugs Containing Five-Membered Heterocyclic Groups
inferredcites →https://doi.org/10.1021/es048166dopenalex-snapshot
Oxidative Transformation of Fluoroquinolone Antibacterial Agents and Structurally Related Amines by Manganese Oxide
inferredcites →https://doi.org/10.1021/es048331popenalex-snapshot
Triplet-Sensitized Photodegradation of Sulfa Drugs Containing Six-Membered Heterocyclic Groups: Identification of an SO2 Extrusion Photoproduct
inferredcites →https://doi.org/10.1021/es050054eopenalex-snapshot
Interactions of Fluoroquinolone Antibacterial Agents with Aqueous Chlorine: Reaction Kinetics, Mechanisms, and Transformation Pathways
inferredcites →https://doi.org/10.1021/es050895lopenalex-snapshot
Fate and Effects of Enrofloxacin in Aquatic Systems under Different Light Conditions
inferredcites →https://doi.org/10.1021/es051443bopenalex-snapshot
Role of Fe(III), Phosphate, Dissolved Organic Matter, and Nitrate during the Photodegradation of Domoic Acid in the Marine Environment
inferredcites →https://doi.org/10.1021/es060337mopenalex-snapshot
Water Hardness as a Photochemical Parameter: Tetracycline Photolysis as a Function of Calcium Concentration, Magnesium Concentration, and pH
inferredcites →https://doi.org/10.1021/es060502yopenalex-snapshot
Photodegradation Processes of the Antiepileptic Drug Carbamazepine, Relevant To Estuarine Waters
inferredcites →https://doi.org/10.1021/es0606778openalex-snapshot
Aquatic Photochemistry of Nitrofuran Antibiotics
inferredcites →https://doi.org/10.1021/es070097qopenalex-snapshot
Visible-Light-Mediated TiO2 Photocatalysis of Fluoroquinolone Antibacterial Agents
inferredcites →https://doi.org/10.1021/es100278nopenalex-snapshot
Photochemical Degradation of Marbofloxacin and Enrofloxacin in Natural Waters
inferredcites →https://doi.org/10.1021/es104009sopenalex-snapshot
Occurrence and Transport of Tetracycline, Sulfonamide, Quinolone, and Macrolide Antibiotics in the Haihe River Basin, China
inferredcites →https://doi.org/10.1021/es3052685openalex-snapshot
Kinetics and Modeling of Degradation of Ionophore Antibiotics by UV and UV/H2O2
inferredcites →https://doi.org/10.1021/es400425bopenalex-snapshot
Distinct Photolytic Mechanisms and Products for Different Dissociation Species of Ciprofloxacin
inferredcites →https://doi.org/10.1021/es402472xopenalex-snapshot
Degradation of Antibiotic Activity during UV/H2O2 Advanced Oxidation and Photolysis in Wastewater Effluent
inferredcites →https://doi.org/10.1021/es402662gopenalex-snapshot
Evidence and Recommendations to Support the Use of a Novel Passive Water Sampler to Quantify Antibiotics in Wastewaters
inferredcites →https://doi.org/10.1021/es5023834openalex-snapshot
Role of Dissolved Organic Matter in Ice Photochemistry
inferredcites →https://doi.org/10.1021/es8000689openalex-snapshot
Ozonation of Ciprofloxacin in Water: HRMS Identification of Reaction Products and Pathways
inferredcites →https://doi.org/10.1021/es8031727openalex-snapshot
Light-Source-Dependent Effects of Main Water Constituents on Photodegradation of Phenicol Antibiotics: Mechanism and Kinetics
inferredcites →https://doi.org/10.1021/es900811copenalex-snapshot
Formation of Chlorinated Intermediate from Bisphenol A in Surface Saline Water under Simulated Solar Light Irradiation
inferredcites →https://doi.org/10.1021/es902852vopenalex-snapshot
Aquatic Photochemistry of Fluoroquinolone Antibiotics: Kinetics, Pathways, and Multivariate Effects of Main Water Constituents
inferredcites →https://doi.org/10.1093/toxsci/kfr132openalex-snapshot
Characterization of Novel Ligands of ERα, Erβ, and PPARγ: The Case of Halogenated Bisphenol A and Their Conjugated Metabolites
inferredcites →https://doi.org/10.1126/science.1127291openalex-snapshot
The Challenge of Micropollutants in Aquatic Systems
inferredcites →https://doi.org/10.1897/05-384r.1openalex-snapshot
Changes in antibacterial activity of triclosan and sulfa drugs due to photochemical transformations

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Degradation of enoxacin with different dissociated species during the transformation of ferrihydrite-antibiotic coprecipitates
inferred← citeshttps://doi.org/10.1016/j.scitotenv.2025.181143openalex-snapshot
Temporal dynamics of lake microbiota under nanoplastic and enrofloxacin stress
inferred← citeshttps://doi.org/10.1016/j.seppur.2023.125822openalex-snapshot
Boosting the activation of peroxydisulfate and the degradation of ofloxacin over polyaniline-derived N/B co-doped carbon through electron transfer dominated oxidation processes
inferred← citeshttps://doi.org/10.1016/j.seppur.2024.129533openalex-snapshot
Peroxymonosulfate activation by mineralized PVDF-TA@Co template based ZIF-67/8 electrospinning membranes for ofloxacin degradation under visible-light
inferred← citeshttps://doi.org/10.1016/j.seppur.2026.137193openalex-snapshot
Chemical scavengers as probes for mechanistic elucidation in persulfate-based advanced oxidation processes: Insights into their accuracy and reliability
inferred← citeshttps://doi.org/10.1016/j.watres.2018.10.027openalex-snapshot
Influence of chemical speciation on photochemical transformation of three fluoroquinolones (FQs) in water: Kinetics, mechanism, and toxicity of photolysis products
inferred← citeshttps://doi.org/10.1016/j.watres.2018.11.009openalex-snapshot
The importance of reactive oxygen species on the aqueous phototransformation of sulfonamide antibiotics: kinetics, pathways, and comparisons with direct photolysis
inferred← citeshttps://doi.org/10.1016/j.watres.2019.115083openalex-snapshot
Rate constants of hydroxyl radicals reaction with different dissociation species of fluoroquinolones and sulfonamides: Combined experimental and QSAR studies
inferred← citeshttps://doi.org/10.1016/j.watres.2025.124277openalex-snapshot
Hydrophilicity-dependent photodegradation of antibiotics in ice: Freeze-concentration effects and dissolved organic matter interactions drive divergent kinetics, pathways and toxicity
inferred← citeshttps://doi.org/10.1021/acs.est.4c01141openalex-snapshot
Deciphering the Role of Microbial Extracellular and Intracellular Organic Matter in Antibiotic Photodissipation: Molecular and Fluorescent Profiling under Natural Radiation
inferred← citeshttps://doi.org/10.1021/acs.est.4c03206openalex-snapshot
Solar Photodegradation of a Novel des-F(6)-Fluoroquinolone, Garenoxacin, and Ecotoxicity of Its Phototransformation Products
inferred← citeshttps://doi.org/10.1021/acs.jafc.9b05908openalex-snapshot
Photolysis-Induced Neurotoxicity Enhancement of Chlorpyrifos in Aquatic System: A Case Investigation on Caenorhabditis elegans
inferred← citeshttps://doi.org/10.1021/acsabm.1c00749openalex-snapshot
[Ru(bpy)3]2+@Ce-UiO-66/Mn:Bi2S3 Heterojunction and Its Exceptional Photoelectrochemical Aptasensing Properties for Ofloxacin Detection
inferred← citeshttps://doi.org/10.1021/acsomega.0c05370openalex-snapshot
Fluorescence Spectroscopy and Chemometrics: A Simple and Easy Way for the Monitoring of Fluoroquinolone Mixture Degradation
inferred← citeshttps://doi.org/10.1021/acsomega.2c00523openalex-snapshot
Facile Fabrication of Durable Biochar/H2-TiO2 for Highly Efficient Solar-Driven Degradation of Enrofloxacin: Properties, Degradation Pathways, and Mechanism
inferred← citeshttps://doi.org/10.1021/acsomega.9b03270openalex-snapshot
Preparation of an Antidanofloxacin Monoclonal Antibody and Development of Immunoassays for Detecting Danofloxacin in Meat
inferred← citeshttps://doi.org/10.1021/bk-2024-1476.ch003openalex-snapshot
Photodegradation of Emerging Contaminants in Water
inferred← citeshttps://doi.org/10.1038/s41598-019-40201-9openalex-snapshot
The degradation of levofloxacin in infusions exposed to daylight with an identification of a degradation product with HPLC-MS
inferred← citeshttps://doi.org/10.1038/s41598-024-51485-xopenalex-snapshot
Research progress on composite material of bismuth vanadate catalyzing the decomposition of Quinolone antibiotics
inferred← citeshttps://doi.org/10.1038/s44221-026-00663-4openalex-snapshot
Antibiotic transformation products exert selective pressure for antimicrobial resistance comparable to parent compounds
inferred← citeshttps://doi.org/10.1039/c7dt04360kopenalex-snapshot
Facile synthesis of carbon quantum dots loaded with mesoporous g-C 3 N 4 for synergistic absorption and visible light photodegradation of fluoroquinolone antibiotics
inferred← citeshttps://doi.org/10.1039/c7em00111hopenalex-snapshot
Study of the simulated sunlight photolysis mechanism of ketoprofen: the role of superoxide anion radicals, transformation byproducts, and ecotoxicity assessment
inferred← citeshttps://doi.org/10.1039/c7nj02053hopenalex-snapshot
Visible light driven photocatalytic degradation of fluoroquinolone levofloxacin drug using Ag 2 O/TiO 2 quantum dots: a mechanistic study and degradation pathway
inferred← citeshttps://doi.org/10.1039/c7nj05118bopenalex-snapshot
Solar light driven photocatalytic degradation of levofloxacin using TiO 2 /carbon-dot nanocomposites
inferred← citeshttps://doi.org/10.1039/c7ra09564copenalex-snapshot
Photolysis of sulfamethazine using UV irradiation in an aqueous medium
inferred← citeshttps://doi.org/10.1039/c8ra01237gopenalex-snapshot
Photo-reduction of heavy metal ions and photo-disinfection of pathogenic bacteria under simulated solar light using photosensitized TiO 2 nanofibers
inferred← citeshttps://doi.org/10.1039/d2ew00082bopenalex-snapshot
Essential role of sunlight irradiation in aqueous micropollutant transformations: influence of the water matrix and changes in toxicities
inferred← citeshttps://doi.org/10.1039/d4cy00906aopenalex-snapshot
Modification of porous bismuth molybdate for high removal of antibiotics and H 2 O 2 production
inferred← citeshttps://doi.org/10.1039/d5ew00686dopenalex-snapshot
UV/O 3 degradation of norfloxacin in complex lake and reservoir water matrices: performance, mechanisms, and pilot-scale verification
inferred← citeshttps://doi.org/10.1080/00319104.2016.1250270openalex-snapshot
Study on the inclusion interaction of p-sulfonatocalix[n]arenes with norfloxacin
inferred← citeshttps://doi.org/10.1080/02772248.2019.1687706openalex-snapshot
Determination of minimum inhibitory concentration and half maximal inhibitory concentration of antibiotics and their degradation products to assess the eco-toxicological potential
inferred← citeshttps://doi.org/10.1080/21655979.2021.1974657openalex-snapshot
Antibiotics: An overview on the environmental occurrence, toxicity, degradation, and removal methods
inferred← citeshttps://doi.org/10.1098/rsos.171457openalex-snapshot
Photocatalytic degradation of sulfamethazine in aqueous solution using ZnO with different morphologies
inferred← citeshttps://doi.org/10.1098/rsos.221086openalex-snapshot
Green approach for tracking the photofate of ciprofloxacin and levofloxacin in different matrices adopting synchronous fluorescence spectroscopy: a kinetic study
inferred← citeshttps://doi.org/10.1098/rsos.250891openalex-snapshot
Photolysis of fluoroquinolone antibiotics in aquatic environments: mechanisms, influencing factors and environmental implications—a mini review
inferred← citeshttps://doi.org/10.1128/spectrum.01611-24openalex-snapshot
Complete degradation of polycyclic antibiotic methacycline by a micro/nanostructured biogenic Mn oxide composite from engineered Mn(II)-oxidizing Pseudomonas sp. MB04B
inferred← citeshttps://doi.org/10.1360/n972016-00140openalex-snapshot
Kinetics and pathways for aqueous ROS photooxidation of sulfamethazine
inferred← citeshttps://doi.org/10.20546/ijcmas.2016.506.080openalex-snapshot
UV and Solar Degradation of Ofloxacin Antibiotic
inferred← citeshttps://doi.org/10.2139/ssrn.4868065openalex-snapshot
Peroxymonosulfate Activation By Mineralized Pvdf-Ta@Co Template Based Zif-67/8 Electrospinning Membranes For Ofloxacin Degradation Under Visible-Light
inferred← citeshttps://doi.org/10.2139/ssrn.5247903openalex-snapshot
Bactericidal Action of Impregnated Ag/Tio2 Catalysts Mediated by Reactive Oxygen Species Under Black Light Irradiation
inferred← citeshttps://doi.org/10.2166/wst.2017.531openalex-snapshot
Reuse and recovery of raw hospital wastewater containing ofloxacin after photocatalytic treatment with nano graphene oxide magnetite
inferred← citeshttps://doi.org/10.2903/j.efsa.2023.8194openalex-snapshot
Guidance document on the impact of water treatment processes on residues of active substances or their metabolites in water abstracted for the production of drinking water
inferred← citeshttps://doi.org/10.3233/mgc-220104openalex-snapshot
Nano-CuOx for ciprofloxacin effective removal via wet peroxide oxidation catalysis and its practical application in wastewater
inferred← citeshttps://doi.org/10.3390/antibiotics12050932openalex-snapshot
Performance of a Pilot-Scale Continuous Flow Ozone-Based Hospital Wastewater Treatment System
inferred← citeshttps://doi.org/10.3390/catal12111336openalex-snapshot
A Study of the Degradation of LEV by Transparent PVA/NCD-TiO2 Nanocomposite Films with Enhanced Visible-Light Photocatalytic Activity
inferred← citeshttps://doi.org/10.3390/compounds5020023openalex-snapshot
Critical Effect of Oxygen Concentration and Acidity on the Efficiency of Photodegradation of Levofloxacin with Solar UVB Light; Cytotoxicity on Mammalian Cells of the Photoproducts and Its Activity on Pathogenic Bacteria
inferred← citeshttps://doi.org/10.3390/ma14226814openalex-snapshot
Electrocatalytic Degradation of Levofloxacin, a Typical Antibiotic in Hospital Wastewater
inferred← citeshttps://doi.org/10.3390/molecules27206956openalex-snapshot
rGO-WO3 Heterostructure: Synthesis, Characterization and Utilization as an Efficient Adsorbent for the Removal of Fluoroquinolone Antibiotic Levofloxacin in an Aqueous Phase
inferred← citeshttps://doi.org/10.3390/molecules28020777openalex-snapshot
Use of Fluorescence Spectroscopy and Chemometrics to Visualise Fluoroquinolones Photodegradation Major Trends: A Confirmation Study with Mass Spectrometry
inferred← citeshttps://doi.org/10.3390/molecules29245982openalex-snapshot
The Photocatalytic Degradation of Enrofloxacin Using an Ecofriendly Natural Iron Mineral: The Relationship Between the Degradation Routes, Generated Byproducts, and Antimicrobial Activity of Treated Solutions
inferred← citeshttps://doi.org/10.3390/nano10050910openalex-snapshot
Bi2WO6/C-Dots/TiO2: A Novel Z-Scheme Photocatalyst for the Degradation of Fluoroquinolone Levofloxacin from Aqueous Medium
inferred← citeshttps://doi.org/10.3390/nano11071660openalex-snapshot
Complete Degradation and Detoxification of Ciprofloxacin by a Micro-/Nanostructured Biogenic Mn Oxide Composite from a Highly Active Mn2+-Oxidizing Pseudomonas Strain
inferred← citeshttps://doi.org/10.3390/toxics10010035openalex-snapshot
Use of Nanotechnology to Mitigate Biofouling in Stainless Steel Devices Used in Food Processing, Healthcare, and Marine Environments
inferred← citeshttps://doi.org/10.3390/toxics9080194openalex-snapshot
Antibiotics in Aquaculture Wastewater: Is It Feasible to Use a Photodegradation-Based Treatment for Their Removal?
inferred← citeshttps://doi.org/10.3390/w14213403openalex-snapshot
Combined Effects of Polystyrene Nanoplastics and Enrofloxacin on the Life Histories and Gut Microbiota of Daphnia magna
inferred← citeshttps://doi.org/10.4491/eer.2020.524openalex-snapshot
Photocatalytic degradation of flumequine by N-doped TiO2 catalysts under simulated sunlight
inferred← citeshttps://doi.org/10.4995/thesis/10251/177357openalex-snapshot
Emerging Photochemical Processes Involving Iron for Wastewater Treatment
inferred← citeshttps://doi.org/10.70675/175ffe7az37a5z4323zaed1ze2c6526c5711openalex-snapshot
Photodegradation of contaminants of emerging concern in environmental matrices : a new holistic perspective to complete the laboratory modeling approach
inferred← citeshttps://doi.org/10.70675/28beabbdz2f85z4cd9z8a6ezf86f2fbec0a6openalex-snapshot
An Integrated approach for identifying contaminants of concern in environment
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