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Estimation of Transport Parameters of Perfluoroalkyl Acids (PFAAs) in Unsaturated Porous Media: Critical Experimental and Modeling Improvements

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Outgoing claims: the papers this work cites, builds on, or argues with.

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Travel times in the vadose zone: Variability in space and time
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Property Estimation of Per- and Polyfluoroalkyl Substances: A Comparative Assessment of Estimation Methods
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Hydrogeophysical Methods at the Laboratory Scale
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Pore-Scale Modeling of Multiphase Flow and Transport: Achievements and Perspectives
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Preferential flow in a sandy vadose zone: 2. Mechanism and implications
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Multidimensional simulation of PFAS transport and leaching in the vadose zone: Impact of surfactant-induced flow and subsurface heterogeneities
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Novel methods for measuring air–water interfacial area in unsaturated porous media
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Measuring air–water interfacial area for soils using the mass balance surfactant-tracer method
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Occurrence of select perfluoroalkyl substances at U.S. Air Force aqueous film-forming foam release sites other than fire-training areas: Field-validation of critical fate and transport properties
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Occurrence and distribution of per- and polyfluoroalkyl substances (PFASs) in the seawater and sediment of the South China sea coastal region
inferredcites →https://doi.org/10.1016/j.chemosphere.2020.126305openalex-snapshot
Low-concentration tracer tests to measure air-water interfacial area in porous media
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Adsorption isotherm models: Classification, physical meaning, application and solving method
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Testing the validity of the miscible-displacement interfacial tracer method for measuring air-water interfacial area: Independent benchmarking and mathematical modeling
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Unification of surface tension isotherms of PFOA or GenX salts in electrolyte solutions by mean ionic activity
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Per- and polyfluorinated substances (PFASs): Environmental challenges
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Sorption of perfluoroalkyl ether carboxylic acids (PFECAs) at the air-water interface in porous media: Modeling perspectives
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Evidence of preferential path formation and path memory effect during successive infiltration and drainage cycles in uniform sand columns
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Transport and retention of perfluorooctanoic acid (PFOA) in natural soils: Importance of soil organic matter and mineral contents, and solution ionic strength
inferredcites →https://doi.org/10.1016/j.jconhyd.2020.103661openalex-snapshot
Subsurface transport potential of perfluoroalkyl acids (PFAAs): Column experiments and modeling
inferredcites →https://doi.org/10.1016/j.jconhyd.2020.103731openalex-snapshot
Air-water interfacial adsorption coefficients for PFAS when present as a multi-component mixture
inferredcites →https://doi.org/10.1016/j.jconhyd.2021.103842openalex-snapshot
The Mass Transfer Index (MTI): A semi-empirical approach for quantifying transport of solutes in variably saturated porous media
inferredcites →https://doi.org/10.1016/j.jconhyd.2022.104001openalex-snapshot
A field study to assess the role of air-water interfacial sorption on PFAS leaching in an AFFF source area
inferredcites →https://doi.org/10.1016/j.jhazmat.2020.123688openalex-snapshot
Effects of ionic strength and cation type on the transport of perfluorooctanoic acid (PFOA) in unsaturated sand porous media
inferredcites →https://doi.org/10.1016/j.jhazmat.2021.125169openalex-snapshot
Simulating PFAS adsorption kinetics, adsorption isotherms, and nonideal transport in saturated soil with tempered one-sided stable density (TOSD) based models
inferredcites →https://doi.org/10.1016/j.jhydrol.2021.127172openalex-snapshot
Model validation and analyses of parameter sensitivity and uncertainty for modeling long-term retention and leaching of PFAS in the vadose zone
inferredcites →https://doi.org/10.1016/j.jhydrol.2022.127479openalex-snapshot
Transport of perfluorooctanoic acid in unsaturated porous media mediated by SDBS
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Influences of temperature, pH and salinity on the surface property and self-assembly of 1:1 salt-free catanionic surfactant
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Pore network structure linked by X-ray CT to particle characteristics and transport parameters
inferredcites →https://doi.org/10.1016/j.scitotenv.2017.09.065openalex-snapshot
Assessing the potential contributions of additional retention processes to PFAS retardation in the subsurface
inferredcites →https://doi.org/10.1016/j.scitotenv.2020.136744openalex-snapshot
The influence of solution chemistry on air-water interfacial adsorption and transport of PFOA in unsaturated porous media
inferredcites →https://doi.org/10.1016/j.scitotenv.2020.139186openalex-snapshot
Distribution and effects of branched versus linear isomers of PFOA, PFOS, and PFHxS: A review of recent literature
inferredcites →https://doi.org/10.1016/j.scitotenv.2020.140017openalex-snapshot
PFAS concentrations in soils: Background levels versus contaminated sites
inferredcites →https://doi.org/10.1016/j.scitotenv.2021.145427openalex-snapshot
Fate and transport of per- and polyfluoroalkyl substances (PFASs) in the vadose zone
inferredcites →https://doi.org/10.1016/j.scitotenv.2021.148893openalex-snapshot
A new framework for modeling the effect of salt on interfacial adsorption of PFAS in environmental systems
inferredcites →https://doi.org/10.1016/j.scitotenv.2021.150595openalex-snapshot
The impact of multiple-component PFAS solutions on fluid-fluid interfacial adsorption and transport of PFOS in unsaturated porous media
inferredcites →https://doi.org/10.1016/j.watres.2018.05.020openalex-snapshot
Physicochemical factors controlling the retention and transport of perfluorooctanoic acid (PFOA) in saturated sand and limestone porous media
inferredcites →https://doi.org/10.1016/j.watres.2018.10.035openalex-snapshot
Comprehensive retention model for PFAS transport in subsurface systems
inferredcites →https://doi.org/10.1016/j.watres.2020.116778openalex-snapshot
Examining the robustness and concentration dependency of PFAS air-water and NAPL-water interfacial adsorption coefficients
inferredcites →https://doi.org/10.1016/j.watres.2021.117405openalex-snapshot
Ideal versus Nonideal Transport of PFAS in Unsaturated Porous Media
inferredcites →https://doi.org/10.1016/j.watres.2021.117785openalex-snapshot
Air-water interfacial areas relevant for transport of per and poly-fluoroalkyl substances
inferredcites →https://doi.org/10.1016/s0022-1694(99)00047-5openalex-snapshot
Estimation of relative hydraulic conductivity of sandy soils based on a sheet flow model
inferredcites →https://doi.org/10.1016/s0309-1708(96)00036-xopenalex-snapshot
Multiphase flow and transport modeling in heterogeneous porous media: challenges and approaches
inferredcites →https://doi.org/10.1021/acs.est.0c00792openalex-snapshot
Enhanced Extraction of AFFF-Associated PFASs from Source Zone Soils
inferredcites →https://doi.org/10.1021/acs.est.0c01838openalex-snapshot
Comment on “Uptake of Poly- and Perfluoroalkyl Substances at the Air–Water Interface”
inferredcites →https://doi.org/10.1021/acs.est.0c02488openalex-snapshot
Response to the Comment on “Uptake of Poly- and Perfluoroalkyl Substances at the Air-Water Interface”
inferredcites →https://doi.org/10.1021/acs.est.0c03117openalex-snapshot
Aqueous Film-Forming Foams Exhibit Greater Interfacial Activity than PFOA, PFOS, or FOSA
inferredcites →https://doi.org/10.1021/acs.est.0c08506openalex-snapshot
Environmental Source Tracking of Per- and Polyfluoroalkyl Substances within a Forensic Context: Current and Future Techniques
inferredcites →https://doi.org/10.1021/acs.est.1c01919openalex-snapshot
Impact of a Hydrocarbon Surfactant on the Retention and Transport of Perfluorooctanoic Acid in Saturated and Unsaturated Porous Media
inferredcites →https://doi.org/10.1021/acs.est.8b02348openalex-snapshot
Adsorption of PFOA at the Air–Water Interface during Transport in Unsaturated Porous Media
inferredcites →https://doi.org/10.1021/acs.est.9b04008openalex-snapshot
Uptake of Poly- and Perfluoroalkyl Substances at the Air–Water Interface
inferredcites →https://doi.org/10.1021/acs.estlett.9b00355openalex-snapshot
Accumulation of PFOA and PFOS at the Air–Water Interface
inferredcites →https://doi.org/10.1021/es061474mopenalex-snapshot
Measuring Air−Water Interfacial Areas with X-ray Microtomography and Interfacial Partitioning Tracer Tests
inferredcites →https://doi.org/10.1021/es062449jopenalex-snapshot
Modeling Sorption of Anionic Surfactants onto Sediment Materials: An a priori Approach for Perfluoroalkyl Surfactants and Linear Alkylbenzene Sulfonates
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Perfluorinated Surfactants in Surface, Subsurface Water and Microlayer from Dalian Coastal Waters in China
inferredcites →https://doi.org/10.1021/es7032026openalex-snapshot
Aerosol Enrichment of the Surfactant PFO and Mediation of the Water−Air Transport of Gaseous PFOA
inferredcites →https://doi.org/10.1021/es991359uopenalex-snapshot
Perfluorinated Surfactants and the Environmental Implications of Their Use in Fire-Fighting Foams
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The effect of water content on solute transport in unsaturated porous media
inferredcites →https://doi.org/10.1029/2000wr900007openalex-snapshot
Experimental measurement of air‐water interfacial area during gravity drainage and secondary imbibition in porous media
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Relationships among air‐water interfacial area, capillary pressure, and water saturation for a sandy porous medium
inferredcites →https://doi.org/10.1029/2006wr005814openalex-snapshot
Comparison of height‐averaged and point‐measured capillary pressure–saturation relations for sands using a modified Tempe cell
inferredcites →https://doi.org/10.1029/2010wr009092openalex-snapshot
A new capillary and thin film flow model for predicting the hydraulic conductivity of unsaturated porous media
inferredcites →https://doi.org/10.1029/2018wr023554openalex-snapshot
Saturation Dependence of Non‐Fickian Transport in Porous Media
inferredcites →https://doi.org/10.1029/2019wr026667openalex-snapshot
A Mathematical Model for the Release, Transport, and Retention of Per‐ and Polyfluoroalkyl Substances (PFAS) in the Vadose Zone
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Multiple-rate mass transfer for modeling diffusion and surface reactions in media with pore-scale heterogeneity
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Hydraulic Behavior of Quasi‐Saturated Soils in the Presence of Entrapped Air: Laboratory Experiments
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Determination of effective air‐water interfacial area in partially saturated porous media using surfactant adsorption
inferredcites →https://doi.org/10.1029/wr025i009p01971openalex-snapshot
Modeling the transport of solutes influenced by multiprocess nonequilibrium
inferredcites →https://doi.org/10.1039/c8em00343bopenalex-snapshot
Novel fluid–fluid interface domains in geologic media
inferredcites →https://doi.org/10.1039/c8em00525gopenalex-snapshot
Global transport of perfluoroalkyl acids via sea spray aerosol
inferredcites →https://doi.org/10.1061/(asce)0733-9372(1996)122:9(830)openalex-snapshot
Solution of the Advection-Dispersion Equation: Continuous Load of Finite Duration
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Electrical Conductivity Breakthrough Curves
inferredcites →https://doi.org/10.1063/1.5009075openalex-snapshot
Influence of capillary end effects on steady-state relative permeability estimates from direct pore-scale simulations
inferredcites →https://doi.org/10.1071/en11007openalex-snapshot
Water-to-air transfer of perfluorinated carboxylates and sulfonates in a sea spray simulator
inferredcites →https://doi.org/10.1073/pnas.2011716117openalex-snapshot
Direct characterization of solute transport in unsaturated porous media using fast X-ray synchrotron microtomography
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Sorption nonideality during organic contaminant transport in porous media
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Quasi-Saturated Soil and Its Research Directions
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Calibration and Uncertainty Analysis for Complex Environmental Models
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Modelling and Interpretation of Adsorption Isotherms
inferredcites →https://doi.org/10.17226/10102openalex-snapshot
Conceptual Models of Flow and Transport in the Fractured Vadose Zone
inferredcites →https://doi.org/10.2113/4.1.139openalex-snapshot
The Effect of Entrapped Air on the Quasi-Saturated Soil Hydraulic Conductivity and Comparison with the Unsaturated Hydraulic Conductivity
inferredcites →https://doi.org/10.2136/sssaj1976.03615995004000040011xopenalex-snapshot
Mass Transfer Studies in Sorbing Porous Media I. Analytical Solutions
inferredcites →https://doi.org/10.2136/sssaj2004.1539openalex-snapshot
Anomalous Transport in “Classical” Soil and Sand Columns
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Solute Transport Dynamics by High‐Resolution Dye Tracer Experiments—Image Analysis and Time Moments
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Modeling Nonequilibrium Flow and Transport Processes Using HYDRUS
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Dynamic Effect in Capillary Pressure- Saturation Relationship and its Impact on Unsaturated Flow
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Research on the Correction Method of the Capillary End Effect of the Relative Permeability Curve of the Steady State
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A Modified HYDRUS Model for Simulating PFAS Transport in the Vadose Zone

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Air-Water Interfacial Collapse and Dual Rate‑Limited Solid Desorption Control Perfluoroalkyl Acid Leaching from the Vadose Zone
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Bridging single‐species research and mixture reality: Emerging contaminants fate and transport in vadose zones
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Bridging Science and Practice: Literature Review and Expert Insights on Per‐ and Polyfluoroalkyl Substances Transport Modeling
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Determining groundwater recharge for quantifying PFAS mass discharge from unsaturated source zones
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Per- and polyfluoroalkyl substances (PFAS) as contaminants in groundwater resources – A comprehensive review of subsurface transport processes
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PFAS Porewater concentrations in unsaturated soil: Field and laboratory comparisons inform on PFAS accumulation at air-water interfaces
inferred← citeshttps://doi.org/10.1016/j.jconhyd.2024.104382openalex-snapshot
Air-water interfacial collapse and rate-limited solid desorption control Perfluoroalkyl acid leaching from the vadose zone
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Factors influencing residual air saturation during consecutive imbibition processes in an air-water two-phase fine sandy medium – A laboratory-scale experimental study
inferred← citeshttps://doi.org/10.1016/j.jconhyd.2024.104424openalex-snapshot
Non-Fickian transport processes accelerate the movement of PFOS in unsaturated media: An experimental and modelling study
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Release of poly- and perfluoroalkyl substances from AFFF-impacted soils: Effects of water saturation in vadose zone soils
inferred← citeshttps://doi.org/10.1016/j.jconhyd.2025.104728openalex-snapshot
PFAS conceptual site model of an AFFF-impacted firefighting training area informed by high resolution soil, porewater, and groundwater sampling
inferred← citeshttps://doi.org/10.1016/j.jconhyd.2026.104859openalex-snapshot
Effects of transient air-water interfacial area on PFOA transport in unsaturated soil
inferred← citeshttps://doi.org/10.1016/j.jenvman.2024.123163openalex-snapshot
Fate, distribution, and transport dynamics of Per- and Polyfluoroalkyl Substances (PFASs) in the environment
inferred← citeshttps://doi.org/10.1016/j.jhazmat.2022.129782openalex-snapshot
Enrichment of poly- and perfluoroalkyl substances (PFAS) in the surface microlayer and foam in synthetic and natural waters
inferred← citeshttps://doi.org/10.1016/j.jhazmat.2025.138728openalex-snapshot
The accumulation of per- and polyfluoroalkyl substances (PFAS) at the air−water interface: A systematic review
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Fractal geometry of fingering front morphologies of water and NAPL flow in homogeneous porous media: A comparison study
inferred← citeshttps://doi.org/10.1016/j.scitotenv.2024.177420openalex-snapshot
Influence of kinetic air-water interfacial partitioning on unsaturated transport of PFAS in sandy soils
inferred← citeshttps://doi.org/10.1016/j.scitotenv.2025.179036openalex-snapshot
Laboratory validation of a simplified model for estimating equilibrium PFAS mass leaching from unsaturated soils
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Quantifying the adsorption of PFAS and hydrocarbon surfactants at the air–water interface: A systematic review and meta-analysis of surface-science measurements, molecular-modeling simulations, and environmental-application results
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inferred← citeshttps://doi.org/10.1016/j.watres.2025.124463openalex-snapshot
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inferred← citeshttps://doi.org/10.1021/acs.est.2c00882openalex-snapshot
Retention of PFOS and PFOA Mixtures by Trapped Gas Bubbles in Porous Media
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inferred← citeshttps://doi.org/10.1021/acs.est.2c07316openalex-snapshot
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inferred← citeshttps://doi.org/10.1021/acs.est.2c08806openalex-snapshot
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inferred← citeshttps://doi.org/10.1021/acs.est.3c00267openalex-snapshot
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