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Hole Trapping in Halide Perovskites Induces Phase Segregation

https://doi.org/10.1021/accountsmr.2c00076
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Unique Properties of Halide Perovskites as Possible Origins of the Superior Solar Cell Performance
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Bright Light‐Emitting Diodes Based on Organometal Halide Perovskite Nanoplatelets
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Improving the Stability of Metal Halide Perovskite Materials and Light‐Emitting Diodes
inferredcites →https://doi.org/10.1002/adma.202105585openalex-snapshot
Photoinduced Halide Segregation in Ruddlesden–Popper 2D Mixed Halide Perovskite Films
inferredcites →https://doi.org/10.1002/admi.201500195openalex-snapshot
Silver Iodide Formation in Methyl Ammonium Lead Iodide Perovskite Solar Cells with Silver Top Electrodes
inferredcites →https://doi.org/10.1002/adom.202001440openalex-snapshot
Photoinduced Phase Segregation in Mixed Halide Perovskites: Thermodynamic and Kinetic Aspects of Cl–Br Segregation
inferredcites →https://doi.org/10.1002/aenm.202002614openalex-snapshot
Incorporating Electrochemical Halide Oxidation into Drift‐Diffusion Models to Explain Performance Losses in Perovskite Solar Cells under Prolonged Reverse Bias
inferredcites →https://doi.org/10.1002/aenm.202002934openalex-snapshot
Reversible Pb2+/Pb0 and I−/I3− Redox Chemistry Drives the Light‐Induced Phase Segregation in All‐Inorganic Mixed Halide Perovskites
inferredcites →https://doi.org/10.1016/j.isci.2020.101415openalex-snapshot
Inhibition of Phase Segregation in Cesium Lead Mixed-Halide Perovskites by B-Site Doping
inferredcites →https://doi.org/10.1016/j.joule.2021.07.011openalex-snapshot
The role of halide oxidation in perovskite halide phase separation
inferredcites →https://doi.org/10.1016/j.trechm.2020.01.010openalex-snapshot
Photoinduced Anion Segregation in Mixed Halide Perovskites
inferredcites →https://doi.org/10.1016/j.trechm.2020.10.010openalex-snapshot
Carrier Dynamics and Evaluation of Lasing Actions in Halide Perovskites
inferredcites →https://doi.org/10.1016/s0898-8838(08)60194-4openalex-snapshot
Reduction Potentials Involving Inorganic Free Radicals in Aqueous Solution
inferredcites →https://doi.org/10.1021/acs.chemmater.0c02100openalex-snapshot
How Chloride Suppresses Photoinduced Phase Segregation in Mixed Halide Perovskites
inferredcites →https://doi.org/10.1021/acs.chemmater.6b00847openalex-snapshot
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors
inferredcites →https://doi.org/10.1021/acs.jpcc.6b11853openalex-snapshot
Light-Induced Degradation of CH3NH3PbI3 Hybrid Perovskite Thin Film
inferredcites →https://doi.org/10.1021/acs.jpclett.1c00367openalex-snapshot
Modulation of Photoinduced Iodine Expulsion in Mixed Halide Perovskites with Electrochemical Bias
inferredcites →https://doi.org/10.1021/acs.jpclett.6b00002openalex-snapshot
Cesium Lead Halide Perovskites with Improved Stability for Tandem Solar Cells
inferredcites →https://doi.org/10.1021/acs.jpclett.6b02375openalex-snapshot
Iodine Migration and Degradation of Perovskite Solar Cells Enhanced by Metallic Electrodes
inferredcites →https://doi.org/10.1021/acs.jpclett.8b01512openalex-snapshot
Tunable Polaron Distortions Control the Extent of Halide Demixing in Lead Halide Perovskites
inferredcites →https://doi.org/10.1021/acs.nanolett.5b04884openalex-snapshot
High Photoluminescence Quantum Yield in Band Gap Tunable Bromide Containing Mixed Halide Perovskites
inferredcites →https://doi.org/10.1021/acs.nanolett.6b04453openalex-snapshot
Origin of Reversible Photoinduced Phase Separation in Hybrid Perovskites
inferredcites →https://doi.org/10.1021/acs.nanolett.8b00505openalex-snapshot
Local Observation of Phase Segregation in Mixed-Halide Perovskite
inferredcites →https://doi.org/10.1021/acsami.7b06816openalex-snapshot
Light and Electrically Induced Phase Segregation and Its Impact on the Stability of Quadruple Cation High Bandgap Perovskite Solar Cells
inferredcites →https://doi.org/10.1021/acsenergylett.0c00925openalex-snapshot
Iodine (I) Expulsion at Photoirradiated Mixed Halide Perovskite Interface. Should I Stay or Should I Go?
inferredcites →https://doi.org/10.1021/acsenergylett.0c01474openalex-snapshot
Lattice Compression Increases the Activation Barrier for Phase Segregation in Mixed-Halide Perovskites
inferredcites →https://doi.org/10.1021/acsenergylett.0c02475openalex-snapshot
Halide Segregation in Mixed-Halide Perovskites: Influence of A-Site Cations
inferredcites →https://doi.org/10.1021/acsenergylett.6b00158openalex-snapshot
Tracking Iodide and Bromide Ion Segregation in Mixed Halide Lead Perovskites during Photoirradiation
inferredcites →https://doi.org/10.1021/acsenergylett.6b00495openalex-snapshot
Light-Induced Phase Segregation in Halide-Perovskite Absorbers
inferredcites →https://doi.org/10.1021/acsenergylett.7b00282openalex-snapshot
Defect-Assisted Photoinduced Halide Segregation in Mixed-Halide Perovskite Thin Films
inferredcites →https://doi.org/10.1021/acsenergylett.7b00357openalex-snapshot
Shift Happens . How Halide Ion Defects Influence Photoinduced Segregation in Mixed Halide Perovskites
inferredcites →https://doi.org/10.1021/acsenergylett.7b00442openalex-snapshot
Suppressed Ion Migration in Low-Dimensional Perovskites
inferredcites →https://doi.org/10.1021/acsenergylett.7b00525openalex-snapshot
Current-Induced Phase Segregation in Mixed Halide Hybrid Perovskites and its Impact on Two-Terminal Tandem Solar Cell Design
inferredcites →https://doi.org/10.1021/acsenergylett.7b00589openalex-snapshot
A Victim of Halide Ion Segregation. How Light Soaking Affects Solar Cell Performance of Mixed Halide Lead Perovskites
inferredcites →https://doi.org/10.1021/acsenergylett.7b01134openalex-snapshot
Hybrid Perovskites for Multijunction Tandem Solar Cells and Solar Fuels. A Virtual Issue
inferredcites →https://doi.org/10.1021/acsenergylett.7b01151openalex-snapshot
Light-Induced Anion Phase Segregation in Mixed Halide Perovskites
inferredcites →https://doi.org/10.1021/acsenergylett.8b00047openalex-snapshot
Suppressed Ion Migration along the In-Plane Direction in Layered Perovskites
inferredcites →https://doi.org/10.1021/acsenergylett.8b01369openalex-snapshot
Vacancy-Mediated Anion Photosegregation Kinetics in Mixed Halide Hybrid Perovskites: Coupled Kinetic Monte Carlo and Optical Measurements
inferredcites →https://doi.org/10.1021/acsenergylett.8b01562openalex-snapshot
Impact of Surfaces on Photoinduced Halide Segregation in Mixed-Halide Perovskites
inferredcites →https://doi.org/10.1021/acsenergylett.8b02002openalex-snapshot
Electronic Traps and Phase Segregation in Lead Mixed-Halide Perovskite
inferredcites →https://doi.org/10.1021/acsenergylett.9b00892openalex-snapshot
Suppressed Ion Migration in Reduced-Dimensional Perovskites Improves Operating Stability
inferredcites →https://doi.org/10.1021/acsenergylett.9b01280openalex-snapshot
Bidirectional Halide Ion Exchange in Paired Lead Halide Perovskite Films with Thermal Activation
inferredcites →https://doi.org/10.1021/acsenergylett.9b02265openalex-snapshot
How Interplay between Photo and Thermal Activation Dictates Halide Ion Segregation in Mixed Halide Perovskites
inferredcites →https://doi.org/10.1021/acsnano.0c08897openalex-snapshot
Spectral Instability of Layered Mixed Halide Perovskites Results from Anion Phase Redistribution and Selective Hole Injection
inferredcites →https://doi.org/10.1021/jacs.0c00434openalex-snapshot
TiO 2 -Assisted Halide Ion Segregation in Mixed Halide Perovskite Films
inferredcites →https://doi.org/10.1021/jacs.0c10348openalex-snapshot
Photocorrosion at Irradiated Perovskite/Electrolyte Interfaces
inferredcites →https://doi.org/10.1021/jacs.2c02148openalex-snapshot
How Hole Injection Accelerates Both Ion Migration and Nonradiative Recombination in Metal Halide Perovskites
inferredcites →https://doi.org/10.1021/jacs.5b03796openalex-snapshot
2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications
inferredcites →https://doi.org/10.1021/jacs.6b04661openalex-snapshot
Transformation of Sintered CsPbBr3 Nanocrystals to Cubic CsPbI3 and Gradient CsPbBr x I3– x through Halide Exchange
inferredcites →https://doi.org/10.1021/jacs.6b10049openalex-snapshot
Intrinsic Halide Segregation at Nanometer Scale Determines the High Efficiency of Mixed Cation/Mixed Halide Perovskite Solar Cells
inferredcites →https://doi.org/10.1021/jacs.7b02817openalex-snapshot
Essentially Trap-Free CsPbBr3 Colloidal Nanocrystals by Postsynthetic Thiocyanate Surface Treatment
inferredcites →https://doi.org/10.1021/jacs.9b04568openalex-snapshot
Electrochemical Hole Injection Selectively Expels Iodide from Mixed Halide Perovskite Films
inferredcites →https://doi.org/10.1021/nl400349bopenalex-snapshot
Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells
inferredcites →https://doi.org/10.1038/nature25989openalex-snapshot
Maximizing and stabilizing luminescence from halide perovskites with potassium passivation
inferredcites →https://doi.org/10.1038/nnano.2015.90openalex-snapshot
Metal-halide perovskites for photovoltaic and light-emitting devices
inferredcites →https://doi.org/10.1038/s41467-017-00284-2openalex-snapshot
Rationalizing the light-induced phase separation of mixed halide organic–inorganic perovskites
inferredcites →https://doi.org/10.1038/s41467-019-08610-6openalex-snapshot
Suppressed phase separation of mixed-halide perovskites confined in endotaxial matrices
inferredcites →https://doi.org/10.1038/s41563-018-0038-0openalex-snapshot
Large tunable photoeffect on ion conduction in halide perovskites and implications for photodecomposition
inferredcites →https://doi.org/10.1038/s41586-020-2219-7openalex-snapshot
Two-dimensional halide perovskite lateral epitaxial heterostructures
inferredcites →https://doi.org/10.1039/c3ee43161dopenalex-snapshot
The origin of high efficiency in low-temperature solution-processable bilayer organometal halide hybrid solar cells
inferredcites →https://doi.org/10.1039/c4ee00168kopenalex-snapshot
Interface energetics in organo-metal halide perovskite-based photovoltaic cells
inferredcites →https://doi.org/10.1039/c4sc03141eopenalex-snapshot
Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics
inferredcites →https://doi.org/10.1039/c5ee01265aopenalex-snapshot
Defect migration in methylammonium lead iodide and its role in perovskite solar cell operation
inferredcites →https://doi.org/10.1039/c6ee03014aopenalex-snapshot
Photovoltaic mixed-cation lead mixed-halide perovskites: links between crystallinity, photo-stability and electronic properties
inferredcites →https://doi.org/10.1039/c6ee03352kopenalex-snapshot
Migration of cations induces reversible performance losses over day/night cycling in perovskite solar cells
inferredcites →https://doi.org/10.1103/physrevapplied.5.014012openalex-snapshot
Optical Transitions in Hybrid Perovskite Solar Cells: Ellipsometry, Density Functional Theory, and Quantum Efficiency Analyses for CH 3 NH 3 PbI 3
inferredcites →https://doi.org/10.1103/physrevb.67.155405openalex-snapshot
Electronic structures of lead iodide based low-dimensional crystals
inferredcites →https://doi.org/10.1126/science.1243982openalex-snapshot
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
inferredcites →https://doi.org/10.1126/science.aad5845openalex-snapshot
A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells
inferredcites →https://doi.org/10.1126/science.aaz5074openalex-snapshot
Triple-halide wide–band gap perovskites with suppressed phase segregation for efficient tandems

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Surface Doping Boosts Triplet Generation Yield in Perovskite‐Sensitized Upconversion
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Light‐Induced Frenkel Defect Pair Formation Can Lead to Phase‐Segregation of Otherwise Miscible Halide Perovskite Alloys
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Photolysis of Mixed Halide Perovskite Nanocrystals
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Ramifications of Ion Migration in 2D Lead Halide Perovskites
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Role of Trapped Carriers Dynamics in Operating Lead Halide Wide-Bandgap Perovskite Solar Cells
inferred← citeshttps://doi.org/10.1021/acsenergylett.4c00736openalex-snapshot
Charge Transfer Kinetics in Halide Perovskites: On the Constraints of Time-Resolved Spectroscopy Measurements
inferred← citeshttps://doi.org/10.1021/acsenergylett.4c02546openalex-snapshot
Ionic Lockdown: Sealing Migration Channels across Device Interfaces in Mixed Halide Perovskite Solar Cells
inferred← citeshttps://doi.org/10.1021/acsenergylett.4c03073openalex-snapshot
Rationalizing Light-Induced Phase Segregation Reversal by Halide Oxidation and Diffusion in Mixed Halide Perovskites
inferred← citeshttps://doi.org/10.1021/acsenergylett.5c02199openalex-snapshot
Iodine’s Wild Ride Leading to Photoinstability in Halide Perovskite Solar Cells
inferred← citeshttps://doi.org/10.1021/acsenergylett.5c03033openalex-snapshot
Fables and Facts about Halide Perovskites, “Miracle” Energy Materials
inferred← citeshttps://doi.org/10.1021/acsenergylett.5c03731openalex-snapshot
Tunable n- and p-Type Behavior of Ruddlesden–Popper and Dion–Jacobson 2D Perovskites
inferred← citeshttps://doi.org/10.1021/acsenergylett.5c04123openalex-snapshot
Finite Size Effects on Light-Induced Correlated Ionic and Electronic Transport in Mixed Halide Perovskites
inferred← citeshttps://doi.org/10.1021/acsenergylett.6c01666openalex-snapshot
Top-Interface Molecular Engineering with Carbazoles Mitigates Phase Segregation in Mixed-Halide Perovskite Solar Cells
inferred← citeshttps://doi.org/10.1021/acsnano.2c10781openalex-snapshot
Excitation Intensity- and Size-Dependent Halide Photosegregation in CsPb(I0.5Br0.5)3 Perovskite Nanocrystals
inferred← citeshttps://doi.org/10.1021/acsnano.3c07165openalex-snapshot
Modeling the Photoelectrochemical Evolution of Lead-Based, Mixed-Halide Perovskites Due to Photosegregation
inferred← citeshttps://doi.org/10.1021/acsnano.5c01423openalex-snapshot
Hole Trapping in Lead Halide Perovskite Nanocrystal–Viologen Hybrids and Its Impact on Back Electron Transfer
inferred← citeshttps://doi.org/10.1021/acsnano.6c05416openalex-snapshot
Dynamic Ion Migration in 2D Halide Perovskites
inferred← citeshttps://doi.org/10.1021/jacs.3c03539openalex-snapshot
Origins of Photoluminescence Instabilities at Halide Perovskite/Organic Hole Transport Layer Interfaces
inferred← citeshttps://doi.org/10.1021/jacs.4c03669openalex-snapshot
Structural Evolution and Photoluminescence Quenching across the FASnI 3– x Br x ( x = 0–3) Perovskites
inferred← citeshttps://doi.org/10.1021/jacs.5c15574openalex-snapshot
Surface Passivation for Halide Optoelectronics: Comparing Optimization and Reactivity of Amino-Silanes with Formamidinium
inferred← citeshttps://doi.org/10.1038/s41467-024-46044-xopenalex-snapshot
Toward stabilization of formamidinium lead iodide perovskites by defect control and composition engineering
inferred← citeshttps://doi.org/10.1038/s41560-024-01451-8openalex-snapshot
Redox mediator-stabilized wide-bandgap perovskites for monolithic perovskite-organic tandem solar cells
inferred← citeshttps://doi.org/10.1038/s41560-026-01965-3openalex-snapshot
Irreversible organic cations chemistry limits organic–inorganic halide perovskite stability under illumination or bias
inferred← citeshttps://doi.org/10.1038/s41565-026-02165-6openalex-snapshot
Chemical hardness engineering synchronizes crystallization in perovskite tandems
inferred← citeshttps://doi.org/10.1038/s41578-023-00582-wopenalex-snapshot
Long-term operating stability in perovskite photovoltaics
inferred← citeshttps://doi.org/10.1038/s41578-023-00642-1openalex-snapshot
Perovskite–organic tandem solar cells
inferred← citeshttps://doi.org/10.1038/s41893-025-01529-5openalex-snapshot
Reductive cation for scalable wide-bandgap perovskite solar cells in ambient air
inferred← citeshttps://doi.org/10.1039/d2nr05767kopenalex-snapshot
Generating spin-triplet states at the bulk perovskite/organic interface for photon upconversion
inferred← citeshttps://doi.org/10.1039/d4cc06377eopenalex-snapshot
Dual-locking strategy with a charge-delocalizing ligand for stable perovskites
inferred← citeshttps://doi.org/10.1039/d4sc07955hopenalex-snapshot
Advancements and prospects for eco-friendly, high-performance silver bismuth halide solar cells
inferred← citeshttps://doi.org/10.1039/d4ta07807aopenalex-snapshot
Light-induced degradation of mixed-cation, mixed-halide perovskite: observed rates and influence of oxygen
inferred← citeshttps://doi.org/10.1039/d4tc02975eopenalex-snapshot
Has the perovskite LED stability problem been solved?
inferred← citeshttps://doi.org/10.1039/d5ee06683bopenalex-snapshot
Photostable wide-bandgap perovskites with enhanced interface coupling for all-perovskite tandems
inferred← citeshttps://doi.org/10.1039/d5sc06511aopenalex-snapshot
Design principles of spacer cations for suppressing phase segregation in 2D halide perovskites
inferred← citeshttps://doi.org/10.1039/d5se00426hopenalex-snapshot
Grain boundary passivation as an optimal strategy for perovskite solar cells with improved stability
inferred← citeshttps://doi.org/10.1039/d6ta02861fopenalex-snapshot
Suppressing halide phase segregation in wide-bandgap perovskites via iodide immobilization for perovskite–organic tandem solar cells
inferred← citeshttps://doi.org/10.1039/d6ta03326aopenalex-snapshot
Understanding halide segregation in metal halide perovskites through defect thermodynamics
inferred← citeshttps://doi.org/10.1039/d6ta04887kopenalex-snapshot
Spacer-induced 2D/3D molecular modulation engineering unlocks >25% efficient and long-term stable inverted wide-bandgap perovskite solar cells
inferred← citeshttps://doi.org/10.1063/5.0155845openalex-snapshot
Outdoor stability testing of perovskite solar cells: Necessary step toward real-life applications
inferred← citeshttps://doi.org/10.1063/5.0190465openalex-snapshot
Impact of photoinduced phase segregation in mixed-halide perovskite absorbers on their material and device stability
inferred← citeshttps://doi.org/10.1063/5.0285567openalex-snapshot
Interfacial energy-level engineering with bilayer hole transport layers for suppressing phase separation in mixed-halide perovskites
inferred← citeshttps://doi.org/10.1063/5.0287683openalex-snapshot
Deconstructing the dynamic loop of phase segregation in mixed-halide perovskites
inferred← citeshttps://doi.org/10.1109/icsict62049.2024.10830944openalex-snapshot
Pseudo-Parallel Symmetrical and Crossed Perovskite Solar Cells for Bifacial Applications
inferred← citeshttps://doi.org/10.1117/12.3002090openalex-snapshot
Nickel oxide hole transport layer engineering for mitigation of photo segregation in mixed halide organic-inorganic lead halide perovskites
inferred← citeshttps://doi.org/10.1126/science.add8786openalex-snapshot
Radical polymeric p-doping and grain modulation for stable, efficient perovskite solar modules
inferred← citeshttps://doi.org/10.1186/s40580-024-00459-wopenalex-snapshot
Spectroelectrochemical insights into the intrinsic nature of lead halide perovskites
inferred← citeshttps://doi.org/10.2139/ssrn.4852788openalex-snapshot
Ultrafast Hole Transfer Mediated by a Conjugated Self-Assembled Monolayer Enables Efficient and Stable Wide-Bandgap Perovskite Solar Cells
inferred← citeshttps://doi.org/10.26599/nre.2026.9120259openalex-snapshot
Stable wide bandgap perovskite solar cells: From photo-induced phase segregation mechanisms to suppression strategies
inferred← citeshttps://doi.org/10.3390/cryst12101425openalex-snapshot
Charge Carrier Recombination Dynamics in MAPb(Br1−yIy)3 Single Crystals
inferred← citeshttps://doi.org/10.3390/nano16050328openalex-snapshot
Band Structure-Driven Design of a α-CsPbI3 Ammonia Sensor for Industrial Applications
inferred← citeshttps://doi.org/10.35848/1347-4065/ae88a1openalex-snapshot
Efficient hole extraction suppresses photo-induced phase segregation in inorganic perovskite solar cells
inferred← citeshttps://doi.org/10.54227/elab.20250001openalex-snapshot
Interfaces in Monolithic Perovskite/ Organic Hybrid Solar Cells: Progresses, Prospects and Challenges
inferred← citeshttps://doi.org/10.70675/adc126ecz98e5z4843z87fez0d5916979ec0openalex-snapshot
Analyse des mécanismes de dégradation des cellules et mini-modules en pérovskite : développement de méthodologies et de modèles phénoménologiques
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