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Pd-Catalyzed Highly Enantioselective Synthesis of Planar Chiral Ferrocenylpyridine Derivatives

https://doi.org/10.1021/acs.organomet.5b00730

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What this work says

Outgoing claims: the papers this work cites, builds on, or argues with.

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Asymmetric Synthesis of Novel Ferrocenyl Ligands with Planar and Central Chirality

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Ferrocenes

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Metallocenes

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Chiral Ferrocenes in Asymmetric Catalysis

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Asymmetric Synthesis and Highly Diastereoselective ortho‐Lithiation of Ferrocenyl Sulfoxides. Application to the Synthesis of Ferrocenyl Derivatives with Planar Chirality

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Insertion of Carbenoids into CpH Bonds of Ferrocenes: An Enantioselective‐Catalytic Entry to Planar‐Chiral Ferrocenes

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Catalytic Enantioselective Hydrogenolysis of [Cr(CO)3(5,8‐Dibromonaphthalene)]

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PdII‐Catalyzed Enantioselective Activation of C(sp2)H and C(sp3)H Bonds Using Monoprotected Amino Acids as Chiral Ligands

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Enantioselective Palladium‐Catalyzed Direct Arylations at Ambient Temperature: Access to Indanes with Quaternary Stereocenters

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Enantioselective Palladium‐Catalyzed Direct Alkylation and Olefination Reaction of Simple Arenes

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Kinetic Resolution of Planar‐Chiral (η6‐Arene)Chromium Complexes by Molybdenum‐Catalyzed Asymmetric Ring‐Closing Metathesis

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Chiral Monodentate Phosphines and Bulky Carboxylic Acids: Cooperative Effects in Palladium‐Catalyzed Enantioselective C(sp3)–H Functionalization

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Enantioselective CH Arylation Strategy for Functionalized Dibenzazepinones with Quaternary Stereocenters

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inferredcites →https://doi.org/10.1002/chem.201000011openalex-snapshot

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Diastereo‐ and Enantioselective Intramolecular C(sp3)H Arylation for the Synthesis of Fused Cyclopentanes

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Synthesis of 3,3‐Disubstituted Oxindoles by Palladium‐Catalyzed Asymmetric Intramolecular α‐Arylation of Amides: Reaction Development and Mechanistic Studies

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Asymmetric C(sp2)H Activation

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Enantioselective Strecker Reactions between Aldimines and Trimethylsilyl Cyanide Promoted by Chiral N , N′ ‐Dioxides

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Chiral N‐Oxides in Asymmetric Catalysis

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Catalytic asymmetric induction of planar chirality: palladium catalyzed intramolecular Mizoroki–Heck reaction of prochiral (arene)chromium complexes

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Application of the Suzuki reaction to the asymmetric desymmetrisation of 1,2- and 1,3-disubstituted bulky cobalt metallocenes

inferredcites →https://doi.org/10.1016/s0040-4039(00)60069-2openalex-snapshot

Catalytic asymmetric induction of planar chirality by palladium-catalyzed asymmetric cross-coupling of a meso (arene)chromium complex

inferredcites →https://doi.org/10.1021/ar030051bopenalex-snapshot

Asymmetric Catalysis with “Planar-Chiral” Derivatives of 4-(Dimethylamino)pyridine

inferredcites →https://doi.org/10.1021/cs500813zopenalex-snapshot

Pd(II)-Catalyzed Intermolecular Direct C–H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution

inferredcites →https://doi.org/10.1021/ja003573kopenalex-snapshot

Planar-Chiral Pyridine N-Oxides, a New Family of Asymmetric Catalysts: Exploiting an η5-C5Ar5 Ligand to Achieve High Enantioselectivity1

inferredcites →https://doi.org/10.1021/ja00783a030openalex-snapshot

Stereoselective synthesis. VIII. Absolute configuration of a 1,2-disubstituted ferrocene derivative with planar and central elements of chirality and the mechanism of the optically active .alpha.-ferrocenyl tertiary amines

inferredcites →https://doi.org/10.1021/ja025670eopenalex-snapshot

Catalytic, Enantioselective Aldol Additions to Ketones

inferredcites →https://doi.org/10.1021/ja302278sopenalex-snapshot

Palladium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles via Enantioselective C–H Bond Functionalization

inferredcites →https://doi.org/10.1021/ja311082uopenalex-snapshot

Enantioselective Synthesis of Planar Chiral Ferrocenes via Palladium-Catalyzed Direct Coupling with Arylboronic Acids

inferredcites →https://doi.org/10.1021/ja500444vopenalex-snapshot

Enantioselective Synthesis of Planar Chiral Ferrocenes via Pd(0)-Catalyzed Intramolecular Direct C–H Bond Arylation

inferredcites →https://doi.org/10.1021/ja500699xopenalex-snapshot

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inferredcites →https://doi.org/10.1021/ja910348zopenalex-snapshot

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inferredcites →https://doi.org/10.1021/ja981091ropenalex-snapshot

(S)-3,3‘-Dimethyl-2,2‘-biquinoline N,N‘-Dioxide as an Efficient Catalyst for Enantioselective Addition of Allyltrichlorosilanes to Aldehydes

inferredcites →https://doi.org/10.1021/jo400159yopenalex-snapshot

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inferredcites →https://doi.org/10.1021/ol0159468openalex-snapshot

A Catalytic-Enantioselective Entry to Planar Chiral π-Complexes: Enantioselective Methoxycarbonylation of 1,2-Dichlorobenzene−Cr(CO)3

inferredcites →https://doi.org/10.1021/ol502509fopenalex-snapshot

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inferredcites →https://doi.org/10.1021/ol502520bopenalex-snapshot

Asymmetric Synthesis of Planar Chiral Ferrocenes by Enantioselective Intramolecular C–H Arylation of N -(2-Haloaryl)ferrocenecarboxamides

inferredcites →https://doi.org/10.1021/om010679vopenalex-snapshot

The First Planar-Chiral Stable Carbene and Its Metal Complexes

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Kinetic Resolution of Planar-Chiral Ferrocenes by Molybdenum-Catalyzed Enantioselective Metathesis

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Functionalization of Planar Chiral Fused Arene Ruthenium Complexes: Synthesis, X-ray Structures, and Spectroscopic Characterization of Monodentate Triarylphosphines

inferredcites →https://doi.org/10.1021/om400564xopenalex-snapshot

Selective Syntheses of Planar-Chiral Ferrocenes

inferredcites →https://doi.org/10.1021/om400845topenalex-snapshot

Highly Enantiomerically Enriched Planar Chiral Cyclopentadienyl(indenyl)ruthenium Complexes

inferredcites →https://doi.org/10.1021/om9005356openalex-snapshot

Synthesis of Planar Chiral Phosphapalladacycles by N-Acyl Amino Acid Mediated Enantioselective Palladation

inferredcites →https://doi.org/10.1021/om991041aopenalex-snapshot

Diastereoselective Synthesis of Ferrocenyl Sulfoximines with Planar and Central Chirality

inferredcites →https://doi.org/10.1039/b816707aopenalex-snapshot

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

inferredcites →https://doi.org/10.1039/b910977copenalex-snapshot

Synthesis of highly enantiomerically enriched planar chiral ruthenium complexes via Pd-catalysed asymmetric hydrogenolysis

inferredcites →https://doi.org/10.1039/c1cc10347dopenalex-snapshot

Highly efficient desymmetrisation of a tricarbonylchromium 1,4-dibromonaphthalene complex by asymmetric Suzuki–Miyaura coupling

inferredcites →https://doi.org/10.1039/c1cc14292eopenalex-snapshot

Enantioselective synthesis of 2-methyl indolines by palladium catalysed asymmetric C(sp3)–H activation/cyclisation

inferredcites →https://doi.org/10.1039/c2cc16864bopenalex-snapshot

Synthesis of a [2.2]paracyclophane based planar chiral palladacycle by a highly selective kinetic resolution/C–H activation reaction

inferredcites →https://doi.org/10.1039/c2sc20111aopenalex-snapshot

Asymmetric C(sp3)-H/C(Ar) coupling reactions. Highly enantio-enriched indolines via regiodivergent reaction of a racemic mixture

inferredcites →https://doi.org/10.1039/c3ra46996dopenalex-snapshot

Recent development of direct asymmetric functionalization of inert C–H bonds

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Scope and mechanism of asymmetric C(sp3)–H/C(Ar)–X coupling reactions: computational and experimental study

inferredcites →https://doi.org/10.1039/c3sc50577dopenalex-snapshot

Redox of ferrocene controlled asymmetric dehydrogenative Heck reaction via palladium-catalyzed dual C–H bond activation

inferredcites →https://doi.org/10.1039/c4ra07832bopenalex-snapshot

Palladium-catalyzed intramolecular Cp–H bond functionalization/arylation: an enantioselective approach to planar chiral quinilinoferrocenes

inferredcites →https://doi.org/10.1055/s-0029-1216818openalex-snapshot

Transition-Metal-Catalyzed Enantioselective Synthesis of Compounds with Non-Centrochirality

inferredcites →https://doi.org/10.1055/s-1995-4864openalex-snapshot

Synthesis of 2-[2-(Diphenylphosphino)ferrocenyl]oxazoline Ligands

inferredcites →https://doi.org/10.1055/s-2003-41417openalex-snapshot

Catalytic-Enantioselective Methoxycarbonylation of 1,3-Dichloroarenetricarbonyl-chromium(0) Complexes: A Desymmetrization Approach to Planar Chirality

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Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

inferredcites →https://doi.org/10.3390/molecules14114747openalex-snapshot

Kinetic Resolution: A Powerful Tool for the Synthesis of Planar-Chiral Ferrocenes

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Rh(III)-catalyzed directed C–H bond amidation of ferrocenes with isocyanates

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Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes

What points at this work

Incoming claims: where this work appears in other papers’ reference lists and arguments.

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Catalytic, Enantioselective, CH Functionalization to Form Carbon–Carbon Bonds

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Enantioselective Epoxide Opening

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ASYMMETRIC SYNTHESIS OF PLANAR CHIRAL AND HELICALLY CHIRAL COMPOUNDS

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High‐Turnover Palladium Catalysts

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Planar Chirality via C(sp 2 )–H Activation Involved in Stereodiscriminant Step

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Palladium‐Catalyzed Asymmetric C(sp2)H Functionalization

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Asymmetric CH Functionalization of Ferrocene

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Transition Metal‐Catalyzed Desymmetrizations Based on CH Activation Processes

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A Family of Chiral Ferrocenyl Diols: Modular Synthesis, Solid‐State Characterization, and Application in Asymmetric Organocatalysis

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Steigerung der Katalysatoreffizienz in der C‐H‐Aktivierungskatalyse

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Enantioselective Twofold C−H Annulation of Formamides and Alkynes without Built‐in Chelating Groups

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A Family of Chiral Ferrocenyl Diols: Modular Synthesis, Solid‐State Characterization, and Application in Asymmetric Organocatalysis

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Increasing Catalyst Efficiency in C−H Activation Catalysis

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Enantioselective Twofold C−H Annulation of Formamides and Alkynes without Built‐in Chelating Groups

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Synthesis of Planar Chiral Ferrocenes by Catalytic Desymmetrization Reactions

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Copper-Mediated Diastereoselective C–H Thiolation of Ferrocenes

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Enantioselective Synthesis of Planar Chiral Pyridoferrocenes via Palladium-Catalyzed Imidoylative Cyclization Reactions

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Amide-Directed Cobalt(III)-Catalyzed C–H Amidation of Ferrocenes

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Transition Metal Catalyzed Enantioselective C(sp 2 )–H Bond Functionalization

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Development of a Tunable Chiral Pyridine Ligand Unit for Enantioselective Iridium-Catalyzed C–H Borylation

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Rhodium(III)-Catalyzed Enantioselective C–H Activation/Annulation of Ferrocenecarboxamides with Internal Alkynes

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Binaphthyl Scaffold: A Class of Versatile Structure in Asymmetric C–H Functionalization

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Kinetic Resolution of Planar-Chiral Ferrocenylphosphine Derivatives by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis and Their Application in Asymmetric Catalysis

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Palladium-Catalyzed Enantioselective C(sp2)–H Imidoylation by Desymmetrization

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Catalytic Asymmetric C–H Arylation of (η6-Arene)Chromium Complexes: Facile Access to Planar-Chiral Phosphines

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An Enantioselective Oxidative C–H/C–H Cross-Coupling Reaction: Highly Efficient Method To Prepare Planar Chiral Ferrocenes

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Enantioselective C–H Functionalization–Addition Sequence Delivers Densely Substituted 3-Azabicyclo[3.1.0]hexanes

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Enantioselective Assembly of Ferrocenes with Axial and Planar Chiralities via Palladium/Chiral Norbornene Cooperative Catalysis

inferred← citeshttps://doi.org/10.1039/c6cc02624aopenalex-snapshot

Mild access to planar-chiral ortho-condensed aromatic ferrocenes via gold( i )-catalyzed cycloisomerization of ortho-alkynylaryl ferrocenes

inferred← citeshttps://doi.org/10.1039/c6ra11370bopenalex-snapshot

Functionalization of pyridyl ketones using deprotolithiation-in situ zincation

inferred← citeshttps://doi.org/10.1039/c9cc06529fopenalex-snapshot

Synthesis of planar chiral ferrocenes via a Pd(0)-catalyzed syn -carbopalladation/asymmetric C–H alkenylation process

inferred← citeshttps://doi.org/10.1039/d2cc06492hopenalex-snapshot

Design and synthesis of a new family of planar and central chiral ferrocenyl phosphine ligands

inferred← citeshttps://doi.org/10.1039/d4dt03063jopenalex-snapshot

Pd-catalysed C–H bond functionalisation route to 1,2-dihydroferroceno[ c ]isoquinoline and its annellated derivatives and the reactivity of these compounds

inferred← citeshttps://doi.org/10.1039/d4qo01409jopenalex-snapshot

Enantioselective construction of planar, axially and central chiral ferrocenyl phosphines via a Pd-catalyzed domino reaction and diastereoselective phosphination

inferred← citeshttps://doi.org/10.1039/d4sc00621fopenalex-snapshot

Access to chiral dihydrophenanthridines via a palladium(0)-catalyzed Suzuki coupling and C–H arylation cascade reaction using new chiral-bridged biphenyl bifunctional ligands

inferred← citeshttps://doi.org/10.1039/d5ob01301aopenalex-snapshot

Construction of planar chiral ferrocene diketone derivatives via a cascade Pd-catalyzed asymmetric C–H arylation/α-arylation reaction

inferred← citeshttps://doi.org/10.1039/d5sc00158gopenalex-snapshot

Asymmetric synthesis of metallocenes with planar and central chirality by rhodium-catalyzed desymmetrization reactions

inferred← citeshttps://doi.org/10.1055/a-2685-9280openalex-snapshot

Ferrocene-Templated Synthesis of Fused Aminofulvenes: Elaboration of Chalaniline A and a Reversed Regioisomer via a Ferroceno[b]chromone

inferred← citeshttps://doi.org/10.1126/science.aao4798openalex-snapshot

Enantioselective C(sp 3 )‒H bond activation by chiral transition metal catalysts

inferred← citeshttps://doi.org/10.1246/bcsj.20170415openalex-snapshot

Synthesis of Ferrocene-Fused Pyrans through Alkynoxy-Directed C–H Activation/Cyclization

inferred← citeshttps://doi.org/10.1360/ssc-2020-0192openalex-snapshot

Chiral ligands for palladium-catalyzed asymmetric C–H activation

inferred← citeshttps://doi.org/10.5802/crchim.429openalex-snapshot

From deprotometalation of ferrocenyl ketones to fused ferrocene structures

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