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Toward an Atomic-Level Understanding of Ceria-Based Catalysts: When Experiment and Theory Go Hand in Hand

https://doi.org/10.1021/acs.accounts.1c00226
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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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The Role of the Interface in CO Oxidation on Au/CeO2 Multilayer Nanotowers
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Cerium Oxide Nanorods with Unprecedented Low‐Temperature Oxygen Storage Capacity
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Ceria Nanocrystals Exposing Wide (100) Facets: Structure and Polarity Compensation
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Activation and Deactivation of Gold/Ceria–Zirconia in the Low‐Temperature Water–Gas Shift Reaction
inferredcites →https://doi.org/10.1002/cctc.201501129openalex-snapshot
Direct Evidence for the Participation of Oxygen Vacancies in the Oxidation of Carbon Monoxide over Ceria‐Supported Gold Catalysts by using Operando Raman Spectroscopy
inferredcites →https://doi.org/10.1002/cctc.202001066openalex-snapshot
Synthesis, Structure and Catalytic Properties of Faceted Oxide Crystals
inferredcites →https://doi.org/10.1007/s11244-016-0732-6openalex-snapshot
CO Oxidation on Ceria Supported Gold Catalysts Studied by Combined Operando Raman/UV–Vis and IR Spectroscopy
inferredcites →https://doi.org/10.1016/0021-9517(84)90371-3openalex-snapshot
Ceria in automotive exhaust catalysts I. Oxygen storage
inferredcites →https://doi.org/10.1016/b978-0-12-801217-8.00006-2openalex-snapshot
Surface Effects in the Reactivity of Ceria
inferredcites →https://doi.org/10.1016/j.apsusc.2016.06.163openalex-snapshot
Substrate-dependent Au cluster: A new insight into Au /CeO2
inferredcites →https://doi.org/10.1016/j.cattod.2015.01.049openalex-snapshot
The non-innocent role of cerium oxide in heterogeneous catalysis: A theoretical perspective
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Ceria and its related materials for VOC catalytic combustion: A review
inferredcites →https://doi.org/10.1016/j.cattod.2020.03.044openalex-snapshot
Raman spectroscopy as a powerful tool to characterize ceria-based catalysts
inferredcites →https://doi.org/10.1016/j.jcat.2011.09.011openalex-snapshot
On the structure dependence of CO oxidation over CeO2 nanocrystals with well-defined surface planes
inferredcites →https://doi.org/10.1016/j.jcat.2020.01.022openalex-snapshot
Identification of single-atom active sites in CO oxidation over oxide-supported Au catalysts
inferredcites →https://doi.org/10.1016/j.jcat.2020.09.027openalex-snapshot
Dynamics of gold clusters on ceria during CO oxidation
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Oxygen vacancies in transition metal and rare earth oxides: Current state of understanding and remaining challenges
inferredcites →https://doi.org/10.1016/j.surfrep.2014.12.001openalex-snapshot
The surface chemistry of cerium oxide
inferredcites →https://doi.org/10.1021/acs.chemrev.5b00603openalex-snapshot
Fundamentals and Catalytic Applications of CeO 2 -Based Materials
inferredcites →https://doi.org/10.1021/acs.jpcc.6b00959openalex-snapshot
Ceria and Its Defect Structure: New Insights from a Combined Spectroscopic Approach
inferredcites →https://doi.org/10.1021/acs.jpcc.7b06643openalex-snapshot
Raman Spectra of Polycrystalline CeO 2 : A Density Functional Theory Study
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Real-Time Observation of the Defect Dynamics in Working Au/CeO 2 Catalysts by Combined Operando Raman/UV–Vis Spectroscopy
inferredcites →https://doi.org/10.1021/acs.jpclett.0c02607openalex-snapshot
Elucidating the Oxygen Storage-Release Dynamics in Ceria Nanorods by Combined Multi-Wavelength Raman Spectroscopy and DFT
inferredcites →https://doi.org/10.1021/acs.jpclett.8b02728openalex-snapshot
Experimental and Theoretical Study on the Nature of Adsorbed Oxygen Species on Shaped Ceria Nanoparticles
inferredcites →https://doi.org/10.1021/acsanm.9b02243openalex-snapshot
Recent Progress in Autocatalytic Ceria Nanoparticles-Based Translational Research on Brain Diseases
inferredcites →https://doi.org/10.1021/acscatal.5b00739openalex-snapshot
Insight into the Deactivation of Au/CeO2 Catalysts Studied by In Situ Spectroscopy during the CO-PROX Reaction
inferredcites →https://doi.org/10.1021/acscatal.6b02685openalex-snapshot
Water-Mediated Mars–Van Krevelen Mechanism for CO Oxidation on Ceria-Supported Single-Atom Pt 1 Catalyst
inferredcites →https://doi.org/10.1021/acscatal.7b01246openalex-snapshot
Ceria Catalysts at Nanoscale: How Do Crystal Shapes Shape Catalysis?
inferredcites →https://doi.org/10.1021/acscatal.7b01563openalex-snapshot
Active Au Species During the Low-Temperature Water Gas Shift Reaction on Au/CeO2: A Time-Resolved Operando XAS and DRIFTS Study
inferredcites →https://doi.org/10.1021/acscatal.8b03539openalex-snapshot
Catalytic CO Oxidation over Au Nanoparticles Supported on CeO 2 Nanocrystals: Effect of the Au–CeO 2 Interface
inferredcites →https://doi.org/10.1021/acscatal.8b04536openalex-snapshot
Elucidating the Role of Support Oxygen in the Water–Gas Shift Reaction over Ceria-Supported Gold Catalysts Using Operando Spectroscopy
inferredcites →https://doi.org/10.1021/acsomega.8b02410openalex-snapshot
Breaking H2 with CeO2: Effect of Surface Termination
inferredcites →https://doi.org/10.1021/cr3004949openalex-snapshot
Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment
inferredcites →https://doi.org/10.1021/cs500614fopenalex-snapshot
CO Oxidation Activity at Room Temperature over Au/CeO2 Catalysts: Disclosure of Induction Period and Humidity Effect
inferredcites →https://doi.org/10.1021/ja043752sopenalex-snapshot
Spectroscopic Evidence for the Supply of Reactive Oxygen during CO Oxidation Catalyzed by Gold Supported on Nanocrystalline CeO2
inferredcites →https://doi.org/10.1021/ja207510vopenalex-snapshot
CO Oxidation Mechanism on CeO 2 -Supported Au Nanoparticles
inferredcites →https://doi.org/10.1021/ja902109kopenalex-snapshot
Reaction Mechanisms for the CO Oxidation on Au/CeO2 Catalysts: Activity of Substitutional Au3+/Au+ Cations and Deactivation of Supported Au+ Adatoms
inferredcites →https://doi.org/10.1021/jp055584bopenalex-snapshot
Shape-Selective Synthesis and Oxygen Storage Behavior of Ceria Nanopolyhedra, Nanorods, and Nanocubes
inferredcites →https://doi.org/10.1021/jp073974nopenalex-snapshot
An Evaluation of Harmonic Vibrational Frequency Scale Factors
inferredcites →https://doi.org/10.1021/jp804140eopenalex-snapshot
Great Influence of Anions for Controllable Synthesis of CeO2 Nanostructures: From Nanorods to Nanocubes
inferredcites →https://doi.org/10.1021/jz301778bopenalex-snapshot
CO Oxidation at the Interface of Au Nanoclusters and the Stepped-CeO 2 (111) Surface by the Mars–van Krevelen Mechanism
inferredcites →https://doi.org/10.1021/jz4009079openalex-snapshot
Fluxionality of Au Clusters at Ceria Surfaces during CO Oxidation: Relationships among Reactivity, Size, Cohesion, and Surface Defects from DFT Simulations
inferredcites →https://doi.org/10.1038/35005040openalex-snapshot
Direct oxidation of hydrocarbons in a solid-oxide fuel cell
inferredcites →https://doi.org/10.1038/am.2013.88openalex-snapshot
Cerium oxide nanoparticle: a remarkably versatile rare earth nanomaterial for biological applications
inferredcites →https://doi.org/10.1038/ncomms7511openalex-snapshot
Dynamic formation of single-atom catalytic active sites on ceria-supported gold nanoparticles
inferredcites →https://doi.org/10.1038/nmat4804openalex-snapshot
Entropic contributions enhance polarity compensation for CeO2(100) surfaces
inferredcites →https://doi.org/10.1038/s41467-019-11871-wopenalex-snapshot
Remarkable active-site dependent H2O promoting effect in CO oxidation
inferredcites →https://doi.org/10.1038/s41467-021-21132-4openalex-snapshot
Dynamic structure of active sites in ceria-supported Pt catalysts for the water gas shift reaction
inferredcites →https://doi.org/10.1038/s41929-020-0427-zopenalex-snapshot
Highly durable metal ensemble catalysts with full dispersion for automotive applications beyond single-atom catalysts
inferredcites →https://doi.org/10.1038/srep15613openalex-snapshot
Untangling the biological effects of cerium oxide nanoparticles: the role of surface valence states
inferredcites →https://doi.org/10.1039/c0cp01123aopenalex-snapshot
Theory of gold on ceria
inferredcites →https://doi.org/10.1039/c4ta03718aopenalex-snapshot
Low pressure induced porous nanorods of ceria with high reducibility and large oxygen storage capacity: synthesis and catalytic applications
inferredcites →https://doi.org/10.1039/c6cs00863aopenalex-snapshot
Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and methane and alcohol reforming
inferredcites →https://doi.org/10.1039/c7ce00922dopenalex-snapshot
Growth mechanism of ceria nanorods by precipitation at room temperature and morphology-dependent photocatalytic performance
inferredcites →https://doi.org/10.1039/c7cs00076fopenalex-snapshot
Surface point defects on bulk oxides: atomically-resolved scanning probe microscopy
inferredcites →https://doi.org/10.1039/c7nr09447gopenalex-snapshot
Dual effects of water vapor on ceria-supported gold clusters
inferredcites →https://doi.org/10.1039/c8fd00002fopenalex-snapshot
The electronic properties of Au clusters on CeO 2 (110) surface with and without O-defects
inferredcites →https://doi.org/10.1039/c9cp03408kopenalex-snapshot
A DFT+ U revisit of reconstructed CeO 2 (100) surfaces: structures, thermostabilities and reactivities
inferredcites →https://doi.org/10.1039/c9cs00588aopenalex-snapshot
A review of defect structure and chemistry in ceria and its solid solutions
inferredcites →https://doi.org/10.1039/c9ee03492gopenalex-snapshot
A tailored oxide interface creates dense Pt single-atom catalysts with high catalytic activity
inferredcites →https://doi.org/10.1039/c9fd00133fopenalex-snapshot
Insight into the mechanism of the water–gas shift reaction over Au/CeO 2 catalysts using combined operando spectroscopies
inferredcites →https://doi.org/10.1039/d0cs01059fopenalex-snapshot
New advances in using Raman spectroscopy for the characterization of catalysts and catalytic reactions
inferredcites →https://doi.org/10.1039/d0cy00392aopenalex-snapshot
Influence of gold on the reactivity behaviour of ceria nanorods in CO oxidation: combining operando spectroscopies and DFT calculations
inferredcites →https://doi.org/10.1063/1.2800015openalex-snapshot
Tuning LDA+U for electron localization and structure at oxygen vacancies in ceria
inferredcites →https://doi.org/10.1103/physrevlett.124.056002openalex-snapshot
Visualizing Anisotropic Oxygen Diffusion in Ceria under Activated Conditions
inferredcites →https://doi.org/10.1103/physrevlett.125.256101openalex-snapshot
Vibrational Frequencies of Cerium-Oxide-Bound CO: A Challenge for Conventional DFT Methods
inferredcites →https://doi.org/10.1126/science.1085721openalex-snapshot
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
inferredcites →https://doi.org/10.1146/annurev-chembioeng-062011-080939openalex-snapshot
Atomically Dispersed Supported Metal Catalysts
inferredcites →https://doi.org/10.3389/fchem.2018.00526openalex-snapshot
Rare Earth Doped Ceria: The Complex Connection Between Structure and Properties
inferredcites →https://doi.org/10.3389/fchem.2019.00028openalex-snapshot
Ceria-Based Materials in Hydrogenation and Reforming Reactions for CO2 Valorization
inferredcites →https://doi.org/10.3390/catal10030286openalex-snapshot
Ceria-Based Catalysts Studied by Near Ambient Pressure X-ray Photoelectron Spectroscopy: A Review

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Identification of Low-Temperature Active Species for Co Preferential Oxidation Over Ceo2-Cuo Composite Catalysts
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Operando Mobile Catalysis for Reverse Water Gas Shift Reaction
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Thermally Triggered Redox Flexibility of Pt/CeO 2 Cluster Catalyst Against In‐Situ Atomic Redispersion
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Operando Mobile Catalysis for Reverse Water Gas Shift Reaction
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Thermally Triggered Redox Flexibility of Pt/CeO 2 Cluster Catalyst Against In‐Situ Atomic Redispersion
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O2 Activation on Au/CeOX(111) Model Catalysts and Its Role in CO Oxidation
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Effects of Molybdenum Doping on the Enhanced Electrocatalytic Nitrogen Reduction Reaction Performance of CeO2 Nanorods: Theoretical and Experimental Investigations
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Theoretical study of structure sensitivity on ceria‐supported single platinum atoms and its influence on carbon monoxide adsorption
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Introduction
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Catalyst Characterization
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Analysis of electrical microstructure and sensor response in cerium oxide fibers-based interdigitated electrode (IDE) devices
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Insights on catalytic mechanism of CeO2 as multiple nanozymes
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Recent progress on catalyst design of nitrogen reduction reaction by density functional theory
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Enhanced oxidation activity of monomeric, cluster, and nanocrystalline CeOₓ species dispersed on MgO nanosheets
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Sequencing the CuOx active species for CO preferential oxidation at low-temperature over CeO2-CuO composite catalysts
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Photothermal CO2 hydrogenation to CO on CeO2 catalyst via redox mechanism
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Structural and optical characteristics of cadmium doped Ce0.80(Zr0.20-xCdx)O2 (x = 0 - 0.20) ceria: An experimental and density functional theory (DFT) investigations
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Importance of Metal–Support Interactions for CO 2 Hydrogenation: An Operando Near-Ambient Pressure X-ray Photoelectron Spectroscopy Study on Gold-Loaded In 2 O 3 and CeO 2 Catalysts
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Role of H2O Adsorption in CO Oxidation over Cerium-Oxide Cluster Anions (CeO2)nO– (n = 1–4)
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Mechanism of the Periodic Unsteady-State Water–Gas Shift Reaction on Highly Dispersed Cu-Loaded CeO2 Catalysts
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Improved Selectivity and Stability in Methane Dry Reforming by Atomic Layer Deposition on Ni-CeO2–ZrO2/Al2O3 Catalysts
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Electronic Configurations Effect of Ceria Nanowire-Based Catalysts for Efficient CO Oxidation
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Europium-Doped Cerium Oxide Nanoparticles for Microglial Amyloid Beta Clearance and Homeostasis
inferred← citeshttps://doi.org/10.1021/acssuschemeng.4c01322openalex-snapshot
Effect of Exposed Facets and Oxidation State of CeO2 Nanoparticles on CO2 Adsorption and Desorption
inferred← citeshttps://doi.org/10.1021/jacs.4c05053openalex-snapshot
Environment-Driven Variability in Absolute Band Edge Positions and Work Functions of Reduced Ceria
inferred← citeshttps://doi.org/10.1021/jacs.5c18832openalex-snapshot
In Situ Formed Pt–Ga Hetero Duo-Atomic Catalyst for Efficient Hydrogen Storage in N-Heterocycles
inferred← citeshttps://doi.org/10.1021/jacs.5c21866openalex-snapshot
Electron-Pump Driven Redox Design for Boosting the Reactivity of Ceria
inferred← citeshttps://doi.org/10.1038/s41467-025-64643-0openalex-snapshot
Concentrated-solar catalytic methane dry reforming with ultrahigh conversion and durability
inferred← citeshttps://doi.org/10.1038/s44160-026-01004-9openalex-snapshot
Click-locking strategy enables automated synthesis of single-atom catalysts with industrial compatibility
inferred← citeshttps://doi.org/10.1039/d2mh00236aopenalex-snapshot
Chemiresistive NH 3 detection at sub-zero temperatures by polypyrrole- loaded Sn 1− x Sb x O 2 nanocubes
inferred← citeshttps://doi.org/10.1039/d2nr02236bopenalex-snapshot
Confinement chemistry of FeO x centers for activating molecular oxygen under ambient conditions
inferred← citeshttps://doi.org/10.1039/d2nr03172hopenalex-snapshot
Tuning ceria catalysts in aqueous media at the nanoscale: how do surface charge and surface defects determine peroxidase- and haloperoxidase-like reactivity
inferred← citeshttps://doi.org/10.1039/d3cy00121kopenalex-snapshot
Iron-doped Co 3 O 4 catalysts prepared by a surfactant-assisted method as effective catalysts for malic acid oxidative decarboxylation
inferred← citeshttps://doi.org/10.1039/d3cy00494eopenalex-snapshot
Unravelling the mechanism of CO 2 activation over low-loaded Cu/CeO 2 (111) catalysts using operando and transient spectroscopies
inferred← citeshttps://doi.org/10.1039/d3en00810jopenalex-snapshot
In chemico methodology for engineered nanomaterial categorization according to number, nature and oxidative potential of reactive surface sites
inferred← citeshttps://doi.org/10.1039/d3gc02466kopenalex-snapshot
Dual active-sites of Co and oxygen vacancies in Co-doped CeO 2 -catalyzed toluene oxidation for the subsequent Knoevenagel condensation process
inferred← citeshttps://doi.org/10.1039/d3ra01552aopenalex-snapshot
Synthesis of mesoporous SiO 2 –CeO 2 hybrid nanostructures with high catalytic activity for transamidation reaction
inferred← citeshttps://doi.org/10.1039/d3ra02817hopenalex-snapshot
Fine control for the preparation of ceria nanorods (111)
inferred← citeshttps://doi.org/10.1039/d3re00027copenalex-snapshot
Unravelling catalytic activity trends in ceria surfaces toward the oxygen reduction and water oxidation reactions
inferred← citeshttps://doi.org/10.1039/d4cs00588kopenalex-snapshot
Nanoscale chemical characterization of materials and interfaces by tip-enhanced Raman spectroscopy
inferred← citeshttps://doi.org/10.1039/d4nr01296hopenalex-snapshot
Composition-dependent morphologies of CeO 2 nanoparticles in the presence of Co-adsorbed H 2 O and CO 2 : a density functional theory study
inferred← citeshttps://doi.org/10.1039/d4ra06187jopenalex-snapshot
Direct dimethyl carbonate synthesis from CO 2 and methanol over a flower-like CeO 2 catalyst with 2-cyanopyridine as a dehydrating agent in continuous packed-bed reactor
inferred← citeshttps://doi.org/10.1039/d5cp01283jopenalex-snapshot
Persistence of Ce 3+ species on the surface of ceria during redox cycling: a modulated chemical excitation investigation
inferred← citeshttps://doi.org/10.1039/d5cy00216hopenalex-snapshot
Correlating spatially resolved catalysis and Raman spectroscopy during CO oxidation over Cu/CeO 2 catalysts
inferred← citeshttps://doi.org/10.1039/d5gc00008dopenalex-snapshot
Tailoring the electronic structure and acid–base properties of MgO by Ce doping promotes biomass-derived formic acid production at room temperature
inferred← citeshttps://doi.org/10.1039/d5ta08474aopenalex-snapshot
Shedding light on cerium( iii / iv ), the unsung hero, and mitigating its chemical inertness with Ni
inferred← citeshttps://doi.org/10.1039/d6cy00763eopenalex-snapshot
Structure sensitivity of Cu/CeO 2 catalysts unraveled by combined Raman and UV-vis modulation excitation spectroscopy
inferred← citeshttps://doi.org/10.1039/d6gc03822kopenalex-snapshot
Designing platinum–ceria nanorod catalysts for hydrogen oxidation with high CO and H 2 S tolerance
inferred← citeshttps://doi.org/10.1080/15435075.2023.2281330openalex-snapshot
Carbon dioxide conversion to value-added products and fuels: opportunities and challenges: a critical review
inferred← citeshttps://doi.org/10.1088/1361-648x/ac238bopenalex-snapshot
Facet-dependent stability of near-surface oxygen vacancies and excess charge localization at CeO 2 surfaces
inferred← citeshttps://doi.org/10.1088/1361-648x/ac730aopenalex-snapshot
Cerium metal oxidation studied by IR reflection-absorption and Raman scattering spectroscopies
inferred← citeshttps://doi.org/10.1107/s1600576724003108openalex-snapshot
Implications of size dispersion on X-ray scattering of crystalline nanoparticles: CeO 2 as a case study
inferred← citeshttps://doi.org/10.1590/1980-5373-mr-2024-0149openalex-snapshot
Evaluation of Properties Changes by the Addition of Surfactant in the Synthesis of Ni/CeO2
inferred← citeshttps://doi.org/10.2139/ssrn.5260210openalex-snapshot
Aggregation and Dissolution Behaviour of Cerium Oxide Nanoparticles for Nuclear Fuel Debris Retrieval
inferred← citeshttps://doi.org/10.2139/ssrn.7381070openalex-snapshot
Elucidating the deactivation of Pd/CeO2 nanocubes, nanorods, and nano-octahedrons in lean methane oxidation
inferred← citeshttps://doi.org/10.31390/gradschool_theses.5767openalex-snapshot
Improved Selectivity and Stability in Methane Dry Reforming by Atomic Layer Deposition onto Ni-CeO2-ZrO2/Al2O3 Catalysts
inferred← citeshttps://doi.org/10.33774/chemrxiv-2021-5nnc6openalex-snapshot
Facet-Dependent Stability of Near-Surface Oxygen Vacancies and Excess Charge Localization at CeO2 Surfaces
inferred← citeshttps://doi.org/10.3390/catal11121556openalex-snapshot
Investigations of the Effect of H2 in CO Oxidation over Ceria Catalysts
inferred← citeshttps://doi.org/10.3390/catal16070619openalex-snapshot
Cerium-Promoted Nickel–Alumina Catalysts for Methane Partial Oxidation: Optimal Loading Strategy for Enhanced Syngas Production
inferred← citeshttps://doi.org/10.3390/molecules30234615openalex-snapshot
Impact of Sm3+ Ions on Oxygen Vacancy Formation in Ceria Systems
inferred← citeshttps://doi.org/10.3390/nano13212873openalex-snapshot
Inorganic Nanoparticles as Radiosensitizers for Cancer Treatment
inferred← citeshttps://doi.org/10.3390/nano16160980openalex-snapshot
Smart Adsorption-Based Nanocatalysts for Active Food Packaging: A Critical Look at the Gap Between Concept and Application
inferred← citeshttps://doi.org/10.3390/pr10091773openalex-snapshot
In Situ DRIFTS Study of Single-Atom, 2D, and 3D Pt on γ-Al2O3 Nanoflakes and Nanowires for C2H4 Oxidation
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