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Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen von [Na(12-Krone-4)2][M{N(SiMe3)2}3(OSiMe3)] (M = Sm, Yb), [Na(THF)3Sm{N(SiMe3)2}3(C≡C-Ph)], [Na(THF)6][Lu2(μ-NH2)(μ-NSiMe3){N(SiMe3)2}4] sowie von [NaN(SiMe3)2(THF)]2. Anwendungen der Seltenerdkomplexe als…
Synthetically Important Alkali‐Metal Utility Amides: Lithium, Sodium, and Potassium Hexamethyldisilazides, Diisopropylamides, and Tetramethylpiperidides
Organometallic Polymers Assembled from Cation–π Interactions: Use of Ferrocene as a Ditopic Linker Within the Homologous Series [{(Me3Si)2NM}2⋅(Cp2Fe)]∞ (M=Na, K, Rb, Cs; Cp=cyclopentadienyl)
Synthesis, Structure and Theoretical Studies of the Hydrido Inverse Crown [K2Mg2(NiPr2)4(μ‐H)2·(toluene)2]: a Rare Example of a Molecular Magnesium Hydride with a Mg‐(μ‐H)2‐Mg Double Bridge
Novel 18-crown-6 organometallic rubidium and cesium complexes containing cyclopentadienyl, indenyl, pentamethylcyclopentadienyl, and fluorenyl as carbanions
Synthetic and Structural Studies of Mixed Sodium Bis(trimethylsilyl)amide/Sodium Halide Aggregates in the Presence of η2-N,N-, η3-N,N,N/N,O,N-, and η4-N,N,N,N-Donor Ligands
Synthesis and Structures of Monomeric Magnesium, Calcium, Strontium, and Barium Amides Involving the N,N-(2,4,6-Trimethylphenyl)(trimethylsilyl)amido Ligand
Structure and reactivity of sterically hindered lithium amides and their diethyl etherates: crystal and molecular structures of [Li{N(SiMe3)2}(OEt2)]2 and tetrakis(2,2,6,6-tetramethylpiperidinatolithium)
Effect of Polydentate Donor Molecules on Lithium Hexamethyldisilazide Aggregation: An X-ray Crystallographic and a Combination Semiempirical PM3/Single Point ab Initio Theoretical Study
Intermetallic Lithium−Magnesium Hexamethyldisilazide: Synthesis and Structure, Discovery of an Oxygen-Centered Variant, and a Reaction with Benzonitrile That Produces a Novel Amidinate Cage Compound with a Trigonal Bipyramidal Li4MgO Core
Synthesis and Structures of the Crystalline Heavier Alkali Metal Alkyls: X-ray Structures of [K(μ-R){O(Me)But}]∞, [(pmdeta)K(μ-R)K(μ-R)2K(μ-R)K(pmdeta)], and [Cs(μ-R)(tmeda)]∞ (R = CH(SiMe3)2)
Synthesis and Solid State Structures of Sterically Congested Sodium and Cesium Silyl(fluorosilyl)phosphanide Aggregates and Structural Characterization of the Trimeric Sodium Bis(trimethylsilyl)amide
Low co-ordination numbers in lanthanide and actinide compounds. Part I. The preparation and characterization of tris{bis(trimethylsilyl)-amido}lanthanides
Introducing a Hydrogen‐Bond Donor into a Weakly Nucleophilic Brønsted Base: Alkali Metal Hexamethyldisilazides (MHMDS, M=Li, Na, K, Rb and Cs) with Ammonia
Alkali Metal Carbatrane Compounds [TismPriBenz]M: Synthesis and Structural Characterization of a Complete Series of Monomeric Alkali Metal Alkyl Compounds
Stereoselective Electrophilic α-Alkynylation of α,α-Disubstituted N-tert-Butanesulfinyl Ketimines for Construction of Less Accessible Acyclic Quaternary Stereocenters
Straightforward synthesis of rubidium bis(trimethylsilyl)amide and complexes of the alkali metal bis(trimethylsilyl)amides with weakly coordinating 2,2,5,5-tetramethyltetrahydrofuran
Influence of alkali metal cations on the formation of the heterobimetallic actinide tert -butoxides [AnM 3 (O t Bu) 7 ] and [AnM 2 (O t Bu) 6 ] (An IV = Th, U; M I = Li, Na, K, Rb, Cs)
Heterobimetallic Uranium(V)-Alkali Metal Alkoxides: Expanding the Chemistry of f-Block Elements
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