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Stabilizing a 20-Electron Metallaazulyne by Aromaticity

https://doi.org/10.1021/acs.inorgchem.2c00594

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Electrophilic Aromatic Substitution Reactions of a Metallabenzene: Nitration and Halogenation of the Osmabenzene [Os{C(SMe)CHCHCHCH}I(CO)(PPh3)2]

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Synthesis and Characterization of a Metallabenzyne

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An Osmium Containing Benzene Analog, Os(CSCHCHCHCH)(CO)(Pph 3 ) 2 , Carbonyl(5‐Thioxo‐1, 3‐Pentadiene‐1, 5‐Diyl‐ C 1 , C 5 , S )‐Bis(Triphenylphosphine)Osmium, and its Precursors

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Unprecedented Tetranuclear Complexes with 20‐Electron NiII Centers: The Role of Pressure and Temperature on Their Solid‐State and Solution Fragmentation

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Synthesis and Characterization of Stable Ruthenabenzenes

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Unprecedented Tetranuclear Complexes with 20‐Electron NiII Centers: The Role of Pressure and Temperature on Their Solid‐State and Solution Fragmentation

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Selective Synthesis of Osmanaphthalene and Osmanaphthalyne by Intramolecular CH Activation

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Triplet State Aromaticity: NICS Criterion, Hyperconjugation, and Charge Effects

inferredcites →https://doi.org/10.1002/chem.200801774openalex-snapshot

Synthesis, Characterization and Electrochemical Properties of Stable Osmabenzenes Containing PPh3 Substituents

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The NICS‐ XY ‐Scan: Identification of Local and Global Ring Currents in Multi‐Ring Systems

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Theoretical Analysis of the Mackay Icosahedral Cluster Pd55(PiPr3)12(μ3‐CO)20: An Open‐Shell 20‐Electron Superatom

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Zwitterionic Aromaticity on Azulene Extrapolated to carbo ‐Azulene

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Electron Delocalization in Planar Metallacycles: Hückel or Möbius Aromatic?

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Recent development in the chemistry of transition metal-containing metallabenzenes and metallabenzynes

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Fused-ring metallabenzenes

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A hierarchy of chemical bonding indices in real space from reduced density matrices and cumulants

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Chromocene, ferrocene, cobaltocene, and nickelocene derivatives with isopropyl and methyl or trimethylsilyl substituents

inferredcites →https://doi.org/10.1016/s0010-8545(02)00120-0openalex-snapshot

From nickelocene to novel organonickel compounds

inferredcites →https://doi.org/10.1016/s0022-328x(00)00717-8openalex-snapshot

Reaction between the thiocarbonyl complex, Os(CS)(CO)(PPh3)3, and propyne: crystal structure of a new sulfur-substituted osmabenzene

inferredcites →https://doi.org/10.1021/acs.accounts.1c00146openalex-snapshot

Metalla-aromatics: Planar, Nonplanar, and Spiro

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Carbolong Chemistry: A Story of Carbon Chain Ligands and Transition Metals

inferredcites →https://doi.org/10.1021/acs.accounts.9b00092openalex-snapshot

Unconventional Aromaticity in Organometallics: The Power of Transition Metals

inferredcites →https://doi.org/10.1021/acs.chemrev.0c00392openalex-snapshot

Metallaaromatic Chemistry: History and Development

inferredcites →https://doi.org/10.1021/acs.jpca.9b10113openalex-snapshot

Bond Order Densities in Real Space

inferredcites →https://doi.org/10.1021/acs.organomet.7b00213openalex-snapshot

Synthesis, Characterization and Reactivity of Formal 20 Electron Zirconocene-Pentafulvene Complexes

inferredcites →https://doi.org/10.1021/ar400087xopenalex-snapshot

The Chemistry of Aromatic Osmacycles

inferredcites →https://doi.org/10.1021/cr030088+openalex-snapshot

Nucleus-Independent Chemical Shifts (NICS) as an Aromaticity Criterion

inferredcites →https://doi.org/10.1021/cr0300901openalex-snapshot

Anisotropy of the Induced Current Density (ACID), a General Method To Quantify and Visualize Electronic Delocalization

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Revised Basis Sets for the LANL Effective Core Potentials

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The eighteen electron rule

inferredcites →https://doi.org/10.1021/j100096a001openalex-snapshot

Ab Initio Calculation of Vibrational Absorption and Circular Dichroism Spectra Using Density Functional Force Fields

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Nuclear Magnetic Resonance Shielding Tensors Calculated with a Sum-over-States Density Functional Perturbation Theory

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Bis-cyclopentadienyl Compounds of Nickel and Cobalt

inferredcites →https://doi.org/10.1021/ja035655popenalex-snapshot

Formation of Unusual Iridabenzene and Metallanaphthalene Containing Electron-Withdrawing Substituents

inferredcites →https://doi.org/10.1021/ja0486871openalex-snapshot

Osmabenzenes from the Reactions of HC≡CCH(OH)C≡CH with OsX2(PPh3)3 (X = Cl, Br)

inferredcites →https://doi.org/10.1021/ja960582dopenalex-snapshot

Nucleus-Independent Chemical Shifts: A Simple and Efficient Aromaticity Probe

inferredcites →https://doi.org/10.1021/ja970779lopenalex-snapshot

Synthesis and Reactivity of a Metallapyrylium1

inferredcites →https://doi.org/10.1021/jacs.1c02237openalex-snapshot

Ruthenabenzene: A Robust Precatalyst

inferredcites →https://doi.org/10.1021/jacs.1c08106openalex-snapshot

Releasing Antiaromaticity in Metal-Bridgehead Naphthalene

inferredcites →https://doi.org/10.1021/jacs.9b03257openalex-snapshot

Cd 12 Ag 32 (SePh) 36 : Non-Noble Metal Doped Silver Nanoclusters

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Synthesis and Characterization of a Novel Dialdehyde and Cyclic Anhydride

inferredcites →https://doi.org/10.1021/jp011945lopenalex-snapshot

Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements

inferredcites →https://doi.org/10.1021/jp035163zopenalex-snapshot

Analysis of Aromatic Delocalization: Individual Molecular Orbital Contributions to Nucleus-Independent Chemical Shifts

inferredcites →https://doi.org/10.1021/jp0538464openalex-snapshot

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inferredcites →https://doi.org/10.1021/ol016217vopenalex-snapshot

Dissected Nucleus-Independent Chemical Shift Analysis of π-Aromaticity and Antiaromaticity

inferredcites →https://doi.org/10.1021/ol0529546openalex-snapshot

Which NICS Aromaticity Index for Planar π Rings Is Best?

inferredcites →https://doi.org/10.1021/om0008068openalex-snapshot

Synthesis, Spectroscopy, and Reactivity of a Metallapyrylium1

inferredcites →https://doi.org/10.1021/om0510371openalex-snapshot

An Osmabenzofuran from Reaction between Os(PhC⋮CPh)(CS)(PPh3)2 and Methyl Propiolate and the C-Protonation of this Compound to Form a Tethered Osmabenzene

inferredcites →https://doi.org/10.1021/om061066ropenalex-snapshot

Stepwise Reactions of Acetylenes with Iridium Thiocarbonyl Complexes To Produce Isolable Iridacyclobutadienes and Conversion of These to either Cyclopentadienyliridium or Tethered Iridabenzene Complexes

inferredcites →https://doi.org/10.1021/om070195kopenalex-snapshot

Synthesis and Characterization of Stable Ruthenabenzenes Starting from HC⋮CCH(OH)C⋮CH

inferredcites →https://doi.org/10.1021/om100888zopenalex-snapshot

Regioselective Mono-, Di-, and Trifunctionalization of Iridabenzofurans through Electrophilic Substitution Reactions

inferredcites →https://doi.org/10.1021/om400469eopenalex-snapshot

Conversion of a Hydrido–Butenylcarbyne Complex to η2-Allene-Coordinated Complexes and Metallabenzenes

inferredcites →https://doi.org/10.1021/om800857kopenalex-snapshot

Stable Cationic and Neutral Ruthenabenzenes

inferredcites →https://doi.org/10.1021/om800907vopenalex-snapshot

Synthesis of Coordinated η2-α,β-Unsaturated Ketone Osmacycles from an Osmium-Coordinated Alkyne Alcohol Complex

inferredcites →https://doi.org/10.1038/nature20798openalex-snapshot

Aromatic and antiaromatic ring currents in a molecular nanoring

inferredcites →https://doi.org/10.1038/nchem.1690openalex-snapshot

Stabilization of anti-aromatic and strained five-membered rings with a transition metal

inferredcites →https://doi.org/10.1038/nchem.2743openalex-snapshot

Main-chain metallopolymers at the static–dynamic boundary based on nickelocene

inferredcites →https://doi.org/10.1038/ncomms4265openalex-snapshot

Planar Möbius aromatic pentalenes incorporating 16 and 18 valence electron osmiums

inferredcites →https://doi.org/10.1038/s41467-021-21648-9openalex-snapshot

A tris-spiro metalla-aromatic system featuring Craig-Möbius aromaticity

inferredcites →https://doi.org/10.1038/s42004-020-00419-5openalex-snapshot

Open questions on aromaticity in organometallics

inferredcites →https://doi.org/10.1039/c39820000811openalex-snapshot

Metallacyclohexatrienes or ‘metallabenzenes.’ Synthesis of osmabenzene derivatives and X-ray crystal structure of [Os(CSCHCHCHCH)(CO)(PPh 3 ) 2 ]

inferredcites →https://doi.org/10.1039/c4cp02932aopenalex-snapshot

A uniform approach to the description of multicenter bonding

inferredcites →https://doi.org/10.1039/c5cs00004aopenalex-snapshot

Aromaticity of metallabenzenes and related compounds

inferredcites →https://doi.org/10.1039/d1cc03261eopenalex-snapshot

Carbolong chemistry: nucleophilic aromatic substitution of a triflate functionalized iridapentalene

inferredcites →https://doi.org/10.1039/d1sc01571kopenalex-snapshot

Direct amidation of metallaaromatics: access to N -functionalized osmapentalynes via a 1,5-bromoamidated intermediate

inferredcites →https://doi.org/10.1063/1.1677527openalex-snapshot

Self—Consistent Molecular Orbital Methods. XII. Further Extensions of Gaussian—Type Basis Sets for Use in Molecular Orbital Studies of Organic Molecules

inferredcites →https://doi.org/10.1063/1.438955openalex-snapshot

Self-consistent molecular orbital methods. XX. A basis set for correlated wave functions

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Self-consistent molecular orbital methods 25. Supplementary functions for Gaussian basis sets

inferredcites →https://doi.org/10.1063/1.448800openalex-snapshot

Ab initio effective core potentials for molecular calculations. Potentials for main group elements Na to Bi

inferredcites →https://doi.org/10.1063/1.448975openalex-snapshot

Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals

inferredcites →https://doi.org/10.1063/1.464913openalex-snapshot

Density-functional thermochemistry. III. The role of exact exchange

inferredcites →https://doi.org/10.1103/physreva.38.3098openalex-snapshot

Density-functional exchange-energy approximation with correct asymptotic behavior

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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A Deep Insight into the Nature of the Si-N Bond

inferred← citeshttps://doi.org/10.1002/chem.202202334openalex-snapshot

Pentacyclic and Hexacyclic Osmaarynes and Their Derivatives

inferred← citeshttps://doi.org/10.1021/acs.inorgchem.3c01029openalex-snapshot

Aromaticity of Osmaacenes in Their Lowest-Lying Singlet and Triplet States

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