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Polybutadiene Vitrimers Based on Dioxaborolane Chemistry and Dual Networks with Static and Dynamic Cross-links

https://doi.org/10.1021/acs.macromol.9b01288

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Boronic Acids

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Polybutadiènes hydroxytéléchéliques, 5. Addition des thiols sur les double liaisons des polybutadiènes hydroxytéléchéliques radicalaire et anionique. Etude des mécanismes d'addition par 1H et 13C NMR

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Rubber elasticity in highly crosslinked polyethyl acrylate

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Architecture-transformable polymers: Reshaping the future of stimuli-responsive polymers

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Reprocessable Acid-Degradable Polycarbonate Vitrimers

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Vitrimers Designed Both To Strongly Suppress Creep and To Recover Original Cross-Link Density after Reprocessing: Quantitative Theory and Experiments

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Phase Separation and Self-Assembly in Vitrimers: Hierarchical Morphology of Molten and Semicrystalline Polyethylene/Dioxaborolane Maleimide Systems

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Poly(thioether) Vitrimers via Transalkylation of Trialkylsulfonium Salts

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inferredcites →https://doi.org/10.1098/rsta.1976.0001openalex-snapshot

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An Enhanced Intermolecular Boron–Nitrogen Coordination Strategy for Vitrimers with Mechanical Robustness and Continuous Reprocessability

inferred← citeshttps://doi.org/10.1021/acs.chemrev.5c00307openalex-snapshot

From β-Dicarbonyl Chemistry to Dynamic Polymers

inferred← citeshttps://doi.org/10.1021/acs.iecr.1c04717openalex-snapshot

Controllable Preparation of the Reversibly Cross-Linked Rubber Based on Imine Bonds Starting from Telechelic Liquid Rubber

inferred← citeshttps://doi.org/10.1021/acs.iecr.2c02089openalex-snapshot

Recyclable Sulfur-Cured Rubbers with Enhanced Creep Resistance and Retained Mechanical Properties by Terminal Metal Coordination

inferred← citeshttps://doi.org/10.1021/acs.iecr.2c03133openalex-snapshot

Preparation of Styrene–Butadiene Rubber Vitrimers with High Strength and Toughness through Imine and Hydrogen Bonds

inferred← citeshttps://doi.org/10.1021/acs.iecr.3c04238openalex-snapshot

Fabrication of Recyclable Polyisoprene Elastomers with Tuneable Mechanical Properties by Incorporating Dynamic Bonds and Separated Polystyrene Phase

inferred← citeshttps://doi.org/10.1021/acs.iecr.4c02983openalex-snapshot

Reprocessable and Self-Healable Boronic-Ester-Based SBS Vitrimers with Improved Thermomechanical Property and Adhesive Performance

inferred← citeshttps://doi.org/10.1021/acs.iecr.4c02989openalex-snapshot

New Insights into the Strengthening Mechanism of Nanofillers in Terminally Functionalized Polyisoprene Rubbers

inferred← citeshttps://doi.org/10.1021/acs.iecr.4c04134openalex-snapshot

Synthesis of Cross-Linked Polyolefin Elastomers with High Performance Yet Good Reprocessability

inferred← citeshttps://doi.org/10.1021/acs.macromol.0c00453openalex-snapshot

Network Design to Control Polyimine Vitrimer Properties: Physical Versus Chemical Approach

inferred← citeshttps://doi.org/10.1021/acs.macromol.0c01691openalex-snapshot

Arresting Elevated-Temperature Creep and Achieving Full Cross-Link Density Recovery in Reprocessable Polymer Networks and Network Composites via Nitroxide-Mediated Dynamic Chemistry

inferred← citeshttps://doi.org/10.1021/acs.macromol.0c02221openalex-snapshot

Tuning the Viscosity Profiles of High-Tg Poly(1,2,3-triazolium) Covalent Adaptable Networks by the Chemical Structure of the N-Substituents

inferred← citeshttps://doi.org/10.1021/acs.macromol.0c02530openalex-snapshot

Unentangled Vitrimer Melts: Interplay between Chain Relaxation and Cross-link Exchange Controls Linear Rheology

inferred← citeshttps://doi.org/10.1021/acs.macromol.0c02649openalex-snapshot

Synthesis of Polyethylene Vitrimers in a Single Step: Consequences of Graft Structure, Reactive Extrusion Conditions, and Processing Aids

inferred← citeshttps://doi.org/10.1021/acs.macromol.0c02699openalex-snapshot

Biosourced Acetal and Diels–Alder Adduct Concurrent Polyurethane Covalent Adaptable Network

inferred← citeshttps://doi.org/10.1021/acs.macromol.0c02706openalex-snapshot

Neighboring Group Participation and Internal Catalysis Effects on Exchangeable Covalent Bonds: Application to the Thriving Field of Vitrimer Chemistry

inferred← citeshttps://doi.org/10.1021/acs.macromol.0c02744openalex-snapshot

Mechanical and Structural Consequences of Associative Dynamic Cross-Linking in Acrylic Diblock Copolymers

inferred← citeshttps://doi.org/10.1021/acs.macromol.0c02870openalex-snapshot

Strengthening Polyethylene Thermoplastics through a Dynamic Covalent Networking Additive Based on Alkylboron Chemistry

inferred← citeshttps://doi.org/10.1021/acs.macromol.1c00029openalex-snapshot

Highly Stretchable, Ultratough, and Multifunctional Poly(vinyl chloride)-Based Plastics via a Green, Star-Shaped Macromolecular Additive

inferred← citeshttps://doi.org/10.1021/acs.macromol.1c00948openalex-snapshot

Polystyrene Hybrid-Vitrimer Based on the Hemiacetal Ester Exchange Reaction

inferred← citeshttps://doi.org/10.1021/acs.macromol.1c01046openalex-snapshot

Fast Reprocessing of Acetal Covalent Adaptable Networks with High Performance Enabled by Neighboring Group Participation

inferred← citeshttps://doi.org/10.1021/acs.macromol.1c02406openalex-snapshot

Correlation between Self-Assembled Nanostructures and Bond Exchange Properties for Polyacrylate-Based Vitrimer-like Materials with a Trans-N-Alkylation Bond Exchange Mechanism

inferred← citeshttps://doi.org/10.1021/acs.macromol.1c02613openalex-snapshot

Relaxation of Vitrimers with Kinetically Distinct Mixed Dynamic Bonds

inferred← citeshttps://doi.org/10.1021/acs.macromol.2c00752openalex-snapshot

Metal–Ligand Complexes as Dynamic Sacrificial Bonds in Elastic Polymers

inferred← citeshttps://doi.org/10.1021/acs.macromol.2c01595openalex-snapshot

Raman Spectroscopy Reveals Phase Separation in Imine-Based Covalent Adaptable Networks

inferred← citeshttps://doi.org/10.1021/acs.macromol.2c01711openalex-snapshot

Triblock Elastomeric Vitrimers: Preparation, Morphology, Rheology, and Applications

inferred← citeshttps://doi.org/10.1021/acs.macromol.3c00482openalex-snapshot

Structural Design of CANs with Fine-Tunable Relaxation Properties: A Theoretical Framework Based on Network Structure and Kinetics Modeling

inferred← citeshttps://doi.org/10.1021/acs.macromol.3c00883openalex-snapshot

Time–Temperature Superposition of Polybutadiene Vitrimers

inferred← citeshttps://doi.org/10.1021/acs.macromol.3c01129openalex-snapshot

Combination of Fluorine and Tertiary Amine Activation in Catalyst-Free Thia-Michael Covalent Adaptable Networks

inferred← citeshttps://doi.org/10.1021/acs.macromol.3c01983openalex-snapshot

Model Polyisoprene Vitrimers

inferred← citeshttps://doi.org/10.1021/acs.macromol.3c02289openalex-snapshot

Microstructure, Viscoelasticity, and Extensional Rheology of Ethylene–Propylene Copolymer Vitrimers

inferred← citeshttps://doi.org/10.1021/acs.macromol.3c02372openalex-snapshot

High-Performance Olefin Thermoplastic Elastomer Based on Dynamically Cross-Linking Crystalline Macromers and Elastic Backbones

inferred← citeshttps://doi.org/10.1021/acs.macromol.4c00666openalex-snapshot

Tunable Waterborne Aspartic Acid-Based Covalent Adaptable Networks with Internal Catalysis and Incorporation in Bioinspired Nanocomposites

inferred← citeshttps://doi.org/10.1021/acs.macromol.4c01363openalex-snapshot

Cross-Linking Vitrimers after Melt Processing Using Supramolecularly Masked Dynamic Cross-Linkers

inferred← citeshttps://doi.org/10.1021/acs.macromol.5c00552openalex-snapshot

Critical Role of the Steric Factor in the Viscoelasticity of Vitrimers

inferred← citeshttps://doi.org/10.1021/acs.macromol.5c01535openalex-snapshot

Understanding the Interfacial Exchange Reaction Kinetics and Rheological Behavior of Multiphase Vitrimers

inferred← citeshttps://doi.org/10.1021/acs.macromol.5c02945openalex-snapshot

Immiscible Polydimethylsiloxane/Polybutadiene Vitrimer Blends

inferred← citeshttps://doi.org/10.1021/acs.macromol.5c03243openalex-snapshot

Tuning the Viscoelastic Properties of Dioxazaborocane Vitrimers via Chemical Design of the Functional Groups

inferred← citeshttps://doi.org/10.1021/acs.macromol.6c00582openalex-snapshot

Network Topology and Linear Viscoelasticity of Vitrimers─A Polymer Physics Perspective

inferred← citeshttps://doi.org/10.1021/acs.macromol.6c00599openalex-snapshot

Viscoelastic Properties of Transient Polymer Networks with Stimuli-Responsive Cross-Link Junctions

inferred← citeshttps://doi.org/10.1021/acs.macromol.6c01360openalex-snapshot

Temperature and Pressure Effects on the Dynamics of Elastomeric Dioxaborolane Vitrimers

inferred← citeshttps://doi.org/10.1021/acs.macromol.6c01730openalex-snapshot

Large-Strain Viscoelasticity of Partial Vitrimer Silicone Rubber Networks with Stress-Assisted Bond Exchange and Topological Constraints

inferred← citeshttps://doi.org/10.1021/acs.macromol.9b02204openalex-snapshot

Rheological Properties of Covalent Adaptable Networks with 1,2,3-Triazolium Cross-Links: The Missing Link between Vitrimers and Dissociative Networks

inferred← citeshttps://doi.org/10.1021/acs.macromol.9b02325openalex-snapshot

Strong, Reconfigurable, and Recyclable Thermosets Cross-Linked by Polymer–Polymer Dynamic Interaction Based on Commodity Thermoplastics

inferred← citeshttps://doi.org/10.1021/acs.macromol.9b02415openalex-snapshot

Linear Viscoelasticity and Flow of Self-Assembled Vitrimers: The Case of a Polyethylene/Dioxaborolane System

inferred← citeshttps://doi.org/10.1021/acsami.0c09712openalex-snapshot

Assembling of Reprocessable Polybutadiene-Based Vitrimers with High Strength and Shape Memory via Catalyst-Free Imine-Coordinated Boroxine

inferred← citeshttps://doi.org/10.1021/acsami.1c23007openalex-snapshot

Self-Strengthening, Self-Welding, Shape Memory, and Recyclable Polybutadiene-Based Material Driven by Dual-Dynamic Units

inferred← citeshttps://doi.org/10.1021/acsami.2c13339openalex-snapshot

Renewable Vanillin-Based Thermoplastic Polybutadiene Rubber: High Strength, Recyclability, Self-Welding, Shape Memory, and Antibacterial Properties

inferred← citeshttps://doi.org/10.1021/acsami.3c16568openalex-snapshot

Confinement of Oligopeptides by Terminally Functionalized Polyisoprene to Improve Their Mechanical Strength, Creep Resistance, and Antifatigue Properties

inferred← citeshttps://doi.org/10.1021/acsami.4c02431openalex-snapshot

Self-Healing Transparent Poly(dimethyl)siloxane with Tunable Mechanical Properties: Toward Enhanced Aging Materials for Space Applications

inferred← citeshttps://doi.org/10.1021/acsapm.0c00016openalex-snapshot

Catalyst-Free Partially Bio-Based Polyester Vitrimers

inferred← citeshttps://doi.org/10.1021/acsapm.0c00397openalex-snapshot

Preparation of Colorless, Highly Transparent, Epoxy-Based Vitrimers by the Thiol-Epoxy Click Reaction and Evaluation of Their Shape-Memory Properties

inferred← citeshttps://doi.org/10.1021/acsapm.0c00523openalex-snapshot

Polystyrene-Based Vitrimers: Inexpensive and Recyclable Thermosets

inferred← citeshttps://doi.org/10.1021/acsapm.0c01335openalex-snapshot

Biobased, Biodegradable, Self-Healing Boronic Ester Vitrimers from Epoxidized Soybean Oil Acrylate

inferred← citeshttps://doi.org/10.1021/acsapm.3c00874openalex-snapshot

Vitrimerization of Linear Polyurethane via Group Revival-Induced Crosslinking

inferred← citeshttps://doi.org/10.1021/acsapm.3c00914openalex-snapshot

Vitrification: Versatile Method To Modulate Properties of Myrcene-Based Rubbers

inferred← citeshttps://doi.org/10.1021/acsapm.3c01472openalex-snapshot

Probing the Solubility of Imine-Based Covalent Adaptable Networks

inferred← citeshttps://doi.org/10.1021/acsapm.3c02336openalex-snapshot

Fabrication of Recyclable Polyurethane Elastomers with Excellent Mechanical and Creep-Resistant Properties Based on a Bio-Sourced Azine Chain Extender

inferred← citeshttps://doi.org/10.1021/acsapm.3c02515openalex-snapshot

Reprocessable Biobased Statistical and Block Copolymer Methacrylic-Based Vitrimers with a Shape Memory Effect

inferred← citeshttps://doi.org/10.1021/acsapm.4c03116openalex-snapshot

Biobased Reprintable Bis-Dynamic Covalent Photopolymer Composition for Digital Light Processing 3D Printing with Self-Healing Properties

inferred← citeshttps://doi.org/10.1021/acsapm.4c04101openalex-snapshot

Boronate Esters Dynamic Networks for the Reduction of Mechanical Anisotropy in Vat 3D Printed Manufacts

inferred← citeshttps://doi.org/10.1021/acsapm.5c00606openalex-snapshot

Unexpected Effects of Alkyl Side Group Length on the Relaxation Rate in Disulfide Exchange Poly(acrylate) Networks

inferred← citeshttps://doi.org/10.1021/acsapm.5c02198openalex-snapshot

Creep-Resistant Covalent Adaptable Heterogeneous Networks

inferred← citeshttps://doi.org/10.1021/acsapm.5c02906openalex-snapshot

Multimaterial Digital Light Processing Three-Dimensional Printing of Materials with Different Relaxation Kinetics

inferred← citeshttps://doi.org/10.1021/acsapm.6c02626openalex-snapshot

Self-Healable and Microstructure-Programmable Vitrimeric Nonisocyanate Polyurethane Foams via Decoupled Fabrication

inferred← citeshttps://doi.org/10.1021/acsmacrolett.1c00257openalex-snapshot

Chemical and Mechanical Tunability of 3D-Printed Dynamic Covalent Networks Based on Boronate Esters

inferred← citeshttps://doi.org/10.1021/acsmacrolett.5c00267openalex-snapshot

Impact of Cross-Link Density on Polybutadiene Permanent and Vitrimer Networks

inferred← citeshttps://doi.org/10.1021/acsmacrolett.5c00329openalex-snapshot

Nitroarene Photoactivation Promotes Oxidative Deconstruction of Olefinic Polymers

inferred← citeshttps://doi.org/10.1021/acsmacrolett.5c00741openalex-snapshot

A Modular Route toward Macromer-Based Dynamic Gels via Prebonded Boronic Ester Cross-Links

inferred← citeshttps://doi.org/10.1021/acsmaterialsau.3c00074openalex-snapshot

Tuning the Mechanical and Dynamic Properties of Elastic Vitrimers by Tailoring the Substituents of Boronic Ester

inferred← citeshttps://doi.org/10.1021/acsmaterialslett.1c00314openalex-snapshot

A Tough and Self-Healing Polymer Enabled by Promoting Bond Exchange in Boronic Esters with Neighboring Hydroxyl Groups

inferred← citeshttps://doi.org/10.1021/acsmaterialslett.4c00076openalex-snapshot

Improving the Thermomechanical Properties and Processability of Elastomeric Vitrimers Using Thermoreversible Organic Nanofillers

inferred← citeshttps://doi.org/10.1021/acsomega.1c06416openalex-snapshot

Hydroxyl-Terminated Polybutadiene-Based Polyurethane with Self-Healing and Reprocessing Capabilities

inferred← citeshttps://doi.org/10.1021/acsomega.2c01102openalex-snapshot

Enhancement of the Mechanical Properties of Poly(lactic acid)/Epoxidized Soybean Oil Blends by the Addition of 3-Aminophenylboronic Acid

inferred← citeshttps://doi.org/10.1021/acsomega.5c06453openalex-snapshot

Elastomer-Based Vitrimers─A Review of the Preparation, Characterization, and Applications

inferred← citeshttps://doi.org/10.1021/acspolymersau.5c00004openalex-snapshot

How to Characterize Covalent Adaptable Networks: A User Guide

inferred← citeshttps://doi.org/10.1021/acssuschemeng.5c09126openalex-snapshot

Lignin-Based Acetal Networks: Safer Degradation Pathways for Acid-, Heat-, and Flame-Resistant Circular Thermosets

inferred← citeshttps://doi.org/10.1021/acssuschemeng.5c11665openalex-snapshot

Biobased Amide Bis-Benzoxazines Enable Tunable, Reprocessable Benzoxazine/Polyether Diamine Vitrimers

inferred← citeshttps://doi.org/10.1021/jacs.2c08104openalex-snapshot

Structure–Reactivity–Property Relationships in Covalent Adaptable Networks

inferred← citeshttps://doi.org/10.1021/jacs.2c11858openalex-snapshot

Remolding and Deconstruction of Industrial Thermosets via Carboxylic Acid-Catalyzed Bifunctional Silyl Ether Exchange

inferred← citeshttps://doi.org/10.1021/jacs.4c12730openalex-snapshot

Toward Sustainable Polydienes

inferred← citeshttps://doi.org/10.1021/jacs.4c14032openalex-snapshot

Precise Carboxylic Acid-Functionalized Polyesters in Reprocessable Vitrimers

inferred← citeshttps://doi.org/10.1021/jacsau.5c01642openalex-snapshot

Covalent Adaptable Networks from Commodity Polybutadiene and Rubber Waste

inferred← citeshttps://doi.org/10.1021/prechem.5c00441openalex-snapshot

Chemically Recyclable Thermoplastic Elastomers: Preparation, Properties, and On-Demand Depolymerization

inferred← citeshttps://doi.org/10.1039/9781837675470-00031openalex-snapshot

Dynamic Covalent Chemistry in Rubber Crosslinking

inferred← citeshttps://doi.org/10.1039/9781837675470-00107openalex-snapshot

Dual-crosslinked Network Design

inferred← citeshttps://doi.org/10.1039/c9py01546aopenalex-snapshot

Thermally healable and reprocessable polymethacrylate networks based on diol-mediated metathesis of 6-membered boronic esters

inferred← citeshttps://doi.org/10.1039/d0mh01142hopenalex-snapshot

Synergy between dynamic covalent boronic ester and boron–nitrogen coordination: strategy for self-healing polyurethane elastomers at room temperature with unprecedented mechanical properties

inferred← citeshttps://doi.org/10.1039/d0py00114gopenalex-snapshot

Influence of the polymer matrix on the viscoelastic behaviour of vitrimers

inferred← citeshttps://doi.org/10.1039/d0py00164copenalex-snapshot

Functionalization of polyisoprene and polystyrene via reactive processing using azidoformate grafting agents, and its application to the synthesis of dioxaborolane-based polyisoprene vitrimers

inferred← citeshttps://doi.org/10.1039/d0py00233jopenalex-snapshot

Cross-linker control of vitrimer flow

inferred← citeshttps://doi.org/10.1039/d0py00235fopenalex-snapshot

Highly elastic, strong, and reprocessable cross-linked polyolefin elastomers enabled by boronic ester bonds

inferred← citeshttps://doi.org/10.1039/d0sc01069copenalex-snapshot

Vitrimers: directing chemical reactivity to control material properties

inferred← citeshttps://doi.org/10.1039/d0sc05458eopenalex-snapshot

Molecular control over vitrimer-like mechanics – tuneable dynamic motifs based on the Hammett equation in polyimine materials

inferred← citeshttps://doi.org/10.1039/d0sm00742kopenalex-snapshot

Rates of transesterification in epoxy–thiol vitrimers

inferred← citeshttps://doi.org/10.1039/d0sm01544jopenalex-snapshot

Effect of precise linker length, bond density, and broad temperature window on the rheological properties of ethylene vitrimers

inferred← citeshttps://doi.org/10.1039/d1py00187fopenalex-snapshot

Reprocessable covalent adaptable networks with excellent elevated-temperature creep resistance: facilitation by dynamic, dissociative bis(hindered amino) disulfide bonds

inferred← citeshttps://doi.org/10.1039/d1ra06686bopenalex-snapshot

Bio-based, self-adhesive, and self-healing ionogel with excellent mechanical properties for flexible strain sensor

inferred← citeshttps://doi.org/10.1039/d2ra06829jopenalex-snapshot

Vitrimer ionogels towards sustainable solid-state electrolytes

inferred← citeshttps://doi.org/10.1039/d2sc05528gopenalex-snapshot

Characterising different molecular landscapes in dynamic covalent networks

inferred← citeshttps://doi.org/10.1039/d2tc04603bopenalex-snapshot

Reprocessable polyurethane elastomers based on reversible ketal exchange: dielectric properties and water resistance

inferred← citeshttps://doi.org/10.1039/d3lp00242jopenalex-snapshot

A direct comparison of the thermal reprocessing potential of associative and dissociative reversible bonds in thermosets

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