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Effect of Ionizing Radiation on the Redox Chemistry of Penta- and Hexavalent Americium

https://doi.org/10.1021/acs.inorgchem.9b00854

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Reaction between nitrous acid and hydrogen peroxide in perchloric acid medium

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The Chemistry of the Actinide and Transactinide Elements

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Preparation and investigation of properties of divalent americium ions in aqueous solutions by the impulse radiolysis method

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Radiolytic reduction of Am (VI) and Am (V)

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Disproportionation of Am (IV)

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Oxidation of Am(III) and stability of Am(IV) and Am(VI) in mineral acid solutions

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Aqueous aerosol oxidation of nitrous acid by O2, O3 AND H2O2

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Higher oxidation states of americium in phosphate solutions

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The alpha half-life of amer cium-241

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Behaviour of americium(IV) in phosphoric acid solutions

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Enthalpy formation of americium dioxide and a thermochemical estimate of the electrode potential Am4+/Am3+

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Standard Potentials in Aqueous Solution.

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The study of reactivity of actinide ions towards hydrated electrons and hydrogen atoms in acid aqueous solutions by a pulse radiolysis method

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Radiochemistry and Nuclear Chemistry

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Determination of Optimal Conditions for Synthesis of Peroxynitrite by Mixing Acidified Hydrogen Peroxide with Nitrite

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Extraction chromatographic method for rapid separation of americium from other transuranium elements

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Hexavalent Americium Recovery Using Copper(III) Periodate

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Kinetics of the Autoreduction of Hexavalent Americium in Aqueous Nitric Acid

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Decay Mechanism of NO3•Radical in Highly Concentrated Nitrate and Nitric Acidic Solutions in the Absence and Presence of Hydrazine

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Multi-Scale Modeling of the Gamma Radiolysis of Nitrate Solutions

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Reevaluation of Neptunium–Nitric Acid Radiation Chemistry by Multiscale Modeling

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Plutonium and Americium Alpha Radiolysis of Nitric Acid Solutions

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Higher Oxidation States of Americium: Preparation, Characterization and Use for Separations

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Reduction potential of the nitrate radical in aqueous solution

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Rates of oxidation of selected actinides by Cl2-

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Preparation and Properties of Aqueous Tetravalent Americium

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The Kinetics of the Disproportionation of Americium(V)

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Pulse-radiolysis studies of americium ions in aqueous perchlorate media

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Tributylphosphate Extraction Behavior of Bismuthate-Oxidized Americium

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Formation and decay of peroxynitrous acid: a pulse radiolysis study

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Decomposition of pernitric acid in aqueous solution

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Hexavalent Americium1

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A NEW VALENCE STATE OF AMERICIUM, AM(VI)1

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The Heats of Formation of AmO2+(aq) and AmO2++(aq) in 1 M HClO41

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Interaction of Nitrous Acid with Hydrogen Peroxide and with Water

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Effects of Track Structure on the Ion Radiolysis of the Fricke Dosimeter

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Effect of pH on H2O2 Production in the Radiolysis of Water

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Monte Carlo Simulation of Range and Energy Deposition by Electrons in Gaseous and Liquid Water

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Temperature Dependence of Hydrogen Atom Reaction with Nitrate and Nitrite Species in Aqueous Solution

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Stochastic models of multi-species kinetics in radiation-induced spurs

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γ-Radiolysis study of concentrated nitric acid solutions

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Kinetics and mechanism of the formation and decay of peroxynitrous acid in perchloric acid solutions

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168. Pernitrous acid. The reaction between hydrogen peroxide and nitrous acid, and the properties of an intermediate product

inferredcites →https://doi.org/10.1039/jr9540002214openalex-snapshot

The separation and purification of americium-241 and the absorption spectra of tervalent and quinquevalent americium solutions

inferredcites →https://doi.org/10.1063/1.1698619openalex-snapshot

The Solution Absorption Spectra of Americium(III), (V), and (VI)

inferredcites →https://doi.org/10.1063/1.1749558openalex-snapshot

The Oxidation of Fe++ to Fe+++ by the Irradiation with X-Rays of Solutions of Ferrous Sulfate in Sulfuric Acid

inferredcites →https://doi.org/10.1063/1.555805openalex-snapshot

Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O− in Aqueous Solution

inferredcites →https://doi.org/10.1080/07366299.2012.671108openalex-snapshot

Diamylamylphosphonate Solvent Extraction of Am(VI) from Nuclear Fuel Raffinate Simulant Solution

inferredcites →https://doi.org/10.1080/07366299.2013.850288openalex-snapshot

Characterizing Diamylamylphosphonate (DAAP) as an Americium Ligand for Nuclear Fuel-Cycle Applications

inferredcites →https://doi.org/10.1080/10256019008624364openalex-snapshot

Reactivity of Ions of Actinides Towards Inorganic Free Radicals in Irradiated Aqueous Solutions

inferredcites →https://doi.org/10.1126/science.aac9217openalex-snapshot

Electrochemical oxidation of 243 Am(III) in nitric acid by a terpyridyl-derivatized electrode

inferredcites →https://doi.org/10.1134/s1066362207040078openalex-snapshot

Behavior of Am(V) in concentrated HNO3 solutions containing potassium phosphotungstate K10P2W17O61

inferredcites →https://doi.org/10.1177/0003702817721528openalex-snapshot

Optical Absorption Characteristics For 7F0'→5L6' and 7F0'→ 7F6' Transitions of Trivalent Americium Ion in Aqueous Electrolyte Mixtures

inferredcites →https://doi.org/10.1524/ract.1985.38.1.29openalex-snapshot

Radiolytic Oxidation of Am (III) to Am(V) in NaCl Solutions

inferredcites →https://doi.org/10.2172/4188896openalex-snapshot

Kinetics of the oxidation-reduction reactions of uranium, neptunium, plutonium, and americium in aqueous solutions

inferredcites →https://doi.org/10.2172/7232133openalex-snapshot

Chemistry of americium

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Group Separation of Hexavalent Actinides from Lanthanides Through Selective Extraction by 2-Ethylhexyl Phosphonic Acid Mono-2-Ethylhexyl Ester

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Understanding the Stability of the Unusual Oxidation States of Americium in Different Mineral Acids

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Large-Scale Models of Radiation Chemistry and the Principle of Detailed Balancing

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Ultra-Efficient Americium/Lanthanide Separation through Oxidation State Control

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Isolation of an Americium Complex Containing a Radical Ligand

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Curium( iii ) radiation-induced reaction kinetics in aqueous media

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Multiscale modelling of the radical-induced chemistry of acetohydroxamic acid in aqueous solution

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inferred← citeshttps://doi.org/10.1039/d4dt00991fopenalex-snapshot

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The inorganic chemist's guide to actinide radiation chemistry: a review

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