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Ruthenium-Catalyzed Tandem Carbene/Alkyne Metathesis/N–H Insertion: Synthesis of Benzofused Six-Membered Azaheterocycles

https://doi.org/10.1021/acs.orglett.0c00596

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What this work says

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Cyclization by Catalytic Ruthenium Carbene Insertion into CH Bonds

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Tetrazole and ester substituted tetrahydoquinoxalines as potent cholesteryl ester transfer protein inhibitors

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Carbene cascades for the formation of bridged polycyclic rings

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Metal carbene N–H insertion of chiral α,α′-dialkyl α-diazoketones. A novel and concise method for the stereocontrolled synthesis of fully substituted azetidines

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The rich reactivity of transition metal carbenes with alkynes

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Rhodium(II) mediated cyclizations of diazo alkynyl ketones

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Rhodium(II) mediated cyclizations of diazo alkynyl ketones

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Selective C(sp3)–H Bond Insertion in Carbene/Alkyne Metathesis Reactions. Enantioselective Construction of Dihydroindoles

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Selective Vinylogous Reactivity of Carbene Intermediate in Gold-Catalyzed Alkyne Carbocyclization: Synthesis of Indenols

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Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

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