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NHCs in Main Group Chemistry

https://doi.org/10.1021/acs.chemrev.8b00079
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A Spectro- and Conductometric Study of the Reaction of Imidazoline-2-selone Derivatives with Bromine − Crystal Structure of 1,2-Bis(3-methyl-4-imidazolin-2-ylium dibromoselenanide)ethane
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Borane-Substituted Imidazol-2-ylidenes: Syntheses, Structures, and Reactivity
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Synthese und Eigenschaften von [Ph2(Carb)P]AlCl4 (Carb = 2,3-Dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-yliden) - ein stabiler Carben-Komplex des dreiwertigen Phosphors [1]
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A Tris(trifluoromethyl)antimony Adduct of a Nucleophilic Carbene: Geometric Distortions in Carbene Adducts
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Electron-Transfer Properties of Active Aldehydes of Thiamin Coenzyme Models, and Mechanism of Formation of the Reactive Intermediates
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Evidence for an Equilibrium between an N-heterocyclic Carbene and Its Dimer in Solution
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Stable Singlet Carbenes
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Novel Urea Derivatives as Two-Step Redox Systems
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Phosphaalkenes with Inverse Electron Density
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Synthese und Struktur von 1,3-Diisopropyl-4,5-dimethylimidazolium-2-sulfonat: Ein Carbenaddukt des Schwefeltrioxids
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Synthese und Kristallstruktur des Dichlor-Adduktes von 2, 3-Dihydro-1, 3-diisopropyl-4, 5-dimethylimidazol-2-yliden [1]Professor Wolfgang Haubold zum 65. Geburtstag gewidmet
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Neuartige elementorganische Sauerstoffsäuren des Phosphors und Schwefels [1]
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The Facile Preparation of Weakly Coordinating Anions: Structure and Characterisation of Silverpolyfluoroalkoxyaluminates AgAl(ORF)4, Calculation of the Alkoxide Ion Affinity
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Mechanistic Aspects of the Reaction between Br2 and Chalcogenone Donors (LE; E=S, Se): Competitive Formation of 10-E-3, T-Shaped 1:1 Molecular Adducts, Charge-Transfer Adducts, and [(LE)2]2+ Dications
inferredcites →https://doi.org/10.1002/1521-3765(20011015)7:20<4477::aid-chem4477>3.0.co;2-iopenalex-snapshot
C−H Activation with Elemental Sulfur: Synthesis of Cyclic Thioureas from Formaldehyde Aminals and S8
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Synthesis and Structure of a Monomeric Aluminum(I) Compound [{HC(CMeNAr)2}Al] (Ar=2,6–iPr2C6H3): A Stable Aluminum Analogue of a Carbene
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A Homoleptic Carbene-Lithium Complex
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1,2-Bis(3-methyl-imidazolin-2-ylium iodobromoselenanide)ethane: Oxidative Addition of IBr at the Se Atom of a >C=Se Group
inferredcites →https://doi.org/10.1002/1521-3773(20021115)41:22<4294::aid-anie4294>3.0.co;2-wopenalex-snapshot
Formation and Characterization of the First Monoalumoxane, LAlO⋅B(C6F5)3
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The Organometallic Chemistry of N‐heterocyclic Carbenes
inferredcites →https://doi.org/10.1002/9781118730379.ch2openalex-snapshot
Stable Carbenes
inferredcites →https://doi.org/10.1002/9781118730379.ch3openalex-snapshot
Acid–Base Chemistry of Carbenes
inferredcites →https://doi.org/10.1002/9783527664658.ch4openalex-snapshot
Donor–Acceptor Complexes of Main‐Group Elements
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The EDA Perspective of Chemical Bonding
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N-heterocyclic carbenes : effective tools for organometallic synthesis
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N ‐Heterocyclic Carbenes
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NHC Complexes of Main Group Elements: Novel Structures, Reactivity, and Catalytic Behavior
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Donor‐Stabilized Phosphenium Adducts as New Efficient and Immobilizing Ligands in Palladium‐Catalyzed Alkynylation and Platinum‐Catalyzed Hydrogenation in Ionic Liquids
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Über neue Harnstoff‐Derivate
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Ein neuer Zugang zur Carben‐Chemie
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Nucleophile Carben‐Chemie Darstellung des Bis‐[1.3‐diphenyl‐imidazolidinyliden‐(2)]
inferredcites →https://doi.org/10.1002/ange.19971092006openalex-snapshot
N‐Heterocyclische Carbene
inferredcites →https://doi.org/10.1002/ange.200901217openalex-snapshot
9‐Boraanthracene Derivatives Stabilized by N‐Heterocyclic Carbenes
inferredcites →https://doi.org/10.1002/ange.201106589openalex-snapshot
Covalent Capture of Nitrous Oxide by N‐Heterocyclic Carbenes
inferredcites →https://doi.org/10.1002/ange.201204712openalex-snapshot
NHC‐Stabilized Triorganozincates: Syntheses, Structures, and Transformation to Abnormal Carbene–Zinc Complexes
inferredcites →https://doi.org/10.1002/ange.201406930openalex-snapshot
Isolation of an Imino‐N‐heterocyclic Carbene/Germanium(0) Adduct: A Mesoionic Germylene Equivalent
inferredcites →https://doi.org/10.1002/ange.201710358openalex-snapshot
Cyclic (Amino)(Phosphonium Bora‐Ylide)Silanone: A Remarkable Room‐Temperature‐Persistent Silanone
inferredcites →https://doi.org/10.1002/anie.196403841openalex-snapshot
Phosphacyanines, a New Class of Compounds Containing Trivalent Phosphorus
inferredcites →https://doi.org/10.1002/anie.196501502openalex-snapshot
The Crystal Structure of a Phosphacyanine
inferredcites →https://doi.org/10.1002/anie.196807661openalex-snapshot
Tetraaminoethylenes as Strong Electron Donors
inferredcites →https://doi.org/10.1002/anie.197209641openalex-snapshot
Reactions of Electron‐Rich Olefins with Proton‐Active Compounds
inferredcites →https://doi.org/10.1002/anie.198007221openalex-snapshot
ThePCN Group as a Pseudochalcogen; Cyanophosphinidene‐Substituted Heterocycles
inferredcites →https://doi.org/10.1002/anie.198305451openalex-snapshot
2‐Phosphaallyl Cations by Formal Insertion of P⊕ into the CC Double Bond
inferredcites →https://doi.org/10.1002/anie.198402721openalex-snapshot
Chemical Bonding in Higher Main Group Elements
inferredcites →https://doi.org/10.1002/anie.198601641openalex-snapshot
Decamethylsilicocene—Synthesis and Structure
inferredcites →https://doi.org/10.1002/anie.198909921openalex-snapshot
Covalent versus Dative Bonds to Main Group Metals, a Useful Distinction
inferredcites →https://doi.org/10.1002/anie.199008991openalex-snapshot
A 1,2:2,1‐Bis(2‐silapropane‐1,3‐diyl)diborane(6): Stabilization Product of Bis(trisyl)diborane(2)?
inferredcites →https://doi.org/10.1002/anie.199504871openalex-snapshot
Crystal Structure of the Dimeric (4‐tert‐Butylthiazolato)(glyme)lithium: Carbene Character of a Formyl Anion Equivalent
inferredcites →https://doi.org/10.1002/anie.199510211openalex-snapshot
Preparation, Structure, and Reactivity of 1,3,4‐Triphenyl‐4,5‐dihydro‐1 H ‐1,2,4‐triazol‐5‐ylidene, a New Stable Carbene
inferredcites →https://doi.org/10.1002/anie.199608281openalex-snapshot
Main Group Element Analogues of Carbenes, Olefins, and Small Rings
inferredcites →https://doi.org/10.1002/anie.199610111openalex-snapshot
A Stable Tetraazafulvalene
inferredcites →https://doi.org/10.1002/anie.199725031openalex-snapshot
Hexaaryltetrasilabuta‐1,3‐diene: A Molecule with Conjugated SiSi Double Bonds
inferredcites →https://doi.org/10.1002/anie.200352710openalex-snapshot
Anionic Amido N‐Heterocyclic Carbenes: Synthesis of Covalently Tethered Lanthanide–Carbene Complexes
inferredcites →https://doi.org/10.1002/anie.200353347openalex-snapshot
A Silicon Analogue of Vinyllithium: Structural Characterization of a Disilenide
inferredcites →https://doi.org/10.1002/anie.200400654openalex-snapshot
When and How Do Diaminocarbenes Dimerize?
inferredcites →https://doi.org/10.1002/anie.200500402openalex-snapshot
Borinium, Borenium, and Boronium Ions: Synthesis, Reactivity, and Applications
inferredcites →https://doi.org/10.1002/anie.200501841openalex-snapshot
Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron‐Rich Ligands for Transition‐Metal Catalysts: A Quaternary Carbon Atom Makes the Difference
inferredcites →https://doi.org/10.1002/anie.200600987openalex-snapshot
CO Fixation to Stable Acyclic and Cyclic Alkyl Amino Carbenes: Stable Amino Ketenes with a Small HOMO–LUMO Gap
inferredcites →https://doi.org/10.1002/anie.200602552openalex-snapshot
Carbodiphosphoranes: The Chemistry of Divalent Carbon(0)
inferredcites →https://doi.org/10.1002/anie.200701632openalex-snapshot
C(NHC) 2 : Divalent Carbon(0) Compounds with N‐Heterocyclic Carbene Ligands—Theoretical Evidence for a Class of Molecules with Promising Chemical Properties
inferredcites →https://doi.org/10.1002/anie.200702029openalex-snapshot
Synthesis and Electronic Structure of a Terminal Alkylborylene Complex
inferredcites →https://doi.org/10.1002/anie.200702288openalex-snapshot
Encapsulated N‐Heterocyclic Carbenes in Silicones without Reactivity Modification
inferredcites →https://doi.org/10.1002/anie.200702297openalex-snapshot
Dual Character of Arduengo Carbene–Radical Adducts: Addition versus Coordination Product
inferredcites →https://doi.org/10.1002/anie.200703055openalex-snapshot
Carbene Activation of P4 and Subsequent Derivatization
inferredcites →https://doi.org/10.1002/anie.200705620openalex-snapshot
Synthesis of an Extremely Bent Acyclic Allene (A “Carbodicarbene”): A Strong Donor Ligand
inferredcites →https://doi.org/10.1002/anie.200705798openalex-snapshot
Coordination Chemistry of Ene‐1,1‐diamines and a Prototype “Carbodicarbene”
inferredcites →https://doi.org/10.1002/anie.200802596openalex-snapshot
Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N‐Heterocyclic Carbene and B(C6F5)3
inferredcites →https://doi.org/10.1002/anie.200802705openalex-snapshot
Heterolytic Dihydrogen Activation by a Frustrated Carbene–Borane Lewis Pair
inferredcites →https://doi.org/10.1002/anie.200805362openalex-snapshot
Linking Borane with N‐Heterocyclic Carbenes: Effective Hydrogen‐Atom Donors for Radical Reactions
inferredcites →https://doi.org/10.1002/anie.200806058openalex-snapshot
Conversion of Carbon Dioxide into Methanol with Silanes over N‐Heterocyclic Carbene Catalysts
inferredcites →https://doi.org/10.1002/anie.200900878openalex-snapshot
A Hydride‐Rich Magnesium Cluster
inferredcites →https://doi.org/10.1002/anie.200901319openalex-snapshot
Synthesis of Allenylidene Lithium and Silver Complexes, and Subsequent Transmetalation Reactions
inferredcites →https://doi.org/10.1002/anie.200901399openalex-snapshot
N‐Heterocyclic Carbenes as Efficient Organocatalysts for CO2 Fixation Reactions
inferredcites →https://doi.org/10.1002/anie.200901495openalex-snapshot
Tellurium(II)‐Centered Dications from the Pseudohalide “Te(OTf)2”
inferredcites →https://doi.org/10.1002/anie.200901766openalex-snapshot
Lewis Base Stabilized Dichlorosilylene
inferredcites →https://doi.org/10.1002/anie.200902344openalex-snapshot
Nonmetal‐Mediated Fragmentation of P 4 : Isolation of P 1 and P 2 Bis(carbene) Adducts
inferredcites →https://doi.org/10.1002/anie.200902431openalex-snapshot
SiBr2(Idipp): A Stable N‐Heterocyclic Carbene Adduct of Dibromosilylene
inferredcites →https://doi.org/10.1002/anie.200905401openalex-snapshot
Abnormal Reactivity of an N‐Heterocyclic Carbene (NHC) with a Phosphaalkene: A Route to a 4‐Phosphino‐Substituted NHC
inferredcites →https://doi.org/10.1002/anie.200905495openalex-snapshot
N‐Heterocyclic Carbene Stabilized Digermanium(0)
inferredcites →https://doi.org/10.1002/anie.200906884openalex-snapshot
Synthesis and Structure of a Carbene‐Stabilized π‐Boryl Anion
inferredcites →https://doi.org/10.1002/anie.201000577openalex-snapshot
Copper‐Free Asymmetric Allylic Alkylation with Grignard Reagents
inferredcites →https://doi.org/10.1002/anie.201000835openalex-snapshot
Convenient Access to Monosilicon Epoxides with Pentacoordinate Silicon
inferredcites →https://doi.org/10.1002/anie.201000837openalex-snapshot
Metal–Silicon Triple Bonds: The Molybdenum Silylidyne Complex [Cp(CO)2Mo≡Si‐R]
inferredcites →https://doi.org/10.1002/anie.201002889openalex-snapshot
Isolation of a Carbene‐Stabilized Phosphorus Mononitride and Its Radical Cation (PN+.)
inferredcites →https://doi.org/10.1002/anie.201004149openalex-snapshot
Heterolytic SS Bond Cleavage by a Purely Carbogenic Frustrated Lewis Pair
inferredcites →https://doi.org/10.1002/anie.201004215openalex-snapshot
Generation and Reactions of an Unsubstituted N‐Heterocyclic Carbene Boryl Anion
inferredcites →https://doi.org/10.1002/anie.201005534openalex-snapshot
Alane‐Based Classical and Frustrated Lewis Pairs in Polymer Synthesis: Rapid Polymerization of MMA and Naturally Renewable Methylene Butyrolactones into High‐Molecular‐Weight Polymers
inferredcites →https://doi.org/10.1002/anie.201005698openalex-snapshot
Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center
inferredcites →https://doi.org/10.1002/anie.201005903openalex-snapshot
Metal‐Free Activation of EH3 (E=P, As) by an Ylide‐like Silylene and Formation of a Donor‐Stabilized Arsasilene with a HSiAsH Subunit
inferredcites →https://doi.org/10.1002/anie.201007543openalex-snapshot
Trapping the Elusive Parent Borylene
inferredcites →https://doi.org/10.1002/anie.201100634openalex-snapshot
Stable N‐Heterocyclic Carbene Complexes of Hypermetallyl Germanium(II) and Tin(II) Compounds
inferredcites →https://doi.org/10.1002/anie.201102435openalex-snapshot
N‐Heterocyclic Carbenes: Organocatalysts with Moderate Nucleophilicity but Extraordinarily High Lewis Basicity
inferredcites →https://doi.org/10.1002/anie.201102717openalex-snapshot
Synthesis and Reactions of N‐Heterocyclic Carbene Boranes
inferredcites →https://doi.org/10.1002/anie.201103576openalex-snapshot
Trapping the Parent Inorganic Ethylenes H2SiGeH2 and H2SiSnH2 in the Form of Stable Adducts at Ambient Temperature
inferredcites →https://doi.org/10.1002/anie.201106589openalex-snapshot
Covalent Capture of Nitrous Oxide by N‐Heterocyclic Carbenes
inferredcites →https://doi.org/10.1002/anie.201107399openalex-snapshot
Fullerenes as Neutral Carbon‐Based Lewis Acids
inferredcites →https://doi.org/10.1002/anie.201107815openalex-snapshot
Lewis Base Stabilized Dicarbon: Predictions from Theory
inferredcites →https://doi.org/10.1002/anie.201107836openalex-snapshot
Beryllium‐Induced CN Bond Activation and Ring Opening of an N‐Heterocyclic Carbene
inferredcites →https://doi.org/10.1002/anie.201108813openalex-snapshot
Anionic N‐Heterocyclic Carbenes That Contain a Weakly Coordinating Borate Moiety
inferredcites →https://doi.org/10.1002/anie.201201600openalex-snapshot
Multiple‐Charged P1‐Centered Cations: Perspectives in Synthesis
inferredcites →https://doi.org/10.1002/anie.201202137openalex-snapshot
A Cyclic Diaminocarbene with a Pyramidalized Nitrogen Atom: A Stable N‐Heterocyclic Carbene with Enhanced Electrophilicity
inferredcites →https://doi.org/10.1002/anie.201202277openalex-snapshot
Reversible Base Coordination to a Disilene
inferredcites →https://doi.org/10.1002/anie.201204449openalex-snapshot
Base‐Stabilized Diborenes: Selective Generation and η2 Side‐on Coordination to Silver(I)
inferredcites →https://doi.org/10.1002/anie.201204487openalex-snapshot
Conversion of a Singlet Silylene to a stable Biradical
inferredcites →https://doi.org/10.1002/anie.201204524openalex-snapshot
Structures and Reactivities of O‐Methylated Breslow Intermediates
inferredcites →https://doi.org/10.1002/anie.201204712openalex-snapshot
NHC‐Stabilized Triorganozincates: Syntheses, Structures, and Transformation to Abnormal Carbene–Zinc Complexes
inferredcites →https://doi.org/10.1002/anie.201206100openalex-snapshot
Transition Metal Complexes of Anionic N‐Heterocyclic Dicarbene Ligands
inferredcites →https://doi.org/10.1002/anie.201208307openalex-snapshot
A Stable Singlet Biradicaloid Siladicarbene: (L:)2Si
inferredcites →https://doi.org/10.1002/anie.201209060openalex-snapshot
Organic Electron Donors as Powerful Single‐Electron Reducing Agents in Organic Synthesis
inferredcites →https://doi.org/10.1002/anie.201209109openalex-snapshot
31P NMR Chemical Shifts of Carbene–Phosphinidene Adducts as an Indicator of the π‐Accepting Properties of Carbenes
inferredcites →https://doi.org/10.1002/anie.201209757openalex-snapshot
Unusual Tilted Carbene Coordination in Carbene Complexes of Gallium(I) and Indium(I)
inferredcites →https://doi.org/10.1002/anie.201209766openalex-snapshot
Chemical Tricks To Stabilize Silanones and Their Heavier Homologues with EO Bonds (E=Si–Pb): From Elusive Species to Isolable Building Blocks
inferredcites →https://doi.org/10.1002/anie.201300461openalex-snapshot
Dative Bonds in Main‐Group Compounds: A Case for Fewer Arrows!
inferredcites →https://doi.org/10.1002/anie.201300668openalex-snapshot
Formation of Trichlorosilyl‐Substituted Carbon‐Centered Stable Radicals through the Use of π‐Accepting Carbenes
inferredcites →https://doi.org/10.1002/anie.201301137openalex-snapshot
Isolation of a Neutral P8 Cluster by [2+2] Cycloaddition of a Diphosphene Facilitated by Carbene Activation of White Phosphorus
inferredcites →https://doi.org/10.1002/anie.201301363openalex-snapshot
Silicon(II) Coordination Chemistry: N‐Heterocyclic Carbene Complexes of Si2+ and SiI+
inferredcites →https://doi.org/10.1002/anie.201302537openalex-snapshot
A Cyclic Silylone (“Siladicarbene”) with an Electron‐Rich Silicon(0) Atom
inferredcites →https://doi.org/10.1002/anie.201302767openalex-snapshot
Controlled Growth of Dichlorogermanium Oligomers from Lewis Basic Hosts
inferredcites →https://doi.org/10.1002/anie.201302841openalex-snapshot
An Air‐Stable Oxyallyl Radical Cation
inferredcites →https://doi.org/10.1002/anie.201302914openalex-snapshot
[3+2] Fragmentation of an [RP5Cl]+ Cage Cation Induced by an N‐Heterocyclic Carbene
inferredcites →https://doi.org/10.1002/anie.201303107openalex-snapshot
Characterization of the Key Intermediates of Carbene‐Catalyzed Umpolung by NMR Spectroscopy and X‐Ray Diffraction: Breslow Intermediates, Homoenolates, and Azolium Enolates
inferredcites →https://doi.org/10.1002/anie.201303457openalex-snapshot
Deprotonation of a Borohydride: Synthesis of a Carbene‐Stabilized Boryl Anion
inferredcites →https://doi.org/10.1002/anie.201304431openalex-snapshot
Synthesis of an Imidazolium Phosphanide Zwitterion and Its Conversion into Anionic Imidazol‐2‐ylidene Derivatives
inferredcites →https://doi.org/10.1002/anie.201304482openalex-snapshot
A Base‐Stabilized Sila‐β‐Lactone and a Donor/Acceptor‐Stabilized Silanoic Acid
inferredcites →https://doi.org/10.1002/anie.201305228openalex-snapshot
Synthesis of a Dialumene‐Benzene Adduct and Its Reactivity as a Synthetic Equivalent of a Dialumene
inferredcites →https://doi.org/10.1002/anie.201306780openalex-snapshot
NHC‐Stabilized Silagermenylidene: A Heavier Analogue of Vinylidene
inferredcites →https://doi.org/10.1002/anie.201308309openalex-snapshot
NHC‐Mediated Synthesis of an Asymmetric, Cationic Phosphoranide, a Phosphanide, and Coinage‐Metal Phosphanido Complexes
inferredcites →https://doi.org/10.1002/anie.201308385openalex-snapshot
A Di‐Substituted Boron Dication and Its Hydride‐Induced Transformation to an NHC‐Stabilized Borabenzene
inferredcites →https://doi.org/10.1002/anie.201308433openalex-snapshot
Silicon–Oxygen Double Bonds: A Stable Silanone with a Trigonal‐Planar Coordinated Silicon Center
inferredcites →https://doi.org/10.1002/anie.201308609openalex-snapshot
Experimental Charge Density Study of a Silylone
inferredcites →https://doi.org/10.1002/anie.201309325openalex-snapshot
Direct Hydroboration of BB Bonds: A Mild Strategy for the Proliferation of BB Bonds
inferredcites →https://doi.org/10.1002/anie.201310975openalex-snapshot
C 4 Cumulene and the Corresponding Air‐Stable Radical Cation and Dication
inferredcites →https://doi.org/10.1002/anie.201311022openalex-snapshot
Dative Bonds in Main‐Group Compounds: A Case for More Arrows!
inferredcites →https://doi.org/10.1002/anie.201311110openalex-snapshot
Boron Radical Cations from the Facile Oxidation of Electron‐Rich Diborenes
inferredcites →https://doi.org/10.1002/anie.201401024openalex-snapshot
Bis‐NHC Chelate Complexes of Nickel(0) and Platinum(0)
inferredcites →https://doi.org/10.1002/anie.201402445openalex-snapshot
Fusing N‐Heterocyclic Carbenes with Carborane Anions
inferredcites →https://doi.org/10.1002/anie.201402556openalex-snapshot
Evidence for Extensive Single‐Electron‐Transfer Chemistry in Boryl Anions: Isolation and Reactivity of a Neutral Borole Radical
inferredcites →https://doi.org/10.1002/anie.201403078openalex-snapshot
Dative or Not Dative?
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Isolation of a Neutral Boron‐Containing Radical Stabilized by a Cyclic (Alkyl)(Amino)Carbene
inferredcites →https://doi.org/10.1002/anie.201403693openalex-snapshot
The Highly Lewis Acidic Dicationic Phosphonium Salt: [(SIMes)PFPh2][B(C6F5)4]2
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Diborabutatriene: An Electron‐Deficient Cumulene
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Cross‐Coupling Reactions between Stable Carbenes
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One‐, Two‐, and Three‐Electron Reduction of a Cyclic Alkyl(amino)carbene–SbCl3 Adduct
inferredcites →https://doi.org/10.1002/anie.201405201openalex-snapshot
Isolation of a Bis(oxazol‐2‐ylidene)–Phenylborylene Adduct and its Reactivity as a Boron‐Centered Nucleophile
inferredcites →https://doi.org/10.1002/anie.201405238openalex-snapshot
N‐Heterocyclic Carbene Coordinated Neutral and Cationic Heavier Cyclopropylidenes
inferredcites →https://doi.org/10.1002/anie.201406481openalex-snapshot
Synthesis and Isolation of an Acyclic Tridentate Bis(pyridine)carbodicarbene and Studies on Its Structural Implications and Reactivities
inferredcites →https://doi.org/10.1002/anie.201406930openalex-snapshot
Isolation of an Imino‐N‐heterocyclic Carbene/Germanium(0) Adduct: A Mesoionic Germylene Equivalent
inferredcites →https://doi.org/10.1002/anie.201407751openalex-snapshot
A Multiply Functionalized Base‐Coordinated Ge II Compound and Its Reversible Dimerization to the Digermene
inferredcites →https://doi.org/10.1002/anie.201408345openalex-snapshot
Hydroboration of Arynes with N‐Heterocyclic Carbene Boranes
inferredcites →https://doi.org/10.1002/anie.201408354openalex-snapshot
N‐Heterocyclic Carbene–Phosphinidyne Transition Metal Complexes
inferredcites →https://doi.org/10.1002/anie.201408371openalex-snapshot
Synthesis and Reactivity of a CAAC–Aminoborylene Adduct: A Hetero‐Allene or an Organoboron Isoelectronic with Singlet Carbenes
inferredcites →https://doi.org/10.1002/anie.201408993openalex-snapshot
Unexpected Luminescence Behavior of Coinage Metal π‐Diborene Complexes
inferredcites →https://doi.org/10.1002/anie.201409250openalex-snapshot
Hydrogenations at Room Temperature and Atmospheric Pressure with Mesoionic Carbene‐Stabilized Borenium Catalysts
inferredcites →https://doi.org/10.1002/anie.201409513openalex-snapshot
Boron as a Powerful Reductant: Synthesis of a Stable Boron‐Centered Radical‐Anion Radical‐Cation Pair
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The Reactivities of Iminoboranes with Carbenes: BN Isosteres of Carbene–Alkyne Adducts
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Synthesis of Mixed Silylene–Carbene Chelate Ligands from N‐Heterocyclic Silylcarbenes Mediated by Nickel
inferredcites →https://doi.org/10.1002/anie.201409800openalex-snapshot
Frustrated Lewis Pair Chemistry: Development and Perspectives
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Synthesis of Azoimidazolium Dyes with Nitrous Oxide
inferredcites →https://doi.org/10.1002/anie.201411025openalex-snapshot
Nickel‐Triad Complexes of a Side‐on Coordinating Distannene
inferredcites →https://doi.org/10.1002/anie.201411264openalex-snapshot
SiP Double Bonds: Experimental and Theoretical Study of an NHC‐Stabilized Phosphasilenylidene
inferredcites →https://doi.org/10.1002/anie.201412006openalex-snapshot
From an Electron‐Rich Bis(boraketenimine) to an Electron‐Poor Diborene
inferredcites →https://doi.org/10.1002/anie.201500198openalex-snapshot
Planar N‐Heterocyclic Carbene Diarylborenium Ions: Synthesis by Cationic Borylation and Reactivity with Lewis Bases
inferredcites →https://doi.org/10.1002/anie.201500902openalex-snapshot
Alkyl Aryl Ether Bond Formation with PhenoFluor
inferredcites →https://doi.org/10.1002/anie.201502737openalex-snapshot
Synthesis and EPR/UV/Vis‐NIR Spectroelectrochemical Investigation of a Persistent Phosphanyl Radical Dication
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Transition‐Metal‐Mediated Cleavage of a SiSi Double Bond
inferredcites →https://doi.org/10.1002/anie.201503398openalex-snapshot
Reductive Insertion of Elemental Chalcogens into Boron–Boron Multiple Bonds
inferredcites →https://doi.org/10.1002/anie.201504489openalex-snapshot
From Silylone to an Isolable Monomeric Silicon Disulfide Complex
inferredcites →https://doi.org/10.1002/anie.201504494openalex-snapshot
SiSi Double Bonds: Synthesis of an NHC‐Stabilized Disilavinylidene
inferredcites →https://doi.org/10.1002/anie.201504867openalex-snapshot
Encapsulating Inorganic Acetylene, HBNH, Using Flanking Coordinative Interactions
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The Synthesis of B2(SIDip)2 and its Reactivity Between the Diboracumulenic and Diborynic Extremes
inferredcites →https://doi.org/10.1002/anie.201506487openalex-snapshot
Exclusive π Encapsulation of Light Alkali Metal Cations by a Neutral Molecule
inferredcites →https://doi.org/10.1002/anie.201507145openalex-snapshot
Imidazolium Ionic Liquids, Imidazolylidene Heterocyclic Carbenes, and Zeolitic Imidazolate Frameworks for CO2 Capture and Photochemical Reduction
inferredcites →https://doi.org/10.1002/anie.201507586openalex-snapshot
Alkali‐Metal‐Mediated Magnesiations of an N‐Heterocyclic Carbene: Normal, Abnormal, and “Paranormal” Reactivity in a Single Tritopic Molecule
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Expanding the Ligand Framework Diversity of Carbodicarbenes and Direct Detection of Boron Activation in the Methylation of Amines with CO2
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A Persistent 1,2‐Dihydrophosphasilene Adduct
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Iron‐ and Cobalt‐Catalyzed Synthesis of Carbene Phosphinidenes
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A Triatomic Silicon(0) Cluster Stabilized by a Cyclic Alkyl(amino) Carbene
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Double Deprotonation of Pyridinols Generates Potent Organic Electron‐Donor Initiators for Haloarene–Arene Coupling
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Highly Strained Heterocycles Constructed from Boron–Boron Multiple Bonds and Heavy Chalcogens
inferredcites →https://doi.org/10.1002/anie.201602384openalex-snapshot
Neutral Diboron Analogues of Archetypal Aromatic Species by Spontaneous Cycloaddition
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NHC‐CAAC Heterodimers with Three Stable Oxidation States
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Oxidative Cleavage of C=S and P=S Bonds at an AlI Center: Preparation of Terminally Bound Aluminum Sulfides
inferredcites →https://doi.org/10.1002/anie.201608429openalex-snapshot
Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra‐Boron(I) Molecular Square
inferredcites →https://doi.org/10.1002/anie.201609101openalex-snapshot
A Stable Neutral Radical in the Coordination Sphere of Aluminum
inferredcites →https://doi.org/10.1002/anie.201609455openalex-snapshot
Ultrashort Beryllium−Beryllium Distances Rivalling Those of Metal−Metal Quintuple Bonds Between Transition Metals
inferredcites →https://doi.org/10.1002/anie.201609601openalex-snapshot
Dibora[2]ferrocenophane: A Carbene‐Stabilized Diborene in a Strained cis‐Configuration
inferredcites →https://doi.org/10.1002/anie.201610072openalex-snapshot
Formation and Reactivity of Electron‐Precise B−B Single and Multiple Bonds
inferredcites →https://doi.org/10.1002/anie.201610498openalex-snapshot
An Isolable Silicon Dicarbonate Complex from Carbon Dioxide Activation with a Silylone
inferredcites →https://doi.org/10.1002/anie.201610903openalex-snapshot
N‐Heterocyclic Carbene Stabilized Boryl Radicals
inferredcites →https://doi.org/10.1002/anie.201611509openalex-snapshot
The Lightest Element Phosphoranylidene: NHC‐Supported Cyclic Borylidene–Phosphorane with Significant B=P Character
inferredcites →https://doi.org/10.1002/anie.201611851openalex-snapshot
A Stable Monomeric SiO2 Complex with Donor–Acceptor Ligands
inferredcites →https://doi.org/10.1002/anie.201700420openalex-snapshot
An Electrophilic Carbene‐Anchored Silylene–Phosphinidene
inferredcites →https://doi.org/10.1002/anie.201700530openalex-snapshot
Taming Silicon Congeners of CO and CO2: Synthesis of Monomeric SiII and SiIV Chalcogenide Complexes
inferredcites →https://doi.org/10.1002/anie.201701201openalex-snapshot
Cleavage of a P=P Double Bond Mediated by N‐Heterocyclic Carbenes
inferredcites →https://doi.org/10.1002/anie.201701679openalex-snapshot
Reversible Oxidative Addition at Carbon
inferredcites →https://doi.org/10.1002/anie.201702148openalex-snapshot
Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments
inferredcites →https://doi.org/10.1002/anie.201702246openalex-snapshot
C−N Bond Activation and Ring Opening of a Saturated N‐Heterocyclic Carbene by Lateral Alkali‐Metal‐Mediated Metalation
inferredcites →https://doi.org/10.1002/anie.201702760openalex-snapshot
Trapping a Silicon(I) Radical with Carbenes: A Cationic cAAC–Silicon(I) Radical and an NHC–Parent‐Silyliumylidene Cation
inferredcites →https://doi.org/10.1002/anie.201703672openalex-snapshot
Facile Phenylphosphinidene Transfer Reactions from Carbene–Phosphinidene Zinc Complexes
inferredcites →https://doi.org/10.1002/anie.201704185openalex-snapshot
α‐Radical Phosphines: Synthesis, Structure, and Reactivity
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inferred← citeshttps://doi.org/10.1002/ange.202518102openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/ange.8437242openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.1569919openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.1788393openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201813780openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201901470openalex-snapshot
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inferred← citeshttps://doi.org/10.1002/anie.201902238openalex-snapshot
Synthesis of Bisheteroarylalkanes by Heteroarylboration: Development and Application of a Pyridylidene–Copper Complex
inferred← citeshttps://doi.org/10.1002/anie.201908397openalex-snapshot
Ring Contraction by NHC‐Induced Pnictogen Abstraction
inferred← citeshttps://doi.org/10.1002/anie.201909798openalex-snapshot
NHC‐Coordinated Diphosphene‐Stabilized Gold(I) Hydride and Its Reversible Conversion to Gold(I) Formate with CO2
inferred← citeshttps://doi.org/10.1002/anie.201912009openalex-snapshot
Base‐Stabilized [PO]+/[PO2]+ Cations
inferred← citeshttps://doi.org/10.1002/anie.201914015openalex-snapshot
N‐Heterocyclic Carbene Stabilized Dicarbondiphosphides: Strong Neutral Four‐Membered Heterocyclic 6π‐Electron Donors
inferred← citeshttps://doi.org/10.1002/anie.201915183openalex-snapshot
Shigeyoshi Inoue
inferred← citeshttps://doi.org/10.1002/anie.201916395openalex-snapshot
Carbene‐Stabilized Disilicon as a Silicon‐Transfer Agent: Synthesis of a Dianionic Silicon Tris(dithiolene) Complex
inferred← citeshttps://doi.org/10.1002/anie.202002774openalex-snapshot
Regioselective Insertion of Aluminum(I) in the cyclo‐P5 Ring of Pentaphosphaferrocene
inferred← citeshttps://doi.org/10.1002/anie.202009353openalex-snapshot
The [(NHC)B(H)C6F5]+ Cations and Their [B](H)−CO Borane Carbonyls
inferred← citeshttps://doi.org/10.1002/anie.202011677openalex-snapshot
A Room‐Temperature Stable Distonic Radical Cation
inferred← citeshttps://doi.org/10.1002/anie.202012218openalex-snapshot
Frustrated Lewis Pair Chelation as a Vehicle for Low‐Temperature Semiconductor Element and Polymer Deposition
inferred← citeshttps://doi.org/10.1002/anie.202013434openalex-snapshot
Carbenaporphyrins: No Longer Missing Ligands in N‐Heterocyclic Carbene Chemistry
inferred← citeshttps://doi.org/10.1002/anie.202014328openalex-snapshot
Nickel‐Catalyzed Intramolecular 1,2‐Aryl Migration of Mesoionic Carbenes (iMICs)
inferred← citeshttps://doi.org/10.1002/anie.202014398openalex-snapshot
Carbodicarbene Bismaalkene Cations: Unravelling the Complexities of Carbene versus Carbone in Heavy Pnictogen Chemistry
inferred← citeshttps://doi.org/10.1002/anie.202103267openalex-snapshot
Highly Coordinated Heteronuclear Calcium–Iron Carbonyl Cation Complexes [CaFe(CO) n ] + ( n =5–12) with d−d Bonding
inferred← citeshttps://doi.org/10.1002/anie.202103628openalex-snapshot
Stabilization of the Elusive 9‐Carbene‐9‐Borafluorene Monoanion
inferred← citeshttps://doi.org/10.1002/anie.202105529openalex-snapshot
1,3‐Bis(tricyanoborane)imidazoline‐2‐ylidenate Anion—A Ditopic Dianionic N‐Heterocyclic Carbene Ligand
inferred← citeshttps://doi.org/10.1002/anie.202105835openalex-snapshot
Isolation of 1,4‐Diarsinine‐1,4‐diide and 1,4‐Diarsinine Derivatives
inferred← citeshttps://doi.org/10.1002/anie.202106724openalex-snapshot
Formation and Cycloaddition Reactions of a Reactive Boraalkene Stabilized Internally by N ‐Heterocyclic Carbene
inferred← citeshttps://doi.org/10.1002/anie.202108146openalex-snapshot
A Zwitterionic Heterobimetallic Gold–Iron Complex Supported by Bis(N‐Heterocyclic Imine)Silyliumylidene
inferred← citeshttps://doi.org/10.1002/anie.202113947openalex-snapshot
An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small‐Molecule Activation and Rearrangement Chemistry
inferred← citeshttps://doi.org/10.1002/anie.202114143openalex-snapshot
Geometrically Constrained Cationic Low‐Coordinate Tetrylenes: Highly Lewis Acidic σ‐Donor Ligands in Catalytic Systems
inferred← citeshttps://doi.org/10.1002/anie.202115104openalex-snapshot
Reversible Self‐Assembly of an N‐Heterocyclic Carbene on Metal Surfaces
inferred← citeshttps://doi.org/10.1002/anie.202115570openalex-snapshot
Synthesis and Reactivity of N‐Heterocyclic Silylene Stabilized Disilicon(0) Complexes
inferred← citeshttps://doi.org/10.1002/anie.202116131openalex-snapshot
One‐Step Access to Heteroatom‐Functionalized Imidazol(in)ium Salts
inferred← citeshttps://doi.org/10.1002/anie.202116615openalex-snapshot
Calix[4]pyrrolato Stannate(II): A Tetraamido Tin(II) Dianion and Strong Metal‐Centered σ‐Donor
inferred← citeshttps://doi.org/10.1002/anie.202116658openalex-snapshot
Modulating the Frontier Orbitals of an Aluminylene for Facile Dearomatization of Inert Arenes**
inferred← citeshttps://doi.org/10.1002/anie.202206390openalex-snapshot
Gauging Radical Stabilization with Carbenes
inferred← citeshttps://doi.org/10.1002/anie.202213614openalex-snapshot
Mesoionic N‐Heterocyclic Imines as Super Nucleophiles in Catalytic Couplings of Amides with CO2
inferred← citeshttps://doi.org/10.1002/anie.202219211openalex-snapshot
Stable Ketenyl Anions via Ligand Exchange at an Anionic Carbon as Powerful Synthons**
inferred← citeshttps://doi.org/10.1002/anie.202300056openalex-snapshot
Boranes Paving the Way to Anionic Cyclic (Alkyl)(amino)carbenes (Ani‐cAACs)
inferred← citeshttps://doi.org/10.1002/anie.202304665openalex-snapshot
1,3‐Imidazole‐Based Mesoionic Carbenes and Anionic Dicarbenes: Pushing the Limit of Classical N‐Heterocyclic Carbenes
inferred← citeshttps://doi.org/10.1002/anie.202312111openalex-snapshot
Aluminum(III) Cations [(NHC) ⋅ AlMes 2 ] + : Synthesis, Characterization, and Application in FLP‐Chemistry
inferred← citeshttps://doi.org/10.1002/anie.202312858openalex-snapshot
Divergent Synthesis of Chelating Aziridines and Cyclic(Alkyl)(Amino)Carbenes (CAACs) from Pyridyl‐Tethered Robust Azomethine Ylides
inferred← citeshttps://doi.org/10.1002/anie.202316117openalex-snapshot
Reactivity of [Cp*Fe(η5‐As5)] towards Carbenes, Silylenes and Germylenes
inferred← citeshttps://doi.org/10.1002/anie.202318525openalex-snapshot
Boosting the π‐Acceptor Property of Mesoionic Carbenes by Carbonylation with Carbon Monoxide
inferred← citeshttps://doi.org/10.1002/anie.202400227openalex-snapshot
NHC‐Supported 2‐Sila and 2‐Germavinylidenes: Synthesis, Dynamics, First Reactivity and Theoretical Studies
inferred← citeshttps://doi.org/10.1002/anie.202403639openalex-snapshot
How to Decarbonize N ‐Heterocyclic Carbenes (NHCs): The simple Alane Adducts (NHC) ⋅ AlR 3 (R=H, Me, Et)
inferred← citeshttps://doi.org/10.1002/anie.202403652openalex-snapshot
Germaaluminocenes—Masked Heterofulvenes
inferred← citeshttps://doi.org/10.1002/anie.202403755openalex-snapshot
A Coppoborylene Stabilized by Multicenter Covalent Bonding and Its Amphoteric Reactivity to CO
inferred← citeshttps://doi.org/10.1002/anie.202407427openalex-snapshot
Synthesis, Isolation, and Reactivity Studies of ‘Naked’ Acyclic Gallyl and Indyl Anions
inferred← citeshttps://doi.org/10.1002/anie.202410790openalex-snapshot
Bis‐Silylene‐Supported Aluminium Atoms with Aluminylene and Alane Character
inferred← citeshttps://doi.org/10.1002/anie.202415070openalex-snapshot
Carbodicarbene‐Stibenium Ion‐Mediated Functionalization of C(sp 3 )−H and C(sp)−H Bonds
inferred← citeshttps://doi.org/10.1002/anie.202418673openalex-snapshot
Independent LUMO Reactivity in Mesoionic N‐Heterocyclic Thiones: Synthesis of a Stable Radical Anion
inferred← citeshttps://doi.org/10.1002/anie.202419502openalex-snapshot
Zwitterionic 2‐Phosphaethene‐thiolates [(LC)P=CS(LC/P)]+ as PCS Building Blocks (LC=NHC, LP=PR3)
inferred← citeshttps://doi.org/10.1002/anie.202501068openalex-snapshot
Lithium Anionic Dicarbenes or Acetylides: What is in the Name?
inferred← citeshttps://doi.org/10.1002/anie.202505697openalex-snapshot
Zwitterionic Heavier Pnictinidenes in Redox Catalysis
inferred← citeshttps://doi.org/10.1002/anie.202505940openalex-snapshot
Crystalline Silagermenides as Powerful Synthons: Unraveling π‐Bonding and Lone Pair Effects in the Multiple Bonds of Heavier Main Group Analogs of the Vinyl Anion
inferred← citeshttps://doi.org/10.1002/anie.202513210openalex-snapshot
London Dispersion‐Induced Contraction of the Cu─O Bond in Copper(I) Phenolates
inferred← citeshttps://doi.org/10.1002/anie.202514521openalex-snapshot
Isolable Arylphosphinidene Chalcogenides and their Radical Anions
inferred← citeshttps://doi.org/10.1002/anie.202518102openalex-snapshot
Switchable Reactivities of Metalated Phosphasilenes Regulated by Reversible 1,2‐Metal Migration
inferred← citeshttps://doi.org/10.1002/anie.202520101openalex-snapshot
Mesoionic N‐Heterocyclic Olefins, Imines, Thiones, Phosphinidenes and Their Application in Catalysis
inferred← citeshttps://doi.org/10.1002/anie.2724882openalex-snapshot
Isolable C ‐Phosphonio‐Boratavinyl Anion
inferred← citeshttps://doi.org/10.1002/anie.8437242openalex-snapshot
Trimethylphosphine‐Stabilized (Cyano)Phosphinidene: A Versatile PCN Transfer Reagent
inferred← citeshttps://doi.org/10.1002/aoc.5885openalex-snapshot
Symmetrical and Non‐symmetrical Pd (II) Pincer Complexes Bearing Mesoionic N‐heterocyclic Thiones: Synthesis, Characterizations and Catalytic Properties
inferred← citeshttps://doi.org/10.1002/ardp.202100111openalex-snapshot
Silver–N‐heterocyclic carbene complexes‐catalyzed multicomponent reactions: Synthesis, spectroscopic characterization, density functional theory calculations, and antibacterial study
inferred← citeshttps://doi.org/10.1002/asia.201801285openalex-snapshot
Theoretical Investigation of Hydride Insertion into N‐Heterocyclic Carbenes Containing N, P, C, O and S Heteroatoms
inferred← citeshttps://doi.org/10.1002/asia.201901774openalex-snapshot
Group 13 Element Trihalide Complexes of Anionic N‐Heterocyclic Carbenes
inferred← citeshttps://doi.org/10.1002/asia.202000800openalex-snapshot
Pincer‐Type Ligand‐Assisted Catalysis and Small‐Molecule Activation by non‐VSEPR Main‐Group Compounds
inferred← citeshttps://doi.org/10.1002/asia.202100325openalex-snapshot
Antimony(III) Halide‐Assisted Stereospecific Coordination of Thione
inferred← citeshttps://doi.org/10.1002/asia.202100523openalex-snapshot
Intramolecularly Double‐Donor‐Stabilized Stannylene and Its Coordination towards Ag(I) and Au(I) Centers
inferred← citeshttps://doi.org/10.1002/asia.202101157openalex-snapshot
Experimental and Computational Study on Photophysical Properties of Mesoionic Chalcogenones
inferred← citeshttps://doi.org/10.1002/asia.202300411openalex-snapshot
Synthesis, Structural Characterization and Coordination Chemistry of a NHC‐stabilized Iminoborane
inferred← citeshttps://doi.org/10.1002/asia.202301058openalex-snapshot
Synthesis and Reactivity of an Aluminium N ‐heterocyclic Aminal
inferred← citeshttps://doi.org/10.1002/asia.202401085openalex-snapshot
A Convenient Approach for the Synthesis of Multidentate N‐Heterocyclic Carbene Ligand Precursors
inferred← citeshttps://doi.org/10.1002/asia.70209openalex-snapshot
Reactivity and Activation Barrier Origins of Heavy Isocyanide‐Like Molecules Featuring a Group 14═P Double Bond Toward Methyl Iodide: A Chemical Insight
inferred← citeshttps://doi.org/10.1002/cctc.201901255openalex-snapshot
Catalytic CO2 Reduction with Boron‐ and Aluminum Hydrides
inferred← citeshttps://doi.org/10.1002/cctc.202200962openalex-snapshot
N‐Heterocyclic Carbene‐Based Zinc Complexes: Same Precursors for Different Lactide Ring‐Opening Polymerization Mechanisms.
inferred← citeshttps://doi.org/10.1002/cctc.71026openalex-snapshot
Bipyridyl‐ N ‐Heterocyclic Carbene Supported Dinuclear Copper (I) Complexes: Synthesis and Catalytic Activity in Functionalization of Amines
inferred← citeshttps://doi.org/10.1002/ceur.202400066openalex-snapshot
Amido‐Triazole Complexes, “Normal” Triazole‐Based Imines and Metallo‐Mesoionic Imines
inferred← citeshttps://doi.org/10.1002/ceur.202500119openalex-snapshot
Small Molecule Activation by Metallylenes and their Follow‐Up Reactions
inferred← citeshttps://doi.org/10.1002/ceur.202500197openalex-snapshot
Silatranylnitrilium Hexachloridoantimonate, its Brønsted Base‐Assisted CC‐Bond Formation and Transformation to an Unprecedented Carbene‐Type SbCl 5 Complex
inferred← citeshttps://doi.org/10.1002/ceur.202500409openalex-snapshot
Electrophilic Functionalization of Donor‐Stabilized Phosphanylboranes: A New Pathway toward Heavy 13/14/15 Parent Hydride‐Containing Compounds
inferred← citeshttps://doi.org/10.1002/ceur.70282openalex-snapshot
Reversible Dihydrogen Splitting and Diradical Reactivity of 1,4‐Digermabenzene‐1,4‐diide
inferred← citeshttps://doi.org/10.1002/chem.201803370openalex-snapshot
Cationic Complexes of Boron and Aluminum: An Early 21st Century Viewpoint
inferred← citeshttps://doi.org/10.1002/chem.201805267openalex-snapshot
Synthesis of Cyclic Alkyl(amino) Carbene Stabilized Silylenes with Small N‐Donating Substituents
inferred← citeshttps://doi.org/10.1002/chem.201805604openalex-snapshot
The Quest for Stable Silaaldehydes: Synthesis and Reactivity of a Masked Silacarbonyl
inferred← citeshttps://doi.org/10.1002/chem.201900316openalex-snapshot
Metal‐Free Electrochemical Reduction of Carbon Dioxide Mediated by Cyclic(Alkyl)(Amino) Carbenes
inferred← citeshttps://doi.org/10.1002/chem.201900348openalex-snapshot
Low‐Valent Group 14 NHC‐Stabilized Phosphinidenide ate Complexes and NHC‐Stabilized K/P‐Clusters
inferred← citeshttps://doi.org/10.1002/chem.201900458openalex-snapshot
Isolation of Cyclic(Alkyl)(Amino) Carbene–Bismuthinidene Mediated by a Beryllium(0) Complex
inferred← citeshttps://doi.org/10.1002/chem.201900645openalex-snapshot
Bent Phosphaallenes With “Hidden” Lone Pairs as Ligands
inferred← citeshttps://doi.org/10.1002/chem.201900961openalex-snapshot
Cyclic(Alkyl)(Amino)Carbene (CAAC)‐Supported Zn Alkyls: Synthesis, Structure and Reactivity in Hydrosilylation Catalysis
inferred← citeshttps://doi.org/10.1002/chem.201901857openalex-snapshot
Crystalline Divinyldiarsenes and Cleavage of the As=As Bond
inferred← citeshttps://doi.org/10.1002/chem.201902698openalex-snapshot
Benzyl Borane NHC Adducts: Beyond B−C Bond Scission
inferred← citeshttps://doi.org/10.1002/chem.201902877openalex-snapshot
Isolation of an N‐Heterocyclic Carbene Complex of a Borasilene
inferred← citeshttps://doi.org/10.1002/chem.201903242openalex-snapshot
N‐Heterocyclic Carbenes as Key Intermediates in the Synthesis of Fused, Mesoionic, Tricyclic Heterocycles
inferred← citeshttps://doi.org/10.1002/chem.201903259openalex-snapshot
B−B Cleavage and Ring‐Expansion of a 1,4,2,3‐Diazadiborinine with N‐Heterocyclic Carbenes
inferred← citeshttps://doi.org/10.1002/chem.201903348openalex-snapshot
Stable Borepinium and Borafluorenium Heterocycles: A Reversible Thermochromic “Switch” Based on Boron–Oxygen Interactions
inferred← citeshttps://doi.org/10.1002/chem.201903736openalex-snapshot
History and Future of Dative Bonds
inferred← citeshttps://doi.org/10.1002/chem.201903795openalex-snapshot
Isolation of Carbene‐Stabilized Arsenic Monophosphide [AsP] and its Radical Cation [AsP]+. and Dication [AsP]2+
inferred← citeshttps://doi.org/10.1002/chem.201905061openalex-snapshot
Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)2M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)
inferred← citeshttps://doi.org/10.1002/chem.201905704openalex-snapshot
Ambident Reactivity of Imidazolium Cations as Evidence of the Dynamic Nature of N‐Heterocyclic Carbene‐Mediated Organocatalysis
inferred← citeshttps://doi.org/10.1002/chem.202000025openalex-snapshot
How to Bend a Cumulene
inferred← citeshttps://doi.org/10.1002/chem.202000255openalex-snapshot
N,N′‐Ethylene‐Bridged Bis‐2‐Aryl‐Pyrrolinium Cations to E‐Diaminoalkenes: Non‐Identical Stepwise Reversible Double‐Redox Coupled Bond Activation Reactions
inferred← citeshttps://doi.org/10.1002/chem.202000866openalex-snapshot
Facile Access to Dative, Single, and Double Silicon−Metal Bonds Through M−Cl Insertion Reactions of Base‐Stabilized SiII Cations
inferred← citeshttps://doi.org/10.1002/chem.202002939openalex-snapshot
Main Group Multiple Bonds for Bond Activations and Catalysis
inferred← citeshttps://doi.org/10.1002/chem.202003099openalex-snapshot
N‐Heterocyclic Carbene Analogues of Nucleophilic Phosphinidene Transition Metal Complexes
inferred← citeshttps://doi.org/10.1002/chem.202003161openalex-snapshot
Main‐Group Metallocenophanes
inferred← citeshttps://doi.org/10.1002/chem.202003393openalex-snapshot
NHCs as Neutral Donors towards Polyphosphorus Complexes
inferred← citeshttps://doi.org/10.1002/chem.202003513openalex-snapshot
Synthesis and Coordination Behavior of a New Hybrid Bidentate Ligand with Phosphine and Silylene Donors
inferred← citeshttps://doi.org/10.1002/chem.202004418openalex-snapshot
Halogen Complexes of Anionic N‐Heterocyclic Carbenes
inferred← citeshttps://doi.org/10.1002/chem.202005198openalex-snapshot
Diphosphanylmetallocenes of Main‐Group Elements
inferred← citeshttps://doi.org/10.1002/chem.202100105openalex-snapshot
Directed Design of a AuI Complex with a Reduced Mesoionic Carbene Radical Ligand: Insights from 1,2,3‐Triazolylidene Selenium Adducts and Extensive Electrochemical Investigations
inferred← citeshttps://doi.org/10.1002/chem.202100482openalex-snapshot
Isoselective Polymerization of rac‐Lactide by Aluminum Complexes of N‐Heterocyclic Carbene‐Phosphinidene Adducts
inferred← citeshttps://doi.org/10.1002/chem.202100785openalex-snapshot
Catalytic Gold Chemistry: From Simple Salts to Complexes for Regioselective C−H Bond Functionalization
inferred← citeshttps://doi.org/10.1002/chem.202100969openalex-snapshot
A Stable Homoleptic Divinyl Tetrelene Series
inferred← citeshttps://doi.org/10.1002/chem.202101116openalex-snapshot
Taming the Antiferromagnetic Beast: Computational Design of Ultrashort Mn−Mn Bonds Stabilized by N‐Heterocyclic Carbenes
inferred← citeshttps://doi.org/10.1002/chem.202101686openalex-snapshot
Non‐conventional Behavior of a 2,1‐Benzazaphosphole: Heterodiene or Hidden Phosphinidene?
inferred← citeshttps://doi.org/10.1002/chem.202101923openalex-snapshot
Application of the Redox‐Transmetalation Procedure to Access Divalent Lanthanide and Alkaline‐Earth NHC Complexes**
inferred← citeshttps://doi.org/10.1002/chem.202102384openalex-snapshot
Metathesis of P=C Bonds Catalyzed by N‐Heterocyclic Carbenes
inferred← citeshttps://doi.org/10.1002/chem.202102800openalex-snapshot
NMR Crystallography Enhanced by Quantum Chemical Calculations and Liquid State NMR Spectroscopy for the Investigation of Se‐NHC Adducts**
inferred← citeshttps://doi.org/10.1002/chem.202103101openalex-snapshot
Reactivity of the Bicyclic Amido‐Substituted Silicon(I) Ring Compound Si4{N(SiMe3)Mes}4 with FLP‐Type Character
inferred← citeshttps://doi.org/10.1002/chem.202103780openalex-snapshot
An NHC‐Stabilized H2GeBH2 Precursor for the Preparation of Cationic Group 13/14/15 Hydride Chains
inferred← citeshttps://doi.org/10.1002/chem.202104139openalex-snapshot
Rhodium and Iridium Complexes of Anionic Thione and Selone Ligands Derived from Anionic N‐Heterocyclic Carbenes
inferred← citeshttps://doi.org/10.1002/chem.202200166openalex-snapshot
Helical Chiral N‐Heterocyclic Carbene Ligands in Enantioselective Gold Catalysis
inferred← citeshttps://doi.org/10.1002/chem.202200275openalex-snapshot
Tricyanoborane‐Functionalized Anionic N‐Heterocyclic Carbenes: Adjustment of Charge and Stereo‐Electronic Properties
inferred← citeshttps://doi.org/10.1002/chem.202200530openalex-snapshot
N‐Heterocyclic Carbenes Carrying Weakly Coordinating Anions
inferred← citeshttps://doi.org/10.1002/chem.202200739openalex-snapshot
Mesoionic Dithiolates (MIDts) Derived from 1,3‐Imidazole‐Based Anionic Dicarbenes (ADCs)
inferred← citeshttps://doi.org/10.1002/chem.202200761openalex-snapshot
A Series of Rare‐Earth Mesoionic Carbene Complexes
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